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IOSR Journal of Mechanical and Civil Engineering (IOSR-JMCE)
e-ISSN: 2278-1684,p-ISSN: 2320-334X, Volume 8, Issue 2 (Jul. - Aug. 2013), PP 07-18
www.iosrjournals.org
www.iosrjournals.org 7 | Page
Wear Analysis of Polytetrafluoroethylene (PTFE) and it’s
Composites under Wet Conditions
Sandip B. Chaudhari1
, Prof. S.P. Shekhawat2
1
P.G. Student, Department of Mechanical Engineering, SSBT’s COET, Bambhori, Maharashtra, India
2
Associate Professor, Department of Mechanical Engineering, SSBT’s COET, Bambhori, Maharashtra, India
Abstract : In this paper, the effect of load, Velocity of sliding and sliding distance on friction and wear of
materials made of Polytetrafluoroethylele (PTFE) and PTFE composites under wet condition with filler
materials such as 25% bronze, 25% glass fiber and 25 % carbon have studied. The experimental work has
performed on pin-on-disc friction and wear test rig and analyzed with the help of Design Expert software. The
results of experiments are presented in tables and graphs which shows that the addition of bronze, glass and
carbon filler to the virgin PTFE decreases wear rate significantly and there is marginal increase in coefficient
of friction. The highest wear resistance was found for 25% carbon filled PTFE followed by 25% glass filled
PTFE, 25% bronze filled PTFE and virgin PTFE. Through this study, we can develop the best bearing material
for the various industrial applications which is available easily at the minimum cost.
Keywords: Design of Experiments, Friction, Pin-on-Disc, Polytetrafluoroethylene (PTFE), Wear
I. Introduction
Tribological behaviour may be evaluated by several qualitative and quantitative parameters. We select
friction coefficient and wear as relevant for this study. PTFE based materials are notable for their characteristics
such as very low friction coefficient and good resistance to heat and corrosion in different application
environments. Unfortunately, pure PTFE is not performing satisfactory in wear resistance and needs to be
modified. The use of fillers and additives in PTFE is the most common way to improve its tribological and
mechanical properties. The influence of fillers on the tribological behaviour of the composites cannot be
predicted and has to be tested experimentally [1].
1.1 Nature of Problem
Unfortunately PTFE has poor thermal conductivity, high coefficient of thermal expansion and
relatively not strong. PTFE suffers from poor wear resistance too. Because of this PTFE is suitable only for light
loads and at low speeds. Because of the relative softness of PTFE, it is logical to expect that its load-carrying
ability and its wear resistance might be improved by the addition of suitable fillers. Accordingly, several fillers
were tried by researchers in combination with this plastic, including graphite, molybdenum disulfide, fiber glass,
carbon ,bronze, dental silicate, silicon, titanium dioxide, silver, copper, tungsten and molybdenum [2].
1.2 Previous Work
Deepak Bagle [3] has studied the tribological behavior of polytetrafluoroethylene and its composites
with filler materials as carbon and bronze under dry conditions. He found that addition of filler materials such as
bronze and carbon to PTFE causes an increase in hardness and wear resistance, while the coefficient of friction
is slightly increased. From the results the highest wear resistance was found for PTFE with carbon filler
followed by PTFE with bronze filler and pure PTFE. Jaydeep Khedkar et al [4] studied the tribological
behaviour of polytetrafluoroethylene (PTFE) and PTFE composites with filler materials such as carbon,
graphite, glass fibers, MoS2 and poly-p-phenyleneterephthalamide (PPDT) fibers. The present filler additions
found to increase hardness and wear resistance in all composites studied. The highest wear resistance was found
for composites containing (i) 18% carbon + 7% graphite, (ii) 20% glass fibers + 5% MoS2 and (iii) 10% PPDT
fibers.
It was proposed by Lancaster [5] that addition of high aspect ratio filler materials (carbon fibers, glass
fibers) to PTFE can improve its wear resistance due to preferential load supporting action by these fibers. There
have also been some reports on the use of particulate filler materials like MoS2 and graphite to modify the
tribological properties of PTFE.V.B. Raka [6], has study and analyze the effect of applied load, sliding velocity
and sliding time on friction and wear behaviour of Polytetrafluoroethylene (PTFE) and its two composites viz.
