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Plastic Chemical
 
Plastics ​are a wide range of synthetic or semi-synthetic organic 
compounds that are malleable and so can be molded into solid objects. 
Plasticity is the general property of all materials which can deform 
irreversibly without breaking but, in the class of moldable polymers, 
this occurs to such a degree that their actual name derives from this 
specific ability. 
Plastics ​are typically organic polymers of high molecular mass and 
often contain other substances. They are usually synthetic, most 
commonly derived from petrochemicals, however, an array of variants 
are made from renewable materials such as polylactic acid from corn or 
cellulosics from cotton linters. 
AddressBazar.com is an Bangladeshi Online Yellow Page. From here you
will find important and necessary information of various ​plastic chemical
related organizations in Bangladesh.
In developed economies, about a third of plastic is used in packaging 
and roughly the same in buildings in applications such as piping, 
plumbing or vinyl siding. Other uses include automobiles (up to 20% 
plastic), furniture, and toys. In the developing world, the applications of 
plastic ​may differ—42% of India's consumption is used in packaging. 
Worldwide, about 50 kg of plastic is produced annually per person, with 
production doubling every ten years. 
Plastics have many uses in the medical field as well, with the 
introduction of polymer implants and other medical devices derived at 
least partially from ​plastic​. The field of plastic surgery is not named for 
use of plastic materials, but rather the meaning of the word ​plasticity​, 
with regard to the reshaping of flesh. 
The world's first fully synthetic plastic was bakelite, invented in New 
York in 1907, by Leo Baekeland who coined the term ​'plastics'​. Many 
chemists have contributed to the materials science of plastics, 
including Nobel laureate Hermann Staudinger who has been called "the 
father of polymer chemistry" and Herman Mark, known as "the father of 
polymer physics". 
The success and dominance of ​plastics ​starting in the early 20th 
century led to environmental concerns regarding its slow 
decomposition rate after being discarded as trash due to its 
composition of large molecules. Toward the end of the century, one 
approach to this problem was met with wide efforts toward recycling. 
Etymology
 
The word plastic derives from the Greek πλαστικός (plastikos) 
meaning "capable of being shaped or molded" and, in turn, from 
πλαστός (plastos) meaning "molded". 
The plasticity, or malleability, of the material during manufacture 
allows it to be cast, pressed, or extruded into a variety of shapes, such 
as: films, fibers, plates, tubes, bottles, boxes, amongst many others. 
The common noun plastic should not be confused with the technical 
adjective plastic. The adjective is applicable to any material which 
undergoes a ​plastic ​deformation, or permanent change of shape, when 
strained beyond a certain point. For example, aluminum which is 
stamped or forged exhibits plasticity in this sense, but is not plastic in 
the common sense. By contrast, some ​plastics ​will, in their finished 
forms, break before deforming and therefore are not plastic in the 
technical sense. 
Structure
Most plastics contain organic polymers. The vast majority of these 
polymers are formed from chains of carbon atoms, 'pure' or with the 
addition of: oxygen, nitrogen, or sulfur. The chains comprise many 
repeat units, formed from monomers. Each polymer chain will have 
several thousand repeating units. 
The backbone is the part of the chain that is on the "main path", linking 
together a large number of repeat units. 
To customize the properties of a ​plastic​, different molecular groups 
"hang" from this backbone. These pendant units are usually "hung" on 
the monomers, before the monomers themselves are linked together to 
form the polymer chain. It is the structure of these side chains that 
influences the properties of the polymer. 
The molecular structure of the repeating unit can be fine tuned to 
influence specific properties of the polymer. 
Properties and classifications
Plastics are usually classified by: the chemical structure of the 
polymer's backbone and side chains; some important groups in these 
classifications are: the acrylics, polyesters, silicones, polyurethanes, and 
halogenated ​plastics​. 
Plastics can also be classified by: the chemical process used in their 
synthesis, such as: condensation, polyaddition, and cross-linking. 
Plastics can also be classified by: their various physical properties, such 
as: hardness, density, tensile strength, resistance to heat and glass 
transition temperature, and by their chemical properties, such as the 
organic chemistry of the polymer and its resistance and reaction to 
various chemical products and processes, such as: organic solvents, 
oxidation, and ionizing radiation. In particular, most ​plastics ​will melt 
upon heating to a few hundred degrees celsius. 
Other classifications are based on qualities that are relevant for 
manufacturing or product design. Examples of such qualities and 
classes are: thermoplastics and thermosets, conductive polymers, 
biodegradable plastics and engineering plastics and other ​plastics ​with 
particular structures, such as elastomers. 
Thermoplastics and thermosetting polymers
 
