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Investigation on Composite of Aluminium
admixture with Lithium and Alkali Resistant
Glass Fiber for the Application of Ship
Building Materials
2
3rd Year
Mechanical
Engineering
M.KUMARASAMY COLLEGE
OF ENGINEERING
(An Autonomous Institution)
Investigation on Composite of Aluminium 5383
admixture with Lithium and Alkali Resistant Glass
Fiber for the Application of Ship Building Materials
SUBMITTED BY:
TAMILSELVAN M (13BME2204)
VIGNESHWARAN K (13BME2223)
RAM KUMAR P (13BME2239)
SANJEEVI KANNAN S (13BME2343)
GUIDED BY:
Mr.M.VALLIAPPAN,
Assistant Professor,
Mechanical Department,
M.Kumarasamy College
of Engineering,
Thalavapalayam, Karur-
639113.
COMPOSITES MATERIAL
What is a Composite?
• A composite material can be
defined as a combination of
a matrix and a
reinforcement.
• which when combined gives
properties superior to the
properties of the individual
components.
• The primary reason
composite materials are
chosen for components is
because of weight saving for
its relative stiffness and
strength
Why Use Composites?
COMPOSITION
Metal matrix composites
(MMC)
• MMC provides higher yield
strength and modulus than
the polymers.
• In our project we use two
metal matrix composites
are:
• Aluminium5383 alloy-
H116 grade.
• Lithium
Fiber Reinforcement
• Fibers are responsible for
high strength and stiffness
ratio to weight of the
composite.
• In our project we only one
fiber that is:
• Alkali Resistance Glass
Fiber (ARGF)
Aluminium5383 alloy-H116 grade
Chemical composition
Element Content (%)
Aluminum, Al 91.9 - 95.3
Magnesium, Mg 4- 5.2
Manganese, Mn 0.70 – 1
Zinc, Zn ≤ 0.40
Silicon, Si ≤ 0.25
Iron, Fe ≤ 0.25
Chromium, Cr ≤ 0.25
Copper, Cu ≤ 0.20
Zirconium, Zr ≤ 0.20
Titanium, Ti ≤ 0.15
Remainder (each) ≤ 0.050
Remainder (total) ≤ 0.15
Mechanical properties
Properties Metric
Tensile strength 305 MPa
Yield strength 220 MPa
Elongation at break 10%
Shear modulus 26.4 GPa
Poisson’s ratio 0.33
Physical Properties
Properties Metric
Density 2.66 g/cm³
Melting point 585 - 641°C
Thermal expansion co-
efficient (@20-
100°C/68-212°F)
23.8 µm/m°C
Thermal conductivity 117 W/mK
LITHIUM
PROPERTIES VALUE
Atomic number 3
Atomic mass 6.941 g.mol -1
Electro negativity according to
Pauling
1.0
Density 0.53 g.cm -3 at 20 °C
Melting point 180.5 °C
Boiling point 1342 °C
Vanderwaals radius 0.145 nm
Ionic radius 0.06 nm
Isotopes 2
Electronic shell 1s22s1 or [He] 2s1
Energy of first ionisation 520.1 kJ.mol -1
Standard potential - 3.02 V
Discovered by Johann Arfvedson in 1817
ALKALI RESISTANCE GLASS FIBER
Characteristics Value
Appearance White or off-white
Physical State Solid
Softening point 860ºC (1580ºF)
Melting point non applicable
Decomposition
temperature
size and mat binders start
to decompose at 200ºC
Density 2.6 (water = 1)
Water solubility insoluble
Moisture Content < 0.6% (ISO 3344)
Aluminium5383 alloy-H116 grade
• In our mini project , we added 97.5% aluminium
5383 alloy- H116 grade as an metal matrix
composites.
• We added 1950g Al 5383 alloy for 2Kg composite
COMPOSITES MATERIALS
LITHIUM
• Lithium we used 1.8%.
