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International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248-
9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013)
37
EFFECT OF FUEL INJECTION TIMING ON PERFORMANCE,
COMBUSTION AND EMISSION CHARACTERISTICS OF C.I.
ENGINE FUELLED WITH PALM OIL METHYL ESTER
SANJAY PATIL
Associate Professor in Department of Automobile Engineering,
Guru Nanak Dev Engineering College, Bidar
ABSTRACT
This paper presents the parametric study on effect of variation of fuel injection timing on
performance, combustion and emission characteristics of compression ignition engine fuelled
with palm oil methyl ester. During this work, a computer simulation model is used for
analysis. The simulation model uses double wiebe’s function to compute rate of heat release
during premixed as well as diffusive phase of combustion. Effect of advancement and
retardation of fuel injection timing by 2 degree crank angle from preset injection timing of
23°btdc on brake thermal efficiency, brake specific fuel consumption, peak cylinder pressure,
NOx emissions and soot density, etc. are predicted and discussed. Variation of fuel injection
timing from 23°btdc to 21°btdc and 25°btdc resulted in inferior engine performance,
combustion and emission characteristics.
KEY WORDS: Biodiesel, fuel injection timing, simulation, compression ignition engine.
1. INTRODUCTION
The demand for diesel in India during 2006-07 was 52.32 MTs, 66.91MTs during 2011-
12 and the projected demand for diesel is 83.58 MTs during 2016-17[1]. India is highly
dependent on import of crude oil and has been steadily rising over the years. The
transportation sector accounts for almost 50% of the total crude oil consumed [1]. Extensive
consumption of the diesel has resulted in continuous increase in its cost, heavy financial
burden on economy and increase in air pollution. The Ministry of New & Renewable Energy,
GOI made a National Policy on Biofuels for promoting the cultivation, production and use of
biofuels in petrol and diesel engine as an alternative for fossil fuels [2]. Use of bio fuels (such
as biodiesel) as an alternative to diesel could reduce the dependency on petroleum products
and the pollution level, as it is renewable and can be derived from plant species.
IJMERD
© PRJ PUBLICATION
International Journal of Mechanical Engineering Research
And Development (IJMERD), ISSN 2248 – 9347(Print)
ISSN 2248 – 9355(Online), Volume 3, Number 1
Jan - March (2013), pp.37- 42
© PRJ Publication, http://www.prjpublication.com/IJMERD.asp
International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248-
9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013)
38
The engine performance depends on several factors like fuel properties, the combustion
chamber geometry and the injection parameters like injector opening pressure (IOP), fuel
injection timing (FIT), etc. Variation of FIT results in variation in air temperature and
pressure at the time of fuel injection, the delay period, rate of evaporation of fuel, rate of
combustion etc., affecting engine performance, combustion and emission characteristics.
K Muralidharan and P Govindrajan, [3] investigated the effect of injection timing on
performance and emissions characteristics of a single cylinder direct injection diesel engine
fuelled with pongamia pinnata methyl ester and its blend with diesel from 0% to 30% with
increment of 5% ester in diesel at varying loads. The tests were conducted at three different
injection timings (19°, 23° and 27° btdc). The experimental work reveled that at advanced
timing of 27° btdc the engine performance was better than standard timing of 23° btdc with
significant reduction in emissions of HC and CO at all loading conditions. Retardation of
injection timing indicated improvement over NOx and CO2 emissions for blend B10 over
entire range of engine operation. Nwafor. O.M.I [4] investigated effect of variation in
injection timing on performance of natural gas fuelled diesel engine. He observed that
advanced timing resulted in slight increase in brake specific fuel consumption (BSFC) as
compared to standard injection timing of 30° btdc. Advancement of injection timing by 3.5°
crank angle resulted in significant reduction in carbon monoxide and carbon dioxide
emissions as compared to standard timing. A.S. Ramadhas [5] developed a theoretical zero-
dimensional model having single wiebe function with assumed adjustable parameters to
predict the performance of engine fuelled with rubber seed oil.
As the experimental investigation for estimation of engine performance is costly and
timing consuming, a simulation model may be used as a tool for speedy at low cost analysis.
