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Many molecules contain bonds that fall between the extremes of ionic and covalent
bonds. The difference between the electronegativities of the atoms in these molecules is large
enough that the electrons aren't shared equally, and yet small enough that the electrons aren't
drawn exclusively to one of the atoms to form positive and negative ions. The bonds in these
molecules are said to be polar, because they have positive and negative ends, or poles, and the
molecules are often said to have a dipole moment. for Eg : HCl molecules, for example, have a
dipole moment because the hydrogen atom has a slight positive charge and the chlorine atom has
a slight negative charge. Because of the force of attraction between oppositely charged particles,
there is a small dipole-dipole force of attraction between adjacent HCl molecules. non-polar
molecule has it's electron density shifted by a charged molecule, i.e., if a positively charged
species is brought near a species with an evenly distributed charge, the electrons go towards the
side where the positive species is, and away from the opposite side, creating an artificial dipole.
Eg : a helium atom is perfectly symmetrical. But movement of the electrons around the nuclei of
a pair of neighboring helium atoms can become synchronized so that each atom simultaneously
obtains an induced dipole moment.
Solution
Many molecules contain bonds that fall between the extremes of ionic and covalent
bonds. The difference between the electronegativities of the atoms in these molecules is large
enough that the electrons aren't shared equally, and yet small enough that the electrons aren't
drawn exclusively to one of the atoms to form positive and negative ions. The bonds in these
molecules are said to be polar, because they have positive and negative ends, or poles, and the
molecules are often said to have a dipole moment. for Eg : HCl molecules, for example, have a
dipole moment because the hydrogen atom has a slight positive charge and the chlorine atom has
a slight negative charge. Because of the force of attraction between oppositely charged particles,
there is a small dipole-dipole force of attraction between adjacent HCl molecules. non-polar
molecule has it's electron density shifted by a charged molecule, i.e., if a positively charged
species is brought near a species with an evenly distributed charge, the electrons go towards the
side where the positive species is, and away from the opposite side, creating an artificial dipole.
Eg : a helium atom is perfectly symmetrical. But movement of the electrons around the nuclei of
a pair of neighboring helium atoms can become synchronized so that each atom simultaneously
obtains an induced dipole moment.

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Many molecules contain bonds that fall between th.pdf

  • 1. Many molecules contain bonds that fall between the extremes of ionic and covalent bonds. The difference between the electronegativities of the atoms in these molecules is large enough that the electrons aren't shared equally, and yet small enough that the electrons aren't drawn exclusively to one of the atoms to form positive and negative ions. The bonds in these molecules are said to be polar, because they have positive and negative ends, or poles, and the molecules are often said to have a dipole moment. for Eg : HCl molecules, for example, have a dipole moment because the hydrogen atom has a slight positive charge and the chlorine atom has a slight negative charge. Because of the force of attraction between oppositely charged particles, there is a small dipole-dipole force of attraction between adjacent HCl molecules. non-polar molecule has it's electron density shifted by a charged molecule, i.e., if a positively charged species is brought near a species with an evenly distributed charge, the electrons go towards the side where the positive species is, and away from the opposite side, creating an artificial dipole. Eg : a helium atom is perfectly symmetrical. But movement of the electrons around the nuclei of a pair of neighboring helium atoms can become synchronized so that each atom simultaneously obtains an induced dipole moment. Solution Many molecules contain bonds that fall between the extremes of ionic and covalent bonds. The difference between the electronegativities of the atoms in these molecules is large enough that the electrons aren't shared equally, and yet small enough that the electrons aren't drawn exclusively to one of the atoms to form positive and negative ions. The bonds in these molecules are said to be polar, because they have positive and negative ends, or poles, and the molecules are often said to have a dipole moment. for Eg : HCl molecules, for example, have a dipole moment because the hydrogen atom has a slight positive charge and the chlorine atom has a slight negative charge. Because of the force of attraction between oppositely charged particles, there is a small dipole-dipole force of attraction between adjacent HCl molecules. non-polar molecule has it's electron density shifted by a charged molecule, i.e., if a positively charged species is brought near a species with an evenly distributed charge, the electrons go towards the side where the positive species is, and away from the opposite side, creating an artificial dipole. Eg : a helium atom is perfectly symmetrical. But movement of the electrons around the nuclei of a pair of neighboring helium atoms can become synchronized so that each atom simultaneously obtains an induced dipole moment.