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Chemistry Exam Help
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A. Sketch ψ1(x) and ψ2(x) on the figure above. In addition, specify below the qualitatively
most important features that your sketch of ψ1(x) and ψ2(x) must display inside Region
III and at the borders of Region III
B. What do you know about ψ1(0) and dψ1/dx x=0 without solving for E1 and ψ1?.
(i) Is ψ1(0) = 0?
No. ψ1 cannot have a node and still be the lowest energy state.
(ii) Does ψ1(0) have the same sign as ψ1(a/2)?
Yes.
(iii) Is dψ1/dx x=0 = 0?
C. What do you know about ψ2(0) and dψ2/dx x=0 without solving for E2 and ψ2?
(i) Is ψ2(0) = 0?
Yes. ψ2 must be anti symmetric and have a node at x = 0.
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(ii) Is dψ2/dx x=0 = 0?
No.
D. In the table below, in the last column, place an X next to the mathematical form of
ψ1(x) in Region III .
E. Does the exact E1 level lie above or below E1
(0) ?
Yes. ψ1(x) feels the barrier strongly, which results in an increase in energy so that E1 ≫ E1
(0)
F. For the exact E2 level, is the energy difference, |E2 - E2
(0)|, larger or smaller than |E1
- E1
(0) |? Explain why?
The E2 level hardly feels the barrier. It is shifted only slightly to higher energy than E2
(0) .
|E2 - E2
(0)| ≪ |E1 - E1
(0) |
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II. Measurement Theory
Consider the Particle in an Infinite Box "superposition state" wave function,
ψ 1,2 = (1/3)1/2 ψ 1 + (2/3)1/2 ψ 2
where E1 is the Eigen-energy of 𝜓1 and E2 is the Eigen-energy of 𝜓2.
A. Suppose you do one experiment to measure the energy of ψ 1,2 Circle the possible result(s) of
your measurement:
B. Suppose you do 100 identical measurements to measure the energies of identical
systems in state ψ 1,2 .What will you observe?
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III. Semiclassical Quantization
Consider the two potential energy functions:
A. The semi-classical quantization equation below
describes the number of levels below E. Use this to compute the number of levels with
energy less than 0 for V1 and V2.
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B. V1 and V2 have the same product of width times depth, V1 is (a) |V0| and V2 is
(a/2)(2|V0|), but V1 and ave different numbers of bound levels. Which has the larger
fractional effect, increasing the depth of the potential by X% or increasing the width of the
potential by X%?
n(V1) = 21/2 n (V2)
V1, the wider well, has more levels than V2, the deeper well. Width has larger fractional
effect than depth.
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IV. Creation/Annihilation Operators
A Consider the integral
For what values of v – vʹ will the integral be non-zero (these are called selection rules)?
There are four ˆa† and three ˆa , therefore v = vʹ + 1. The integral is non-zero when v – vʹ =
+1.
B Let vʹ = 4 and v be the value determined in part A to give a non-zero integral.
Calculate the value of the above integral (DO NOT SIMPLIFY!).
Starting from right-most factor in the operator, with ψvʹ=4 we have
C Now consider the integral
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Are the selection rules for v' – v the same as in part A? Is the value of the non-zero integral
for vʹ = 4 the same as in part B? If not, calculate the value of the integral (UNSIMPLIFIED!).
The v – vʹ selection rule is the same for Part A but the numerical value of the integral is
different. Starting from the right, we have
which is larger than the value in Part B.
D. Derive the commutation rule ˆN[ ,aˆ] starting from the definition of N.
Live Exam Help
V.〈x〉, p〉, σx, σp and Time Evolution of a Superposition State
A. Show that
B. Derive a similar expression for p!2 . (Be sure to combine a!†aˆ and ˆ aa† ! terms into
an integer times ˆN plus another integer.
Live Exam Help
C. Evaluate σx and σp. (Recall that )
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D.
E. For Ψ(x, t = 0) = c0ψ0 + c1ψ1 + c2ψ2, write the time-dependent wave function, Ψ(x, t).
F. Assume that c0, c1, and c2 are real. Evaluate ˆx t and show that x t oscillates at
angular frequency ω. [HINT: 2cosθ = eiθ + e−iθ .]
Live Exam Help
We know the selection rule for ˆx is Δv = ±1.
We know the selection rule for x!2 is Δv = 0, ±2.
ˆx = ∫ Ψ* ˆxΨdx = c0
2 0+ c1
2 0+ c2
2 0
+c0c1x01e−iωt + c1c0x10eiωt
+c1c2x12e−iωt + c2c1eiωt
+c0c20+ c2c00
Thus ˆx = 2c0c1x01 cosωt + 2c1c2x12 cosωt because x01 = x10 and x12 = x21
x21 = 21/2x10 could give additional simplification.
G. Evaluate x!2t . Show that x!2t includes a contribution that oscillates at an angular
frequency of 2ω.
