This document discusses ad hoc collaborative design for multidisciplinary process chain development applied to thermal management of spacecraft. It motivates the need for software to support ad hoc collaboration between engineers from different disciplines during early design phases. It presents the integration framework RCE, which uses a peer-to-peer network approach to allow tools and optimization methods to be easily, remotely and ad hoc accessed from any participant in the network. RCE was shown to support the ad hoc collaboration needs in developing multidisciplinary process chains, but technical software alone does not solve the human challenges of collaboration.