Hence a computer simulation model is used for analysis of effect of change in FIT on
performance, combustion and emission characteristics of diesel engine fuelled with palm oil
methyl ester (POME). During this work, FIT is changed from 21° btdc to 25° btdc in the step
of 2° CA.
2. SIMULATION
In present analysis, a simulation model based on first law of thermodynamics developed
by author of this paper in his previous work [6] is used. Suitable correlations are established
between adjustable parameters of double wiebe’s function, relative air-fuel ratio, IOP, FIT
and engine operating conditions, so that the simulated cylinder pressure matches closely with
the experimental results. Double wiebe function is used for predicting the rate of heat release
during premixed and diffusion phase of combustion separately [7]. The molecular formulae
for diesel and POME are approximated to C10H22 for and C19H34O2 respectively. This model
simulates the compression and expansion process with ideal gas equation and polytropic
process. An ignition delay is computed using an empirical formula developed by Hardenberg
and Hase[8]. The heat transfer is calculated based on Hohenberg’s equation [9]. NOx
formation has been predicted using zeldovich mechanism explained by Turns [10]. The
model predicts peak cylinder pressure, combustion temperature, brake thermal efficiency,
brake specific fuel consumption, exhaust gas temperature and emissions like nitric oxide and
soot density for neat POME (P100). Basic engine geometry and fuel properties used for
present analysis are indicated in table 1 and 2 respectively.
International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248-
9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013)
39
Table No.1 Table.No.2
3. RESULTS AND DISCUSSION
3.1 Effect of Injection Timing on
(i) Performance parameters.
Figure: 1 Variation of brake thermal efficiency at Figure: 2. Variation of brake specific fuel consumption
Different fuel injection timing at different fuel injection timing
0
5
10
15
20
25
30
0 25 50 75 100
BrakeThermalEfficiency(%)
Load (%)
P100 at 21° btdc
P100 at 23° btdc
P100 at 25° btdc
0.30
0.35
0.40
0.45
0.50
0.55
0 25 50 75 100
BrakeSpecificFuel
Consumption(kg/kW-hr)
Load (%)
P100 at 21° btdc
P100 at 23° btdc
P100 at 25° btdc
Parameter Specification
Type
Four stroke direct
injection
single cylinder VCR diesel
engine
Software used Engine soft
Injector opening
pressure
200 bar
Rated power 3.5 kW @1500 rpm
Cylinder diameter 87.5 mm
Stroke 110 mm
Compression ratio 17.5:1
Injection timing 23 degree before TDC
Properties
Diesel
(D0)
POME
(P100)
Viscosity
in cst(at 30°C)
4.25 4.7
Flash point(°C) 79 170
Fire point(°C) 85 200
Carbon residue (%) 0.1 0.62
Calorific value(kj/kg) 42000 36000
Specific gravity
(at 25°C)
0.830 0.870
International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248-
9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013)
40
Figure: 3 Variation of exhaust gas temperature at
Different fuel injection timing
Figure 1, 2 and 3 shows variation of brake thermal efficiency, brake specific fuel
consumption and exhaust gas temperature at various fuel injection timings. Reduction in
brake thermal efficiency (BTE) is observed at 21°btdc and 25° btdc injection timings as
compared to standard injection timing of 23° btdc. However, reduction in BTE is lower with
retarded timing. Similar trend has been observed with BSFC. The Exhaust gas temperature
(EGT) is increased with retarded timing due to late start of combustion and more heat release
during diffusion phase of combustion. Advancement of FIT resulted in lower EGT due to
earlier start of combustion and earlier occurrence of point of peak pressure and peak rate of
heat release, etc.