One important classification of plastics is by the permanence or 
impermanence of their form, or whether they are: thermoplastics or 
thermosetting polymers. Thermoplastics are the plastics that, when 
heated, do not undergo chemical change in their composition and so 
can be molded again and again. Examples include: polyethylene (PE), 
polypropylene (PP), polystyrene (PS) and polyvinyl chloride (PVC). 
Common ​thermoplastics ​range from 20,000 to 500,000 ​amu​, while 
thermosets are assumed to have infinite molecular weight. 
Thermosets, or thermosetting polymers, can melt and take shape only 
once: after they have solidified, they stay solid. In the thermosetting 
process, a chemical reaction occurs that is irreversible. The 
vulcanization of rubber is an example of a thermosetting process: 
before heating with sulfur, the polyisoprene is a tacky, slightly runny 
material; after vulcanization, the product is rigid and non-tacky. 
Amorphous plastics and crystalline plastics
Many plastics are completely amorphous, such as: all thermosets; 
polystyrene and its copolymers; and polymethyl methacrylate. 
However, some ​plastics ​are partially crystalline and partially 
amorphous in molecular structure, giving them both a melting point, 
the temperature at which the attractive intermolecular forces are 
overcome, and also one or more glass transitions, the temperatures 
above which the extent of localized molecular flexibility is substantially 
increased. These so-called semi-crystalline plastics include: 
polyethylene, polypropylene, polyvinyl chloride, polyamides (nylons), 
polyesters and some polyurethanes. 
Conductive polymers
Intrinsically Conducting Polymers (ICP) are organic polymers that 
conduct electricity. While ​plastics ​can be made electrically conductive, 
with a conductivity of up to 80 kS/cm in stretch-oriented 
polyacetylene, they are still no match for most metals like copper which 
have a conductivity of several hundred kS/cm. Nevertheless, this is a 
developing field. 
Biodegradable plastics and bioplastics
 
Biodegradable plastics are plastics that degrade, or break down, upon 
exposure to: sunlight or ultraviolet radiation, water or dampness, 
bacteria, enzymes or wind abrasion. In some instances, rodent, pest, or 
insect attack can also be considered as forms of biodegradation or 
environmental degradation. 
Some modes of degradation require that the plastic be exposed at the 
surface (aerobic), whereas other modes will only be effective if certain 
conditions exist in landfill or composting systems (anaerobic). 
Some companies produce biodegradable additives, to enhance 
biodegradation. Plastic can have starch powder added as a filler to 
allow it to degrade more easily, but this still does not lead to the 
complete breaking down of the plastic. 
Some researchers have genetically engineered bacteria to synthesize 
completely biodegradable ​plastics​, such as Biopol; however, these are 
expensive at present. 
Bioplastics
While most plastics are produced from petrochemicals, bioplastics are 
made substantially from renewable plant materials such: as cellulose 
and starch. Due both to the finite limits of the petrochemical reserves 
and to the threat of global warming, the development of bioplastics is a 
growing field. 
However, ​bioplastic ​development begins from a very low base and, as 
yet, does not compare significantly with petrochemical production. 
Estimates of the global production capacity for bio-derived materials is 
put at 327,000 tonnes/year. In contrast, global production of 
polyethylene (PE) and polypropylene (PP), the world's leading 
petrochemical derived polyolefins, was estimated at over 150 million 
tonnes in 2015. 

