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History &
Classification of the Periodic Table
1. Fast facts & most abundant element
2. Atomic model Time Line
3. History of Periodic Table
I. Democritus 400BC
II. Aristotle 350BC
III. Johann Dobereiner’s Triads 1829
IV. John Newlands law of Octaves 1864
V. Dmitri Mendeleev Law-Atomic mass 1869
VI. Henry Moseley- Atomic Number 1913
4. Classification of Periodic Table
Periods, Groups, Metals, Nonmetals and Metalloids
JOGA SURI BABU
Assistant Professor
Vishnu Institute of Technology
Bhimavarm
History of the Periodic Table
• Fast facts
• 94 naturally occurring elements
• 24 Synthetic elements
• Oxygen is most abundant element
• Tie together properties that make metals,
metals and non-metals, nonmetals
• Early 1800’s scientists started to note
relationships between certain elements and
their atomic masses
• Classification of elements began using these
similarities
S. No Discovery Year Total Elements
1 Democritus 400BC ATOM
2 Aristotle 350BC 4 elements (Air, Fire, Earth, Water)
3 Johann Dobereiner’s Triads 1829 40
4 John Newlands law of Octaves 1864 56
5 Dmitri Mendeleev Law-Atomic mass 1869 63
6 Henry Moseley- Atomic Number 1913 118
• Dobereiner @40 known elements
• First scientist to observe an important trend
• Noticed certain groups of three elements
had similar physical and chemical
properties but different masses
• Called them TRIADS
• Ex. Li,Na,K Cl,Br,I Cu,Ag,Au Be,Mg,Ca
1). Dobereiner’s triads (1829)
Limitations of Dobereiner’s triads
It’s triads applicable for only few elements. It was not applicable
for all the 30+ known elements.
• mid 1800’s
• 56 @ known elements
• Noted connection of properties and mass were a
repeating pattern in order of increasing mass
• Every 8th element had similar properties(Dobereiner’s
Triads)
• Didn’t know about Noble gases
• Called it Law of Octaves
• Problems occurred as more elements were discovered and
did not fit pattern
• During this time, 56 elements were discovered. He
arranged these known elements in the increasing order of
their ATOMIC MASS.
2). Newland’s law of octaves (1864)
Statement of Newland’s law:
If elements are arranged in the increasing order of
their atomic mass, then the property of every eight
elements (starting from the first element) repeats.
Limitations of Newlands law of octaves
•Similarity in properties as per the law was seen up to calcium
only.
•He stated that only 56 elements exist in nature. But later on,
he was proved wrong and many more elements were
discovered.
•Dissimilar elements were placed in the same slot.
•Similar elements were placed in different slots.
• Mendeleev 1860’s @ 63 known elements
• Father of Periodic Table (P.T.)
• Developed table that showed relationship between
properties of elements and atomic masses
• Remember: the only thing known about atoms is?
• Dalton’s Theories
• No e- or p+
• Carefully planned and in great detail
• Avoided earlier mistakes of forcing elements to fit into
8 pattern like Newland
3). Mendeleev law (1869)
Mendeleev law:
The properties of elements are the periodic functions of
theirs atomic masses
This table is known as the Mendeleev periodic table of elements.
• Believed similar properties occurred after periods that
could vary in length by specific patterns
• Left blank spaces on table were an element did not fit ( did
not force elements in) properties
• Predicted that spaces were undiscovered elements
• Predicted masses and properties of unknowns
• Elements discovered were very close to predictions
• Elements properties repeated in an orderly way
• 1st Periodic Law: properties of the elements are
a periodic function of their increasing atomic
masses
• Mosley explained exceptions with discovery of
Atomic Number
• Modern Periodic Law: properties of the
elements are a periodic function of their
increasing atomic number
Mendeleev law:
The properties of elements are the periodic functions
of theirs atomic masses
4). Modern Periodic Law (1913)
• The properties of the elements are the Periodic
function of their ATOMIC NUMBERS.
Modern Periodic Law was given by Henry Moseley in 1913.
•Mandeleev law says that the properties of elements are the
functions of their atomic mass. While,
•Modern periodic law says that the properties of elements are
the Periodic function of their atomic number.
• Using a P.T.
• Elements arranged in horizontal rows in
order of increasing atomic number
• 5 things found on every P.T.
• 1. Symbol of element
• 2. Atomic number of element
• 3. Atomic mass of element
• 4. 7 periods
• 5. 18 groups and 2 series
Periods in Periodic table:
The periods are the horizontal rows.
There are 7 horizontal rows.
