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Shape Memory Alloy Actuated Peristaltic Pump for Use in
Microgravity
PID: 2641S
Toshiba ExploraVision 2013
Maxwell Tucker, Matias Horst, Christopher Zhen, and Catherine Farmer
Mentored by Dr. Myra Halpin
Abstract
In any spacecraft, plumbing is of vital importance. Pump mechanisms used today
in the International Space Station are prone to frequent malfunction due to their large
number of moving parts. We propose an alternate mechanism, a biomimetic pump that
employs peristalsis, the sequenced contraction of segments used by the human digestive
tract. This peristaltic pump would function by using a pipe embedded with Nitinol, a
shape memory alloy actuated by electrically derived resistive heating. In addition, the
walls of the tubing would be surfaced with hydrophobic materials, creating a passive
flow system. This mechanism will entirely eliminate the need for moving parts and
would increase the pump reliability, as such a mechanism would only fail if the tubing
itself breaks. In time, this technology can expanded for use in systems on Earth,
increasing the reliability of pumps everywhere.
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
Present Technology
Plumbing in space is extremely different from plumbing on Earth, chiefly in that the
lack of gravity renders ineffective conventional pumps designed for use in environments with
gravity . To provide running water in space, NASA employs a system of pumps and fans
which coerce liquid to flow in the right direction. While the aforementioned system works
well, the pumps often break or malfunction due to the sheer number of pieces and systems
within the pump system. NASA is forced to take multiple pump systems on each spaceflight,
which takes up valuable space that could be used for other purposes. In addition, fixing a
plumbing problem in space is very difficult. The only way to repair pumps in space is to
haul up spare equipment and perform repairs that take up an astronauts valuable time.
Furthermore, a pipe malfunction in spaceflight can be deadly to the astronauts on board.
Pumps on spacecraft handle a variety of jobs, including heating, cooling, and recycling of
water. Any failures in the system could lead to insufficient water to maintain life support
on the spacecraft. Current small scale pumps, with dozens of moving parts, are often prone
to failure because they tend to wear easily. Even when the pumps are functioning perfectly,
they are inefficient because energy used to actuate the pump is wasted because of friction and
heat in between moving parts [1]. Much of the energy used in current mechanical systems,
especially fans like the ones employed by the pump system, is converted to noise pollution,
a major aggravation and health hazard for astronauts [6].
One of the most essential parts of our pump is Nitinol. Nitinol is a shape memory alloy
(SMA), which has the ability to assume two distinct structures depending on temperature.
This occurs because of a unique change in crystalline structure that occurs when the alloy
is heated past a transition temperature. When at a lower temperature, the alloy is in its
Marstenite crystalline structure, which is an oblong, narrow shape, but when heated, it
transforms to the Austenite structure, which in contrast is a perfect cube. The difference
between these two structures is what causes the unique properties of the alloy. As the
crystalline structure changes, the Nitinol becomes shorter due to the change from the oblong
2
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
to cubic shape [8].
Image showing the various crystalline phases of Nitinol [2].
The Nitinol wire we used in our prototype to use is small in diameter, 0.2mm, and
contracts when heated. Because of its small diameter, the wire has a higher surface-area to
volume ratio and therefore has high resistance. The method we use to actuate our Nitinol
wire is known as Joule heating, or resistive heating, and involves using the resistance of the
wire to generate heat. Because heat is a natural byproduct of electrical current and the
amount of resistance in the wire, the higher the resistance of the wire, the more heat can be
produced.
Another feature that will be implemented in our pump is a hydrophobic tube lining.
This system will passively encourage a degree of flow in the pipe, repelling water from
the internal surface [10]. A wide variety of substances in common use are hydrophobic.
Superhydrophobicity has been created through physical processing of a variety of plastics [9].
Using polyolefin sputter coated in noble metals, researchers have been able to create a
surface of hydrophobic polydimethylsiloxane, which in turn served as a mask for polystyrene,
polycarbonate, and polyethylene. Parallel methods could readily be used to cast frames for
the pump as well as endow superhydrophobicity upon its inner wall. In addition to repulsion
of the water, the surface would function as an antibacterial agent by decreasing adhesion of
bacteria to the walls of the tube and by decreasing the free energy of the system [11]. Given
NASAs closed loop system, minimizing bacterial growth and establishment in the system
3
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
are vital. Current processes exist to modify the inside of tubing for optimal hydrophobicity.
The combination of these technologies, developed through a long history, will continue to
evolve into more efficient future designs.
History
During the millennia since the invention of the first pump, the variety of applications
for this simple tool has widened, necessitating new pump designs. The peristaltic pump,
invented in 1887 by an American doctor, Eugene Allen, was first designed to transfer blood
between patients [4]. Since the internal pump mechanisms did not contact the blood itself,
lysis of the blood cells did not occur. Peristaltic pumps were optimal for applications where
contact between the fluid being pumped and mechanical parts can be either detrimental to
the liquid or the pump mechanism: corrosive chemicals, high viscosity liquids, and biological
substances that are prone to decay [15].
A second invention vital to our project is the shape memory alloy. In 1932, Arne Olan-
der used heat to restore a deformed silver-cadmium alloy to its original shape. A pair of
researchers, Chang and Read, studied the mechanisms behind this transformation nineteen
years later, exploring the transitions between the martensite and austenite crystal struc-
tures through x-ray crystallography. In 1962, the naval ordnance laboratory, led by William
Buehler, focused on designing a number of other alloys, among them an equal molar com-
pound of nickel and titanium. Named Nitinol (Nickel Titanium Naval Ordnance Laboratory),
the substance remains the most commonly used SMA and is used by our prototype [14]. Ac-
tuators employed in peristaltic pumps are often designed out of shape memory alloy, but
rarely employ wave-based motion [16].
