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 The term “geopolymer” was first used by J.Davidovits in the 
late 1970s. 
 Geopolymers have three dimensional amorphous structure 
and can be synthesized from by products such as fly ash, 
blast furnance slag or geological materials such as metakaolin. 
 However, metakaolin is expensive and is not used widely in 
the construction industry.
 Xray fluorescence (XRF) 
 X-ray diffraction (XRD) 
 Scanning electron micrograph (SEM) 
 Fourier transform infrared spectroscopy (FTIR) 
 Differential scanning calorimetry (DSC) 
 Thermal gravimetric analysis (TGA)
 The chemical composition of the alumino silicate was 
determined using XRF shows the chemical 
composition of fly ash.
 The basic material of the geopolymer based fly ash is 
of a prevailingly amorphous character only seldom 
containing needle-shaped minority crystals. The X-ray 
diffraction (XRD) pattern of fly ash in its as 
received condition is shown in Fig.
 SEM image showing the characteristic morphology of the 
original fly ash. The majority of the fly ash particles are 
spherical in nature and are precipitator type fly ash. 
 This ash consists of a series of spherical particles of different 
sizes (diameters ranging from 200 to 10 Am). Although 
usually hollow, some of these spheres may contain other 
particles of a smaller size in their interiors.
 The FTIR spectra for both raw fly ash and 
geopolymer paste demonstrated remarkable 
differences. The vibration at 1020 cm-1 
corresponding to SiO and AlO in the raw fly ash 
was shifted to less than 1000 cm-1.
DSC was used to measure a number of characteristic 
properties of the geopolymer pastes. 
Using this technique, it is possible to observe exothermic and 
endothermic events as well as glass transition temperatures(Tg). 
The range of investigation is between -30 and 100̊ C
 Wide range of temperatures. 
 Programmed heating/cooling rates 
 Sensitivity 
 Any material may be tested 
Fiber 
Powder 
liquid etc; 
Small amount of material is needed 
Does not take much time 
Clearness of results
 Cannot really control the rate of experiment. 
 Dependent on too many parameters. 
 Very sensitive to any changes. 
 The result depends a lot from the operator. 
 The procedure of standard parameters. 
 Evaluation is not described.
 In this TGA test, the mass loss was measured while the 
specimens were gradually exposed to increasing temperatures. 
Powdered specimens were used in TGA to ensure the 
achievement of thermal equilibrium during transient heating.
 Accurate 
 Low detection limit(up to 10-7 g) 
 Reliable data 
 Easy to use 
 Rather cheap 
Disadvantages 
Destructive 
Limited range of samples 
Time consuming 
Usually not qualitative
 Class C Fly Ash: 
 For class c fly ash-based 
geopolymer paste, low W/F 
could meet the demand for an 
approving fluidity. 
 Class C fly ash-based 
geoolymer pase and mortar 
could both abtain high 
compressive strength after 
curing a 70ͦC for 24h. 
Compressive strengthof mortar 
was much higher than paste 
with same water to fly ash 
ratio.
Class F fly ash: 
Class F fly ash mixed 
with calcium hydroxide 
geopolymer mortar. 
The compressive 
strength and the flexural 
strength of geopolymer 
mortar after being 
demolded cured at 
standard temperature for 
1 day were up to 6.48 
MPa and 2.07 MPa.
 Geopolymer are new materials which have various application 
fields. 
 Geopolymer concrete showed reduction deterioration in its 
properties when exposed to temperatures above 200ͦC. 
 Geopolymers shows significant potential to be a material for 
the future,because it is not only environmentally friendly but 
also possesses excellent mechanical properties. 
 And it also has a great potential for applications in various 
industries.
Thank you

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Characterisation of geo polymer binders ppt

  • 1.
  • 2.  The term “geopolymer” was first used by J.Davidovits in the late 1970s.  Geopolymers have three dimensional amorphous structure and can be synthesized from by products such as fly ash, blast furnance slag or geological materials such as metakaolin.  However, metakaolin is expensive and is not used widely in the construction industry.
  • 3.  Xray fluorescence (XRF)  X-ray diffraction (XRD)  Scanning electron micrograph (SEM)  Fourier transform infrared spectroscopy (FTIR)  Differential scanning calorimetry (DSC)  Thermal gravimetric analysis (TGA)
  • 4.  The chemical composition of the alumino silicate was determined using XRF shows the chemical composition of fly ash.
  • 5.  The basic material of the geopolymer based fly ash is of a prevailingly amorphous character only seldom containing needle-shaped minority crystals. The X-ray diffraction (XRD) pattern of fly ash in its as received condition is shown in Fig.
  • 6.  SEM image showing the characteristic morphology of the original fly ash. The majority of the fly ash particles are spherical in nature and are precipitator type fly ash.  This ash consists of a series of spherical particles of different sizes (diameters ranging from 200 to 10 Am). Although usually hollow, some of these spheres may contain other particles of a smaller size in their interiors.
  • 7.
  • 8.  The FTIR spectra for both raw fly ash and geopolymer paste demonstrated remarkable differences. The vibration at 1020 cm-1 corresponding to SiO and AlO in the raw fly ash was shifted to less than 1000 cm-1.
  • 9. DSC was used to measure a number of characteristic properties of the geopolymer pastes. Using this technique, it is possible to observe exothermic and endothermic events as well as glass transition temperatures(Tg). The range of investigation is between -30 and 100̊ C
  • 10.  Wide range of temperatures.  Programmed heating/cooling rates  Sensitivity  Any material may be tested Fiber Powder liquid etc; Small amount of material is needed Does not take much time Clearness of results
  • 11.  Cannot really control the rate of experiment.  Dependent on too many parameters.  Very sensitive to any changes.  The result depends a lot from the operator.  The procedure of standard parameters.  Evaluation is not described.
  • 12.  In this TGA test, the mass loss was measured while the specimens were gradually exposed to increasing temperatures. Powdered specimens were used in TGA to ensure the achievement of thermal equilibrium during transient heating.
  • 13.  Accurate  Low detection limit(up to 10-7 g)  Reliable data  Easy to use  Rather cheap Disadvantages Destructive Limited range of samples Time consuming Usually not qualitative
  • 14.  Class C Fly Ash:  For class c fly ash-based geopolymer paste, low W/F could meet the demand for an approving fluidity.  Class C fly ash-based geoolymer pase and mortar could both abtain high compressive strength after curing a 70ͦC for 24h. Compressive strengthof mortar was much higher than paste with same water to fly ash ratio.
  • 15. Class F fly ash: Class F fly ash mixed with calcium hydroxide geopolymer mortar. The compressive strength and the flexural strength of geopolymer mortar after being demolded cured at standard temperature for 1 day were up to 6.48 MPa and 2.07 MPa.
  • 16.  Geopolymer are new materials which have various application fields.  Geopolymer concrete showed reduction deterioration in its properties when exposed to temperatures above 200ͦC.  Geopolymers shows significant potential to be a material for the future,because it is not only environmentally friendly but also possesses excellent mechanical properties.  And it also has a great potential for applications in various industries.