25% carbon filled PTFE and 60% bronze filled PTFE, is experimentally examined and analytically analyzed.
Taguchi‟s approach and L9 orthogonal array is used for design of experiment. Depending on pressure, sliding
velocity and sliding time, material used in this study can be ranked as 60BFT>25CFT>PTFE for their friction
Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions
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performance and 25CFT >60BFT >PTFE for their wear performance. Adding fillers to pure PTFE matrix
reduces wear rate for both the composite used in the study.
D.S. Bajaj et al [7], have studied the tribological properties of PTFE can be improved by adding some
filler materials such as glass fibers, carbon, bronze, graphite. Friction and wear are very important surface
phenomenon. This paper describes the dependency of wear and friction on surface roughness, sliding velocity
and contact pressure for PTFE and its composites using a Pin- On-Disc tribometer. The parameters studied
include wear rate and coefficient friction under varying load and for different surface roughness.
1.3 Purpose of Present Study
The present study will be aimed at developing a new bearing material, which is known as super bush
bearing material, which consists of carbon filled PTFE, glass fiber filled PTFE and bronze filled PTFE which is
cost effective and superior in properties to the conventional bronze bearing materials. Fruitful research in this
area could lead to development of superior and less expensive bearing materials. The new carbon filled PTFE,
glass filled PTFE and bronze filled PTFE will be developed during the present investigation and the properties
of these materials will be evaluated. Following are the main objectives of the study.
a. To find the effect of carbon filler, bronze filler and glass fiber filler in PTFE on wear rate.
b. To study the wear behaviour of the selected materials and the effect of various parameters like load,
sliding velocity and sliding distance on wear rate.
II. Experimental Tools, Techniques and Methodology
2.1 Design of Experiment
It is methodology based on statistics and other discipline for arriving at an efficient and effective
planning of experiments with a view to obtain valid conclusion from the analysis of experimental data. Design
of experiments determines the pattern of observations to be made with a minimum of experimental efforts. To
be specific Design of experiments (DOE) offers a systematic approach to study the effects of multiple variables /
factors on products / process performance by providing a structural set of analysis in a design matrix. More
specifically, the use of orthogonal Arrays (OA) for DOE provides an efficient and effective method for
determining the most significant factors and interactions in a given design problem [3].
2.2 Introduction to Design Expert
Design-Expert, version 8 software (DX8) is a powerful and easy-to-use program for design of
experiments (DOE). With it you can quickly set-up an experiment, analyze your data, and graphically display
the results. This intuitive software is a must for anyone wanting to improve a process or a product. Design-
Expert software offers an impressive array of design options and provides the flexibility to handle categorical
factors and combine them with mixture and/or process variables. After building your design, generate a run
sheet with your experiments laid out for you in randomized run order. DX8 offers features for ease of use,
functionality and power that you won't find in general statistical packages. Add, delete or duplicate runs in any
design with the handy design editor. Rotatable 3-D colour plots make response visualization easy [3].
2.3 Taguchi Method
Taguchi has envisaged a new method of conducting the design of experiments which are based on
well defined guidelines. This method uses a special set of arrays called orthogonal array. These standard arrays
stipulate the way of conducting the minimal number of experiments which could give the full information of all
the factors that affect the performance parameter. The crux of the orthogonal arrays method lies in choosing the
level combinations of the input design variables for each experiment. The technique of laying out the conditions
of experiments involving multiple factors was first proposed by the Englishman, Sir R. A. Fisher. The method is
popularly known as the factorial design of experiments. A full factorial design will identify all possible
combinations for a given set of factors. Since most industrial experiments usually involve a significant number
of factors, a full factorial design results in a large number of experiments. To reduce the number of experiments
to a practical level, only a small set from all the possibilities is selected. The method of selecting a limited
number of experiments which produces the most information is known as a partial fraction experiment.
Although this method is well known, there are no general guidelines for its application or the analysis of the
results obtained by performing the experiments. Taguchi constructed a special set of general design guidelines
for factorial experiments that cover many applications.
