Drain Safe Products: They’re Waste Water Compliant, Right? Wrong!
The purpose of this presentation is to offer a practical guide to screen printers on some of the issues related to screen making chemicals and how they can impact waste water.
This presentation was done at the FESPA UK Fabric Printing Now Conference & Printwear & Promotion Live 2016 during the Screen Printing Workshops.
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Drain Safe Products: They’re Waste Water Compliant, Right? Wrong!
1. Drain Safe Products: They’re Waste
Water Compliant, Right? Wrong!
William Shorter
CPS Technical Sales Executive/Product Manager
2. Introduction – William Shorter
• Technical Sales Executive UK / Product
Manager.
• CPS – Chemicals Products & Services
– Established in 1982 in Denmark.
– Located in Oxfordshire, UK.
– Division of MacDermid Autotype Ltd.
• Involved in screen printing for over 21 years.
• Carried out waste water audits for large to small
screen printing companies.
3. Drain Safe Products: They’re Waste Water
Compliant, Right? Wrong!
Clean water and good
sanitation is taken for granted
by millions of people in the
‘developed’ world. We simply
turn on a tap for clean drinking
water and allow it to wash into
a sewer for treatment in some
unseen facility. We also
expect to walk alongside
unpolluted rivers and
waterways that are full of fish
and wildlife.
4. Drain Safe Products: They’re Waste Water
Compliant, Right? Wrong!
• The purpose of this presentation is to offer
a practical guide on some of the issues
related to screen making chemicals and
how they can impact waste water.
6. What does ‘Drain Safe’ mean to you as a
screen printer?
Potential Answers:
1. It’s safe to go down the drain.
2. Compliant with waste water regulations.
3. Does not contain banned chemicals.
4. All of the above.
5. None of the above.
Link to Screen Printers Of The World Unite Community post:
https://plus.google.com/+WilliamShorter/posts/iQmYkdqaXnL
7. Waste Water Regulations
• Waste water regulations are
probably the most diverse set of
‘environmental’ standards.
• The closer you are to the waste
water treatment plant the stricter
these limits can be.
• It is likely that your business has
different ‘consent limits’ for waste
water compared to your
neighbours, depending on the
nature of their work.
8. What is trade effluent?
• Trade effluent is any liquid
waste (effluent), other than
surface water and domestic
sewage, that is discharged
from premises being used
for a business, trade or
industry. Trade effluent can
come from both large and
small premises.
9. Waste Water Regulations
• Water authorities such as
Thames Water, Seven Trent
etc. stipulate and control the
consent limits of trade
effluent.
• It is ‘your’ responsibility to
inform your water authority
that you are discharging
trade effluent to the drain.
10. Can you afford to be non-compliant?
• Non-compliance is a very serious
issue and penalties can range
from improvement notices, fines,
or prevention from discharge into
the drains which would
necessitate all water being
collected for disposal as
‘chemical waste’ at a huge cost
and inconvenience to the
business.
11. Making Sense of the Terminology
• Consent limits stipulate what and how much ‘trade
effluent’ you are allowed to discharge into the drains.
• Consent limits stipulate.
– Maximum volume
– Maximum solids limit
– Temperature range
– COD
– pH range
– Types of chemicals permitted
• Petroleum spirits (white spirit) and some aromatic hydrocarbons
(general purpose screen wash) are unlikely to be permitted to enter
a public sewer.
12. Making Sense of the Terminology
• COD (Chemical Oxygen Demand) is the most
misunderstood parameter and the one that causes most
problems with effluent from the screen making process.
• COD is a measure of how much oxygen is required to
break down the ‘waste’ materials in the water at the
treatment plant.
• Many sewage treatment facilities use a cocktail of bio-
organisms to ‘feed’ on the waste, but if the COD in the
water is too high they will run out of oxygen and die.
13. Understanding Consent Limits
• Consent limits apply
to specific sources of
trade effluent.
