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Carbon nanotubes




               Bruno Calza
               William Sather
Presentation Overview
•   What is it?
•   Applications
•   Characteristics
•   Nano vs. Macro
•   Concerns
•   Conclusions
•   References
What is it?
• Carbon nanotubes are
  allotropes of carbon
• A single wall carbon nanotube
  is a one-atom thick sheet of
  graphite rolled up into a
  seamless cylinder with
  diameter of the order of a
  nanometer
• Discovered in 1991 by S.
  Iijima
Applications
• Clothes: waterproof tear-resistant
  cloth fibers
• Combat jackets: carbon nanotubes
  as ultra strong fibers and to
  monitor the condition of the wearer
• Concrete: CNTs increase the
  tensile strength
• Polyethylene: CNTs increase the
  polymer's elastic modulus by 30%
• Sports equipment: stronger and
  lighter                               BST6 - 2007 Easton Stealth CNT
• Ultrahigh-speed flywheels: the        Regular Flex
  high strength/weight ratio enables
  very high speeds to be achieved
Applications
• Space elevator: this will be
  possible only if tensile
  strengths of more than about
  70 GPa can be achieved.
  Monoatomic oxygen in the
  Earth's upper atmosphere
  would erode carbon nanotubes
  at some altitudes, so a space
  elevator constructed of
  nanotubes would need to be
  protected (by some kind of
  coating). Carbon nanotubes in
  other applications would
  generally not need such
  surface protection.
Applications
• Chemical nanowires: can also be
  used to produce nanowires of other
  chemicals, such as gold or zinc
  oxide
• Computer circuits: there is a
  possibility to build electronic
  computer circuits entirely out of
  nanotubes
• Conductive films: CNTs are ideal
  for high reliability touch screens and
  flexible displays
• Light bulb filament: alternative to
                                           MC and BC series supercapacitors (up to
  tungsten filaments in incandescent       3000 farad capacitance) produced by
  lamps                                    Maxwell Technologies

• Magnets: MWNTs coated with
  magnetite
• Ultra capacitors: increase in energy
  storage ability
Applications
• Electric motor brushes: nanotube composite motor
  brushes are better-lubricated, cooler-running, less brittle,
  stronger and more accurately moldable.
• Optical ignition: a layer of 29% iron enriched SWNT is
  placed on top of a layer of explosive material and can be
  ignited with a regular camera flash.
• Superconductor: nanotubes have been shown to be
  superconducting at low temperatures
• Displays: high-brightness low-energy low-weight displays
  can be made
Applications
• Air pollution filter: future applications of nanotube
  membranes include filtering carbon dioxide from power
  plant emissions
• Biotech container: nanotubes can be opened and filled with
  materials such as biological molecules, raising the
  possibility of applications in biotechnology.
• Hydrogen storage: there is potential to contain the same
  quantity of energy as a 50l gasoline tank in 13.2l of
  nanotubes.
• Water filter: the tubes are so thin that small particles (like
  water molecules) can pass through them, while larger
  particles (such as the chloride ions in salt) are blocked.
Applications
• Oscillator: fastest known oscillators (>
  50 GHz)
• Liquid flow array: liquid flows up to
  five orders of magnitude faster than
  predicted through array
• Slick surface: slicker than Teflon and
  waterproof
• Transistor: “Carbon nanotube transistors
  have the potential to outperform state-of-
  the-art silicon devices,” said Dr. T.C.     A close-up view of the 5-stage CMOS type
  Chen, vice president, Science &              nanotube ring oscillator. The upper right
  Technology, IBM Research. “However, inset shows the nanotube itself with a
  scientists have focused so far on                      diameter of ~2nm.
  fabricating and optimizing individual
  carbon nanotube transistors. Now, we can
  evaluate the potential of carbon nanotube
  electronics in complete circuits -- a
  critical step toward the integration of the
  technology with existing chip-making
  techniques.”