1st Period
2nd Period
3rd Period
4th Period
5th Period
6th Period
7th Period
1. Vertical columns are called GROUPS,1- 18
2. Share similar chemical and physical properties
3. Number of valence e- in a Group are all the same
4. Same ending ECN
5. Only difference is the number of energy levels
MOSELY MODREN LONG PERIODIC TABLE
https://periodictableguide.com/periodic-table-of-
elements/#google_vignette
• An atoms chemical properties are based on
its ending ECN
• Can use the table to read an elements ECN
• Group 1 all end in s1
• Group 2 all end in s2
• Called the s-block
• Transition elements all end in a d (1-10)
• Called d-block
• Groups 13-18 all end in p (1-6)
• Called p-block
• Lathanoids and Actinoids all end in f (1-14)
• Some ECN’s are not what expect however
• Due to the added stability by the
rearrangement of the e- in the outer
sublevels
• Some ECN’s are modified
• Due to stability factors
• Ex. Cr 1s2 2s2 2p6 3s2 3p6 4s2 3d4
• Changes to 1s2 2s2 2p6 3s2 3p6 4s1 3d5
• Half-filled or completely filled sublevels are
more stable than incompletely filled
sublevels
• Due to e- spin and distribution
• Only occurs in incomplete d and f filling
sublevels
• Octet Rule
• When there are 8e- in the outer energy level
of an atom s2p6, the atom is rendered
unreactive
• Atoms react with each other because the
resulting system is more stable after the
reaction than before
• ECN is one of the most important factors
leading to atom stability
• Atoms want to achieve s2p6 (Noble Gas
configuration)
Metals
• Shiny (luster)
• Hard
• Conduct electricity and heat well
• Malleable
• Ductile
• Generally have three or fewer e- in their valance
levels
• Tend to lose e- in the bonding process
• https://periodictableguide.com/all-periodic-
trends-in-periodic-table/
Non-metals
• Brittle
• No luster
• Do not conduct heat and electricity
• Generally have 5 or more e- in their valence shell
• Tend to gain or share e- in the bonding process
Metalloids
Share some of but not all of the characteristics of both metals
and non-metals
History of the Periodic Table SURI BABU JOGA.ppt
History of the Periodic Table SURI BABU JOGA.ppt
History of the Periodic Table SURI BABU JOGA.ppt

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History of the Periodic Table SURI BABU JOGA.ppt

  • 1. History & Classification of the Periodic Table 1. Fast facts & most abundant element 2. Atomic model Time Line 3. History of Periodic Table I. Democritus 400BC II. Aristotle 350BC III. Johann Dobereiner’s Triads 1829 IV. John Newlands law of Octaves 1864 V. Dmitri Mendeleev Law-Atomic mass 1869 VI. Henry Moseley- Atomic Number 1913 4. Classification of Periodic Table Periods, Groups, Metals, Nonmetals and Metalloids JOGA SURI BABU Assistant Professor Vishnu Institute of Technology Bhimavarm
  • 2. History of the Periodic Table
  • 3. • Fast facts • 94 naturally occurring elements • 24 Synthetic elements • Oxygen is most abundant element • Tie together properties that make metals, metals and non-metals, nonmetals • Early 1800’s scientists started to note relationships between certain elements and their atomic masses • Classification of elements began using these similarities
  • 4.
  • 5.
  • 6.
  • 7. S. No Discovery Year Total Elements 1 Democritus 400BC ATOM 2 Aristotle 350BC 4 elements (Air, Fire, Earth, Water) 3 Johann Dobereiner’s Triads 1829 40 4 John Newlands law of Octaves 1864 56 5 Dmitri Mendeleev Law-Atomic mass 1869 63 6 Henry Moseley- Atomic Number 1913 118
  • 8.
  • 9.
  • 10. • Dobereiner @40 known elements • First scientist to observe an important trend • Noticed certain groups of three elements had similar physical and chemical properties but different masses • Called them TRIADS • Ex. Li,Na,K Cl,Br,I Cu,Ag,Au Be,Mg,Ca 1). Dobereiner’s triads (1829)
  • 11.
  • 12. Limitations of Dobereiner’s triads It’s triads applicable for only few elements. It was not applicable for all the 30+ known elements.
  • 13. • mid 1800’s • 56 @ known elements • Noted connection of properties and mass were a repeating pattern in order of increasing mass • Every 8th element had similar properties(Dobereiner’s Triads) • Didn’t know about Noble gases • Called it Law of Octaves • Problems occurred as more elements were discovered and did not fit pattern • During this time, 56 elements were discovered. He arranged these known elements in the increasing order of their ATOMIC MASS. 2). Newland’s law of octaves (1864)
  • 14.
