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CONCEPT OF CHEMICAL ANALYSIS
FOR
CEMENT / ALLIED BUILDING MATERIALS
DR V.K. MATHUR
CONSULTANT & ADVISOR
EX GM – NATIONAL COUNCIL FOR CEMENT AND
BUILDING MATERIALS, NEW DELHI
BOMB CALORIMETER
BOMB CALORIMETER
•The calorific value of a liquid or solid fuel is measured in the bomb calorimeter.
•This device consists of a spherical vessel containing a small sample of the
fuel in an atmosphere of pressurized oxygen.
•The bomb is immersed in an isolated water bath which acts as the calorimeter
for the heat released when combustion is initiated.
BOMB CALORIMETER
BOMB CALORIMETER
•The temperature change in the water is measured by a sensitive
thermometer, and knowing the thermal capacity of the apparatus the
heat released can be determined.
•Once again, the temperature rise is arranged to take place from just
below, to just above the reference temperature of 25℃ with a
maximum rise of about 4℃.
•In practice, the thermal capacity of the apparatus is evaluated
experimentally by burning a known quantity of a reference fuel,
typically benzoic acid, in the device.
•A quantity of water is introduced into the bomb to ensure saturation,
hence the condensation of all the water produced by combustion of the
fuel.
BOMB CALORIMETER
•For best precision, the temperature of the calorimeter jacket must be
closely controlled. This usually requires a waterfilled jacket equipped
with a means for adjusting the jacket temperature, either by an
immersion heater or by hot and
cold water injections.
•With a temperature controlled jacket the calorimeter can be operated
either in an adiabatic or isoperibol mode.
•In an adiabatic system the jacket temperature is adjusted
continuously during a test to keep it equal at all times to the
temperature in the bucket. Thus,by maintaining a zero differential
between the jacket and bucket, there will be no heat transfer between
the jacket and bucket,.
•This type of jacketing was the dominate method for bomb calorimetry.
THANK YOU !

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Bomb_Calorimeter.pptx

  • 1. CONCEPT OF CHEMICAL ANALYSIS FOR CEMENT / ALLIED BUILDING MATERIALS DR V.K. MATHUR CONSULTANT & ADVISOR EX GM – NATIONAL COUNCIL FOR CEMENT AND BUILDING MATERIALS, NEW DELHI
  • 3. BOMB CALORIMETER •The calorific value of a liquid or solid fuel is measured in the bomb calorimeter. •This device consists of a spherical vessel containing a small sample of the fuel in an atmosphere of pressurized oxygen. •The bomb is immersed in an isolated water bath which acts as the calorimeter for the heat released when combustion is initiated.
  • 5. BOMB CALORIMETER •The temperature change in the water is measured by a sensitive thermometer, and knowing the thermal capacity of the apparatus the heat released can be determined. •Once again, the temperature rise is arranged to take place from just below, to just above the reference temperature of 25℃ with a maximum rise of about 4℃. •In practice, the thermal capacity of the apparatus is evaluated experimentally by burning a known quantity of a reference fuel, typically benzoic acid, in the device. •A quantity of water is introduced into the bomb to ensure saturation, hence the condensation of all the water produced by combustion of the fuel.
  • 6. BOMB CALORIMETER •For best precision, the temperature of the calorimeter jacket must be closely controlled. This usually requires a waterfilled jacket equipped with a means for adjusting the jacket temperature, either by an immersion heater or by hot and cold water injections. •With a temperature controlled jacket the calorimeter can be operated either in an adiabatic or isoperibol mode. •In an adiabatic system the jacket temperature is adjusted continuously during a test to keep it equal at all times to the temperature in the bucket. Thus,by maintaining a zero differential between the jacket and bucket, there will be no heat transfer between the jacket and bucket,. •This type of jacketing was the dominate method for bomb calorimetry.