• Domestic effluent
(toilets, kitchen etc)
does not contribute
and is not considered
in the consent limit.
14. Understanding Consent Limits
Typical example of consent limits values could be:-
– COD: <2,000 mg/Litre
– pH: 5 to 10.
– Water temperature: <43°C.
– Solids: <1,000mg/Litre (i.e. 1 gram/Litre)
• Most screen printers will exceed these limits.
16. What does ‘Drain Safe’ mean to you as a
screen printer?
How did people vote?
(in a survey carried out 11/09/15)
1. It’s safe to go down the
drain.
2. Compliant with waste
water regulations.
3. Does not contain
banned chemicals.
4. All of the above.
5. None of the above.
21%
13%
13%
53%
0%
Percentage
17. Drain Safe is Okay, Right? – Wrong!
‘Drain Safe’, actually means the product does not
knowingly contain any chemicals that are banned from
entering the waste water system, it does not guarantee
compliance and therefore should not be assumed is okay.
- remember the points we talked about earlier -
• Your type of business
• Your proximity to your local water authority
• Each water authority can have different compliance
regulations
For example, releasing too much hot water into the drains
would be non-compliant, even though the water itself is
100% ‘drain safe’!
19. Screen Making Processes affect waste
water
• Unexposed emulsion washed out after
exposure.
– A single screen with 1m2 coating of emulsion on a 120/cm mesh
would have a COD of up to 150,000mg/Litre and would require
around 75 Litres of water during washout to get the COD below
2,000mg/Litre.
– Contributes to the pH (acidic), solids content and colour of the
waste water.
– Direct to screen inks will also contribute to the solids, pH and
COD of the waste water.
20. Screen Making – contributes to waste water
• Ink Cleaning
– The waste water from this process may be neutral, acidic or
alkali.
– The ink and screen wash both individually have a COD of
approximately 1,500,000 mg/Litre.
– The ink will contribute to the solids content and colour of the
waste water.
21. Screen Making Processes affect waste
water
Is water based ink safe
or not safe to go down
the drain?
22. Screen Making Processes affect waste
water
• ‘NO’, because
– Contains solvents!
– Contributes to the COD and
solids.
– May also affect the pH.
23. Screen Making Processes affect waste
water
• Stencil Removal
– Stencil removers on average have a pH of 2.
– The inorganic raw materials in the stencil removers will not
contribute to the COD.
– Dissolved cross linked emulsion contributes to the COD, solids
and water colour.
24. Screen Making Processes affect waste
water
• Haze Removal
– The waste water from this process will always be alkali.
– The haze remover and ink stain will contribute to the solids,
COD and colour of the waste water.
26. Identify your sources of trade effluent
• Monitor your process
– Screen Cleaning
– Making
• Take note of or measure the:
– Water Colour
– pH
– Temperature
• Work with your chemical supplier / screen printing supply
company.
– COD ,BOD, Solids etc
• Work with your water authority.
28. Controlling conformance to consent limits
• Emulsion & Stencil Removal:
– Simple steps:
• Scrape emulsion from your coating trough back into the pot.
• Fit filters to the waste water system.
• Hold waste water back and pH neutralise.
– Haze Removal waste water.
– Complex & expensive steps:
• Centrifugal filtration.
– Emulsion solids.
• Chemical waste water treatment.
• Dip tank, cleaning machine or recirculation unit.
– Sludge disposed via waste handling company.
• Balancing tanks.
29. Controlling conformance to consent limits
• Screen Wash & Ink:
– Simple steps:
• Scrape as much ink as possible from your screen prior to
cleaning with screen wash.
• Fit fliters to the waste water system*.
• Use a water dilutable cleaning solvent such as an Aquawash.
• An Aquawash diluted at 1:1 with water will have a typical
COD value of 750,000mg/Litre, diluting at 2:1 with water will
reduce this to 500,000mg/Litre.
