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Chapter 5.
Air Pollution Meteorology
VALLURI MAHENDRA
Asst. Prof.
22.12.2023 S. Demir 2
Outline
 Introduction
 Solar Radiation
 Atmospheric Pressure
 Lapse rate & Potential Temperature
 Atmospheric Stability
 Coriolis Force & Gravitational Force
 Pressure Gradient Force
 Overall Atmospheric Motion
 Equations of Motion
 Wind Speed Profile
22.12.2023 S. Demir 3
Introduction (1/2)
 Air pollutant cycle
 Emission
 Transport, diffusion, and transformation
 Deposition
 Re-insertion
 In large urban areas, there are several concentrated
pollutant sources
 All sources contribute to pollution at any specific site
 Determined by mainly meteorological conditions
 Dispersion patterns must be established
 Need for mathematical models and meteorological input data
for models
22.12.2023 S. Demir 4
Introduction (2/2)
 Three dominant dispersion mechanisms
 General mean air motion that transport pollutants downwind
 Turbulent velocity fluctuations that disperse pollutants in all
directions
 Diffusion due to concentration gradients
 This chapter is devoted to meteorological fundamentals for
air pollution modelling
22.12.2023 S. Demir 5
Solar Radiation (1/6)
 Solar constant  8.16 J/cm2.min
 0.4-0.8 µ  visible range, maximum intensity
Ref:
http://www.globalwarmingart.com/image
s/4/4c/Solar_Spectrum.png
22.12.2023 S. Demir 6
Solar Radiation (2/6)
 Distribution of solar energy on earth
Ref: OpenLearn Web Site,
http://openlearn.open.ac.uk/file.php/1697/t206b1c01f26.jpg
22.12.2023 S. Demir 7
Solar Radiation (3/6)
 At right angle on June, 21  Tropic of cancer
 At right angle on December, 21  Tropic of capricorn
 At right angle on March, 21 and september, 21  Equator
http://upload.wikimedia.org/wikipedia/commons/8/84/Earth-lighting-equinox_EN.png
22.12.2023 S. Demir 8
Solar Radiation (4/6)
 Example: What is the Sun’s angle over Istanbul on June, 21? Note
that Istanbul is located on 40° N latitude.
 Solution: Sunlight reaches Tropic of Cancer (23° 27′) at right angle
on June, 21.
Where
θ = Sun’s angle at the given latitude
L2 = Latitude of given region
L1 = Latitude of region where sunlight reaches surface at right
angle
 
1
2
90 L
L 

 

  '
'
27
73
27
23
40
90 








22.12.2023 S. Demir 9
Solar Radiation (5/6)
 Example: What is the Sun’s angle over a city located on 39° N
latitude when the sunlight reaches surface at right angle on 21° S
latitude?
 Solution:
 
 
  




30
21
39
90
90 1
2









 L
L
22.12.2023 S. Demir 10
Solar Radiation (6/6)
 Homework (due 18.04.2008)
 Make a brief research on Stefan-Boltzman Law and write a one
page report for your research.
 Comment on what would happen if earth’s inclination were 24°
instead of 23°27′.
 What determines the seasons? Why some regions of earth get
warmer than other regions.
 Calculate the sunlight angle over Istanbul
 on March, 21
 on June, 21
 on September, 21
 on December, 21
22.12.2023 S. Demir 11
Atmospheric Pressure (1/4)
 Force on earth surface due to the weight of the atmosphere
 Defined as force exerted per unit surface area
 Units of measurement  Pascal (Pa), atmospheric pressure
unit (apu, atm), newtons per meter-squared (N/m2), water
column (m H2O), etc.
 1 atm = 101325 Pa
 1 atm = 10.33 m H2O
 1 atm = 760 mm Hg
 1 Pa = 1 N/m2
 Atmospheric pressure at sea level is 1 atm
22.12.2023 S. Demir 12
Atmospheric Pressure (2/4)
 Consider a stationary air parcel as shown
 Force balance (assuming no horizontal
pressure gradient)
 
