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Crude Oil
Key words
Crude oil
Compound
Mixture
Distillation
Hydrocarbons
Saturated
Alkanes
Covalent bond
Evaporating
Condense
Fractional distillation
Fractionating column
Particulates
Combustion
Soot
Biofuels
How crude oil was formed
• Microscopic plants and animals die and fall to the sea bed

• Layers of sand and mud form on top

• Pressure and high temperature cause oil to form

• Oil obtained by drilling
Oil is a fossil fuel
Other fossils fuels are:


 Coal and Gas
Non-renewable          Renewable

                Biofuels – ethanol and
                biodiesel made from plants
Crude oil is a
mixture of a very
large number of
compounds.

These compounds
can be separated
by distillation.
The Fractional Distillation of Crude Oil
                                                                    Average number of
                                                                    C atoms in chain
                                    Fraction          Boiling pt.
                                 Liquid petroleum
                                                        < 25oC             3
                                 gas
         40o
                                  Petrol (gasoline)    25 – 60oC           8
         C

                               Very hot crude oil is pumped into
                                       Naphtha          60 – 180oC        10
                               the fractionating column where the
                               hydrocarbons separate180 – by their boiling points,
                                                        out 220oC         12
                                       Paraffin
                               rising through the column until they get cold
                               enough Diesel
                                        to condense. The compounds that
                                                       220 – 250oC        20
                               condense at a particular temperature are called a
                               FRACTION.
                                        Fuel oil       250 – 300oC        40

                                    Lubricating oil   300 – 350oC         80

         350oC
                                       Bitumen          > 350oC          120
Heated
Crude
Oil
Properties of the fractions
Most of the compounds in crude oil consist of
 molecules made up of hydrogen and carbon atoms
 only (hydrocarbons). Most of these are saturated
 hydrocarbons called alkanes.




              CH4           C2H6
                                          C3H8
Write the chemical                    In general:
formula for these
alkanes
                                       CnH2n+2
                              C4H10
Alkane molecules can be represented in the following
forms:
Fuels

Most alkanes are used as fuels to produce useful forms of
energy.

When completely burned alkanes form carbon dioxide
and water.
Equations for combustion

 CH4      + 2 O2         CO2       + 2 H2O
methane     oxygen       carbon        water
                         dioxide


 C3H8     + 5 O2         3 CO2     + 4 H2O



 C2H4     + 3 O2        2 CO2      +   2H2O
Most fuels, including coal, contain carbon and/or
hydrogen and may also contain some sulfur.

 The gases released into the atmosphere when a fuel burns
 may include:
 •carbon dioxide                     GLOBAL WARMING
 •water (vapour)
 •carbon monoxide
 •sulfur dioxide and                 ACID RAIN
 •oxides of nitrogen.
 Solid particles (particulates - sometimes called soot) may
 also be released.                   GLOBAL DIMMING

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Crude oil

  • 2. Key words Crude oil Compound Mixture Distillation Hydrocarbons Saturated Alkanes Covalent bond Evaporating Condense Fractional distillation Fractionating column Particulates Combustion Soot Biofuels
  • 3. How crude oil was formed • Microscopic plants and animals die and fall to the sea bed • Layers of sand and mud form on top • Pressure and high temperature cause oil to form • Oil obtained by drilling
  • 4. Oil is a fossil fuel Other fossils fuels are: Coal and Gas
  • 5. Non-renewable Renewable Biofuels – ethanol and biodiesel made from plants
  • 6. Crude oil is a mixture of a very large number of compounds. These compounds can be separated by distillation.
  • 7. The Fractional Distillation of Crude Oil Average number of C atoms in chain Fraction Boiling pt. Liquid petroleum < 25oC 3 gas 40o Petrol (gasoline) 25 – 60oC 8 C Very hot crude oil is pumped into Naphtha 60 – 180oC 10 the fractionating column where the hydrocarbons separate180 – by their boiling points, out 220oC 12 Paraffin rising through the column until they get cold enough Diesel to condense. The compounds that 220 – 250oC 20 condense at a particular temperature are called a FRACTION. Fuel oil 250 – 300oC 40 Lubricating oil 300 – 350oC 80 350oC Bitumen > 350oC 120 Heated Crude Oil
  • 8. Properties of the fractions
  • 9. Most of the compounds in crude oil consist of molecules made up of hydrogen and carbon atoms only (hydrocarbons). Most of these are saturated hydrocarbons called alkanes. CH4 C2H6 C3H8 Write the chemical In general: formula for these alkanes CnH2n+2 C4H10
  • 10. Alkane molecules can be represented in the following forms:
  • 11. Fuels Most alkanes are used as fuels to produce useful forms of energy. When completely burned alkanes form carbon dioxide and water.
  • 12. Equations for combustion CH4 + 2 O2 CO2 + 2 H2O methane oxygen carbon water dioxide C3H8 + 5 O2 3 CO2 + 4 H2O C2H4 + 3 O2 2 CO2 + 2H2O
  • 13. Most fuels, including coal, contain carbon and/or hydrogen and may also contain some sulfur. The gases released into the atmosphere when a fuel burns may include: •carbon dioxide GLOBAL WARMING •water (vapour) •carbon monoxide •sulfur dioxide and ACID RAIN •oxides of nitrogen. Solid particles (particulates - sometimes called soot) may also be released. GLOBAL DIMMING