2.4 Statistical Regression Analysis
Statistical regression analysis is the study of the relationship between two or more variables, used to
establish the empirical equation relating input-output parameters, by utilizing least square method. Moreover, it
Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions
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is the most commonly used statistical modelling technique developed based on experimental data. The following
steps are to be considered for carrying out statistical regression analysis of a process.
1. Identifying the important process control variables and finding their upper and lower limits.
2. Developing the design matrix (Statistical design of experiments).
3. Conducting the experiments as per the design matrix and recording the response parameters.
4. Developing the models and calculating the regression coefficients.
5. Checking the adequacy of the models.
6. Testing the significance of coefficients and arriving at the final models.
7. Presenting the direct and interaction effects of the process.
8. Analysis of Results.
2.5 Analysis of Variance (ANOVA)
The adequacy of the models is tested using the analysis of variance (ANOVA) technique. It is a
statistical tool for testing null hypothesis for designed experimentation, where a number of different variables
are being studied simultaneously. ANOVA is used to quickly analyze the variances present in the experiment
with the help of fisher test (F test). The results of F test indicate whether there are differences in the means due
to varying the test conditions. If the estimates are similar, the changes of the subgroup averages being detectably
different are small. If the estimates are significantly different, then the subgroup averages may be significantly
different. If the F value calculated based on the data is greater than the F theoretical value based on F
distribution, then the null hypothesis is rejected and the means are considered to be statistically significant.
Usually analysis of variance computation would be done using a statistical software package. In the present
work more number of variables are involved therefore, analysis of variance is carried out using the standard
“Design Expert 8” statistical software.
2.6 Methodology
In this study the wear rate of each material i.e. plain PTFE, 25% carbon filled PTFE, 25% bronze filled
PTFE and 25% glass filled PTFE have been calculated under the wet conditions (Lubricated condition). So, we
need the Pin-on-Disc apparatus for the experimental work which must provide the lubrication facility. For the
present work following methodology has been followed.
1. It starts with the specimen preparation according to the “Pin-on-Disc Friction and Wear Testing Machine”
specifications. The sample specimens has been prepared by performing necessary turning and facing
operations on the respective rods.
2. After specimen preparation perform the wear test on each of the specimen for varying conditions of load,
sliding distance and sliding velocity.
3. Then calculating the wear rate of each material. For the present work we are using “Pin-on-Disc Friction
and Wear Testing Machine” manufactured by Magnum Engineers which gives the direct values of wear,
coefficient of friction and frictional force so, there is no need to calculate the wear and coefficient of
friction manually.
4. Then experimental results are analyzed with the “Design Expert 8 Software”. Analysis involves the
regression analysis of all four materials which can be done in “Design Expert 8 Software”. Analysis of
experimental data using the design expert software generates the equation of wear for each material. This
equation contains the variables as load, velocity of sliding and sliding distance. By putting the values of all
variables in the given equation we can calculate the wear of all materials. Then we will compare the values
of experimental wear with the values of wear which are obtained by solving the equation of wear.
Then perform the confirmation test. Confirmation tests are done to check the accuracy of the model by
selecting the random values of all involved variables.
III. Laboratory Work
3.1 Experimental Set up
The Pin on Disc Friction & Wear Testing Machine designed and developed
by MAGNUM ENGINEERS is primarily intended for determining the tribological characteristics of wide range
of materials under conditions of various normal loads, sliding speeds & temperatures (optional). A stationary pin
mounted on a pin holder is brought into contact against a rotating disc at a specified speed as the pin is sliding,
resulting frictional force acting between the pin and disc are measured by arresting the deflecting pin holder
against a load cell. Both normal load and speed can be set as desired. Results such as wear rate, frictional force
and coefficient of friction etc. are displayed digitally on the computer screen.
Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions
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3.2 Specifications of Friction & Wear Test Rig
1. Normal Load Range : 0 – 200 N
2. Frictional Force Range : 0 - 200N with a resolution of 1N with tare facility
3. Wear Measurement range : +/-2mm with tare facility RESULTS
4. Disc Speed : 100 to 3000 rpm
5. Preset Timer Range : up to 99:59:59
6. Wear Disc Track Diameter :10 mm- 140 mm
7. Specimen Diameter : 3 mm to 12 mm
8. Specimen Length : 25mm -30 mm
Figure 1: Experimental Set Up
3.3 Specimen Preparation
The standard rod of virgin PTFE and its composite with fillers such as 25% bronze, 25% glass fiber
and 25% carbon are available in the market. The sample specimen has been prepared by performing necessary
turning and facing operations on the respective rods.