Characteristics
• Extraordinary strenght:
  200 times stronger than
  steel
• Unique electrical
  properties: mettalic
  nanotubes can have an
  electrical current density
  more than 1,000 times
  greater than metals such
  as silver an copper.
• They are efficient
  conductors of heat
• Very light
Nano vs. Macro
• Carbon nanotubes are         CNT density    1.3-1.4 g/cm³
  much stronger and lighter
  than the carbon
  (allotropes) and can         Diamond        3.513 g/cm³
  conduct electricity and      density
  heat.
• The reason for this is the   CNT Thermal
  symmtrical shape and         Conductivity   6000 W/m/K
  strong bonds between the
  carbons                      Graphite       (119-
                               Thermal        165) W/m/K
                               Conductivity
Concerns
• Carbon nanotubes injected directly into bloodstream of research lab
  animals cause no immediate adverse health effects and circulate for
  more than one hour before they are removed by the liver. More
  studies are being made about its toxicity.
• People are confused about it. They don’t know if it is fact or fiction.
  This confusion makes them fear this new discipline.
• Single-walled nanotubes are still very expensive to produce, around
  1500 $ per gram
Conclusion
• This is the future of the world. It may provide new solutions
  for the millions of people in developing countries who lack
  access to basic services, such as safe water, reliable energy,
  health care, and education.
• Everthing will become stronger, smaller and lighter.




           The joining of two carbon nanotubes with different
        electrical properties to form a diode has been proposed.
•
                        References
    Who should be given the credit for the discovery of carbon nanotubes? CARBON 44 (2006)
    1621 (ELSEVIER) Retrieved May 17, 2007, from http://en.wikipedia.org
•   Philip G. Collins and Phaedon Avouris (2000), Nanotubes for Electronics - Scientific
    American December 2000, page 67 Retrieved May 17, 2007, from http://en.wikipedia.org
•   Super-tough carbon-nanotube fibers Alan B. Dalton et al. Nature 423, 703 (12 June 2003)
    Retrieved May 17, 2007, from http://en.wikipedia.org
•   Azad Naeemi and James D. Meindl (2007,). "Carbon nanotube interconnects". ISPD '07:
    Proceedings of the 2007 international symposium on Physical design,: 77--84,, {Austin,
    Texas, USA},: ACM Press, New York, NY, USA. Retrieved May 17, 2007, from
    http://en.wikipedia.org
•   S. Sen, I.K. Puri, Nanotechnology 15, 264-268 (2004). Retrieved May 17, 2007, from
    http://en.wikipedia.org
•   The Space Elevator, by Brad C. Edwards, NASA Retrieved May 17, 2007, from
    http://en.wikipedia.org
•   Dekker, Postma et al (2001), Carbon Nanotube Single-Electron Transistors at Room
    Temperature - Science 293.5527 (July 6, 2001) Retrieved May 17, 2007, from
    http://en.wikipedia.org
•   Avouris, Arnold, Collins Engineering Carbon Nanotubes and Nanotube Circuits Using
    Electrical Breakdown - Science 292.5517 (April 27, 2001):706-9 Retrieved May 17, 2007,
    from http://en.wikipedia.org
•   Kalaugher Scalable Interconnection and Integration of Nanowire Devices Without
    Registration Nano Letters 4.5 (2004):915-19 Retrieved May 17, 2007, from
    http://en.wikipedia.org
•   Tesng et alMonolithic Integration of Carbon Nanotube Devices with Silicon MOS
    Technology Nano Letters 4.1 (2004):123-127 Retrieved May 17, 2007, from
    http://en.wikipedia.org
References
•   Kalaugher Scalable Interconnection and Integration of Nanowire Devices Without
    Registration Nano Letters 4.5 (2004):915-19 Retrieved May 17, 2007, from
    http://en.wikipedia.org
•   Tesng et alMonolithic Integration of Carbon Nanotube Devices with Silicon MOS
    Technology Nano Letters 4.1 (2004):123-127 Retrieved May 17, 2007, from
    http://en.wikipedia.org
•   Nanotubes Tracked In Blood And Liver: Study Finds No Adverse Effects Retrieved
    May 17, 2007, from http://scienceandreason.blogspot.com/2006/12/do-carbon-nanotubes-