• Hold waste water back and neutralise.
*Note water based inks and screen wash will not be removed by filtration as they are water
soluble.
30. Controlling conformance to consent limits
• Screen Wash & Ink:
– Complex & expensive steps:
• Centrifugal filtration.
– Ink sludge
• Chemical waste water treatment.
• Dip tank, cleaning machine or recirculation unit.
– Dip tank & cleaning machine sludge disposed via waste
handling company.
• Balancing tanks.
*Note water based inks and screen wash will not be removed by these treatment processes above as
they are water soluble.
31. Controlling conformance to consent limits.
• Haze Removal:
– Simple steps
• Using lower caustic haze removers,
• Apply the minimum amount of haze remover and if possible
use a coating trough to apply the haze remover to the mesh.
• Hold waste water back and pH neutralise.
– Stencil Removal waste water.
– Complex & expensive steps:
• Centrifugal filtration.
• Chemical waste water treatment.
• Balancing tanks.
32. Summary
• Understanding your processes can increase the
likelihood of compliance.
• Compliance is not easy but simple steps can be taken to
increase likelihood of conformance.
• It is your responsibility to inform the water authority of
what you are discharging down the drain.
• Compliance will save you money in the long term.
• Drain Safe Products: They’re Waste Water Compliant,
Right? “Wrong!”
33. CPS Ltd
Chemicals Products and Services
www.cps.eu
cps@cps.eu
T: 01235 773240
F: 01235 771196
Tell Us
What
You Think
This has certainly not always been the case and during periods of industrialisation our environment and waterways have suffered from the effects of pollution. Waste water is now a hot topic but legislation and policies on this subject are also some of the most difficult to understand. The purpose of this presentation is to offer a practical guide on some of the issues related to screen making chemicals, inks and emulsions and how they can impact on waste water.
When it comes to screen cleaning chemicals we all look for a screen wash, stencil remover, degreaser haze remover etc that are referenced as being drain safe by our screen printing suppliers. But what does drain safe really mean?
Ask the audience to chose what they think drainsafe means?
Waste water regulations are probably the most diverse set of ‘environmental’ standards, as different rules apply at EU, Country, Regional and Local Authority levels, they also differ by Water Company and even individual building. From our own experience we’ve established that the closer you are to the waste water treatment plant the stricter these limits can be. It is also likely that your business has different ‘consent limits’ for waste water compared to your neighbours, depending on the nature of their work.
The most important thing is to establish exactly what regulations apply to your business and your Water Company can advise you on this. If you are discharging effluent into a sewer you will require a ‘trade effluent consent’ and you will be given strict ‘consent limits’ for a range of parameters. Your Water Company may require you to conduct periodical monitoring of your waste water or they may choose to conduct their own ‘spot checks’.
The most important thing is to establish exactly what regulations apply to your business and your Water Company can advise you on this. If you are discharging effluent into a sewer you will require a ‘trade effluent consent’ and you will be given strict ‘consent limits’ for a range of parameters. Your Water Company may require you to conduct periodical monitoring of your waste water or they may choose to conduct their own ‘spot checks’.
The consent limit stipulates what and how much ‘trade effluent’ you are allowed to discharge into the drains. This is made up of many key properties of waste water that the Water Company treating the water will be concerned about i.e. maximum daily volumes and discharge rate, pH, COD (Chemical Oxygen Demand), Solids, Temperature etc. It will also stipulate the types of chemicals that are allowed down the drain, for example any substance likely to produce flammable or harmful vapours (such as petroleum spirits and some aromatic hydrocarbons) are unlikely to be permitted to enter a public sewer.