NASA’s unsuccessful use of conventional pumping systems on several space flights moti-
vated research into peristaltic pumps. Consequently, several 1986 projects focused on devel-
oping peristaltic pumps for microgravity environments. These new pumps were hermetically
sealed and, unlike previous pumps, had a mechanism to leave the pipes controlled by the
pumps uncompressed in their off state. An extension of this was a piezoelectrically actuated
4
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
peristaltic pump developed in 2004. Using electricity, metal was expanded and contracted
in a specific wave pattern that induced peristaltic flow [5].
Future Technology
The pump which we have designed mimics peristalsis, a mechanism that is used to great
effect in the digestive systems of many organisms. While a number of pumps exist that
use this mechanism, they are only effective in specific situations. Our pump differs from
previous peristaltic pumps in that it more accurately mimics the process used in the body
through the contraction of Nitinol wires. This manner of activation mimics the contraction
of muscles in the body and removes the need for moving parts.
One of the major pitfalls of current technology is the limited contraction of Nitinol wire.
On average, a contraction of about 5% of the total length of the wire can be expected [8] [2].
In our pump design, this limited contraction does not allow for full occlusion of the tubing,
preventing the pump from operating at full efficiency; it will not be very effective when
under the influence of Earth’s gravity. In the future, better SMAs, with more efficient
contractions, may allow the construction of a pump that fully occludes the tubing and thus
prevents backflow entirely. With this improved technology, this type of pump could see
use in almost any conceivable situation, and its high reliability would make it attractive for
almost any application in which pumping is necessary.
The development of a readily applicable superhydrophobic surface for the interior of our
pipe will have progressed notably over the next twenty years. A multitude of fields exist that
may lead to the development of hydrophobic surfaces. Self-assembling monolayers offer a
relatively high-cost, yet high-value, method for chemically generating hydrophobic surfaces.
Xerogels, a type of solidified silicon-based gels, promise to be more long-lasting as a means of
hydrophobic coating [12]. Fluoropolymers, another readily applicable hydrophobic surface,
are very low-cost, pliable, and flexible in application; however, recent concerns over their
potential toxicity removes them from consideration as a reasonable chemical family [17].
Future developments may include either safe fluoropolymers or another plastic with similar
5
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
properties. Present technologies allow physical modification of some plastics to generate
hydrophobicity; if these technologies are simplified and made applicable to more plastics,
then they can be employed on the peristaltic pump [9].
Another technology that must be improved upon is the embedding of SMA wire into
rubber tubing. Currently, there are very few examples of wire embedded tubing. Those
that do exist are largely used in the medical field and are too rigid to be useful in this
application. Therefore, significant research must be done to create tubing which is both
flexible and embedded with a shape memory alloy. Furthermore, it is important to consider
the placement of SMA wire in the tubing. A pattern will need to be devised which delivers
the best compromise of force and contraction, allowing for the most efficient movement of
fluids through the pump mechanism.
Breakthroughs
Although NASA recognizes that there could be improvements to both the efficiency and
reliability and our product idea addresses both concerns, there are several problems that
must be addressed for peristaltic pumps to become a viable solution in space and perhaps
even Earth. These problems are not simple design problems and will require technological
breakthroughs that we hope will be available in the future. The biggest obstacle in the way
of our pipe is the low efficiency of our SMA wire. As we previously explained, SMAs are
specially made metals which have two crystalline structures that vary based on temperature
and stress. This change from the martensite to the austenite crystalline structure when the
SMA is heated causes the change in shape or, in our case, contraction. The only problem
with this is that the maximum contraction for the most efficient SMA, nickel-titanium, is
only around 8 percent before any deformation is permanent [2]. This 8 percent is definitely
not ideal for use in our peristaltic pump and in the future, scientists may discover more
efficient SMAs that deliver more contraction. Another problem with current SMAs is that
because they deform with heat and need to cool back down to change back to their original
shape, SMAs change shape very slowly. Though the heating process is very quick, the cooling
6
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
process is significantly slower and, for the purposes of the pump, the wire takes too long to
expand. In our pump, this would be a problem because it would limit the amount of water
flowing through the tube and the speed of the water current. Ideally, in the future there will
be an SMA with a lower activation temperature which would take less heat and, as a result,
time to contract and expand. SMAs are a relatively new technology and can be improved
with some more research.
Other than the actual SMA wire that we use there are several other things that we could
improve with further research. One problem that we ran into while designing a prototype
was that if the wire was wrapped too tightly around the piping, the wire would come in
contact with itself, causing the system to short-circuit and not function correctly. This can
be solved if we find an effective insulator that would prevent the transfer of electricity, but at
the same time, be able to expand and contract with the wire. This electrical insulator would
also have to allow heat to pass through so that it does not interfere with the cooling and
heating of the wire. The final area of improvement is finding suitable piping material. The
actual material for the pipe needs to be both strong and easily compressible. Though there
are materials that satisfy our needs right now to an extent, such as certain types of Tygon
and rubber tubing, as technology advances, there will be new materials that are stronger
and more flexible which would improve our pipe. Similarly, since our final idea involves a
piping that already includes the SMA wire wrapped and embedded inside, in the future, a
pipe like this can be mass-produced to make it more efficient and cost-effective.