    present-health.html
•   Health, safety, environmental and social issues Retrieved May 17, 2007, from
    http://www.nanotec.org.uk/workshopOct03health.htm

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Carbon nanotubes bc

  • 1. Carbon nanotubes Bruno Calza William Sather
  • 2. Presentation Overview • What is it? • Applications • Characteristics • Nano vs. Macro • Concerns • Conclusions • References
  • 3. What is it? • Carbon nanotubes are allotropes of carbon • A single wall carbon nanotube is a one-atom thick sheet of graphite rolled up into a seamless cylinder with diameter of the order of a nanometer • Discovered in 1991 by S. Iijima
  • 4. Applications • Clothes: waterproof tear-resistant cloth fibers • Combat jackets: carbon nanotubes as ultra strong fibers and to monitor the condition of the wearer • Concrete: CNTs increase the tensile strength • Polyethylene: CNTs increase the polymer's elastic modulus by 30% • Sports equipment: stronger and lighter BST6 - 2007 Easton Stealth CNT • Ultrahigh-speed flywheels: the Regular Flex high strength/weight ratio enables very high speeds to be achieved
  • 5. Applications • Space elevator: this will be possible only if tensile strengths of more than about 70 GPa can be achieved. Monoatomic oxygen in the Earth's upper atmosphere would erode carbon nanotubes at some altitudes, so a space elevator constructed of nanotubes would need to be protected (by some kind of coating). Carbon nanotubes in other applications would generally not need such surface protection.
  • 6. Applications • Chemical nanowires: can also be used to produce nanowires of other chemicals, such as gold or zinc oxide • Computer circuits: there is a possibility to build electronic computer circuits entirely out of nanotubes • Conductive films: CNTs are ideal for high reliability touch screens and flexible displays • Light bulb filament: alternative to MC and BC series supercapacitors (up to tungsten filaments in incandescent 3000 farad capacitance) produced by lamps Maxwell Technologies • Magnets: MWNTs coated with magnetite • Ultra capacitors: increase in energy storage ability
  • 7. Applications • Electric motor brushes: nanotube composite motor brushes are better-lubricated, cooler-running, less brittle, stronger and more accurately moldable. • Optical ignition: a layer of 29% iron enriched SWNT is placed on top of a layer of explosive material and can be ignited with a regular camera flash. • Superconductor: nanotubes have been shown to be superconducting at low temperatures • Displays: high-brightness low-energy low-weight displays can be made
  • 8. Applications • Air pollution filter: future applications of nanotube membranes include filtering carbon dioxide from power plant emissions • Biotech container: nanotubes can be opened and filled with materials such as biological molecules, raising the possibility of applications in biotechnology. • Hydrogen storage: there is potential to contain the same quantity of energy as a 50l gasoline tank in 13.2l of nanotubes. • Water filter: the tubes are so thin that small particles (like water molecules) can pass through them, while larger particles (such as the chloride ions in salt) are blocked.
  • 9. Applications • Oscillator: fastest known oscillators (> 50 GHz) • Liquid flow array: liquid flows up to five orders of magnitude faster than predicted through array • Slick surface: slicker than Teflon and waterproof • Transistor: “Carbon nanotube transistors have the potential to outperform state-of- the-art silicon devices,” said Dr. T.C. A close-up view of the 5-stage CMOS type Chen, vice president, Science & nanotube ring oscillator. The upper right Technology, IBM Research. “However, inset shows the nanotube itself with a scientists have focused so far on diameter of ~2nm. fabricating and optimizing individual carbon nanotube transistors. Now, we can evaluate the potential of carbon nanotube electronics in complete circuits -- a critical step toward the integration of the technology with existing chip-making techniques.”
