nano synthesis top-down and boyttom up

1. p- m-
To down and
Botto
up Processes
Presented by: Preeti Choudhary
MScApplied Physics

2. Outline of Presentation
 Top-down approach
 Bottom-up approach
 Why will it be needed?
 Applications
 Challenges of Bottom-up processing
 The future of top-down and bottom-up processing
 Summary

3. p-
To
Down
Approach
 Uses the traditional
methods to pattern a
bulk wafer as in EE
418 lab.
 Is limited by
resolution of
lithography.
the
http://pages.unibas.ch/phys-meso/Education/Projektstudien/Lithographie/Litho-M1-Lithography.html

4. p-
What Constitutes a To
down
Process?
 Adding a layer of
material over the
entire wafer and
patterning that layer
through
photolithography.
 Patterning bulk silicon
by etching away
certain areas. www.nanoscience.at/ aboutnano_en.html

5. p-
Current To down
T
echnology
193 nmArF excimer laser
photolithography stepper  Use of 193 excimer
laser with phase shift
masks to for features
65 nm in size.
 Phase shift masks and
complex optics are
used to achieve this
resolution.
http://www.lrsm.upenn.edu/~frenchrh/lithography.htm

6. p-
Problems with the To
down
Process
Cost of new machines and
clean room environments
grows exponentially with
newer technologies.
Physical limits of
photolithography are
becoming a problem.
With smaller geometries
and conventional
materials, heat dissipation



is a problem. http://www.cit.gu.edu.au/~s55086/qucomp/gifs/intro.moore1.gif

7. m-
Botto Up Approach
 The opposite of the
top-down approach.
 Instead of taking
material away to make
structures, the bottom-
up approach
selectively adds atoms
to create structures.
http://idol.union.edu/~malekis/ESC24/KoskywebModules/sa_topd.htm

8. m
The Ideas Behind the Botto -
up Approach
 Nature uses the
bottom up approach.
– Cells
– Crystals
– Humans
 Chemistry and biology
can help to assemble
and control growth. http://www.csacs.mcgill.ca/selfassembly.htm

9. p- m-
To
down
Versus Botto up
Top Down Process Bottom Up Process
Start with bulk wafer
Start with bulk wafer
Alter area of wafer where
structure is to be created by
adding polymer or seed
crystals or other
techniques.
Apply layer of
photoresist
Expose wafer with UV
light through mask and
etch wafer
Grow or assemble the
structure on the area
determined by the seed
crystals or polymer.
(self assembly)
Etched wafer with
desired pattern
Similar results can be obtained through bottom-up and top-down processes

10. m-
Why is Botto Up Processing
Needed?
Allows smaller geometries than photolithography.
Certain structures such as Carbon Nanotubes and
Si nanowires are grown through a bottom-up
process.
New technologies such as organic semiconductors
employ bottom-up processes to pattern them.
Can make formation of films and structures much
easier.
Is more economical than top-down in that it does
not waste material to etching.






11. Self Assembly
 The principle behind bottom-up processing.
 Self assembly is the coordinated action
independent entities to produce larger,
ordered structures or achieve a desired
shape.
 Found in nature.
 Start on the atomic scale.
of

12. m-
Applications of Botto Up
Processing
 Self-organizing deposition
of silicon nanodots.
 Formation of Nanowires.
 Nanotube transistor.
 Self-assembled
monolayers.
 Carbon nanotube
interconnects.
http://web.ics.purdue.edu/~mmaschma/bias_image_gallery1.htm

13. elf-
S organizing Deposition of
Silicon Nanodots.
 Most common
applications are in
optical devices and
memory.
 Silicon nanodots are
deposited onto silicon
dioxide with no need
for lithographic
patterning.
http://www.iht.rwth-aachen.de/en/Forschung/nano/bottomup/deposition.php

14. Making Nanodots
Polymer template for nanodot
Process for making
nanodots
Apply layer of self-
assembled polymer
film.
Grow layer of
desired material to
create nanodot.
1.
2.
65 billion nanodots per square cm
http://news.bbc.co.uk/1/hi/sci/tech/33010241.stm

15. Nanodots
Each nanodot can
hold one bit of
information.
13 nm high
80 nm wide
10 Trillion dots
per square inch.
SelfAssembled Nanodots
http://physics.nist.gov/Divisions/Div841/Gp3/Projects/Atom/atom_dots_proj.html

16. Types of Carbon Nanotubes
Semimetallic and
semiconducting
metallic
http://www.tipmagazine.com/tip/INPHFA/vol-10/iss-
1/p24.html

17. Growing Carbon Nanotubes
Deposit few particles of Iron
(most common) to act as
catalyst.
Apply a hot environment of
carbon containing gas (typically
CH4)
The particle catalyzes the
decomposition of the gas and
carbon dissolves in the particle.
When the particle is
supersaturated with carbon, it
extrudes the excess carbon in
the form of a tube.