• For that we added 36g for
2kg composites.
AR- Glass Fiber
• ARGF we used 0.7%.
• For that we added 14g for
2kg composites.
Metal Pouring into Stir casting
Machine
Step 1:
Initially , we added 1950g bare
aluminium 5383 alloy in stir casting
machine.
CASTING
Step 2:
we heated aluminium 5383 alloy upto 750ºC ,
then we added lithium alloy at 165ºC also
addition to that alkali resistance glass fiber will
directly added into aluminium 5383 alloy.
MOULDING CAVITY
Step 3:
After mixture aluminium 5383 alloy with
lithium and ARGF, stirring was done at 600rpm.
Finally mixture of liquid composites will filled in
die cavity
MOLTEN METAL
Step 4:
After that the molten metal can be
taken from die cavity.
MACHINING
BRINELL HARDNESS TEST CHARPY IMPACT TEST
MACHINING
ROCKWELL HARDNESS
TEST DOUBLE SHEAR TEST
Nacl
CORROSION RESISTANCE TEST
• Nacl-5% , 10gm for 200ml test
• Pure water -95%, 190ml for
200ml test
• Initial weight of
specimen=25.980g
• Final weight of specimen=26.32g
• Observation time=185hrs.
• FORMULA:
• weight loss percentage = [(Initial
weight - Final Weight) / initial
weight]*100
• weight loss percentage=-13.086%
Hcl
CORROSION
RESISTANCE TEST
• Hcl-0.5M , 8.5ml for 200ml test
• Pure water -191.5ml for 200ml
test
• Initial weight of
specimen=25.670g
• Final weight of
specimen=23.12g
• Observation time=185hrs.
• FORMULA:
• weight loss percentage = [(Initial
weight - Final Weight) / initial
weight]*100
• weight loss percentage=9.993%
BRINELL HARDNESS TEST
Type of indenter = 1/16 inch ball indenter
Diameter of indenter D= 2.5mm
S.NO Specimen Load applied(p)
Kg F
Diammeter of
Impression
(d)mm
Area (A)
mm²
Brinell Hardness
number
kg/mm²
1 Aluminium5383+lithium
+alkali resistance glass
fiber
187.5 1.4 1.6 111.357259
ROCKWELL HARDNESS TEST
S.No Specimen Load Indenter Trial1 Trial2 Average
hardness
1 Aluminium
5383+lithium
+GRP
100 Ball and
1/16inch
20 25 22.5
CHARPY IMPACT TEST
S.No Specimen Width(mm) Depth(mm)
{below
nothch}
Area
(mm²)
Frictional
Energy(J)
Energy spent
in
Breaking(J)
Energy
Absorbed
by
Specimen
(J)
1 Aluminium
5383+
lithium+
GRP
10 6 60 6 10 4
DOUBLE SHEAR TEST
• Material of specimen = Aluminium 5383+ lithium+ ARGF
• Diameter of rod(d)= 20mm
• Cross sectional area of the rod(A)=314mm²
• Load at failure(W)=75.80N
• Ultimate Double shear stress (Z) = W/2A N/mm²
• Z = (75.08)/(2*314)
• Z = 0.1195 N/mm²
CONCLUSION
• In this work 1.8% of lithium is mixed with 97.5% of
aluminium5383 alloy-h116 grade and added with 0.7% of alkali
resistance glass fiber can successfully fabricated by using stir
casting machine.
• Then moulding material could be machined to get perfect shape for
further testing.
• We done Brinell hardness testing and get 111.357259kg/mm²
hardness value.
• Then we done rockwell hardness testing and get 22.5HRB.
• Then we done charpy impact test and get energy absorption of
specimen is 4J
• Then we done double shear stress test , load failure take place at
75.80N.
• Then we done corrosion test by using 5% of Nacl in an observation
of 20hrs, in that the is no weight loss occurred .
• When every 1% of lithium is added with an material, its total weight
will be reduced 3%.