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Chemistry Exam Help

  • 1. For more information, Visit: https://www.liveexamhelper.com/ Contact: +1 678 648 4277 Mail us at: info@liveexamhelper.com Chemistry Exam Help Live Exam Help
  • 3. A. Sketch ψ1(x) and ψ2(x) on the figure above. In addition, specify below the qualitatively most important features that your sketch of ψ1(x) and ψ2(x) must display inside Region III and at the borders of Region III B. What do you know about ψ1(0) and dψ1/dx x=0 without solving for E1 and ψ1?. (i) Is ψ1(0) = 0? No. ψ1 cannot have a node and still be the lowest energy state. (ii) Does ψ1(0) have the same sign as ψ1(a/2)? Yes. (iii) Is dψ1/dx x=0 = 0? C. What do you know about ψ2(0) and dψ2/dx x=0 without solving for E2 and ψ2? (i) Is ψ2(0) = 0? Yes. ψ2 must be anti symmetric and have a node at x = 0. Live Exam Help
  • 4. (ii) Is dψ2/dx x=0 = 0? No. D. In the table below, in the last column, place an X next to the mathematical form of ψ1(x) in Region III . E. Does the exact E1 level lie above or below E1 (0) ? Yes. ψ1(x) feels the barrier strongly, which results in an increase in energy so that E1 ≫ E1 (0) F. For the exact E2 level, is the energy difference, |E2 - E2 (0)|, larger or smaller than |E1 - E1 (0) |? Explain why? The E2 level hardly feels the barrier. It is shifted only slightly to higher energy than E2 (0) . |E2 - E2 (0)| ≪ |E1 - E1 (0) | Live Exam Help
  • 5. II. Measurement Theory Consider the Particle in an Infinite Box "superposition state" wave function, ψ 1,2 = (1/3)1/2 ψ 1 + (2/3)1/2 ψ 2 where E1 is the Eigen-energy of 𝜓1 and E2 is the Eigen-energy of 𝜓2. A. Suppose you do one experiment to measure the energy of ψ 1,2 Circle the possible result(s) of your measurement: B. Suppose you do 100 identical measurements to measure the energies of identical systems in state ψ 1,2 .What will you observe? Live Exam Help
  • 6. III. Semiclassical Quantization Consider the two potential energy functions: A. The semi-classical quantization equation below describes the number of levels below E. Use this to compute the number of levels with energy less than 0 for V1 and V2. Live Exam Help
  • 7. B. V1 and V2 have the same product of width times depth, V1 is (a) |V0| and V2 is (a/2)(2|V0|), but V1 and ave different numbers of bound levels. Which has the larger fractional effect, increasing the depth of the potential by X% or increasing the width of the potential by X%? n(V1) = 21/2 n (V2) V1, the wider well, has more levels than V2, the deeper well. Width has larger fractional effect than depth. Live Exam Help
  • 8. IV. Creation/Annihilation Operators A Consider the integral For what values of v – vʹ will the integral be non-zero (these are called selection rules)? There are four ˆa† and three ˆa , therefore v = vʹ + 1. The integral is non-zero when v – vʹ = +1. B Let vʹ = 4 and v be the value determined in part A to give a non-zero integral. Calculate the value of the above integral (DO NOT SIMPLIFY!). Starting from right-most factor in the operator, with ψvʹ=4 we have C Now consider the integral Live Exam Help
  • 9. Are the selection rules for v' – v the same as in part A? Is the value of the non-zero integral for vʹ = 4 the same as in part B? If not, calculate the value of the integral (UNSIMPLIFIED!). The v – vʹ selection rule is the same for Part A but the numerical value of the integral is different. Starting from the right, we have which is larger than the value in Part B. D. Derive the commutation rule ˆN[ ,aˆ] starting from the definition of N. Live Exam Help
  • 10. V.〈x〉, p〉, σx, σp and Time Evolution of a Superposition State A. Show that B. Derive a similar expression for p!2 . (Be sure to combine a!†aˆ and ˆ aa† ! terms into an integer times ˆN plus another integer. Live Exam Help
  • 11. C. Evaluate σx and σp. (Recall that ) Live Exam Help
  • 12. D. E. For Ψ(x, t = 0) = c0ψ0 + c1ψ1 + c2ψ2, write the time-dependent wave function, Ψ(x, t). F. Assume that c0, c1, and c2 are real. Evaluate ˆx t and show that x t oscillates at angular frequency ω. [HINT: 2cosθ = eiθ + e−iθ .] Live Exam Help
  • 13. We know the selection rule for ˆx is Δv = ±1. We know the selection rule for x!2 is Δv = 0, ±2. ˆx = ∫ Ψ* ˆxΨdx = c0 2 0+ c1 2 0+ c2 2 0 +c0c1x01e−iωt + c1c0x10eiωt +c1c2x12e−iωt + c2c1eiωt +c0c20+ c2c00 Thus ˆx = 2c0c1x01 cosωt + 2c1c2x12 cosωt because x01 = x10 and x12 = x21 x21 = 21/2x10 could give additional simplification. G. Evaluate x!2t . Show that x!2t includes a contribution that oscillates at an angular frequency of 2ω. Live Exam Help