Design Process
Before arriving at our current idea of using a SMA-embedded pipe in a peristaltic pump
we considered several other possibilities that would accomplish our task of efficiently trans-
porting water in microgravity. First, we attempted to develop passive control mechanisms
for water. The polar liquid exhibits remarkable properties on earth due to its cohesive and
adhesive nature. By manipulating the hydrophobicity and hydrophilicity of the surfaces,
7
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
we can control the flow of the liquid. Recent research into amphipathic films allowed de-
velopment of surfaces to collect atmospheric moisture. A cylindrical pipe, the interior of
which was coated with a hydrophobic substance, such a self assembled monolayer, would
repel water. If a core composed of another extremely hydrophobic substance were threaded
through this pipe, positive pressure away from the center and towards the wall of the pipe
would develop; countered by the effect of the hydrophobic pipe wall, water would be force
out of the tube. Whenever water was removed from this pump system, water from elsewhere
would be repelled from its location and would diffuse towards the newly opened volume .
However, this design is not optimal for several reasons. First, it is only optimal for water
and only functional for polar liquids. Common coolants, such as liquid nitrogen, as well as
certain substances necessary for atmospheric controls, such as liquid oxygen, are nonpolar;
this system would be useless for controlling their movement. Additionally, this system ex-
hibits exceedingly passive control over the liquid. Pressure is sufficiently minimal the that
backflow becomes a problem; if outside forces oppose the flow of the liquid, this pump design
lacks the force to oppose.
Our next development was the use of shape memory alloys to cause the flow of water
through a segment of tubing via peristalsis. This mechanism was inspired by the natural
movement of earthworms and research on autonomous worm-like robots from MIT [7].
The MIT Meshworm, which uses SMA wire and peristaltic movement to propel itself.
However, the contraction of Nitinol at this time is not sufficient to cause peristaltic
movement when simply wrapped around the a segment of tubing. This lead us to our next
design iteration. Though this design would be very efficient because contraction from Nitinol
wire around the pump would act in all directions, pressing both down along the pump as
8
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
well as contracting it sideways. This type of contraction would be ideal because, taking
advantage of waters adhesion and cohesion, a contraction of the pump along its horizontal
axis would aid contraction in the vertical direction move the water. A major problem that
we ran into is that having the wire wrapped around the outside of the wire would be an
electrical hazard. Since the Nitinol wire is being actuated by an electrical current, having
electricity flowing along an exposed wire on the outside of a pump would be a problem
as it could come in contact with other parts of the spacecraft or the astronauts themselves.
Similarly, if the piping broke, water, or whatever substance that was inside the tubing, would
immediately come in contact with electricity flowing along the Nitinol wire and could cause
even more severe damage. Another problem with wrapping the wire would be that the wire
could possibly slip around and come into contact with itself, causing it to short-circuit. This
would be a large problem because it would cause the whole pump to fail.
A third idea that has been explored was to place the water-filled tubing on a stiff back-
plate. This allows for the use of a segment of Nitinol SMA attached to each end of the plate.
With this innovation, the contraction of a long length of Nitinol can be focused into a very
small region, allowing us to overcome the limitations of the small percentage of contraction
in current SMAs. A prototype of this design has been created, and will be flown on a NASA
microgravity plane this spring as part of the High school students United with NASA to
Create Hardware (HUNCH) program.
The prototype pump, set to fly in microgravity in spring 2013.
9
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
However, this design also possesses many drawbacks. In order to optimize the percent-
age of Nitinol contraction on the tubing, we would have to sacrifice the multi-directional
contraction that was the key factor in the first iteration of our shape-memory alloy pump
and replace it with only lateral contraction, decreasing water flow inside the pump. This
design is also less space-efficient; the greater length of wire necessary to induce contraction
could impede already cramped space-craft operation. By the nature of the design, a wider
back-plate will result in a greater degree of contraction. This also suggests that the back-
plate needs to be at least wide enough to provide significant contraction; we approximated
this width using trigonometry and concluded that the length of the Nitinol wire must be at
least 25 times the inner diameter of the piping used. For example, our prototype was built
with in-diameter piping, so we needed a back-plate with a width of at least 10 inches for the
piping to completely contract. This extra width added to the design adds to the bulkiness
of the system and makes the design as a whole not ideal.
Ultimately, we decided that the best solution would be to draw from all of the above
ideas and create an integrated system that would be simple to use and install, as well as
more efficient than any of the above ideas alone. Drawing from our first rejected concept, the
interior of our pump tubing can be coated with materials of varying levels of hydrophobicity.
This will allow for the passive flow of water through the tubing. To create an active pressure
gradient, shape memory alloys will be embedded in the wall of the tubing and contract in a
peristaltic motion. This design eliminates the need for a hard back-plate, and and allows for
much simpler installation and use. Wire-embedded tubing would also alleviate the electrical
hazard present in wire-wrapped tubing because the pipe wall would serve as an insulator
for the wire. This design results in a pump which is extremely efficient, requires no moving
parts, and which can transport a large variety of fluids in microgravity.
Consequences
The potential benefits from adoption of our pump both by NASA and by others would
be innumerable. The simple design and low number of parts needed make the pump easy
10
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
to repair in spaceflight, allowing the space normally taken up by redundant systems needed
in case a traditional pump broke to be used for other purposes. In a shuttle with a highly
specific weight capacity, the extra space could be used to maximize mission productivity by
carrying different experiments or holding new equipment. In time, the SMA pump could
also be used on Earth in both private homes and larger endeavors. Repair and maintenance
of such a pump would be much simpler than that of a traditional pump, as any leaks or
breaks would be easily detectable and quickly rectified.
While we believe that the SMA pump would have a largely positive influence on society,
there are also some potential drawbacks to incorporating this technology into homes. One of
the main problems would be reduced water flow, as an SMA pump cannot rival the power of
a traditional pump in a gravity environment. The slow contraction of the SMA means that
water is not forced quickly through the pump system, resulting in reduced water pressure
and flow. However, this would probably be less of a problem in space, as the water would
not be inhibited by gravity and would continue to move with little resistance. Another
problem with the SMA pump technology is the cost of the pump. At its current price, the
amount of SMA necessary to create a full-size working pump is far more expensive than the
cost of an ordinary pump of equal size. Unless the cost of the SMA decreased dramatically,
the SMA pump technology might be inaccessible to many who would otherwise benefit by
it. After prolonged use, the heat applied to the SMA permanently deforms the wire. While
replacement of the alloy would not be difficult, it could be expensive and also environmentally
unsustainable, especially if the pump is adopted for widespread use.
