Electron allows developers to build desktop applications with web technologies like HTML, CSS, and JavaScript. It uses Chromium and Node.js to package these apps so they can run on Windows, Mac, and Linux. Some key benefits of Electron include rapid development, shared code/UI across platforms, offline capabilities, and access to native device functionality and APIs. Popular apps built with Electron include Atom, Slack, and Visual Studio Code. The document provides an overview of Electron and tips for developing desktop apps with its tools and frameworks.