1) Dental amalgam is a mixture of liquid mercury and a silver alloy powder composed of silver, tin, and copper, sometimes with zinc. When the alloy powder and mercury are mixed through the amalgamation process, it forms a malleable plastic mass that can be condensed into a cavity.
2) There are different types of amalgam depending on factors like copper and zinc content, particle shape and size. Spherical particles are preferred as they require less mercury, amalgamate more easily and have better early strength.
3) Potential disadvantages include dimensional changes during setting, creep over time, inadequate tensile strength, low edge strength, thermal conductivity and corrosion; but proper manipulation can minimize many of these issues.
2. (1) DEFINITION OF DENTAL
AMALGAM
It is the combination of dental amalgam alloy
composed of silver, tin and copper with
mercury (sometimes it contains zinc).
DEFINITION OF AMALGAMATION
PROCESS
It is the process of alloying of mercury being in
liquid state to Ag-Sn metal alloy being in the
solid state.
2
3. (II) TYPES OF AMALGAM
1) According to copper content:
1- Conventional amalgam (Cu is less than 6%)
2- High copper amalgam (Non-β 2 amalgam) (Cu is
more than 6%).
2) According to Zinc content:
1- Zinc containing amalgam.
2- Zinc- free amalgam.
When zinc comes in contact with moisture (saliva)
delayed 2ndry expansion will occur.
3
9. (4) ACCORDING TO PARTICLE SIZE:
1- Micro-cut alloy particle.
2- Fine-cut alloy particle.
3- Coarse-cut alloy particle.
The best form is the Fine-cut .
9
10. SPHERICAL AMALGAM ALLOY
PARTICLES CHARACTARISTICS:
1- Zinc content not required.
2- Less amount of Hg is needed.
3- Amalgamates more easily.
4- Less technique sensitive (adv.).
5- Increased early compressive strength.
6- Easier to condense, carve & polish.
10
11. MICRO-CUT AMALGAM ALLOY PARTICLES
less than 10 microns
* CHARACTARISTICS :
- Greater amount of Hg required
- Less plastic mass.
- Decreased compressive strength.
11
13. COARSE-CUT AMALGAM ALLOY PARTICLES
[Greater than 30 microns].
* CHARACTARISTICS :
- Less amount of Hg required (adv but as
particles are rough & large less adaptation)
- Rough surface texture.
- Decreased adaptation to cavity walls.
- Increased compressive strength.
13
15. COMPOSITION OF CONVENTIONAL SILVER/ TIN
AMALGAM ALLOY:
* Silver : not less than 65% by wt.
* Tin : not less than 25% by wt.
* Copper: not more than 6% by wt.
* Zinc : not more than 0-2% by wt.
15
17. * Silver : It is the main ingredient of amalgam
used to:
- strength & hardness of amalgam.
- flow.
- Some expansion.
17
18. * Tin: tin is introduced to give
plasticity of mass as tin has a great affinity to Hg
so. It is attracted to Hg & so it gives plasticity to
mass allows amalgamation process to take place
easily
* Strength
* Flow
* Cause contraction
18
20. * Zinc:
Acts as a scavenger or deoxidizer during
manufacturing.
It prevents the formation of oxides on
Cu, Ag & Sn.
Disadv.: if amalgam is applied below free
gum margin , moisture contamination will
cause excessive delayed secondary
expansion ( 3-5 days after placement of
restoration).
20
21. COMPOSITION OF HIGH COPPER
AMALGAM ALLOY:
* Silver : not less than 40%
* Tin : not less than 25%
* Copper : 10 β 30%
* Zinc : 0-2%
- We cannot remove tin from the ingredients
otherwise amalgam will be granular.
- The increase in the % of copper is on the
expense of Ag.
21
22. ** CHARACTARISTICS OF HIGH
COPPER AMALGAM:
(1) Higher early compressive strength.
(2) Increased corrosion resistance.