 
 
 
g
dh
dP
g
h
P
g
h
P
h
g
P
h
gA
hA
g
Vg
mg
P
A
mg
PA
A
P
P
G
A
P
P
A
P
F
F
h
h
Net






























































0
0
lim
lim
0




22.12.2023 S. Demir 13
Atmospheric Pressure (3/4)
 Integrating from h = z0 to h = z produces
 
 
     























0
0 exp
;
0
0
z
z
g
RT
M
z
P
z
P
gdh
RT
M
P
dP
gdh
RT
M
P
dP
g
RT
PM
dh
dP
RT
PM
g
dh
dP
A
z
z
A
z
P
z
P
A
A
A


22.12.2023 S. Demir 14
Atmospheric Pressure (4/4)
 Homework (due 18.04.2008)
 Make a research about pressure measurement devices and
prepare a one-page report for your research. Give brief
explanations for each type.
 Calculate the atmospheric pressure on top of Everest if it is
1013 mb at sea level.
22.12.2023 S. Demir 15
Lapse Rate & Potential Temperature (1/5)
 Adiabatic  no heat exchange
with surroundings
 Consider an air parcel moving
upward so rapidly that it
experiences no heat exchange
with surrounding atmosphere
 Enthalpy change:
where
H1 = initial enthalpy of air parcel
H2 = final enthalpy of air parcel
U1 = initial internal energy
U2 = final internal energy
V1 = initial volume
V2 = final volume
1
2 H
H
H 


22.12.2023 S. Demir 16
 Enthalpy change is a
function of only temperature
when pressure is constant
 Substituting differential
pressure as follows:
 Since the process is
adiabatic, no heat exchange
occurs
Lapse Rate & Potential Temperature (2/5)
 By enthalpy’s definition
 In infinitesimal expression
 Internal energy substitution
 By internal energy definition
   
pV
U
H
pV
U
pV
U
H









 1
2
  pdV
Vdp
dU
pV
d
dU
dH 




  pdV
Vdp
W
Q
d
dH 



Vdp
dQ
pdV
Vdp
pdV
dQ
dH 





dT
C
Vdp
dQ
dH p



dT
C
gVdh
dQ p

 
m
C
C
gV
dh
dT
dT
C
gVdh
p
p
100
98
.
0










22.12.2023 S. Demir 17
Lapse Rate & Potential Temperature (3/5)
 This approximation assumed there is no phase change in
the air parcel
 called Dry Adiabatic Lapse Rate (DALR)
 If any phase change takes place during the motion, the
temperature change will be far more different from DALR
 Called Saturated (Wet) Adiabatic Lapse Rate (SALR, WALR)
 Variable, must be calculated for each case
 Also significant in some cases; this course does not focus on it
 For standardization purposes, Standard Lapse Rate (SLR),
also known as Normal Lapse Rate (NLR), has been defined
 On average, in middle latitude, temperature changes from 1°C
to -56.7°C
 SLR = -0.66°C/100 m
22.12.2023 S. Demir 18
Lapse Rate & Potential Temperature (4/5)
 Lapse rate measurements are taken by a device called
Radiosonde
 Results of measurements are plotted to obtain Environmental
Lapse Rate (ELR)
 ELR is real atmospheric lapse rate
 Another significant concept is Potential Temperature
 Defined as possible ground level temperature of an air parcel at
a given altitude
  H
DALR
T
Tp *