Overall, the biggest consequence of adoption of a peristaltic pump would be that piping
on space and Earth would be simpler, and eventually, more efficient. As was previously
mentioned, the simple design would allow fewer repair materials to be taken on the flight,
leaving more room for scientific experiments and innovation, which forms the core of the
space program. As space colonization becomes more prevalent in the distant future, the
need for pumps that are efficient in microgravity will increase. If the peristaltic pump we
11
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
designed is used, pumping would become more efficient and easier to assemble and fix. Our
final design of a Nitinol wire embedded in a length of tubing would be much simpler than
the extremely complicated system used in current NASA ships. A simpler design is useful
because it can be transported pre-assembled and would be extremely easy to install and
maintain. Installation would be as simple as hooking up the pipe and setting up a power
system that would provide a stable source of electricity and prevent against spikes which
could short the Nitinol wire. If a section of piping fails due to a shortage of the wire or
breakage of the pipe, it can be replaced by removing that section of piping and adding a new
piece of piping and rewiring the Nitinol wire inside. Our pump is also more energy efficient
because the amount of electricity needed to power the length of piping is significantly less
because the electrical energy is used to directly power the pipe by generating heat instead
of being converted into mechanical energy.
The pump could also be very beneficial in many applications on Earth. For example, such
a pump could dramatically change medical systems, including the IV pump, which already
uses a form of peristalsis. It would be a simple matter to replace current IV tubing with
tubing embedded with SMA wire, and such a change would decrease the machines chance of
failure . There are also many other medical applications in which a micro-section of a wire-
embedded tube could be beneficial, such as stents and major artery replacements. The pump
could also be used on an industrial scale as a closed-loop cooling system. The pump could
take in water from any source, pump it through a system to cool it, then return the water to
its original source without contaminating the water or the system it is cooling. The potential
applications for the pump are numerous; we believe that our design of a Nitinol-actuated
peristaltic pump has the potential to greatly benefit society as a whole.
12
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
References
[1] Plumbing the space station. http://science.nasa.gov/science-news/science-at-nasa/
2001/ast03apr 2/, April 2001.
[2] Nitinol / flexinol actuator wire. http://www.imagesco.com/articles/nitinol/04.html,
2012.
[3] Precision flexinol position control using arduino. http://robotics.hobbizine.com/
flexinolresist.html, June 2012.
[4] E. E. Allen. Instrument for the transfusion of blood, 1887.
[5] Yoseph Bar-cohen and Zensheu Chatig. Piezoelectrically Actuated Miniature Peristaltic
Pump. Jet Propulsion Laboratory, 1991.
[6] Peter Bond. The Continuing Story of The International Space Station. Springer, 2002.
[7] Jennifer Chu. Soft autonomous robot inches along like an earthworm. http://web.mit.
edu/newsoffice/2012/autonomous-earthworm-robot-0810.html, August 2012.
[8] WB Cross, AH Kariotis, and FJ Stimler. Nitinol characterization study. 1969.
[9] Lauren R Freschauf, Jolie McLane, Himanshu Sharma, and Michelle Khine. Shrink-
induced superhydrophobic and antibacterial surfaces in consumer plastics. PloS one,
7(8):e40987, January 2012.
[10] Lutz Maibaum and David Chandler. A Coarse-Grained Model of Water Confined in a
Hydrophobic Tube. The Journal of Physical Chemistry B, 107(5):1189–1193, February
2003.
[11] Benjamin J Privett, Jonghae Youn, Sung A Hong, Jiyeon Lee, Junhee Han, Jae Ho
Shin, and Mark H Schoenfisch. Antibacterial fluorinated silica colloid superhydrophobic
13
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
surfaces. Langmuir : the ACS journal of surfaces and colloids, 27(15):9597–601, August
2011.
[12] Pradip B. Sarawade, Jong-Kil Kim, Askwar Hilonga, Dang Viet Quang, and Hee Taik
Kim. Synthesis of hydrophilic and hydrophobic xerogels with superior properties using
sodium silicate. Microporous and Mesoporous Materials, 139(1-3):138–147, March 2011.
[13] Viktor Shkolnikov, John Ramunas, and Juan G. Santiago. A self-priming, roller-free,
miniature, peristaltic pump operable with a single, reciprocating actuator. Sensors and
Actuators A: Physical, 160(1-2):141–146, May 2010.
[14] Ralph C. Smith. Smart Material Systems: Model Developments(Google eBook). SIAM,
2005.
[15] Milan Still. Peristaltic Pump. http://patimg1.uspto.gov/.piw?docid=00922205
&PageNum=3&IDKey=41F6B76EFA05&HomeUrl=http://patft.uspto.gov/netacgi/
nph-Parser?Sect2=PTO1%26Sect2=HITOFF%26p=1%26u=%252Fnetahtml
%252FPTO%252Fsearch-bool.html%26r=1%26f=G%26l=50%26d=PALL
%26S1=0922205.PN.%26OS=PN/922205%26RS=PN/922205, 1909.
[16] Jan Van Humbeeck. Non-medical applications of shape memory alloys. Materials Sci-
ence and Engineering: A, 273-275(null):134–148, December 1999.
[17] Stephen T. Washburn, Timothy S. Bingman, Scott K. Braithwaite, Robert C. Buck,
L. William Buxton, Harvey J. Clewell, Lynne A. Haroun, Janet E. Kester, Robert W.
Rickard, and Annette M. Shipp. Exposure Assessment and Risk Characterization for
Perfluorooctanoate in Selected Consumer Articles. Environmental Science & Technol-
ogy, 39(11):3904–3910, June 2005.