  • 15. Statement of Newland’s law: If elements are arranged in the increasing order of their atomic mass, then the property of every eight elements (starting from the first element) repeats. Limitations of Newlands law of octaves •Similarity in properties as per the law was seen up to calcium only. •He stated that only 56 elements exist in nature. But later on, he was proved wrong and many more elements were discovered. •Dissimilar elements were placed in the same slot. •Similar elements were placed in different slots.
  • 16. • Mendeleev 1860’s @ 63 known elements • Father of Periodic Table (P.T.) • Developed table that showed relationship between properties of elements and atomic masses • Remember: the only thing known about atoms is? • Dalton’s Theories • No e- or p+ • Carefully planned and in great detail • Avoided earlier mistakes of forcing elements to fit into 8 pattern like Newland 3). Mendeleev law (1869) Mendeleev law: The properties of elements are the periodic functions of theirs atomic masses
  • 17. This table is known as the Mendeleev periodic table of elements.
  • 18.
  • 19. • Believed similar properties occurred after periods that could vary in length by specific patterns • Left blank spaces on table were an element did not fit ( did not force elements in) properties • Predicted that spaces were undiscovered elements • Predicted masses and properties of unknowns • Elements discovered were very close to predictions • Elements properties repeated in an orderly way
  • 20. • 1st Periodic Law: properties of the elements are a periodic function of their increasing atomic masses • Mosley explained exceptions with discovery of Atomic Number • Modern Periodic Law: properties of the elements are a periodic function of their increasing atomic number Mendeleev law: The properties of elements are the periodic functions of theirs atomic masses
  • 21. 4). Modern Periodic Law (1913) • The properties of the elements are the Periodic function of their ATOMIC NUMBERS. Modern Periodic Law was given by Henry Moseley in 1913. •Mandeleev law says that the properties of elements are the functions of their atomic mass. While, •Modern periodic law says that the properties of elements are the Periodic function of their atomic number.
  • 22. • Using a P.T. • Elements arranged in horizontal rows in order of increasing atomic number • 5 things found on every P.T. • 1. Symbol of element • 2. Atomic number of element • 3. Atomic mass of element • 4. 7 periods • 5. 18 groups and 2 series
  • 23. Periods in Periodic table: The periods are the horizontal rows. There are 7 horizontal rows. 1st Period 2nd Period 3rd Period 4th Period 5th Period 6th Period 7th Period
  • 24. 1. Vertical columns are called GROUPS,1- 18 2. Share similar chemical and physical properties 3. Number of valence e- in a Group are all the same 4. Same ending ECN 5. Only difference is the number of energy levels
  • 25. MOSELY MODREN LONG PERIODIC TABLE
  • 27.
  • 28. • An atoms chemical properties are based on its ending ECN • Can use the table to read an elements ECN • Group 1 all end in s1 • Group 2 all end in s2 • Called the s-block • Transition elements all end in a d (1-10) • Called d-block
  • 29. • Groups 13-18 all end in p (1-6) • Called p-block • Lathanoids and Actinoids all end in f (1-14) • Some ECN’s are not what expect however • Due to the added stability by the rearrangement of the e- in the outer sublevels
  • 30. • Some ECN’s are modified • Due to stability factors • Ex. Cr 1s2 2s2 2p6 3s2 3p6 4s2 3d4 • Changes to 1s2 2s2 2p6 3s2 3p6 4s1 3d5 • Half-filled or completely filled sublevels are more stable than incompletely filled sublevels • Due to e- spin and distribution • Only occurs in incomplete d and f filling sublevels
  • 31. • Octet Rule • When there are 8e- in the outer energy level of an atom s2p6, the atom is rendered unreactive • Atoms react with each other because the resulting system is more stable after the reaction than before • ECN is one of the most important factors leading to atom stability • Atoms want to achieve s2p6 (Noble Gas configuration)
  • 32. Metals • Shiny (luster) • Hard • Conduct electricity and heat well • Malleable • Ductile • Generally have three or fewer e- in their valance levels • Tend to lose e- in the bonding process • https://periodictableguide.com/all-periodic- trends-in-periodic-table/
  • 33. Non-metals • Brittle • No luster • Do not conduct heat and electricity • Generally have 5 or more e- in their valence shell • Tend to gain or share e- in the bonding process Metalloids Share some of but not all of the characteristics of both metals and non-metals