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Aldehydes and ketones
2020
⑨ Benzene to Acetophenone
' + CHIOU
¥14s
,
"
3
Csz
Benzene
⑤ Ethyne to ethanol 2015
CHICH É
Hgsoy
< "
3-
" °
ethanol
ethyne
⑥ Benzaldehyde from phenol 2013
OH
€-7 ¥-1 , .-
CHO
Ahly AIU
]
d Acetone to brobene
or
2020
probanone to brobene 2017
Ctg
-
É-
Ctg
" AIH "
; CH
,
-
d%- Ctg
443kt,
conc .
Has 04
ctg-CH-C.tk
e Ethanol to probanone 2018
CH
}
-
É-
H + CH]MgBr →
CHI MgBr%ᵗ
<
% :{µ
,-
OH Ctg -
É-
CH
}
(f) Ethanol to 2-
hydroxy.
propanoicaoid .
2013
CH
}
-1=0
HCM
> Ctg-41
-
CN
↳ %
'
u
OH
( Hz-
CH -
COOH
bit
(g) Propanone to bropan -2-01
2013
( "
311=0 + µ ,
Nits CHIH-
OH
CH}
CH}
(h) Probanone to propane
2013
Cone.
2h -
Hg / HU
C. Hz -
( =D
7 GHz-
CHz-CH3
Clemmensen
{Hz Reduction
i) Benzoyl chloride to benzaldehyde 2013
E-a E-a
Pd / Bason 1-
¥4 + Ha → 1-4
Poisoned by
S
(j) Ethanol to but -
2- enal 2013
CH
} +
cH⑤ ←°
"
CH
]
-
cµ=cn
-
É
he
Carboxylic Acid
a) Toluene to benzoic acid
/ Ethylbenzene to benzoic Acid
2018 2017
fH3
É% ÉÑ" +É
"
¥4
""
kmnae.am
,
"°"
↓ tgo
-1
É
⑤ Acetylene to acetic acid 2013
CH ICH + H2O
ᵗʰˢ°"
> CH
}
-
%-
H
Hgsoy
C.Hz -
COOH
④ Batan -1-01 to butanoic acid 2012
CH.zctlgftfc.tkOH
↳ ↳ -
""°"
?
CHzCHzCH,
OH
Jones
reagent
⑨ 4- Methylacetobhenone to benzene -1,42°
"
-
dicarboxylic acid
%- CH
} POOH
iikmnoy / KOH
,
EH ii)Hz0+ I
ÉH}
COOH
② Ethyl cyanide to ethanoic acid
CH
}
-
CH,
-
CN CH
]
-
CH
,
-
%-
Nth
Partial
Hydrolysis ↓ Brat NaOH
<
%H°ᵗ
ctg-ctf-OH-CHz-CHz-NHzctb.CO
OH Hzsoy
⑦ Benzoic acid to m - bromo benzoic acid.
2012
É , EETs.
⑨ Propanoic acid to acetic acid 2019
CH
} CHZCOOH Yaffa > CHI -
CH
} Go
4
CHRGCOOH <
KMn°Y CH, CHOU <
KOH
CH}
-
Ctf-
Br
2015,2017
⑨ Benzoic acid to benzaldehyde
Hz.
/ Pd-
Basely ¥jH
¥-04
sock
,
É¥"
Rosamund Redn
d) Ethanoic acid to 2-
hydroxy.
ethanoicucid
201.7
CH
]
-
COOH É a- CH
,
-
Coote El
HO -
CH
,
-
COOH
( j ) A-cetophenone to benzoic acid
2017
CH
} →
◦ Na
+ CHU
}
↓ 1430
-1
T¥
#OH
Amines
⑨ Benzoic acid to aniline 2019
,C0NHz
1¥00"n
°
_
""
i,
u
[¥
"
⑥ Ethane nitrile to ethanamine 2015
CH] CN + 4TH] %H CH}
-
Ctf
-
MHz
② Benzyl chloride to 2- Phenyl ethanamine 2012
ICH,
-6
,ᵗʰcMHy, 1¥42
-
CHINH,
i
⑨ Nitrobenzene into aniline
2014
1^102 ,NHz
+ 6TH] +2110
② Ethanoic acid into methenamine zone
CH]
-
COOH CH]
-
¥-6 CHz-cNHz
Ctf
-
MHz
#{Eon'
I
(f) Benzene to Aniline 2012
for
%É + see] u^"ʰ
⑨ Bromo methane to ethanol
2019
CH}
-
Br Ctg -
CN É
CH
]CHzNHz
Hs CH
]CHzOH
⑨ Aniline into N -
phenylelhanamide
2014
MHz
+ Ctg _
-
o - -
ctg
he
-
CH
}
±
Acetanilide
d) Aniline to phenol 2015
MHz
÷%É÷EÉ
"
(j ) ftp.CONHz to GHS-
MHz 2015
CONH,
-1 Boz -14140k
?⃝
-
NH,
30 Most Important Organic Conversions.pdf

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30 Most Important Organic Conversions.pdf