14
PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
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PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
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PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
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PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
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PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity
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Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity

  • 1. Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity PID: 2641S Toshiba ExploraVision 2013 Maxwell Tucker, Matias Horst, Christopher Zhen, and Catherine Farmer Mentored by Dr. Myra Halpin Abstract In any spacecraft, plumbing is of vital importance. Pump mechanisms used today in the International Space Station are prone to frequent malfunction due to their large number of moving parts. We propose an alternate mechanism, a biomimetic pump that employs peristalsis, the sequenced contraction of segments used by the human digestive tract. This peristaltic pump would function by using a pipe embedded with Nitinol, a shape memory alloy actuated by electrically derived resistive heating. In addition, the walls of the tubing would be surfaced with hydrophobic materials, creating a passive flow system. This mechanism will entirely eliminate the need for moving parts and would increase the pump reliability, as such a mechanism would only fail if the tubing itself breaks. In time, this technology can expanded for use in systems on Earth, increasing the reliability of pumps everywhere.
  • 2. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity Present Technology Plumbing in space is extremely different from plumbing on Earth, chiefly in that the lack of gravity renders ineffective conventional pumps designed for use in environments with gravity . To provide running water in space, NASA employs a system of pumps and fans which coerce liquid to flow in the right direction. While the aforementioned system works well, the pumps often break or malfunction due to the sheer number of pieces and systems within the pump system. NASA is forced to take multiple pump systems on each spaceflight, which takes up valuable space that could be used for other purposes. In addition, fixing a plumbing problem in space is very difficult. The only way to repair pumps in space is to haul up spare equipment and perform repairs that take up an astronauts valuable time. Furthermore, a pipe malfunction in spaceflight can be deadly to the astronauts on board. Pumps on spacecraft handle a variety of jobs, including heating, cooling, and recycling of water. Any failures in the system could lead to insufficient water to maintain life support on the spacecraft. Current small scale pumps, with dozens of moving parts, are often prone to failure because they tend to wear easily. Even when the pumps are functioning perfectly, they are inefficient because energy used to actuate the pump is wasted because of friction and heat in between moving parts [1]. Much of the energy used in current mechanical systems, especially fans like the ones employed by the pump system, is converted to noise pollution, a major aggravation and health hazard for astronauts [6]. One of the most essential parts of our pump is Nitinol. Nitinol is a shape memory alloy (SMA), which has the ability to assume two distinct structures depending on temperature. This occurs because of a unique change in crystalline structure that occurs when the alloy is heated past a transition temperature. When at a lower temperature, the alloy is in its Marstenite crystalline structure, which is an oblong, narrow shape, but when heated, it transforms to the Austenite structure, which in contrast is a perfect cube. The difference between these two structures is what causes the unique properties of the alloy. As the crystalline structure changes, the Nitinol becomes shorter due to the change from the oblong 2
  • 3. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity to cubic shape [8]. Image showing the various crystalline phases of Nitinol [2]. The Nitinol wire we used in our prototype to use is small in diameter, 0.2mm, and contracts when heated. Because of its small diameter, the wire has a higher surface-area to volume ratio and therefore has high resistance. The method we use to actuate our Nitinol wire is known as Joule heating, or resistive heating, and involves using the resistance of the wire to generate heat. Because heat is a natural byproduct of electrical current and the amount of resistance in the wire, the higher the resistance of the wire, the more heat can be produced. Another feature that will be implemented in our pump is a hydrophobic tube lining. This system will passively encourage a degree of flow in the pipe, repelling water from the internal surface [10]. A wide variety of substances in common use are hydrophobic. Superhydrophobicity has been created through physical processing of a variety of plastics [9]. Using polyolefin sputter coated in noble metals, researchers have been able to create a surface of hydrophobic polydimethylsiloxane, which in turn served as a mask for polystyrene, polycarbonate, and polyethylene. Parallel methods could readily be used to cast frames for the pump as well as endow superhydrophobicity upon its inner wall. In addition to repulsion of the water, the surface would function as an antibacterial agent by decreasing adhesion of bacteria to the walls of the tube and by decreasing the free energy of the system [11]. Given NASAs closed loop system, minimizing bacterial growth and establishment in the system 3
  • 4. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity are vital. Current processes exist to modify the inside of tubing for optimal hydrophobicity. The combination of these technologies, developed through a long history, will continue to evolve into more efficient future designs. History During the millennia since the invention of the first pump, the variety of applications for this simple tool has widened, necessitating new pump designs. The peristaltic pump, invented in 1887 by an American doctor, Eugene Allen, was first designed to transfer blood between patients [4]. Since the internal pump mechanisms did not contact the blood itself, lysis of the blood cells did not occur. Peristaltic pumps were optimal for applications where contact between the fluid being pumped and mechanical parts can be either detrimental to the liquid or the pump mechanism: corrosive chemicals, high viscosity liquids, and biological substances that are prone to decay [15]. A second invention vital to our project is the shape memory alloy. In 1932, Arne Olan- der used heat to restore a deformed silver-cadmium alloy to its original shape. A pair of researchers, Chang and Read, studied the mechanisms behind this transformation nineteen years later, exploring the transitions between the martensite and austenite crystal struc- tures through x-ray crystallography. In 1962, the naval ordnance laboratory, led by William Buehler, focused on designing a number of other alloys, among them an equal molar com- pound of nickel and titanium. Named Nitinol (Nickel Titanium Naval Ordnance Laboratory), the substance remains the most commonly used SMA and is used by our prototype [14]. Ac- tuators employed in peristaltic pumps are often designed out of shape memory alloy, but rarely employ wave-based motion [16]. NASA’s unsuccessful use of conventional pumping systems on several space flights moti- vated research into peristaltic pumps. Consequently, several 1986 projects focused on devel- oping peristaltic pumps for microgravity environments. These new pumps were hermetically sealed and, unlike previous pumps, had a mechanism to leave the pipes controlled by the pumps uncompressed in their off state. An extension of this was a piezoelectrically actuated 4