• When an AR-Glass fiber is mixed with aluminium 5383 alloy to
increases the corrosion resistance compare to bare aluminium.
REFERENCES
1) Rajeshkumar Gangaram Bhandare, Parshuram M. Sonawane , "Preparation of Aluminium Matrix
Composite by Using StirCasting Method" , international Journal of Engineering and Advanced Technology
(IJEAT) ISSN: 2249 – 8958, Volume-3, Issue-2, December 2013
2) J. White, I. Hughes, T. Willis, R. Jordan "METAL MATRIX COMPOSITES BASED ON ALUMINIUM
LITHIUM AND SILICON CARBIDE" HAL Id: jpa-00226571 ,https://hal.archives-ouvertes.fr/jpa-
00226571.
3) Mathivanan Periasamya*, Balakrishnan Manickamb, Krishnan Hariharasubramanian , "Impact Properties
of Aluminium – Glass Fiber Reinforced Plastics Sandwich Panels", Materials Research. 2012; 15(3): 347-
354,
DOI: 10.1590/S1516-14392012005000036.
4) G. G. Sozhamannan1*, S. Balasivanandha Prabu2, V. S. K. Venkatagalapathy1 " Effect of Processing
Paramters on Metal Matrix Composites: Stir Casting Process ", Journal of Surface Engineered Materials
and Advanced Technology, 2012, 2, 1115 http://dx.doi.org/10.4236/jsemat.2012.21002 Published Online
January 2012 (http://www.SciRP.org/journal/jsemat)
5) RADM Brian M. Salerno,U. S. Coast Guard Assistant Commandant,Assistant Commandant for Marine Safety,
Security and StewardshipChairman, Ship Structure Committee" ALUMINUM STRUCTURE DESIGN AND
FABRICATION GUIDE"SSC-452
, NTIS # PB2007
6) Cindie Giummarra, Bruce Thomas and Roberto J. Rioja, "NEW ALUMINUM LITHIUM ALLOYS FOR
AEROSPACE APPLICATIONS", Proceedings of the Light Metals Technology Conference 2007.

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Investigation on composite of aluminium 5383 admixture with lithium and alkali resistant glass fiber for the application of ship building materials

  • 1.
  • 2. Investigation on Composite of Aluminium admixture with Lithium and Alkali Resistant Glass Fiber for the Application of Ship Building Materials 2 3rd Year Mechanical Engineering M.KUMARASAMY COLLEGE OF ENGINEERING (An Autonomous Institution)
  • 3. Investigation on Composite of Aluminium 5383 admixture with Lithium and Alkali Resistant Glass Fiber for the Application of Ship Building Materials SUBMITTED BY: TAMILSELVAN M (13BME2204) VIGNESHWARAN K (13BME2223) RAM KUMAR P (13BME2239) SANJEEVI KANNAN S (13BME2343) GUIDED BY: Mr.M.VALLIAPPAN, Assistant Professor, Mechanical Department, M.Kumarasamy College of Engineering, Thalavapalayam, Karur- 639113.
  • 4. COMPOSITES MATERIAL What is a Composite? • A composite material can be defined as a combination of a matrix and a reinforcement. • which when combined gives properties superior to the properties of the individual components. • The primary reason composite materials are chosen for components is because of weight saving for its relative stiffness and strength Why Use Composites?
