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1
The vibrational
transition in BeO
is observed at a
wavelength of
6.724 μm. What
is the effective
force constant of
BeO?
Helping Tools
No.1
No.2
2
No.3
Solution
1 2
1 2
2
Let us first calculate the
reduced mass of BeO as
(9.0122 )(15.9994)
(9.0122 ) (15.9994)
144.19
5.76
25.01
r
m m
m
m m
u
u
u
u
u
=
+
=
+
= =
3
8
6
14 1
12
We know that frequency
& wavelength are related by
3 10
6.724 10
0.446 10
44.6 10
m
X
c s
f
X m
X Xs
X Hz
 −
−
= =
=
=
2
2
2
2
2 2
We know that vibrational
frequency is given as:
1 1
2 2
1
4
k kXc
f
m mXc
kc
f X
mc
 

= =
 =
2 2 2
2
12 2 2
2
24 2
2
16
2
24 6
16 2
30
16 2
14 18
2
4
(44.6 10 ) 4 (3.14) 5.76 931.5
1989.16 10 ( ) 39.44 5365.44
9 10
420932022.78 10 10
9 10
420932022.78 10
9 10
46770224.75 10 4677.022475 10
f X Xmc
k
c
X Hz X X X X MeV
c
X Hz X X MeV
m
X
s
X X eV
X m
X eV
X m
X eV X e
m

 =
=
=
=
=
= = 2
21 3
2 2
4.677 10 4.677 10
( )
V
m
eV eV
X X
m nm
= =

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BeO Vibrational Transitions.pdf

  • 1. 1 The vibrational transition in BeO is observed at a wavelength of 6.724 μm. What is the effective force constant of BeO? Helping Tools No.1 No.2
  • 2. 2 No.3 Solution 1 2 1 2 2 Let us first calculate the reduced mass of BeO as (9.0122 )(15.9994) (9.0122 ) (15.9994) 144.19 5.76 25.01 r m m m m m u u u u u = + = + = =
  • 3. 3 8 6 14 1 12 We know that frequency & wavelength are related by 3 10 6.724 10 0.446 10 44.6 10 m X c s f X m X Xs X Hz  − − = = = = 2 2 2 2 2 2 We know that vibrational frequency is given as: 1 1 2 2 1 4 k kXc f m mXc kc f X mc    = =  = 2 2 2 2 12 2 2 2 24 2 2 16 2 24 6 16 2 30 16 2 14 18 2 4 (44.6 10 ) 4 (3.14) 5.76 931.5 1989.16 10 ( ) 39.44 5365.44 9 10 420932022.78 10 10 9 10 420932022.78 10 9 10 46770224.75 10 4677.022475 10 f X Xmc k c X Hz X X X X MeV c X Hz X X MeV m X s X X eV X m X eV X m X eV X e m   = = = = = = = 2 21 3 2 2 4.677 10 4.677 10 ( ) V m eV eV X X m nm = =