(ii) Combustion Parameters
Figure: 4 Variation of peak pressure at different Figure: 5 Variation of heat release rate at different
Fuel injection timing Fuel injection timing
Figure 4 and 5 shows variation of peak pressure and net rate of heat release with change
in fuel injection timing. Advancement in FIT shows increase in peak pressure due to longer
ignition delay period; earlier start of injection of fuel and injection of more quantity fuel
180
230
280
330
380
430
0 25 50 75 100
ExhaustGasTemeprature(°c)
Load (%)
P100 at 21° btdc
P100 at 23° btdc
P100 at 25° btdc
50
52
54
56
58
60
62
64
66
68
0 25 50 75 100
PeakPressure(bar)
Load (%)
P100 at 21° btdc
P100 at 23° btdc
P100 at 25° btdc
-0.01
0
0.01
0.02
0.03
0.04
0.05
0.06
157 207
NetHeatReleaseRate(kJ/CA)
Crank Angle (CA)
P100 at 23° btdc
P100 at 21° btdc
P100 at 25° btdc
International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248-
9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013)
41
during delay period, etc. increase in maximum rate of net heat release and shifting of point of
peak heat release rate earlier during compression is also observed with advanced injection
timing. Retardation of FIT from rated value resulted in lower peak pressure and net rate of
heat release. Also, with retarded injection timing, occurrence of peak heat release rate
observed to be late in the cycle. This may be due to combined effect of late injection and
shorter delay period, etc.
(iii) Emission Parameters
Figure: 6 Variation of oxides of nitrogen at different Figure: 7 Variation of soot density at different
Fuel injection timing fuel injection timing
Figure 7 and 8 shows variation of nitric oxide and soot density at various fuel injection
timings. The advancement in injection timing shows reduction in soot density due to
availability of sufficient time for combustion. Whereas, retardation of injection timing shows
increase in soot density due to incomplete combustion of fuel, slow and late combustion and
reduction in highest local peak temperature, etc. The nitric oxide emissions are higher with
advanced timing and lower with retarded timing as compared to rated FIT.
4. CONCLUSION
From the results of computer simulation model and experimental results following conclusion
are drawn.
• Advancement and retardation of FIT resulted in lower BTE and higher BSFC.
• Reduction in EGT at advanced FIT of 25° btdc and increase in EGT at 21° btdc is
observed.
• Advanced injection timing resulted in higher peak pressure and net rate of heat
release.
• The simulation results are found to be in closer approximation with experimental
results.
0
200
400
600
800
1000
1200
1400
1600
1800
0 25 50 75 100
OxidesofNitrogen(ppm)
Load (%)
P100 at 21° btdc
P100 at 23° btdc
P100 at 25° btdc
0.00E+00
1.00E-07
2.00E-07
3.00E-07
4.00E-07
5.00E-07
6.00E-07
7.00E-07
0 25 50 75 100
Soot(gm/m^3)
Load (%)
P100 at 21° btdc
P100 at 23° btdc
P100 at 25° btdc
International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248-
9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013)
42
ACKNOWLEDGEMENT
I would like to express my gratitude to my Guide Dr. M. M. Akarte, National Institute
of Industrial Engineering Mumbai- India for his valuable advice and guidance throughout this
work.
REFERENCES
[1] Energy Statistics (2012), Central Statistics Office National Statistical Organization
Ministry of Statistics and Programme Implementation, Government of India.
www.mospi.gov.in.
[2] National Policy on Biofuels Ministry of New & Renewable Energy, Government of
India.
[3] K.Murlidharan and P.Govindrajan. (2011), “Influence of injection timing on the
Performance and Emission Characteristics of DI Engine using Pongamia Pinnata
Mehtyl Ester”, European Journal of Scientific Research, Vol. 59.No 3. pp 417-431.
[4] O.M.I. Nwafor (2007), “Effect of advanced injection timing on emission
characteristics of diesel engine running on natural gas”. Renewable Energy 32, pp.
2361-2368.
[5] A.S. Ramadhas, S. Jayaraj, C. Muraleedharan (2006), “Theoretical modeling and
experimental studies on biodiesel-fueled engine”, Renewable Energy 31, pp. 1813–
1826.
[6] Sanjay Patil (2013), “Thermodynamic Modeling for Performance Analysis of
Compression Ignition Engine Fuelled with Biodiesel and its Blends with Diesel”
International Journal of Recent Technology and Engineering, Volume-1, Issue-6,
pp.134-138
[7] Colin R. Ferguson and Allan T.Kirkpatrick, Internal Combustion Engines Applied
Thermo sciences, second edition, John Wiley & Sons, Inc.
[8] J.B. Heywood (1988), “Internal Combustion Engines Fundamentals”, Mc Graw Hill,
ISBN 0-07-100499-8.
[9] Ganesan, V (2000), Computer simulation of Compression-Ignition engine processes,
University Press (India) Ltd., Hyderabad, India.