where
θ = Tp = potential temperature of air parcel
T = Temperature of air parcel
H = Height of air parcel from ground
DALR = Dry adiabatic lapse rate
22.12.2023 S. Demir 19
Lapse Rate & Potential Temperature (5/5)
 Homework (due 18.04.2008)
 Calculate potential temperature for given data
 Calculate the atmospheric temperature at 800 m from the
ground if the atmosphere shows adiabatic characteristic and
the ground level temperature is 12°C.
Height, m Temperature, °C
350 8
750 2
1200 14
22.12.2023 S. Demir 20
Atmospheric Stability (4/8)
 Subadiabatic
22.12.2023 S. Demir 21
Atmospheric Stability (5/8)
 Inversion
22.12.2023 S. Demir 22
Atmospheric Stability (7/8)
 Example: Calculate vertical temperature gradient and comment on
atmospheric stability condition if the atmospheric temperature at
835 m is 12 °C when the ground temperature is 25 °C.
 Solution:
The atmosphere is said to be unstable since ELR < DALR
m
C
m
C
m
C
z
T
T
dz
dT
ELR
ground
aloft
100
56
.
1
0156
.
0
0
835
25
12 













22.12.2023 S. Demir 23
Atmospheric Stability (8/8)
 Homework (due 25.04.2008)
 Following measurements are taken over Istanbul at different
times. Determine atmospheric stability condition for each case.
 Briefly explain stable air, unstable air, neutral air and inversion.
 Make a brief research about the role of atmospheric stability in
dispersion of pollutants in the atmosphere and prepare a-one-
page report for your research.
 What is conditional stability? Explain.
Height,
m
Temperature, °C
Case 1 Case 2 Case 3 Case 4
0 14 22 17 4
1000 8 8 7 6
22.12.2023 S. Demir 24
Coriolis Force
 “The Coriolis effect is an apparent deflection
of moving objects from a straight path when
they are viewed from a rotating frame of
reference. Coriolis effect is caused by the
Coriolis force, which appears in the equation
of motion of an object in a rotating frame of
reference.” (Wikipedia Web Site,
http://en.wikipedia.org/wiki/Coriolis_Force)
 
 











x
v
m
F
f
x
v
m
F
Coriolis
coriolis
Coriolis
2
2
22.12.2023 S. Demir 25
Gravitational Force (3/3)
 Homework (due 25.04.2008)
 Determine the acceleration of an object near the Martian surface
due to gravitational attraction force
 Determine the acceleration of an object near the Moon’s surface
due to gravitational attraction force
THANK YOU
22.12.2023 S. Demir 26

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Air Pollution Meteorology.ppt