  • 5. COMPOSITION Metal matrix composites (MMC) • MMC provides higher yield strength and modulus than the polymers. • In our project we use two metal matrix composites are: • Aluminium5383 alloy- H116 grade. • Lithium Fiber Reinforcement • Fibers are responsible for high strength and stiffness ratio to weight of the composite. • In our project we only one fiber that is: • Alkali Resistance Glass Fiber (ARGF)
  • 6. Aluminium5383 alloy-H116 grade Chemical composition Element Content (%) Aluminum, Al 91.9 - 95.3 Magnesium, Mg 4- 5.2 Manganese, Mn 0.70 – 1 Zinc, Zn ≤ 0.40 Silicon, Si ≤ 0.25 Iron, Fe ≤ 0.25 Chromium, Cr ≤ 0.25 Copper, Cu ≤ 0.20 Zirconium, Zr ≤ 0.20 Titanium, Ti ≤ 0.15 Remainder (each) ≤ 0.050 Remainder (total) ≤ 0.15 Mechanical properties Properties Metric Tensile strength 305 MPa Yield strength 220 MPa Elongation at break 10% Shear modulus 26.4 GPa Poisson’s ratio 0.33 Physical Properties Properties Metric Density 2.66 g/cm³ Melting point 585 - 641°C Thermal expansion co- efficient (@20- 100°C/68-212°F) 23.8 µm/m°C Thermal conductivity 117 W/mK
  • 7. LITHIUM PROPERTIES VALUE Atomic number 3 Atomic mass 6.941 g.mol -1 Electro negativity according to Pauling 1.0 Density 0.53 g.cm -3 at 20 °C Melting point 180.5 °C Boiling point 1342 °C Vanderwaals radius 0.145 nm Ionic radius 0.06 nm Isotopes 2 Electronic shell 1s22s1 or [He] 2s1 Energy of first ionisation 520.1 kJ.mol -1 Standard potential - 3.02 V Discovered by Johann Arfvedson in 1817
  • 8. ALKALI RESISTANCE GLASS FIBER Characteristics Value Appearance White or off-white Physical State Solid Softening point 860ºC (1580ºF) Melting point non applicable Decomposition temperature size and mat binders start to decompose at 200ºC Density 2.6 (water = 1) Water solubility insoluble Moisture Content < 0.6% (ISO 3344)
  • 9. Aluminium5383 alloy-H116 grade • In our mini project , we added 97.5% aluminium 5383 alloy- H116 grade as an metal matrix composites. • We added 1950g Al 5383 alloy for 2Kg composite
  • 10. COMPOSITES MATERIALS LITHIUM • Lithium we used 1.8%. • For that we added 36g for 2kg composites. AR- Glass Fiber • ARGF we used 0.7%. • For that we added 14g for 2kg composites.
  • 11. Metal Pouring into Stir casting Machine Step 1: Initially , we added 1950g bare aluminium 5383 alloy in stir casting machine.
  • 12. CASTING Step 2: we heated aluminium 5383 alloy upto 750ºC , then we added lithium alloy at 165ºC also addition to that alkali resistance glass fiber will directly added into aluminium 5383 alloy.
  • 13. MOULDING CAVITY Step 3: After mixture aluminium 5383 alloy with lithium and ARGF, stirring was done at 600rpm. Finally mixture of liquid composites will filled in die cavity
  • 14. MOLTEN METAL Step 4: After that the molten metal can be taken from die cavity.