COD (Chemical Oxygen Demand) is the most misunderstood parameter and the one that causes most problems with effluent from the screen making process. It is a measure of how much oxygen is required to break down the ‘waste’ materials in the water at the treatment plant. Many sewage treatment facilities use a cocktail of bio-organisms to ‘feed’ on the waste, but if the COD in the water is too high they will run out of oxygen and die. Different treatment plants have different requirements and one of the issues the Water Company needs to deal with is optimising the incoming COD levels to ensure the bio-organisms are ‘fed’ at the right level. In Scandinavian regions, for example, many treatment plants are optimised for high COD levels and other factors such as ‘nitrification’ of the water are highly critical. In other regions low COD values are preferred.
The consent limit typically applies to the specific source of ‘industrial effluent’ which in the case of screen printers may be a screen cleaning machine or the booth used to develop stencils. Therefore, other waste water from sources such as toilets, kitchens and wash rooms are excluded and it is not possible to ‘dilute’ the trade effluent with these other sources, even though they will most likely end up in the same sewer.
The consent limit typically applies to the specific source of ‘industrial effluent’ which in the case of screen printers may be a screen cleaning machine or the booth used to develop stencils. Therefore, other waste water from sources such as toilets, kitchens and wash rooms are excluded and it is not possible to ‘dilute’ the trade effluent with these other sources, even though they will most likely end up in the same sewer.
Don’t panic, there are simple measures to minimise any possibility of a non compliance, especially if you understand how the processes of screen cleaning and screen making affects the waste water and you select the correct cleaning chemicals.
All emulsions, capillary films and fillers coated onto the screen will eventually end up in the waste water, either as unexposed emulsion washed out after exposure, or during the decoating process after printing. They also have high COD values. A single screen with 1m2 coating of emulsion on a 120/cm mesh would have a COD of up to 150,000mg/Litre and would require around 75 Litres of water during washout and decoating to get the waste water COD to below 2,000mg/Litre.
The waste water from this process will always be acidic. This is due to the nature of the raw materials in the stencil remover used to breakdown the emulsion. The pH of stencil remover once diluted (at the correct ratio) or in a ready to use format will typically have a pH of 2. However, as the chemicals used in the stencil remover are inorganic, they will not contribute to the COD of the waste water. If pH is an issue, the waste water from the stencil removal stage can be ‘neutralised’ by holding back the water in a tank and adding waste water from the haze removal stage prior to discharging to the sewer.
The waste water from this process will always be alkali due to the caustic chemicals used in these types of cleaning products. Using lower caustic haze removers, and those that can be left on the mesh overnight to dry, can minimise the pH of the waste water from this process. If you want to reduce the COD, apply the minimum amount of haze remover and if possible use a coating trough to apply the haze remover to the mesh. The pH of this process can be neutralised by holding back the waste water in a tank along with water from washing out and decoating screens prior to discharging to the sewer.
“Prevention is better than cure” and treating your own waste water on-site should be seen as a last resort if all other steps have been taken to meet consent levels. Many print facilities have been forced to install waste water treatment for different stages of the process due to high volumes or very demanding local regulations.
Always take expert advise and be clear on what you are trying to achieve and why. Again, your local Water Company can probably offer good and impartial advice and your chemical supplier and screen printing supply company should also be in a good position to assist you.
Various approaches can be used to treat waste water in-house, prior to discharge. These include settlement tanks, chemical treatment (pH adjustment, flocculation and coagulation), filtration , centrifrugal filtration and carbon absorption of organic materials. Many printers fall into the trap of purchasing complex equipment which will ‘over-treat’ their waste water, i.e. remove solids through flocculation/coagulation and filtration and adjust the pH level when all that is required is pH adjustment to ensure compliance.
The waste water from this process will always be alkali due to the caustic chemicals used in these types of cleaning products. Using lower caustic haze removers, and those that can be left on the mesh overnight to dry, can minimise the pH of the waste water from this process. If you want to reduce the COD, apply the minimum amount of haze remover and if possible use a coating trough to apply the haze remover to the mesh. The pH of this process can be neutralised by holding back the waste water in a tank along with water from washing out and decoating screens prior to discharging to the sewer.