Each specimen has the following dimension:
1. Diameter of Specimen : 8 mm
2. Length of Specimen : 25 mm
Figure 2: Test Specimens
Gap for Oil
Collection
Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions
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3.4 Procedure
1. Insert the test specimen into the pin holder.
2. Put the desired load on load span.
3. Switch on the control panel and set the desired speed and time.
4. Switch on the computer which is connected to the control panel and open the program Wear & Friction
monitor by double clicking the icon.
5. Then enter the desired parameters such as specimen diameter, speed, time, load etc. in the program.
6. Now click on “START TEST” icon of program and press the button “CYCLE START”
simultaneously. So the test will start after pressing the button.
7. As we are taking the tests in wet condition so switch on lubricant motor if continuous lubrication is
required otherwise drop lubrication can be done. Here we are using drop lubrication and dropping the
two drops of lubricant on the disc after every one minute.
8. Test will automatically stopped once preset time is over and the results are directly saved in computer.
There is no need to take the readings manually.
Above procedure can be used for various conditions of load, speed and time and for all test specimens.
Table 1: Assigning Codes for Four PTFE Materials
Material Chemical Composition in Wt.%
I Plain PTFE
II 25% Bronze filled PTFE
III 25% Glass fiber filled PTFE
IV 25% Carbon filled PTFE
3.5 Result Data
The Pin on Disc Friction & Wear Testing Machine designed and developed
by MAGNUM ENGINEERS shows results digitally. So, wear rate (microns), frictional force (N), and
coefficient of friction can be directly read and there is no need to calculate them manually which greatly saves
the time.
Table 2: Result Data of Material ‘I’ & ‘II’
Sr.
No.
Load
in
Weight
Span
(kg)
Disc
Speed
(N)in
(rpm)
Sliding
Distance
(L) in
(km)
Velocity
of
Sliding*
(Vr) in
(m/s)
Time*
(T) in
(min)
Wear Rate
(I) of
„Material I‟
in
(microns)
Coefficient
of Friction
of „Material
I‟ ( µ )
Wear Rate
(I) of
„Material
II‟ in
(microns)
Coefficient
of Friction
of „Material
II‟ ( µ )
1 1 500 1.5 2.62 9.55 19.556 0.1701 14.222 0.1779
2 1 700 3.0 3.66 14.04 24.222 0.1724 17.222 0.1764
3 1 900 4.5 4.71 16.32 25.111 0.1715 18.444 0.1753
4 2 500 3.0 2.62 19.09 33.222 0.1690 23.00 0.1708
5 2 700 4.5 3.66 20.49 34.44 0.1679 25.33 0.1724
6 2 900 1.5 4.71 5.30 19.55 0.1624 15.55 0.1692
7 3 500 4.5 2.62 29.02 54.22 0.1561 41.77 0.1599
8 3 700 1.5 3.66 7.23 22.22 0.1544 16.00 0.1582
9 3 900 3.0 4.71 11.01 23.22 0.1554 18.00 0.1601
Table 3: Result Data of Material ‘III’ & ‘IV’
Sr.
No.