  • 15. MACHINING BRINELL HARDNESS TEST CHARPY IMPACT TEST
  • 17. Nacl CORROSION RESISTANCE TEST • Nacl-5% , 10gm for 200ml test • Pure water -95%, 190ml for 200ml test • Initial weight of specimen=25.980g • Final weight of specimen=26.32g • Observation time=185hrs. • FORMULA: • weight loss percentage = [(Initial weight - Final Weight) / initial weight]*100 • weight loss percentage=-13.086%
  • 18. Hcl CORROSION RESISTANCE TEST • Hcl-0.5M , 8.5ml for 200ml test • Pure water -191.5ml for 200ml test • Initial weight of specimen=25.670g • Final weight of specimen=23.12g • Observation time=185hrs. • FORMULA: • weight loss percentage = [(Initial weight - Final Weight) / initial weight]*100 • weight loss percentage=9.993%
  • 19. BRINELL HARDNESS TEST Type of indenter = 1/16 inch ball indenter Diameter of indenter D= 2.5mm S.NO Specimen Load applied(p) Kg F Diammeter of Impression (d)mm Area (A) mm² Brinell Hardness number kg/mm² 1 Aluminium5383+lithium +alkali resistance glass fiber 187.5 1.4 1.6 111.357259
  • 20. ROCKWELL HARDNESS TEST S.No Specimen Load Indenter Trial1 Trial2 Average hardness 1 Aluminium 5383+lithium +GRP 100 Ball and 1/16inch 20 25 22.5
  • 21. CHARPY IMPACT TEST S.No Specimen Width(mm) Depth(mm) {below nothch} Area (mm²) Frictional Energy(J) Energy spent in Breaking(J) Energy Absorbed by Specimen (J) 1 Aluminium 5383+ lithium+ GRP 10 6 60 6 10 4
  • 22. DOUBLE SHEAR TEST • Material of specimen = Aluminium 5383+ lithium+ ARGF • Diameter of rod(d)= 20mm • Cross sectional area of the rod(A)=314mm² • Load at failure(W)=75.80N • Ultimate Double shear stress (Z) = W/2A N/mm² • Z = (75.08)/(2*314) • Z = 0.1195 N/mm²
  • 23. CONCLUSION • In this work 1.8% of lithium is mixed with 97.5% of aluminium5383 alloy-h116 grade and added with 0.7% of alkali resistance glass fiber can successfully fabricated by using stir casting machine. • Then moulding material could be machined to get perfect shape for further testing. • We done Brinell hardness testing and get 111.357259kg/mm² hardness value. • Then we done rockwell hardness testing and get 22.5HRB. • Then we done charpy impact test and get energy absorption of specimen is 4J • Then we done double shear stress test , load failure take place at 75.80N. • Then we done corrosion test by using 5% of Nacl in an observation of 20hrs, in that the is no weight loss occurred . • When every 1% of lithium is added with an material, its total weight will be reduced 3%. • When an AR-Glass fiber is mixed with aluminium 5383 alloy to increases the corrosion resistance compare to bare aluminium.
  • 24. REFERENCES 1) Rajeshkumar Gangaram Bhandare, Parshuram M. Sonawane , "Preparation of Aluminium Matrix Composite by Using StirCasting Method" , international Journal of Engineering and Advanced Technology (IJEAT) ISSN: 2249 – 8958, Volume-3, Issue-2, December 2013 2) J. White, I. Hughes, T. Willis, R. Jordan "METAL MATRIX COMPOSITES BASED ON ALUMINIUM LITHIUM AND SILICON CARBIDE" HAL Id: jpa-00226571 ,https://hal.archives-ouvertes.fr/jpa- 00226571. 3) Mathivanan Periasamya*, Balakrishnan Manickamb, Krishnan Hariharasubramanian , "Impact Properties of Aluminium – Glass Fiber Reinforced Plastics Sandwich Panels", Materials Research. 2012; 15(3): 347- 354, DOI: 10.1590/S1516-14392012005000036. 4) G. G. Sozhamannan1*, S. Balasivanandha Prabu2, V. S. K. Venkatagalapathy1 " Effect of Processing Paramters on Metal Matrix Composites: Stir Casting Process ", Journal of Surface Engineered Materials and Advanced Technology, 2012, 2, 1115 http://dx.doi.org/10.4236/jsemat.2012.21002 Published Online January 2012 (http://www.SciRP.org/journal/jsemat) 5) RADM Brian M. Salerno,U. S. Coast Guard Assistant Commandant,Assistant Commandant for Marine Safety, Security and StewardshipChairman, Ship Structure Committee" ALUMINUM STRUCTURE DESIGN AND FABRICATION GUIDE"SSC-452 , NTIS # PB2007 6) Cindie Giummarra, Bruce Thomas and Roberto J. Rioja, "NEW ALUMINUM LITHIUM ALLOYS FOR AEROSPACE APPLICATIONS", Proceedings of the Light Metals Technology Conference 2007.