  • 1. Chapter 5. Air Pollution Meteorology VALLURI MAHENDRA Asst. Prof.
  • 2. 22.12.2023 S. Demir 2 Outline  Introduction  Solar Radiation  Atmospheric Pressure  Lapse rate & Potential Temperature  Atmospheric Stability  Coriolis Force & Gravitational Force  Pressure Gradient Force  Overall Atmospheric Motion  Equations of Motion  Wind Speed Profile
  • 3. 22.12.2023 S. Demir 3 Introduction (1/2)  Air pollutant cycle  Emission  Transport, diffusion, and transformation  Deposition  Re-insertion  In large urban areas, there are several concentrated pollutant sources  All sources contribute to pollution at any specific site  Determined by mainly meteorological conditions  Dispersion patterns must be established  Need for mathematical models and meteorological input data for models
  • 4. 22.12.2023 S. Demir 4 Introduction (2/2)  Three dominant dispersion mechanisms  General mean air motion that transport pollutants downwind  Turbulent velocity fluctuations that disperse pollutants in all directions  Diffusion due to concentration gradients  This chapter is devoted to meteorological fundamentals for air pollution modelling
  • 5. 22.12.2023 S. Demir 5 Solar Radiation (1/6)  Solar constant  8.16 J/cm2.min  0.4-0.8 µ  visible range, maximum intensity Ref: http://www.globalwarmingart.com/image s/4/4c/Solar_Spectrum.png
  • 6. 22.12.2023 S. Demir 6 Solar Radiation (2/6)  Distribution of solar energy on earth Ref: OpenLearn Web Site, http://openlearn.open.ac.uk/file.php/1697/t206b1c01f26.jpg
  • 7. 22.12.2023 S. Demir 7 Solar Radiation (3/6)  At right angle on June, 21  Tropic of cancer  At right angle on December, 21  Tropic of capricorn  At right angle on March, 21 and september, 21  Equator http://upload.wikimedia.org/wikipedia/commons/8/84/Earth-lighting-equinox_EN.png
  • 8. 22.12.2023 S. Demir 8 Solar Radiation (4/6)  Example: What is the Sun’s angle over Istanbul on June, 21? Note that Istanbul is located on 40° N latitude.  Solution: Sunlight reaches Tropic of Cancer (23° 27′) at right angle on June, 21. Where θ = Sun’s angle at the given latitude L2 = Latitude of given region L1 = Latitude of region where sunlight reaches surface at right angle   1 2 90 L L        ' ' 27 73 27 23 40 90         
  • 9. 22.12.2023 S. Demir 9 Solar Radiation (5/6)  Example: What is the Sun’s angle over a city located on 39° N latitude when the sunlight reaches surface at right angle on 21° S latitude?  Solution:            30 21 39 90 90 1 2           L L
  • 10. 22.12.2023 S. Demir 10 Solar Radiation (6/6)  Homework (due 18.04.2008)  Make a brief research on Stefan-Boltzman Law and write a one page report for your research.  Comment on what would happen if earth’s inclination were 24° instead of 23°27′.  What determines the seasons? Why some regions of earth get warmer than other regions.  Calculate the sunlight angle over Istanbul  on March, 21  on June, 21  on September, 21  on December, 21
  • 11. 22.12.2023 S. Demir 11 Atmospheric Pressure (1/4)  Force on earth surface due to the weight of the atmosphere  Defined as force exerted per unit surface area  Units of measurement  Pascal (Pa), atmospheric pressure unit (apu, atm), newtons per meter-squared (N/m2), water column (m H2O), etc.  1 atm = 101325 Pa  1 atm = 10.33 m H2O  1 atm = 760 mm Hg  1 Pa = 1 N/m2  Atmospheric pressure at sea level is 1 atm
  • 12. 22.12.2023 S. Demir 12 Atmospheric Pressure (2/4)  Consider a stationary air parcel as shown  Force balance (assuming no horizontal pressure gradient)         g dh dP g h P g h P h g P h gA hA g Vg mg P A mg PA A P P G A P P A P F F h h Net                                                               0 0 lim lim 0    
  • 13. 22.12.2023 S. Demir 13 Atmospheric Pressure (3/4)  Integrating from h = z0 to h = z produces                                  0 0 exp ; 0 0 z z g RT M z P z P gdh RT M P dP gdh RT M P dP g RT PM dh dP RT PM g dh dP A z z A z P z P A A A  
  • 14. 22.12.2023 S. Demir 14 Atmospheric Pressure (4/4)  Homework (due 18.04.2008)  Make a research about pressure measurement devices and prepare a one-page report for your research. Give brief explanations for each type.  Calculate the atmospheric pressure on top of Everest if it is 1013 mb at sea level.