  • 5. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity peristaltic pump developed in 2004. Using electricity, metal was expanded and contracted in a specific wave pattern that induced peristaltic flow [5]. Future Technology The pump which we have designed mimics peristalsis, a mechanism that is used to great effect in the digestive systems of many organisms. While a number of pumps exist that use this mechanism, they are only effective in specific situations. Our pump differs from previous peristaltic pumps in that it more accurately mimics the process used in the body through the contraction of Nitinol wires. This manner of activation mimics the contraction of muscles in the body and removes the need for moving parts. One of the major pitfalls of current technology is the limited contraction of Nitinol wire. On average, a contraction of about 5% of the total length of the wire can be expected [8] [2]. In our pump design, this limited contraction does not allow for full occlusion of the tubing, preventing the pump from operating at full efficiency; it will not be very effective when under the influence of Earth’s gravity. In the future, better SMAs, with more efficient contractions, may allow the construction of a pump that fully occludes the tubing and thus prevents backflow entirely. With this improved technology, this type of pump could see use in almost any conceivable situation, and its high reliability would make it attractive for almost any application in which pumping is necessary. The development of a readily applicable superhydrophobic surface for the interior of our pipe will have progressed notably over the next twenty years. A multitude of fields exist that may lead to the development of hydrophobic surfaces. Self-assembling monolayers offer a relatively high-cost, yet high-value, method for chemically generating hydrophobic surfaces. Xerogels, a type of solidified silicon-based gels, promise to be more long-lasting as a means of hydrophobic coating [12]. Fluoropolymers, another readily applicable hydrophobic surface, are very low-cost, pliable, and flexible in application; however, recent concerns over their potential toxicity removes them from consideration as a reasonable chemical family [17]. Future developments may include either safe fluoropolymers or another plastic with similar 5
  • 6. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity properties. Present technologies allow physical modification of some plastics to generate hydrophobicity; if these technologies are simplified and made applicable to more plastics, then they can be employed on the peristaltic pump [9]. Another technology that must be improved upon is the embedding of SMA wire into rubber tubing. Currently, there are very few examples of wire embedded tubing. Those that do exist are largely used in the medical field and are too rigid to be useful in this application. Therefore, significant research must be done to create tubing which is both flexible and embedded with a shape memory alloy. Furthermore, it is important to consider the placement of SMA wire in the tubing. A pattern will need to be devised which delivers the best compromise of force and contraction, allowing for the most efficient movement of fluids through the pump mechanism. Breakthroughs Although NASA recognizes that there could be improvements to both the efficiency and reliability and our product idea addresses both concerns, there are several problems that must be addressed for peristaltic pumps to become a viable solution in space and perhaps even Earth. These problems are not simple design problems and will require technological breakthroughs that we hope will be available in the future. The biggest obstacle in the way of our pipe is the low efficiency of our SMA wire. As we previously explained, SMAs are specially made metals which have two crystalline structures that vary based on temperature and stress. This change from the martensite to the austenite crystalline structure when the SMA is heated causes the change in shape or, in our case, contraction. The only problem with this is that the maximum contraction for the most efficient SMA, nickel-titanium, is only around 8 percent before any deformation is permanent [2]. This 8 percent is definitely not ideal for use in our peristaltic pump and in the future, scientists may discover more efficient SMAs that deliver more contraction. Another problem with current SMAs is that because they deform with heat and need to cool back down to change back to their original shape, SMAs change shape very slowly. Though the heating process is very quick, the cooling 6
  • 7. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity process is significantly slower and, for the purposes of the pump, the wire takes too long to expand. In our pump, this would be a problem because it would limit the amount of water flowing through the tube and the speed of the water current. Ideally, in the future there will be an SMA with a lower activation temperature which would take less heat and, as a result, time to contract and expand. SMAs are a relatively new technology and can be improved with some more research. Other than the actual SMA wire that we use there are several other things that we could improve with further research. One problem that we ran into while designing a prototype was that if the wire was wrapped too tightly around the piping, the wire would come in contact with itself, causing the system to short-circuit and not function correctly. This can be solved if we find an effective insulator that would prevent the transfer of electricity, but at the same time, be able to expand and contract with the wire. This electrical insulator would also have to allow heat to pass through so that it does not interfere with the cooling and heating of the wire. The final area of improvement is finding suitable piping material. The actual material for the pipe needs to be both strong and easily compressible. Though there are materials that satisfy our needs right now to an extent, such as certain types of Tygon and rubber tubing, as technology advances, there will be new materials that are stronger and more flexible which would improve our pipe. Similarly, since our final idea involves a piping that already includes the SMA wire wrapped and embedded inside, in the future, a pipe like this can be mass-produced to make it more efficient and cost-effective. Design Process Before arriving at our current idea of using a SMA-embedded pipe in a peristaltic pump we considered several other possibilities that would accomplish our task of efficiently trans- porting water in microgravity. First, we attempted to develop passive control mechanisms for water. The polar liquid exhibits remarkable properties on earth due to its cohesive and adhesive nature. By manipulating the hydrophobicity and hydrophilicity of the surfaces, 7