[10] S.R.Turns (2000), “An introduction to combustion-concepts and applications”,
McGraw Hill Series in Mechanical Engineering.

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Effect of fuel injection timing

  • 1. International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248- 9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013) 37 EFFECT OF FUEL INJECTION TIMING ON PERFORMANCE, COMBUSTION AND EMISSION CHARACTERISTICS OF C.I. ENGINE FUELLED WITH PALM OIL METHYL ESTER SANJAY PATIL Associate Professor in Department of Automobile Engineering, Guru Nanak Dev Engineering College, Bidar ABSTRACT This paper presents the parametric study on effect of variation of fuel injection timing on performance, combustion and emission characteristics of compression ignition engine fuelled with palm oil methyl ester. During this work, a computer simulation model is used for analysis. The simulation model uses double wiebe’s function to compute rate of heat release during premixed as well as diffusive phase of combustion. Effect of advancement and retardation of fuel injection timing by 2 degree crank angle from preset injection timing of 23°btdc on brake thermal efficiency, brake specific fuel consumption, peak cylinder pressure, NOx emissions and soot density, etc. are predicted and discussed. Variation of fuel injection timing from 23°btdc to 21°btdc and 25°btdc resulted in inferior engine performance, combustion and emission characteristics. KEY WORDS: Biodiesel, fuel injection timing, simulation, compression ignition engine. 1. INTRODUCTION The demand for diesel in India during 2006-07 was 52.32 MTs, 66.91MTs during 2011- 12 and the projected demand for diesel is 83.58 MTs during 2016-17[1]. India is highly dependent on import of crude oil and has been steadily rising over the years. The transportation sector accounts for almost 50% of the total crude oil consumed [1]. Extensive consumption of the diesel has resulted in continuous increase in its cost, heavy financial burden on economy and increase in air pollution. The Ministry of New & Renewable Energy, GOI made a National Policy on Biofuels for promoting the cultivation, production and use of biofuels in petrol and diesel engine as an alternative for fossil fuels [2]. Use of bio fuels (such as biodiesel) as an alternative to diesel could reduce the dependency on petroleum products and the pollution level, as it is renewable and can be derived from plant species. IJMERD © PRJ PUBLICATION International Journal of Mechanical Engineering Research And Development (IJMERD), ISSN 2248 – 9347(Print) ISSN 2248 – 9355(Online), Volume 3, Number 1 Jan - March (2013), pp.37- 42 © PRJ Publication, http://www.prjpublication.com/IJMERD.asp
  • 2. International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248- 9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013) 38 The engine performance depends on several factors like fuel properties, the combustion chamber geometry and the injection parameters like injector opening pressure (IOP), fuel injection timing (FIT), etc. Variation of FIT results in variation in air temperature and pressure at the time of fuel injection, the delay period, rate of evaporation of fuel, rate of combustion etc., affecting engine performance, combustion and emission characteristics. K Muralidharan and P Govindrajan, [3] investigated the effect of injection timing on performance and emissions characteristics of a single cylinder direct injection diesel engine fuelled with pongamia pinnata methyl ester and its blend with diesel from 0% to 30% with increment of 5% ester in diesel at varying loads. The tests were conducted at three different injection timings (19°, 23° and 27° btdc). The experimental work reveled that at advanced timing of 27° btdc the engine performance was better than standard timing of 23° btdc with significant reduction in emissions of HC and CO at all loading conditions. Retardation of injection timing indicated improvement over NOx and CO2 emissions for blend B10 over entire range of engine operation. Nwafor. O.M.I [4] investigated effect of variation in injection timing on performance of natural gas fuelled diesel engine. He observed that advanced timing resulted in slight increase in brake specific fuel consumption (BSFC) as compared to standard injection timing of 30° btdc. Advancement of injection timing by 3.5° crank angle resulted in significant reduction in carbon monoxide and carbon dioxide emissions as compared to standard timing. A.S. Ramadhas [5] developed a theoretical zero- dimensional model having single wiebe function with assumed adjustable parameters to predict the performance of engine fuelled with rubber seed oil. As the experimental investigation for estimation of engine performance is costly and timing consuming, a simulation model may be used as a tool for speedy at low cost analysis. Hence a computer simulation model is used for analysis of effect of change in FIT on performance, combustion and emission characteristics of diesel engine fuelled with palm oil methyl ester (POME). During this work, FIT is changed from 21° btdc to 25° btdc in the step of 2° CA. 2. SIMULATION In present analysis, a simulation model based on first law of thermodynamics developed by author of this paper in his previous work [6] is used. Suitable correlations are established between adjustable parameters of double wiebe’s function, relative air-fuel ratio, IOP, FIT and engine operating conditions, so that the simulated cylinder pressure matches closely with the experimental results. Double wiebe function is used for predicting the rate of heat release during premixed and diffusion phase of combustion separately [7]. The molecular formulae for diesel and POME are approximated to C10H22 for and C19H34O2 respectively. This model simulates the compression and expansion process with ideal gas equation and polytropic process. An ignition delay is computed using an empirical formula developed by Hardenberg and Hase[8]. The heat transfer is calculated based on Hohenberg’s equation [9]. NOx formation has been predicted using zeldovich mechanism explained by Turns [10]. The model predicts peak cylinder pressure, combustion temperature, brake thermal efficiency, brake specific fuel consumption, exhaust gas temperature and emissions like nitric oxide and soot density for neat POME (P100). Basic engine geometry and fuel properties used for present analysis are indicated in table 1 and 2 respectively.