  • 10. Characteristics • Extraordinary strenght: 200 times stronger than steel • Unique electrical properties: mettalic nanotubes can have an electrical current density more than 1,000 times greater than metals such as silver an copper. • They are efficient conductors of heat • Very light
  • 11. Nano vs. Macro • Carbon nanotubes are CNT density 1.3-1.4 g/cm³ much stronger and lighter than the carbon (allotropes) and can Diamond 3.513 g/cm³ conduct electricity and density heat. • The reason for this is the CNT Thermal symmtrical shape and Conductivity 6000 W/m/K strong bonds between the carbons Graphite (119- Thermal 165) W/m/K Conductivity
  • 12. Concerns • Carbon nanotubes injected directly into bloodstream of research lab animals cause no immediate adverse health effects and circulate for more than one hour before they are removed by the liver. More studies are being made about its toxicity. • People are confused about it. They don’t know if it is fact or fiction. This confusion makes them fear this new discipline. • Single-walled nanotubes are still very expensive to produce, around 1500 $ per gram
  • 13. Conclusion • This is the future of the world. It may provide new solutions for the millions of people in developing countries who lack access to basic services, such as safe water, reliable energy, health care, and education. • Everthing will become stronger, smaller and lighter. The joining of two carbon nanotubes with different electrical properties to form a diode has been proposed.
  • 14. References Who should be given the credit for the discovery of carbon nanotubes? CARBON 44 (2006) 1621 (ELSEVIER) Retrieved May 17, 2007, from http://en.wikipedia.org • Philip G. Collins and Phaedon Avouris (2000), Nanotubes for Electronics - Scientific American December 2000, page 67 Retrieved May 17, 2007, from http://en.wikipedia.org • Super-tough carbon-nanotube fibers Alan B. Dalton et al. Nature 423, 703 (12 June 2003) Retrieved May 17, 2007, from http://en.wikipedia.org • Azad Naeemi and James D. Meindl (2007,). "Carbon nanotube interconnects". ISPD '07: Proceedings of the 2007 international symposium on Physical design,: 77--84,, {Austin, Texas, USA},: ACM Press, New York, NY, USA. Retrieved May 17, 2007, from http://en.wikipedia.org • S. Sen, I.K. Puri, Nanotechnology 15, 264-268 (2004). Retrieved May 17, 2007, from http://en.wikipedia.org • The Space Elevator, by Brad C. Edwards, NASA Retrieved May 17, 2007, from http://en.wikipedia.org • Dekker, Postma et al (2001), Carbon Nanotube Single-Electron Transistors at Room Temperature - Science 293.5527 (July 6, 2001) Retrieved May 17, 2007, from http://en.wikipedia.org • Avouris, Arnold, Collins Engineering Carbon Nanotubes and Nanotube Circuits Using Electrical Breakdown - Science 292.5517 (April 27, 2001):706-9 Retrieved May 17, 2007, from http://en.wikipedia.org • Kalaugher Scalable Interconnection and Integration of Nanowire Devices Without Registration Nano Letters 4.5 (2004):915-19 Retrieved May 17, 2007, from http://en.wikipedia.org • Tesng et alMonolithic Integration of Carbon Nanotube Devices with Silicon MOS Technology Nano Letters 4.1 (2004):123-127 Retrieved May 17, 2007, from http://en.wikipedia.org
  • 15. References • Kalaugher Scalable Interconnection and Integration of Nanowire Devices Without Registration Nano Letters 4.5 (2004):915-19 Retrieved May 17, 2007, from http://en.wikipedia.org • Tesng et alMonolithic Integration of Carbon Nanotube Devices with Silicon MOS Technology Nano Letters 4.1 (2004):123-127 Retrieved May 17, 2007, from http://en.wikipedia.org • Nanotubes Tracked In Blood And Liver: Study Finds No Adverse Effects Retrieved May 17, 2007, from http://scienceandreason.blogspot.com/2006/12/do-carbon-nanotubes- present-health.html • Health, safety, environmental and social issues Retrieved May 17, 2007, from http://www.nanotec.org.uk/workshopOct03health.htm