  • 15. 22.12.2023 S. Demir 15 Lapse Rate & Potential Temperature (1/5)  Adiabatic  no heat exchange with surroundings  Consider an air parcel moving upward so rapidly that it experiences no heat exchange with surrounding atmosphere  Enthalpy change: where H1 = initial enthalpy of air parcel H2 = final enthalpy of air parcel U1 = initial internal energy U2 = final internal energy V1 = initial volume V2 = final volume 1 2 H H H   
  • 16. 22.12.2023 S. Demir 16  Enthalpy change is a function of only temperature when pressure is constant  Substituting differential pressure as follows:  Since the process is adiabatic, no heat exchange occurs Lapse Rate & Potential Temperature (2/5)  By enthalpy’s definition  In infinitesimal expression  Internal energy substitution  By internal energy definition     pV U H pV U pV U H           1 2   pdV Vdp dU pV d dU dH        pdV Vdp W Q d dH     Vdp dQ pdV Vdp pdV dQ dH       dT C Vdp dQ dH p    dT C gVdh dQ p    m C C gV dh dT dT C gVdh p p 100 98 . 0          
  • 17. 22.12.2023 S. Demir 17 Lapse Rate & Potential Temperature (3/5)  This approximation assumed there is no phase change in the air parcel  called Dry Adiabatic Lapse Rate (DALR)  If any phase change takes place during the motion, the temperature change will be far more different from DALR  Called Saturated (Wet) Adiabatic Lapse Rate (SALR, WALR)  Variable, must be calculated for each case  Also significant in some cases; this course does not focus on it  For standardization purposes, Standard Lapse Rate (SLR), also known as Normal Lapse Rate (NLR), has been defined  On average, in middle latitude, temperature changes from 1°C to -56.7°C  SLR = -0.66°C/100 m
  • 18. 22.12.2023 S. Demir 18 Lapse Rate & Potential Temperature (4/5)  Lapse rate measurements are taken by a device called Radiosonde  Results of measurements are plotted to obtain Environmental Lapse Rate (ELR)  ELR is real atmospheric lapse rate  Another significant concept is Potential Temperature  Defined as possible ground level temperature of an air parcel at a given altitude   H DALR T Tp *     where θ = Tp = potential temperature of air parcel T = Temperature of air parcel H = Height of air parcel from ground DALR = Dry adiabatic lapse rate
  • 19. 22.12.2023 S. Demir 19 Lapse Rate & Potential Temperature (5/5)  Homework (due 18.04.2008)  Calculate potential temperature for given data  Calculate the atmospheric temperature at 800 m from the ground if the atmosphere shows adiabatic characteristic and the ground level temperature is 12°C. Height, m Temperature, °C 350 8 750 2 1200 14
  • 20. 22.12.2023 S. Demir 20 Atmospheric Stability (4/8)  Subadiabatic
  • 21. 22.12.2023 S. Demir 21 Atmospheric Stability (5/8)  Inversion
  • 22. 22.12.2023 S. Demir 22 Atmospheric Stability (7/8)  Example: Calculate vertical temperature gradient and comment on atmospheric stability condition if the atmospheric temperature at 835 m is 12 °C when the ground temperature is 25 °C.  Solution: The atmosphere is said to be unstable since ELR < DALR m C m C m C z T T dz dT ELR ground aloft 100 56 . 1 0156 . 0 0 835 25 12              
  • 23. 22.12.2023 S. Demir 23 Atmospheric Stability (8/8)  Homework (due 25.04.2008)  Following measurements are taken over Istanbul at different times. Determine atmospheric stability condition for each case.  Briefly explain stable air, unstable air, neutral air and inversion.  Make a brief research about the role of atmospheric stability in dispersion of pollutants in the atmosphere and prepare a-one- page report for your research.  What is conditional stability? Explain. Height, m Temperature, °C Case 1 Case 2 Case 3 Case 4 0 14 22 17 4 1000 8 8 7 6
  • 24. 22.12.2023 S. Demir 24 Coriolis Force  “The Coriolis effect is an apparent deflection of moving objects from a straight path when they are viewed from a rotating frame of reference. Coriolis effect is caused by the Coriolis force, which appears in the equation of motion of an object in a rotating frame of reference.” (Wikipedia Web Site, http://en.wikipedia.org/wiki/Coriolis_Force)                x v m F f x v m F Coriolis coriolis Coriolis 2 2
  • 25. 22.12.2023 S. Demir 25 Gravitational Force (3/3)  Homework (due 25.04.2008)  Determine the acceleration of an object near the Martian surface due to gravitational attraction force  Determine the acceleration of an object near the Moon’s surface due to gravitational attraction force