Load in
Weight
Span
(kg)
Disc
Speed
(N)in
(rpm)
Sliding
Distance
(L) in
(km)
Velocity
of
Sliding*
(Vr) in
(m/s)
Time*
(T) in
(min)
Wear Rate
(I) of
„Material
III‟ in
(microns)
Coefficient of
Friction of
„Material III‟
( µ )
Wear Rate
(I) of
„Material
IV‟ in
(microns)
Coefficient of
Friction of
„Material IV‟
( µ )
1 1 500 1.5 2.62 9.55 13.556 0.1830 12.222 0.1894
2 1 700 3.0 3.66 14.04 16.555 0.1841 13.00 0.1897
3 1 900 4.5 4.71 16.32 17.555 0.1802 13.333 0.1860
4 2 500 3.0 2.62 19.09 22.22 0.1754 15.00 0.1797
5 2 700 4.5 3.66 20.49 23.33 0.1790 15.55 0.1798
6 2 900 1.5 4.71 5.30 15.00 0.1706 12.22 0.1766
7 3 500 4.5 2.62 29.02 36.11 0.1670 20.66 0.1692
8 3 700 1.5 3.66 7.23 16.33 0.1637 12.55 0.1687
9 3 900 3.0 4.71 11.01 16.55 0.1639 13.22 0.1696
*Velocity of sliding & Time is find out from sample calculation and early included in table 2& table 3.
Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions
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3.6 Sample Calculations
For material no. 1 & reading no. (1),
We have, N=500 rpm, L=1.5 Km, d=100 mm
Velocity of sliding Vr =  × d × N m/s
60
 Vr =  × 100×10-3
× 500 m/s
60
 Vr = 2.6179 m/s
 Vr = 2.62 m/s
Sliding distance L = Vr x T ……..m
 Time T = L Sec
Vr
 T = 1500
2.62
 T = 572.5190 Sec
 T = 9.55 min
In this way we can find out velocity of sliding and time for all materials and for all readings which are
summarized in table 2 & table 3.
Table 4: Cumulative Wear Data of All Materials
Sr. No Material Total Wear Rate (I) in (Microns) Average Coefficient of Friction
1 Plain PTFE 255.761 0.1644
2 PTFE + 25% Bronze 189.538 0.1689
3 PTFE + 25% Glass Fiber 177.206 0.1741
4 PTFE + 25% Carbon 127.755 0.1787
IV. Data Analysis & Interpretation
4.1 Regression Analysis of Material ‘I’
Linear regression analyses have been carried out based on the data collected as per design of
experiments, which are discussed below
Table 5: Model Fit Summary of Material ‘I’
Source
Sum of
Squares
Df
Mean
Square
F-value
P-value
Prob >F
Mean vs Total 7888.23 1 7888.23
Linear vs Mean 881.08 3 293.68 16.76 0.0025
2FI vs Linear 104.94 3 34.98 600.69 0.0001 Suggested
Quadratic vs 2FI 0.17 2 0.087 <0.0001 Aliased
Cubic vs Quadratic 0.000 0 0.000 Aliased
Residual 0.000 1 0.000
Total 8874.42 10 887.44
Select the highest order polynomial where the additional terms are significant and the model is not aliased.
Table 6: Model Summary Statistics of Material ‘I’
Source Std. Dev.
R-squared
Adjusted
R-squared
Predicted
R-Squared
PRESS
Linear 4.19 0.8934 0.8401 0.5731 421.03
2FI 0.24 0.9998 0.9995 0.9936 6.28 Suggested
Quadratic 0.000 1.0000 1.0000 + Aliased
Cubic + Aliased
Focus on the model maximizing the "Adjusted R-Squared" and the "Predicted R-Squared".
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From table 5 & 6 it is clear that for predicting the wear behaviour of material, the 2FI approach is
better compared to the Quadratic, Cubic approach hence 2FI approach is used for regression analysis of the
model as approach 1.
4.2 Linear Regression Analysis using 2FI Model
To establish the correlation between the wear parameters velocity of sliding, load and sliding distance,
multiple linear regression models is obtained using statistical software “DESIGN EXPERT 8”. The terms that
are statistically significant are included in the model. The regression coefficient of the model is 0.9991.
Table 7: Effect List of Parameters of Material ‘I’
Term Intercept Effect Sum of Squares % Contribution
A-load 4.17 159.82 16.84
B-velocity -4.53 264.48 27.86
C-sliding distance 6.26 469.03 49.42
AB -4.97 32.31 3.41
AC 3.97 18.63 1.96
BC -1.91 4.75 0.51
ABC Aliased
Lack Of Fit 0.17 0.087
The last column in table 7 shows the percentage contribution of each factor on the total variation indicating
their degree of influence on the result. One can observe from the above table that the sliding distance (49.42%)
has great influence on the wear; followed by velocity of sliding (27.86%). However, the interaction between the
velocity of sliding and sliding distance (0.51%) has negligible influence on the wear.