  • 1. Aldehydes and ketones 2020 ⑨ Benzene to Acetophenone ' + CHIOU ¥14s , " 3 Csz Benzene
  • 2. ⑤ Ethyne to ethanol 2015 CHICH É Hgsoy < " 3- " ° ethanol ethyne
  • 3. ⑥ Benzaldehyde from phenol 2013 OH €-7 ¥-1 , .- CHO Ahly AIU ]
  • 4. d Acetone to brobene or 2020 probanone to brobene 2017 Ctg - É- Ctg " AIH " ; CH , - d%- Ctg 443kt, conc . Has 04 ctg-CH-C.tk
  • 5. e Ethanol to probanone 2018 CH } - É- H + CH]MgBr → CHI MgBr%ᵗ < % :{µ ,- OH Ctg - É- CH }
  • 6. (f) Ethanol to 2- hydroxy. propanoicaoid . 2013 CH } -1=0 HCM > Ctg-41 - CN ↳ % ' u OH ( Hz- CH - COOH bit
  • 7. (g) Propanone to bropan -2-01 2013 ( " 311=0 + µ , Nits CHIH- OH CH} CH}
  • 8. (h) Probanone to propane 2013 Cone. 2h - Hg / HU C. Hz - ( =D 7 GHz- CHz-CH3 Clemmensen {Hz Reduction
  • 9. i) Benzoyl chloride to benzaldehyde 2013 E-a E-a Pd / Bason 1- ¥4 + Ha → 1-4 Poisoned by S
  • 10. (j) Ethanol to but - 2- enal 2013 CH } + cH⑤ ←° " CH ] - cµ=cn - É he
  • 11. Carboxylic Acid a) Toluene to benzoic acid / Ethylbenzene to benzoic Acid 2018 2017 fH3 É% ÉÑ" +É " ¥4 "" kmnae.am , "°" ↓ tgo -1 É
  • 12. ⑤ Acetylene to acetic acid 2013 CH ICH + H2O ᵗʰˢ°" > CH } - %- H Hgsoy C.Hz - COOH
  • 13. ④ Batan -1-01 to butanoic acid 2012 CH.zctlgftfc.tkOH ↳ ↳ - ""°" ? CHzCHzCH, OH Jones reagent
  • 14. ⑨ 4- Methylacetobhenone to benzene -1,42° " - dicarboxylic acid %- CH } POOH iikmnoy / KOH , EH ii)Hz0+ I ÉH} COOH
  • 15. ② Ethyl cyanide to ethanoic acid CH } - CH, - CN CH ] - CH , - %- Nth Partial Hydrolysis ↓ Brat NaOH < %H°ᵗ ctg-ctf-OH-CHz-CHz-NHzctb.CO OH Hzsoy
  • 16. ⑦ Benzoic acid to m - bromo benzoic acid. 2012 É , EETs.
  • 17. ⑨ Propanoic acid to acetic acid 2019 CH } CHZCOOH Yaffa > CHI - CH } Go 4 CHRGCOOH < KMn°Y CH, CHOU < KOH CH} - Ctf- Br
  • 18. 2015,2017 ⑨ Benzoic acid to benzaldehyde Hz. / Pd- Basely ¥jH ¥-04 sock , É¥" Rosamund Redn
  • 19. d) Ethanoic acid to 2- hydroxy. ethanoicucid 201.7 CH ] - COOH É a- CH , - Coote El HO - CH , - COOH
  • 20. ( j ) A-cetophenone to benzoic acid 2017 CH } → ◦ Na + CHU } ↓ 1430 -1 T¥ #OH
  • 21. Amines ⑨ Benzoic acid to aniline 2019 ,C0NHz 1¥00"n ° _ "" i, u [¥ "
  • 22. ⑥ Ethane nitrile to ethanamine 2015 CH] CN + 4TH] %H CH} - Ctf - MHz
  • 23. ② Benzyl chloride to 2- Phenyl ethanamine 2012 ICH, -6 ,ᵗʰcMHy, 1¥42 - CHINH, i
  • 24. ⑨ Nitrobenzene into aniline 2014 1^102 ,NHz + 6TH] +2110
  • 25. ② Ethanoic acid into methenamine zone CH] - COOH CH] - ¥-6 CHz-cNHz Ctf - MHz #{Eon' I
  • 26. (f) Benzene to Aniline 2012 for %É + see] u^"ʰ
  • 27. ⑨ Bromo methane to ethanol 2019 CH} - Br Ctg - CN É CH ]CHzNHz Hs CH ]CHzOH
  • 28. ⑨ Aniline into N - phenylelhanamide 2014 MHz + Ctg _ - o - - ctg he - CH } ± Acetanilide
  • 29. d) Aniline to phenol 2015 MHz ÷%É÷EÉ "
  • 30. (j ) ftp.CONHz to GHS- MHz 2015 CONH, -1 Boz -14140k ?⃝ - NH,