(3) Improved marginal integrity
(4) Lower creep value
22
23. ** TYPES OF HIGH COPPER AMALGAM:
(1) Admixed ( Lathe cut + Spherical)
(2) Single composition (Spherical or
Lathe βcut)
23
24. (1) Admixed high copper amalgam:
* Composition:
10-20% copper
- it is called Admixed type because some
particles are spherical & some are lathe-cut.
- 2/3 lathe-cut.
- 1/3 spherical Ag-Cu (eutectic phase).
24
25. (2) Single COMPOSITION high copper
amalgam :
* COMPOSITION :
13-30% copper.
- Ternary Ag-Sn-Cu.
- Indium or palladium upto10% ( to creep &
corrosion resistance)
- it is made of one type only of alloy lathe cut or
spherical, not a mixture.
- Each alloy particle contains Ag-Sn-Cu whether it.
spherical or lathe β cut this is called ternary
alloy.
- Indium corrosion resistance. 25
27. (IV) PROPERTIES OF AMALGAM
RESTORATION:
Advantages:
(1) Adequate compressive strength.
(2) High abrasion resistance.
(3) Insolubility in oral fluids.
(4) Adaptability to cavity walls.
(5) Convenience of manipulation.
(6) Biocompatibility with oral & dental tissues.
27
28. Disadvantages:
[1] Dimensional changes.
[2] Creep or flow tendency.
[3] Inadequate tensile strength.
[4] Low edge strength.
[5] Thermal conductivity .
[6] Galvanism.
[7] Tarnish & corrosion.
[8] Inharmonious color.
If it is properly manipulated we can
overcome some if not all of these dis-adv.28
29. [1] Dimensional changes:
- Regarding the dimensional changes amalgam
undergoes .3 stages:
a) First stages:
When Hg is added to the alloy powder & after
trituration by 10 min. Amalgam undergoes slight
contraction due to the penetration of Hg into the
alloy particles.
29
30. b) Second stage:
After 10 min. of triturition & till the first 8 hours,
there will be sever expansion due to the formation of
Ο1 phase or silver β mercury phase.
c) Third stage:
After 24 hours there will be very slight contraction as
a result of the setting of amalgam mass, all the
phases of amalgam approach each other.
30
31. [2] Creep or flow tendency:
Deformation of amalgam under load.
* Creep: Deformation of amalgam restoration
under load after it has completely
set.
* Flow: Deformation of amalgam restoration
under load before it has set.
31
33. [3] Inadequate tensile strength:
- Amalgam can fracture at the isthmus (junction
b/w Occlusal & proximal parts) due to its low
tensile strength under tension load.
33
35. [4] Low edge strength:
- The low edge strength is responsible for the
fracture at the margins.
(1) Amalgam ditch can occur I.e. v-shaped
groove that occurs as a result of fracture of the
margins of amalgam between amalgam &
cavity walls at the cavosurface margin.
To prevent this, the cavosurface angle must be
90o to increase the bulk of amalgam at this
area
35
37. [5] Thermal conductivity:
Amalgam can transmit thermal impulses to the
pulp & this can be overcome by putting
cement.
- In deep cavities we put a liner to protect
pulp from Thermal conductivity.
- In shallow cavities there is enough
dentin to protect pulp.
37
38. [6] Galvanism
- If we have two dissimilar metals on the same
side ex: amalgam & the other is gold, saliva acts as
the electrolyte, amalgam acts as anode & gold acts as
cathode so, when they come in contact ions are
transmitted from amalgam to gold & this causes pain.
As an electric current will pass.
- This is associated with corrosion & it is called
galvanic corrosion .
38
39. [7] Tarnish & corrosion
Tarnish
*It is an oxide film that causes discoloration
(blackening).
corrosion
* It is the disintegration of the outer surface.
39
40. * Indications:
- Class I
- Class II
- Class v
- and distal cavities of canine in class III.
* Contra Indication:
- Anterior cavities .
- In the presence of other metallic restoration.
To avoid galvanism.
40
43. Manipulation
The ratio (or the alloy / mercury ratio):
The amount of mercury needed is to coat all the
particles to produce homogeneous coherent
mass of amalgam.