  • 8. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity we can control the flow of the liquid. Recent research into amphipathic films allowed de- velopment of surfaces to collect atmospheric moisture. A cylindrical pipe, the interior of which was coated with a hydrophobic substance, such a self assembled monolayer, would repel water. If a core composed of another extremely hydrophobic substance were threaded through this pipe, positive pressure away from the center and towards the wall of the pipe would develop; countered by the effect of the hydrophobic pipe wall, water would be force out of the tube. Whenever water was removed from this pump system, water from elsewhere would be repelled from its location and would diffuse towards the newly opened volume . However, this design is not optimal for several reasons. First, it is only optimal for water and only functional for polar liquids. Common coolants, such as liquid nitrogen, as well as certain substances necessary for atmospheric controls, such as liquid oxygen, are nonpolar; this system would be useless for controlling their movement. Additionally, this system ex- hibits exceedingly passive control over the liquid. Pressure is sufficiently minimal the that backflow becomes a problem; if outside forces oppose the flow of the liquid, this pump design lacks the force to oppose. Our next development was the use of shape memory alloys to cause the flow of water through a segment of tubing via peristalsis. This mechanism was inspired by the natural movement of earthworms and research on autonomous worm-like robots from MIT [7]. The MIT Meshworm, which uses SMA wire and peristaltic movement to propel itself. However, the contraction of Nitinol at this time is not sufficient to cause peristaltic movement when simply wrapped around the a segment of tubing. This lead us to our next design iteration. Though this design would be very efficient because contraction from Nitinol wire around the pump would act in all directions, pressing both down along the pump as 8
  • 9. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity well as contracting it sideways. This type of contraction would be ideal because, taking advantage of waters adhesion and cohesion, a contraction of the pump along its horizontal axis would aid contraction in the vertical direction move the water. A major problem that we ran into is that having the wire wrapped around the outside of the wire would be an electrical hazard. Since the Nitinol wire is being actuated by an electrical current, having electricity flowing along an exposed wire on the outside of a pump would be a problem as it could come in contact with other parts of the spacecraft or the astronauts themselves. Similarly, if the piping broke, water, or whatever substance that was inside the tubing, would immediately come in contact with electricity flowing along the Nitinol wire and could cause even more severe damage. Another problem with wrapping the wire would be that the wire could possibly slip around and come into contact with itself, causing it to short-circuit. This would be a large problem because it would cause the whole pump to fail. A third idea that has been explored was to place the water-filled tubing on a stiff back- plate. This allows for the use of a segment of Nitinol SMA attached to each end of the plate. With this innovation, the contraction of a long length of Nitinol can be focused into a very small region, allowing us to overcome the limitations of the small percentage of contraction in current SMAs. A prototype of this design has been created, and will be flown on a NASA microgravity plane this spring as part of the High school students United with NASA to Create Hardware (HUNCH) program. The prototype pump, set to fly in microgravity in spring 2013. 9
  • 10. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity However, this design also possesses many drawbacks. In order to optimize the percent- age of Nitinol contraction on the tubing, we would have to sacrifice the multi-directional contraction that was the key factor in the first iteration of our shape-memory alloy pump and replace it with only lateral contraction, decreasing water flow inside the pump. This design is also less space-efficient; the greater length of wire necessary to induce contraction could impede already cramped space-craft operation. By the nature of the design, a wider back-plate will result in a greater degree of contraction. This also suggests that the back- plate needs to be at least wide enough to provide significant contraction; we approximated this width using trigonometry and concluded that the length of the Nitinol wire must be at least 25 times the inner diameter of the piping used. For example, our prototype was built with in-diameter piping, so we needed a back-plate with a width of at least 10 inches for the piping to completely contract. This extra width added to the design adds to the bulkiness of the system and makes the design as a whole not ideal. Ultimately, we decided that the best solution would be to draw from all of the above ideas and create an integrated system that would be simple to use and install, as well as more efficient than any of the above ideas alone. Drawing from our first rejected concept, the interior of our pump tubing can be coated with materials of varying levels of hydrophobicity. This will allow for the passive flow of water through the tubing. To create an active pressure gradient, shape memory alloys will be embedded in the wall of the tubing and contract in a peristaltic motion. This design eliminates the need for a hard back-plate, and and allows for much simpler installation and use. Wire-embedded tubing would also alleviate the electrical hazard present in wire-wrapped tubing because the pipe wall would serve as an insulator for the wire. This design results in a pump which is extremely efficient, requires no moving parts, and which can transport a large variety of fluids in microgravity. Consequences The potential benefits from adoption of our pump both by NASA and by others would be innumerable. The simple design and low number of parts needed make the pump easy 10