Table 8: ANOVA for Selected Factorial Model of Material ‘I’
Source Sum of
Squares
Df Mean
Square
F-value P-value
Prob > F
Model 986.02 6 164.34 2822.03 <0.0001
A-load 45.82 1 45.82 786.83 <0.0001
B-speed 58.19 1 58.19 999.2 <0.0001
C-sliding
distance
103.3 1 103.30 1773.88 <0.0001
AB 32.31 1 32.31 554.76 0.0002
AC 18.63 1 18.63 319.95 0.0004
BC 4.75 1 4.75 81.62 0.0029
Residual 0.17 3 0.058
Cor Total 986.19 9
This analysis was carried out for a level of significance of 5% i.e the level of confidance 95%. The
Model F-value of 2822.03 implies the model is significant. There is only a 0.01% chance that a "Model F-
Value" this large could occur due to noise. Values of "Prob > F" less than 0.0500 indicate model terms are
significant. In this case A, B, C, AB, BC, AC are significant model terms. Values greater than 0.1000 indicate
the model terms are not significant. Final equation in terms of actual factors is
Wear (Microns) = -8.89488 + 13.64941×Load + 8.82208×Velocity of Sliding + 3.33472×SD -
4.75357×Load×Velocity of Sliding + 2.64801×Load×SD - 1.21555×Velocity
of Sliding×SD …………. (1)
Substituting values of the variables for the above equation, the sliding wear of the material “I” can be
calculated. The positive value of the coefficient suggests that the sliding wear of material increases with their
associated variables. Whereas the negative value of the coefficient suggest that the sliding wear of the material
will decreases with the increase in associated variables.
Same procedure can be used for the regression analysis of material „II‟, material „III‟ & material „IV‟.
Therefore, for material „II‟, material „III‟ & material „IV‟ final equation in terms of actual factors are
Wear (Microns)= -8.23498 + 11.23300×Load + 8.84215×Velocity of Sliding - 1.73256×SD –
4.63657×Load×Velocity of Sliding + 3.22306×Load×SD - 0.52162×Velocity
of Sliding×SD …………. (2)
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Wear (Microns) = -7.63966 + 10.17766×Load + 6.87640×Velocity of Sliding + 1.54834×SD -
3.45471×Load×Velocity of Sliding + 1.81235×Load×SD - 0.76617×Velocity
of Sliding×SD ……………. (3)
Wear (Microns) = +5.56007 + 3.27859×Load + 2.50113×Velocity of Sliding - 0.10254×SD –
1.34578×Load×Velocity of Sliding + 0.90871×Load×SD - 0.21560×Velocity
of Sliding×SD ……………. (4)
4.3 Confirmation Test
To test the accuracy of the model the confirmation tests were performed by selecting the set of
parameters as shown in table 9. The wear value for materials calculated from the mathematical model developed
by 2FI Approach were compared with values obtained experimentally as shown in table 10.
Table 9: Parameters used in the Confirmation Test
Table 10: Confirmation Test of all Selected Materials
Material
Velocity
of
Sliding (Vr) in
(m/s)
Load in
(Kg)
Sliding
Distance in
(Km)
Actual
Wear
(Microns)
Predicted
Wear
(Microns)
Deviation
%
I
1.5 2 2 30.111 30.991 -2.923
2.8 3.5 2.5 40.886 39.995 2.184
II
1.5 2 2 21.666 21.446 1.011
2.8 3.5 2.5 30.956 30.619 1.088
III
1.5 2 2 17.85 17.258 3.310
2.8 3.5 2.5 31.985 31.373 1.913
IV
1.5 2 2 14.321 14.614 -2.049
2.8 3.5 2.5 16.756 17.035 -1.666
From the analysis of above table 10, we can observe that the calculated error varies from 1% to 3.31 %.
Therefore the multiple regression equation derived above correlate the evaluation of wear in the polymer with
the degree of approximation.