Ratio 5:8 to 10:08 technique.
* The ratio is by weight and not by volume.
43
44. Excess mercury leads to :
1- strength.
2- Flow and creep.
3- Expansion.
4- Tarnish and corrosions.
44
45. Less mercury leads to :
1- non-coherent.
2- Weak.
3- Less resistance to tarnish and corrosion.
N.B: Each in Hg by 15% results in 1.5% excess in the final
restoration.
45
46. Methods of proportioning:
1- Simple weighing balance .
2- Tablets or pellets where amount of Hg
is measured according to the manufacture
by a mechanical dispenser.
3- Automatic mechanical dispenser.
Dispenser should be
1) clean and dry.
2) Vertical to obtain proper measurement.
3) Half filled.
46
47. Disadvantages:
a) Some alloys can cling to the wall of the
dispenser.
b) Each dispenser is for one type of alloy i.e.
canβt be used universally for all types of
alloys
47
48. 4- Preproportioning capsules (the best
method) proper alloy and Hg ratio is done by
manufacturing and are put in a capsule.
A disc or membrane separates Hg and alloy to prevent
premature amalgamation.
Activation is done before trituration. This is done by
removal of the membrane, and provide contact
between alloy and Hg.
This could be done by - Pressure.
- Twisting cover of capsule
48
51. 5- Self-activated capsules:
The process of amalgamation activates the capsule
Advantages of proportioning capsule:
1- More convenient.
2- Proper Hg alloy ratio variables of dentists are
eliminated.
3- Prevent spill of Hg preventing Hg hazards.
51
52. II- Trituration:
* Definition:
It is the process by which the alloy and mercury
are amalgamated together into:
- Coherent.
- Homogeneous.
- Smooth.
- Plastic mass of amalgam.
52
53. * Methods of trituration:
a. Manual trituration using Mortar and Pestle.
b. Mechanically using electric amalgamator.
A. Hand trituration:
i- Glass mortar and pestle are used.
ii-Should be cleaned to prevent contamination.
iii-The face of the Pestle must have the same shape
as the surface of the mortar for effective trituration.
iv- Both Mortar and Pestle should present an even rough
working surface for effective trituration.
v- The trituration process must be standardized by rate, time
and pressure.
53
56. Aims of trituration.
a. To rub off the oxide layer on the alloy particles.
b. For further reduction of the size of the alloy
particles.
c. To bring the mercury into contact with the alloy
particles to start the reaction.
56
57. * Properly triturated amalgam will appear:
A. Homogeneous.
B. Smooth.
C. Climb along the side of the mortar and
form a curl at its top.
57
58. * Under triturated leads to:
A. Weak.
B. Non-homogeneous.
C. Excess mercury.
D. Appear dull.
E. Non-coherent.
F. Undergo more expansion.
G. More tarnish and corrosion.
58
59. Over triturated leads to:
A. Sets faster.
B. Greater one hour strength.
C. Smooth surface.
D. Less flow.
E. More tarnish and corrosion resistance.
F. The only disadvantages is that it may
undergo contraction farther than expansion.
59
60. B. Mechanical Trituration:
. This method:
1- Saves time.
2- Gives better standardization, for the triturated
amalgam.
* Mulling of amalgam:
It is a process of mulling the properly triturated
amalgam for few sec. In a piece of rubber to
acquire a max. degree of plasticity.
60
61. II. Condensation:
* Definition:
It is the process of packing of the properly triturated
amalgam in the prepared cavity.
*Aims:
1. The adaptation of amalgam to cavity walls and
margins.
2. The adaptation between successive layer of
amalgam .
3. Express excess mercury and density of the alloy.
4. The compressive strength of amalgam.
61
66. * Requirements for proper condensation:
1. Only fresh mixes should be used. (Mixes more than 3.5min.
Should be discarded, this is to avoid layering of amalgam.
2. We must use successive increments for effective
condensation.
3. Great condensation pressure is required, directed, towards
cavity wall, and margins.
