This document compares the Gaussian model and computational fluid dynamics (CFD) for assessing pollutant dispersion, specifically in complex urban environments. It presents results from an analysis comparing the American Meteorological Society/Environmental Protection Agency Regulatory Model (ADMS) Gaussian model to a CFD model. For a single stack and road source in flat terrain, ADMS predicted similar or slightly higher concentrations than CFD. However, for a street canyon scenario, CFD performed better by capturing the three-dimensional and unsteady flow, while ADMS had limitations representing the complex geometry. Further development is still needed to improve importing CFD flow fields into ADMS.