  • 3. International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248- 9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013) 39 Table No.1 Table.No.2 3. RESULTS AND DISCUSSION 3.1 Effect of Injection Timing on (i) Performance parameters. Figure: 1 Variation of brake thermal efficiency at Figure: 2. Variation of brake specific fuel consumption Different fuel injection timing at different fuel injection timing 0 5 10 15 20 25 30 0 25 50 75 100 BrakeThermalEfficiency(%) Load (%) P100 at 21° btdc P100 at 23° btdc P100 at 25° btdc 0.30 0.35 0.40 0.45 0.50 0.55 0 25 50 75 100 BrakeSpecificFuel Consumption(kg/kW-hr) Load (%) P100 at 21° btdc P100 at 23° btdc P100 at 25° btdc Parameter Specification Type Four stroke direct injection single cylinder VCR diesel engine Software used Engine soft Injector opening pressure 200 bar Rated power 3.5 kW @1500 rpm Cylinder diameter 87.5 mm Stroke 110 mm Compression ratio 17.5:1 Injection timing 23 degree before TDC Properties Diesel (D0) POME (P100) Viscosity in cst(at 30°C) 4.25 4.7 Flash point(°C) 79 170 Fire point(°C) 85 200 Carbon residue (%) 0.1 0.62 Calorific value(kj/kg) 42000 36000 Specific gravity (at 25°C) 0.830 0.870
  • 4. International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248- 9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013) 40 Figure: 3 Variation of exhaust gas temperature at Different fuel injection timing Figure 1, 2 and 3 shows variation of brake thermal efficiency, brake specific fuel consumption and exhaust gas temperature at various fuel injection timings. Reduction in brake thermal efficiency (BTE) is observed at 21°btdc and 25° btdc injection timings as compared to standard injection timing of 23° btdc. However, reduction in BTE is lower with retarded timing. Similar trend has been observed with BSFC. The Exhaust gas temperature (EGT) is increased with retarded timing due to late start of combustion and more heat release during diffusion phase of combustion. Advancement of FIT resulted in lower EGT due to earlier start of combustion and earlier occurrence of point of peak pressure and peak rate of heat release, etc. (ii) Combustion Parameters Figure: 4 Variation of peak pressure at different Figure: 5 Variation of heat release rate at different Fuel injection timing Fuel injection timing Figure 4 and 5 shows variation of peak pressure and net rate of heat release with change in fuel injection timing. Advancement in FIT shows increase in peak pressure due to longer ignition delay period; earlier start of injection of fuel and injection of more quantity fuel 180 230 280 330 380 430 0 25 50 75 100 ExhaustGasTemeprature(°c) Load (%) P100 at 21° btdc P100 at 23° btdc P100 at 25° btdc 50 52 54 56 58 60 62 64 66 68 0 25 50 75 100 PeakPressure(bar) Load (%) P100 at 21° btdc P100 at 23° btdc P100 at 25° btdc -0.01 0 0.01 0.02 0.03 0.04 0.05 0.06 157 207 NetHeatReleaseRate(kJ/CA) Crank Angle (CA) P100 at 23° btdc P100 at 21° btdc P100 at 25° btdc
  • 5. International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248- 9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013) 41 during delay period, etc. increase in maximum rate of net heat release and shifting of point of peak heat release rate earlier during compression is also observed with advanced injection timing. Retardation of FIT from rated value resulted in lower peak pressure and net rate of heat release. Also, with retarded injection timing, occurrence of peak heat release rate observed to be late in the cycle. This may be