  • 11. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity to repair in spaceflight, allowing the space normally taken up by redundant systems needed in case a traditional pump broke to be used for other purposes. In a shuttle with a highly specific weight capacity, the extra space could be used to maximize mission productivity by carrying different experiments or holding new equipment. In time, the SMA pump could also be used on Earth in both private homes and larger endeavors. Repair and maintenance of such a pump would be much simpler than that of a traditional pump, as any leaks or breaks would be easily detectable and quickly rectified. While we believe that the SMA pump would have a largely positive influence on society, there are also some potential drawbacks to incorporating this technology into homes. One of the main problems would be reduced water flow, as an SMA pump cannot rival the power of a traditional pump in a gravity environment. The slow contraction of the SMA means that water is not forced quickly through the pump system, resulting in reduced water pressure and flow. However, this would probably be less of a problem in space, as the water would not be inhibited by gravity and would continue to move with little resistance. Another problem with the SMA pump technology is the cost of the pump. At its current price, the amount of SMA necessary to create a full-size working pump is far more expensive than the cost of an ordinary pump of equal size. Unless the cost of the SMA decreased dramatically, the SMA pump technology might be inaccessible to many who would otherwise benefit by it. After prolonged use, the heat applied to the SMA permanently deforms the wire. While replacement of the alloy would not be difficult, it could be expensive and also environmentally unsustainable, especially if the pump is adopted for widespread use. Overall, the biggest consequence of adoption of a peristaltic pump would be that piping on space and Earth would be simpler, and eventually, more efficient. As was previously mentioned, the simple design would allow fewer repair materials to be taken on the flight, leaving more room for scientific experiments and innovation, which forms the core of the space program. As space colonization becomes more prevalent in the distant future, the need for pumps that are efficient in microgravity will increase. If the peristaltic pump we 11
  • 12. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity designed is used, pumping would become more efficient and easier to assemble and fix. Our final design of a Nitinol wire embedded in a length of tubing would be much simpler than the extremely complicated system used in current NASA ships. A simpler design is useful because it can be transported pre-assembled and would be extremely easy to install and maintain. Installation would be as simple as hooking up the pipe and setting up a power system that would provide a stable source of electricity and prevent against spikes which could short the Nitinol wire. If a section of piping fails due to a shortage of the wire or breakage of the pipe, it can be replaced by removing that section of piping and adding a new piece of piping and rewiring the Nitinol wire inside. Our pump is also more energy efficient because the amount of electricity needed to power the length of piping is significantly less because the electrical energy is used to directly power the pipe by generating heat instead of being converted into mechanical energy. The pump could also be very beneficial in many applications on Earth. For example, such a pump could dramatically change medical systems, including the IV pump, which already uses a form of peristalsis. It would be a simple matter to replace current IV tubing with tubing embedded with SMA wire, and such a change would decrease the machines chance of failure . There are also many other medical applications in which a micro-section of a wire- embedded tube could be beneficial, such as stents and major artery replacements. The pump could also be used on an industrial scale as a closed-loop cooling system. The pump could take in water from any source, pump it through a system to cool it, then return the water to its original source without contaminating the water or the system it is cooling. The potential applications for the pump are numerous; we believe that our design of a Nitinol-actuated peristaltic pump has the potential to greatly benefit society as a whole. 12
  • 13. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity References [1] Plumbing the space station. http://science.nasa.gov/science-news/science-at-nasa/ 2001/ast03apr 2/, April 2001. [2] Nitinol / flexinol actuator wire. http://www.imagesco.com/articles/nitinol/04.html, 2012. [3] Precision flexinol position control using arduino. http://robotics.hobbizine.com/ flexinolresist.html, June 2012. [4] E. E. Allen. Instrument for the transfusion of blood, 1887. [5] Yoseph Bar-cohen and Zensheu Chatig. Piezoelectrically Actuated Miniature Peristaltic Pump. Jet Propulsion Laboratory, 1991. [6] Peter Bond. The Continuing Story of The International Space Station. Springer, 2002. [7] Jennifer Chu. Soft autonomous robot inches along like an earthworm. http://web.mit. edu/newsoffice/2012/autonomous-earthworm-robot-0810.html, August 2012. [8] WB Cross, AH Kariotis, and FJ Stimler. Nitinol characterization study. 1969. [9] Lauren R Freschauf, Jolie McLane, Himanshu Sharma, and Michelle Khine. Shrink- induced superhydrophobic and antibacterial surfaces in consumer plastics. PloS one, 7(8):e40987, January 2012. [10] Lutz Maibaum and David Chandler. A Coarse-Grained Model of Water Confined in a Hydrophobic Tube. The Journal of Physical Chemistry B, 107(5):1189–1193, February 2003. [11] Benjamin J Privett, Jonghae Youn, Sung A Hong, Jiyeon Lee, Junhee Han, Jae Ho Shin, and Mark H Schoenfisch. Antibacterial fluorinated silica colloid superhydrophobic 13
  • 14. PID: 2641S Shape Memory Alloy Actuated Peristaltic Pump for Use in Microgravity surfaces. Langmuir : the ACS journal of surfaces and colloids, 27(15):9597–601, August 2011. [12] Pradip B. Sarawade, Jong-Kil Kim, Askwar Hilonga, Dang Viet Quang, and Hee Taik Kim. Synthesis of hydrophilic and hydrophobic xerogels with superior properties using sodium silicate. Microporous and Mesoporous Materials, 139(1-3):138–147, March 2011. [13] Viktor Shkolnikov, John Ramunas, and Juan G. Santiago. A self-priming, roller-free, miniature, peristaltic pump operable with a single, reciprocating actuator. Sensors and Actuators A: Physical, 160(1-2):141–146, May 2010. [14] Ralph C. Smith. Smart Material Systems: Model Developments(Google eBook). SIAM, 2005. [15] Milan Still. Peristaltic Pump. http://patimg1.uspto.gov/.piw?docid=00922205 &PageNum=3&IDKey=41F6B76EFA05&HomeUrl=http://patft.uspto.gov/netacgi/ nph-Parser?Sect2=PTO1%26Sect2=HITOFF%26p=1%26u=%252Fnetahtml %252FPTO%252Fsearch-bool.html%26r=1%26f=G%26l=50%26d=PALL %26S1=0922205.PN.%26OS=PN/922205%26RS=PN/922205, 1909. [16] Jan Van Humbeeck. Non-medical applications of shape memory alloys. Materials Sci- ence and Engineering: A, 273-275(null):134–148, December 1999. [17] Stephen T. Washburn, Timothy S. Bingman, Scott K. Braithwaite, Robert C. Buck, L. William Buxton, Harvey J. Clewell, Lynne A. Haroun, Janet E. Kester, Robert W. Rickard, and Annette M. Shipp. Exposure Assessment and Risk Characterization for Perfluorooctanoate in Selected Consumer Articles. Environmental Science & Technol- ogy, 39(11):3904–3910, June 2005. 14
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