4. Each condensed layer must be properly stable other wise
weak amalgam will result.
66
67. 5- A proper sized and designed condenser must be
used:
i. It should be small enough to exert great pressure, but not too small to
cause holes in the amalgam.
ii. It should be properly angulated to reach all areas of the cavity.
iii. The face of the condenser must be either flat, smooth or serrated.
6- Condensation should be completed under clean
dry condition.
67
68. * Condensation technique:
1- By hand condensation and it should be as follows.
a. The restoration is built from small successive increment.
b. In case of compound cavities, the box should be filled first to the level
of pulpal floor, then the occlusal.
c. Small piece of amalgam is carried by amalgam carrier and forced into
the cavity.
d. The first layer is condensed with great force using small condenser
from the center of the cavity to cavity margins.
68
69. e- The mercury rich amalgam on the surface is removed with
spoon excavator.
f- The process is repeated until the cavity is completely filled.
g- A final dry piece is condensed to over fill the cavity and
over come the excess mercury of the last layer and then
this layer is removed leaving the surface of amalgam with
no excess mercury.
69
70. 2- Mechanical condensation: by
ultrasonic device
* Advantages of mechanical condensation:
1- It is more standardized .
2- Less fatigue to the operator.
3- It produces homogenous amalgam.
4- More strength property for the final amalgam.
5- Less flow.
6- More stability.
7- Less expansion.
70
71. Carving of Amalgam:
1- We use suitable amalgam carver.
2- Amalgam must not be carved unless it
becomes hard enough to resist carving
instrument ( for about 3.5 min).
3- Sharp instrument must be used for carving,
to not disturb the matrix.
4- Avoid carving towards cavity margins to
avoid under filling and expression of
excess mercury towards the margin.
71
73. Excess Hg at the margins may cause:
a- Marginal disintegration .
b- Marginal leakage.
c- Tarnish and corrosion.
73
74. 5- In compound cavities, the occlusal portion is carved 1st
before removal of matrix.
6- After carving of the occlusal portion , the matrix holder
is unscrewed and band is removed either buccally or
lingually. Avoid its removal occlusally to avoid fracture
of the margins.
7- The proximal contour is carved and then contact is
checked by using dental floss, silk.
74
75. Double burnishing technique
Means the amalgam is pre and post carving
burnished
Pre carving burnishing
Using large sized burnisher with heavy pressure
75
76. Benefits of precarving burnishing
A-Increase adaptation of amalgam to cavity
walls and margins
B-Bring the mercury to the surface
C- More cohesive amalgam
D-Continue the process of condensation
76
78. Finishing and polishing of Amalgam:
It should be done to give a luster-like smooth surface
after at least 24 hrs.
* Finishing and polishing is achieved by using:
1- Rotating finishing instruments which include:
a- Finishing stones as carburundum green stones
in form of : coarse.
medium
fine
they are used to correct surface discrepancies. 78
80. b- Interproximal finishing instruments as:
i- finishing strips in form of : coarse.
medium
fine
ii- Abrasive discs.
they are used to correct over hangs and give
smooth interproximal surface.
c- Finishing burs12 fluted.
80
81. 2- Rotating polishing instruments include:
a- Rubber cups in form of coarse, medium or
fine applied with polishing paste at low speed.
b- Rotating soft brush applied with polishing
paste .
81
85. * If amalgam restoration is not finished and
polished, then the surface remains rough
leads to:
a- Surface porosities.
b- Food and plaque accumulation.
c- Tarnish and corrosion.
d- Concentration of stresses.
85
92. ADVANTAGES:
1- High compressive strength properties
(45000PSI).
2- Low coefficient of thermal expansion.
3- Indestructibility in oral fluid.
4- Easy of manipulation.
5- It is capable to take and maintain a good
polish.
92
93. DISADVANTAGES:
1- Low tensile strength.
2- Bad esthetics due to unnatural color and the
tendency for corrosion.
3- High thermal conductivity.
4- Slight changes in dimension during setting.
93