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7.pdf This presentation captures many uses and the significance of the number...7.pdf This presentation captures many uses and the significance of the number...
7.pdf This presentation captures many uses and the significance of the number...
 

Plastic chemical

  • 1. Plastic Chemical   Plastics ​are a wide range of synthetic or semi-synthetic organic  compounds that are malleable and so can be molded into solid objects.  Plasticity is the general property of all materials which can deform  irreversibly without breaking but, in the class of moldable polymers,  this occurs to such a degree that their actual name derives from this  specific ability.  Plastics ​are typically organic polymers of high molecular mass and  often contain other substances. They are usually synthetic, most  commonly derived from petrochemicals, however, an array of variants 
  • 2. are made from renewable materials such as polylactic acid from corn or  cellulosics from cotton linters.  AddressBazar.com is an Bangladeshi Online Yellow Page. From here you will find important and necessary information of various ​plastic chemical related organizations in Bangladesh. In developed economies, about a third of plastic is used in packaging  and roughly the same in buildings in applications such as piping,  plumbing or vinyl siding. Other uses include automobiles (up to 20%  plastic), furniture, and toys. In the developing world, the applications of  plastic ​may differ—42% of India's consumption is used in packaging.  Worldwide, about 50 kg of plastic is produced annually per person, with  production doubling every ten years.  Plastics have many uses in the medical field as well, with the  introduction of polymer implants and other medical devices derived at  least partially from ​plastic​. The field of plastic surgery is not named for  use of plastic materials, but rather the meaning of the word ​plasticity​,  with regard to the reshaping of flesh.  The world's first fully synthetic plastic was bakelite, invented in New  York in 1907, by Leo Baekeland who coined the term ​'plastics'​. Many  chemists have contributed to the materials science of plastics,  including Nobel laureate Hermann Staudinger who has been called "the  father of polymer chemistry" and Herman Mark, known as "the father of  polymer physics". 
  • 3. The success and dominance of ​plastics ​starting in the early 20th  century led to environmental concerns regarding its slow  decomposition rate after being discarded as trash due to its  composition of large molecules. Toward the end of the century, one  approach to this problem was met with wide efforts toward recycling.  Etymology   The word plastic derives from the Greek πλαστικός (plastikos)  meaning "capable of being shaped or molded" and, in turn, from  πλαστός (plastos) meaning "molded". 
  • 4. The plasticity, or malleability, of the material during manufacture  allows it to be cast, pressed, or extruded into a variety of shapes, such  as: films, fibers, plates, tubes, bottles, boxes, amongst many others.  The common noun plastic should not be confused with the technical  adjective plastic. The adjective is applicable to any material which  undergoes a ​plastic ​deformation, or permanent change of shape, when  strained beyond a certain point. For example, aluminum which is  stamped or forged exhibits plasticity in this sense, but is not plastic in  the common sense. By contrast, some ​plastics ​will, in their finished  forms, break before deforming and therefore are not plastic in the  technical sense.  Structure Most plastics contain organic polymers. The vast majority of these  polymers are formed from chains of carbon atoms, 'pure' or with the  addition of: oxygen, nitrogen, or sulfur. The chains comprise many  repeat units, formed from monomers. Each polymer chain will have  several thousand repeating units.  The backbone is the part of the chain that is on the "main path", linking  together a large number of repeat units.  To customize the properties of a ​plastic​, different molecular groups  "hang" from this backbone. These pendant units are usually "hung" on  the monomers, before the monomers themselves are linked together to 