http://www.phys.hawaii.edu/~sattler/Archives/archives91-94Apr7-2.htm

18. Nanotube Transistor
Basic diagram for a
nanotube transistor
Benefits of transistor over
conventional designs:


Smaller
Faster
Less material used
Many of the problems
associated with
conventional devices are
solved
–
–
–
–
www.nanotech-now.com/ news.cgi?story_id=06788

19. or-
Nanotube Transist
Assembled
self
Amine silane
Ti/Au Contact
AFM Image
SiO2
Carbon Nanotube
Diagram of Nanotube
transistor
www-drecam.cea.fr/.../ LEMautoassemblage.html

20. Nanotube Transistor
Construction
 DNA strands connect to
gold electrodes on top of
silicon.
 DNA strands connect to
ends of carbon nanotube.
 Silicon and nanotubes are
mixed and the DNA
makes the connections to
form nanotube transistors.
by DNA
http://www.trnmag.com/Photos/2004/12150
4/DNA%20makes%20nanotube%20transist
ors%20Image.html

21. Problem With Carbon
Nanotube Transistors
Interface between metal
electrodes and carbon
nanotube is very sensitive.
Changing just one atom
can significantly affect
transistor performance.
Self-assembling nanotubes
is not efficient.
Growing nanotubes in
place has had little
success.




http://www.thomas-swan.co.uk/pages/nano_images.html

22. elf-
S assembled Monolayers
(SAMS)
Molecules are
deposited molecule-
by-molecule to form
self-assembled
monolayer.

a
Creates a high quality
layer of material.
Layers are deposited
one layer at a time.


http://www.mtl.kyoto-
u.ac.jp/english/laboratory/nanoscopic/nanoscopic.htm

23. Monolayers
Organic molecules can’t
be deposited using
extreme conditions
because it would damage
the organic molecules.
SAMS technique does not
damage organic
molecules.
SAMS films are nearly
defect free.
Used to deposit organic
semiconductors.




http://www.orfid.com/images/img-vofet1.gif

24. Carbon Nanowire
Interconnects
 Metal contact acts as
catalyst to promote
one-dimensional
crystal growth.
 Can one day be
implemented as
interconnects.
a
Silicon Nanowire Diameter <1nm
http://www.iht.rwth-aachen.de/en/Forschung/nano/bottomup/nanowires.php

25. Nanotube Interconnect Process
http://www.nasa.gov/centers/ames/research/technology-onepagers/carbon_nanotubes_vertical.html

26. Benefits and Challenges of
Nanotube Interconnects
Can have a much greater
conductivity than copper.
Is more heat resistant than
copper.
Carries a much larger
current than copper.
Orientation of carbon
nanotubes remains a
problem.
Technology is not reliable
enough to be used in
device manufacturing.

Carbon nanotubes
grown on a metal
contact through
PECVD.
Carbon nanotubes after
layer of silicon dioxide
added. 


http://www.nasa.gov/centers/ames/research/technology-
onepagers/carbon_nanotubes_vertical.html


27. m-
Challenges for the Botto Up
Approach
 Making sure that the structures
assemble in the correct way.
grow and
 Forming complex patterns and structures
using self assembly.
 Contamination has a significant impact on
devices with such small geometries.
 Fabricating robust structures.

28. m-
Strategies for Botto Up
Processing
 Combination of top-
down and bottom-up
processes to simplify
construction.
 Use catalysts and
stresses to achieve
more one-directional
growth.
http://www.isnm2005.org/_metacanvas/attach_handler.uhtml?attach_id=296&c
ontent_type=application/pdf&filename=Paper%2036.pdf

29. of To
op-
down
Futur
e
and
Bottom-
Up
Processin
g
1.000.000 nrn
molecular electronics
bioelectronics
nEMS & n:notcchnology
1.000 nm
chemistry
biology
atomic manipulation
I nm
195
0
196
0
197
0
198
0
201
0
1990 2000 2020
http://www.imec.be/wwwinter/business/nanotechnology.pdf

30. Advancements Made so Far
 Carbon nanotube
transistor (Stanford U.)
 Organic monolayers for
organic transistor (Y
ale
U.)
 Nanotube based circuit
constructed (IBM)
 Nanomotors and gears
created (NASA)
http://snf.stanford.edu/Education/Nanotechnology.SNF.ppt

31. What to Look For
Nanotube array possibly used in
future televisions.
Vias and interconnects being
implemented with carbon
nanotubes.
Nanotube transistors replacing
conventional designs.
SAMS being used to create
organic semiconductor based
devices.
Carbon nanotubes becoming
more and more prevalent as
their growth is controlled.




http://www.engin.brown.edu/Faculty/Xu/

32. Conclusion
Top-down processing has been and will be the
dominant process in semiconductor
manufacturing.
Newer technologies such as nanotubes and organic
semiconductors will require a bottom-up approach
for processing.
Self-assembly eliminates the need for
photolithography.
Bottom-up processing will become more and more
prevalent in semiconductor manufacturing.
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33. Thank You