due to combined effect of late injection and shorter delay period, etc. (iii) Emission Parameters Figure: 6 Variation of oxides of nitrogen at different Figure: 7 Variation of soot density at different Fuel injection timing fuel injection timing Figure 7 and 8 shows variation of nitric oxide and soot density at various fuel injection timings. The advancement in injection timing shows reduction in soot density due to availability of sufficient time for combustion. Whereas, retardation of injection timing shows increase in soot density due to incomplete combustion of fuel, slow and late combustion and reduction in highest local peak temperature, etc. The nitric oxide emissions are higher with advanced timing and lower with retarded timing as compared to rated FIT. 4. CONCLUSION From the results of computer simulation model and experimental results following conclusion are drawn. • Advancement and retardation of FIT resulted in lower BTE and higher BSFC. • Reduction in EGT at advanced FIT of 25° btdc and increase in EGT at 21° btdc is observed. • Advanced injection timing resulted in higher peak pressure and net rate of heat release. • The simulation results are found to be in closer approximation with experimental results. 0 200 400 600 800 1000 1200 1400 1600 1800 0 25 50 75 100 OxidesofNitrogen(ppm) Load (%) P100 at 21° btdc P100 at 23° btdc P100 at 25° btdc 0.00E+00 1.00E-07 2.00E-07 3.00E-07 4.00E-07 5.00E-07 6.00E-07 7.00E-07 0 25 50 75 100 Soot(gm/m^3) Load (%) P100 at 21° btdc P100 at 23° btdc P100 at 25° btdc
  • 6. International Journal of Mechanical Engineering Research and Development (IJMERD) ISSN 2248- 9347 (Print), ISSN 2248-9355 (Online) Volume 3, Number 1, Jan-March (2013) 42 ACKNOWLEDGEMENT I would like to express my gratitude to my Guide Dr. M. M. Akarte, National Institute of Industrial Engineering Mumbai- India for his valuable advice and guidance throughout this work. REFERENCES [1] Energy Statistics (2012), Central Statistics Office National Statistical Organization Ministry of Statistics and Programme Implementation, Government of India. www.mospi.gov.in. [2] National Policy on Biofuels Ministry of New & Renewable Energy, Government of India. [3] K.Murlidharan and P.Govindrajan. (2011), “Influence of injection timing on the Performance and Emission Characteristics of DI Engine using Pongamia Pinnata Mehtyl Ester”, European Journal of Scientific Research, Vol. 59.No 3. pp 417-431. [4] O.M.I. Nwafor (2007), “Effect of advanced injection timing on emission characteristics of diesel engine running on natural gas”. Renewable Energy 32, pp. 2361-2368. [5] A.S. Ramadhas, S. Jayaraj, C. Muraleedharan (2006), “Theoretical modeling and experimental studies on biodiesel-fueled engine”, Renewable Energy 31, pp. 1813– 1826. [6] Sanjay Patil (2013), “Thermodynamic Modeling for Performance Analysis of Compression Ignition Engine Fuelled with Biodiesel and its Blends with Diesel” International Journal of Recent Technology and Engineering, Volume-1, Issue-6, pp.134-138 [7] Colin R. Ferguson and Allan T.Kirkpatrick, Internal Combustion Engines Applied Thermo sciences, second edition, John Wiley & Sons, Inc. [8] J.B. Heywood (1988), “Internal Combustion Engines Fundamentals”, Mc Graw Hill, ISBN 0-07-100499-8. [9] Ganesan, V (2000), Computer simulation of Compression-Ignition engine processes, University Press (India) Ltd., Hyderabad, India. [10] S.R.Turns (2000), “An introduction to combustion-concepts and applications”, McGraw Hill Series in Mechanical Engineering.