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[object Object],[object Object],Presentation prepared for the Science teachers of the Universidad Peruana de Ciencias Aplicadas, UPC
Entropy = Measures the energy that has lost its capacity to do work
Genesis of the idea ,[object Object]
Perpetual Motion Engine Types: ,[object Object]
Example…
…  of the First Type: (Motion with out energy being furnished) Perpetuum Mobile by Villard de Honnecourt (circa 1230). =
Perpetual Motion Engine Types: ,[object Object]
Example…
...of the Second Type: (movement from only one heat source) Heat Work
Instead of… Heat (Hot) Work Cold
Joule’s Experiment
Joule’s Experiment ,[object Object],[object Object],*(4.18 J per calorie)
But, on the other hand, when transforming caloric energy to mechanical, contrary to the inverse process, part of the high temperature energy is always transformed in low temperature energy. Heat (High Temperature) Work Heat (Low Temperature)
An Assymetry in Nature is Found
We pay a Tax to Nature ,[object Object],“ Nature accepts the equivalence bewteen Heat and Work, but demands a contribution each time that Heat is transformed into Work” Atkins
[object Object],[object Object]
First and Second Law of Thermodynamics ,[object Object],[object Object],[object Object],[object Object]
Sadi Carnot (1876 – 1832)
Carnot’s Cycle (Represents an Ideal Engine) It’s a reversible process: Whereas working as a motor (I to IV) or as a refrigerator (IV to I), the processes are equivalent.
Carnot´s Engine ,[object Object],(Motor) (Refrigerator)
Carnot´s Engine Efficiency
Understanding of Thermodynamics in mid-Nineteenth Century ,[object Object],[object Object],[object Object]
Enters Rudolf Clausius (1822 – 1888)
Clausius’ Great Contribution ,[object Object]
… and determines that both transformations are equivalent Transformation of Energy, Q, into Work, between T 1  and T (T 1  greater than T)  Transformation of Energy, Q between T 2  and T (T 2  greater than T),w/o performing Work i.e, by conduction.
[object Object]
[object Object],For a reversible process
… and called it “Entropy” ,[object Object]
… because procesess in Nature are not reversible, Entropy always increases…  For a ireversible process
Enters Ludwig Boltzman (1844 – 1906)
[object Object],[object Object]
[object Object],[object Object]
Millon pounds metafor
A million pounds together can do more “Work” that the same quantity distributed among a million persons; in this last case, money has increased its “Entropy”.
The End Please look for references in the next slide
References ,[object Object],[object Object],[object Object],[object Object]

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