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WATER DEMINERALIZATION
 Demineralization is the removal of essentially all
inorganic salts. In ion exchange demineralization
hydrogen Cation exchange converts dissolved
salts to their corresponding acids, and basic
anion exchange removes these acids.
 Purpose
 Removal of ionic substances
 Reduction of conductivity
 Control of pH
Demineraliser Resins
 Cationic resins exchange positively charged functional
groups, for undesirable positive ions.
 With their functional groups in the hydrogen form, R – H,
“R” represents the exchange resin and “H” represents the
attached hydrogen ion.
 Anionic resins exchange negatively charged functional
groups for any undesirable negative ion.
 The hydroxyl ion, OH- (R—OH) is commonly used as the
functional group in an anion resin.
Principle Of Demineralization
 The demineralizer system consists of one or
more ion exchange resin columns, including a
strong Cation unit and a strong anion unit. The
Cation resins exchange hydrogen for raw water
cations as shown below:
 The anion resins exchange hydroxyl for raw water
anions.
 In the example, the acids resulting from the Cation
exchange process react with the anion exchange
resin. As a result we form water and the anions are
embedded into the resin.
 Other weak acids are also removed because the resin
is strongly basic.
Ion Exchange Reaction
water.freshformresult weaAssolution.inionsby the
exchangedareresintheinionsthat theisresultnetThe
RR
:followsasisreactionnetThe
arrow.by theindicatedasreactionreversibleaisThis
H
:waterformto
combineresinzingdemineraliby thereleasedionsThe
ions.chlorideandionssodiumform
tosdissociateitwaterindissolvedisNaClWhen
--
2
2





 
OHHClRNaClNaOHRH
OHOH
ClNaNaCl OH
REGENERATION
 Cation exchange resins are regenerated by
treatment with hydrochloric or sulfuric acid,
then washing with water.
 Anion exchange resins are regenerated by
treatment with sodium hydroxide (NaOH), then
washing with water.
Fig Showing:
Demineralizer

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Waterdemineralization 160510120537

  • 2.  Demineralization is the removal of essentially all inorganic salts. In ion exchange demineralization hydrogen Cation exchange converts dissolved salts to their corresponding acids, and basic anion exchange removes these acids.  Purpose  Removal of ionic substances  Reduction of conductivity  Control of pH
  • 3.
  • 4. Demineraliser Resins  Cationic resins exchange positively charged functional groups, for undesirable positive ions.  With their functional groups in the hydrogen form, R – H, “R” represents the exchange resin and “H” represents the attached hydrogen ion.  Anionic resins exchange negatively charged functional groups for any undesirable negative ion.  The hydroxyl ion, OH- (R—OH) is commonly used as the functional group in an anion resin.
  • 5. Principle Of Demineralization  The demineralizer system consists of one or more ion exchange resin columns, including a strong Cation unit and a strong anion unit. The Cation resins exchange hydrogen for raw water cations as shown below:
  • 6.  The anion resins exchange hydroxyl for raw water anions.  In the example, the acids resulting from the Cation exchange process react with the anion exchange resin. As a result we form water and the anions are embedded into the resin.  Other weak acids are also removed because the resin is strongly basic.
  • 7. Ion Exchange Reaction water.freshformresult weaAssolution.inionsby the exchangedareresintheinionsthat theisresultnetThe RR :followsasisreactionnetThe arrow.by theindicatedasreactionreversibleaisThis H :waterformto combineresinzingdemineraliby thereleasedionsThe ions.chlorideandionssodiumform tosdissociateitwaterindissolvedisNaClWhen -- 2 2        OHHClRNaClNaOHRH OHOH ClNaNaCl OH
  • 8.
  • 9. REGENERATION  Cation exchange resins are regenerated by treatment with hydrochloric or sulfuric acid, then washing with water.  Anion exchange resins are regenerated by treatment with sodium hydroxide (NaOH), then washing with water.
  • 10.