  • 5. form the polymer chain. It is the structure of these side chains that  influences the properties of the polymer.  The molecular structure of the repeating unit can be fine tuned to  influence specific properties of the polymer.  Properties and classifications Plastics are usually classified by: the chemical structure of the  polymer's backbone and side chains; some important groups in these  classifications are: the acrylics, polyesters, silicones, polyurethanes, and  halogenated ​plastics​.  Plastics can also be classified by: the chemical process used in their  synthesis, such as: condensation, polyaddition, and cross-linking.  Plastics can also be classified by: their various physical properties, such  as: hardness, density, tensile strength, resistance to heat and glass  transition temperature, and by their chemical properties, such as the  organic chemistry of the polymer and its resistance and reaction to  various chemical products and processes, such as: organic solvents,  oxidation, and ionizing radiation. In particular, most ​plastics ​will melt  upon heating to a few hundred degrees celsius.  Other classifications are based on qualities that are relevant for  manufacturing or product design. Examples of such qualities and  classes are: thermoplastics and thermosets, conductive polymers, 
  • 6. biodegradable plastics and engineering plastics and other ​plastics ​with  particular structures, such as elastomers.  Thermoplastics and thermosetting polymers   One important classification of plastics is by the permanence or  impermanence of their form, or whether they are: thermoplastics or  thermosetting polymers. Thermoplastics are the plastics that, when  heated, do not undergo chemical change in their composition and so  can be molded again and again. Examples include: polyethylene (PE),  polypropylene (PP), polystyrene (PS) and polyvinyl chloride (PVC).  Common ​thermoplastics ​range from 20,000 to 500,000 ​amu​, while  thermosets are assumed to have infinite molecular weight. 
  • 7. Thermosets, or thermosetting polymers, can melt and take shape only  once: after they have solidified, they stay solid. In the thermosetting  process, a chemical reaction occurs that is irreversible. The  vulcanization of rubber is an example of a thermosetting process:  before heating with sulfur, the polyisoprene is a tacky, slightly runny  material; after vulcanization, the product is rigid and non-tacky.  Amorphous plastics and crystalline plastics Many plastics are completely amorphous, such as: all thermosets;  polystyrene and its copolymers; and polymethyl methacrylate.  However, some ​plastics ​are partially crystalline and partially  amorphous in molecular structure, giving them both a melting point,  the temperature at which the attractive intermolecular forces are  overcome, and also one or more glass transitions, the temperatures  above which the extent of localized molecular flexibility is substantially  increased. These so-called semi-crystalline plastics include:  polyethylene, polypropylene, polyvinyl chloride, polyamides (nylons),  polyesters and some polyurethanes.  Conductive polymers Intrinsically Conducting Polymers (ICP) are organic polymers that  conduct electricity. While ​plastics ​can be made electrically conductive,  with a conductivity of up to 80 kS/cm in stretch-oriented  polyacetylene, they are still no match for most metals like copper which 
  • 8. have a conductivity of several hundred kS/cm. Nevertheless, this is a  developing field.  Biodegradable plastics and bioplastics   Biodegradable plastics are plastics that degrade, or break down, upon  exposure to: sunlight or ultraviolet radiation, water or dampness,  bacteria, enzymes or wind abrasion. In some instances, rodent, pest, or  insect attack can also be considered as forms of biodegradation or  environmental degradation.  Some modes of degradation require that the plastic be exposed at the  surface (aerobic), whereas other modes will only be effective if certain  conditions exist in landfill or composting systems (anaerobic). 
  • 9. Some companies produce biodegradable additives, to enhance  biodegradation. Plastic can have starch powder added as a filler to  allow it to degrade more easily, but this still does not lead to the  complete breaking down of the plastic.  Some researchers have genetically engineered bacteria to synthesize  completely biodegradable ​plastics​, such as Biopol; however, these are  expensive at present.  Bioplastics While most plastics are produced from petrochemicals, bioplastics are  made substantially from renewable plant materials such: as cellulose  and starch. Due both to the finite limits of the petrochemical reserves  and to the threat of global warming, the development of bioplastics is a  growing field.  However, ​bioplastic ​development begins from a very low base and, as  yet, does not compare significantly with petrochemical production.  Estimates of the global production capacity for bio-derived materials is  put at 327,000 tonnes/year. In contrast, global production of  polyethylene (PE) and polypropylene (PP), the world's leading  petrochemical derived polyolefins, was estimated at over 150 million  tonnes in 2015.