V. Results & Discussions
5.1 Interaction Effect of Parameters on Wear of Material ‘I’
Figure 3 shows interaction effect of load and velocity of sliding on wear at maximum sliding distance
4500 m. Figure 4 shows interaction effect of load and sliding distance on wear at maximum velocity 4.71m/s.
Figure 5 shows interaction effect of velocity of sliding and sliding distance on wear at maximum load 3 kg.
Figure 3: Graph of Interaction of Load and
Velocity of Sliding with Wear at SD=4500 m
Figure 4: Graph of Interaction of Load and
Sliding Distance with Wear at Vr =4.71 m/s
Material Test
Velocity of
Sliding (Vr)
in (m/s)
Load in (kg)
Sliding Distance (L)
in (km)
I
1 1.5 2 2
2 2.8 3.5 2.5
II
3 1.5 2 2
4 2.8 3.5 2.5
III
5 1.5 2 2
6 2.8 3.5 2.5
IV
7 1.5 2 2
8 2.8 3.5 2.5
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Figure 5: Graph of Interaction of Velocity of Sliding and SD with Wear at Load=3 Kg
5.2 Interaction Effect of Parameters on Wear of Material ‘II’
Figure 6 shows interaction effect of load and velocity of sliding on wear at maximum sliding distance
4500 m. Figure 7 shows interaction effect of load and sliding distance on wear at maximum velocity 4.71m/s.
Figure 8 shows interaction effect of velocity of sliding and sliding distance on wear at maximum load 3 kg.
Figure 6: Graph of Interaction of Load and
Velocity of Sliding with wear at SD=4500 m
Figure 7: Graph of Interaction of Load and
Sliding distance with Wear at Vr =4.71 m/s
Figure 8: Graph of Interaction of Velocity and SD. with Wear at Load=3 Kg
5.3 Interaction Effect of Parameters on Wear of Material ‘III’
Figure 9 shows interaction effect of load and velocity of sliding on wear at maximum sliding distance 4500
m. Figure 10 shows interaction effect of load and sliding distance on wear at maximum velocity 4.71m/s. Figure
11 shows interaction effect of velocity of sliding and sliding distance on wear at maximum load 3 kg.
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Figure 9: Graph of Interaction of Load and
Velocity of Sliding with Wear at SD=4500 m
Figure 10: Graph of Interaction of Load and
Sliding distance with Wear at Vr =4.71 m/s
Figure 11: Graph of Interaction of Velocity and SD with Wear at Load=3 Kg
5.4 Interaction Effect of Parameters on Wear of Material ‘IV’
Figure 12 shows interaction effect of load and velocity of sliding on wear at maximum sliding distance
4500 m. Figure 13 shows interaction effect of load and sliding distance on wear at maximum velocity 4.71m/s.
Figure 14 shows interaction effect of velocity of sliding and sliding distance on wear at maximum load 3 kg.
Figure 12: Graph of Interaction of Load and
Velocity of Sliding with Wear at SD=4500 m
Figure 13: Graph of Interaction of Load and
Sliding distance with Wear at Vr =4.71 m/s
Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions
www.iosrjournals.org 17 | Page
Figure 14: Graph of Interaction of Velocity and SD with Wear at Load=3 Kg
5.5 Comparative Study of Materials
One can observe from the Figure 15-17 that as load increases wear of all material goes on increasing
and sliding distance has great influence on the wear for of all the tested materials. For all the test materials as
velocity of sliding increases wear of all material goes on decreasing. It is observed that the wear of material
“IV” is less than material “III”, material “II” and pure PTFE i.e. material “I” has higher wear rate.
Figure 15: Wear v/s Load
Figure 16: Wear v/s Velocity of Sliding
Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions
www.iosrjournals.org 18 | Page
Figure 17: Wear v/s Sliding Distance
VI. Conclusions
The following conclusions can be drawn from the study:
 Addition of filler materials such as bronze, glass and carbon to PTFE causes an increase in hardness and
wear resistance, while the coefficient of friction is slightly increased.
 Wear of pure PTFE is decreased about 26% by adding 25% bronze, 31% by adding 25% glass and 50% by
adding 25% carbon.
 It is observed that the addition of carbon filler to plain PTFE improves wear resistance significantly as
compared to glass and bronze filler.
 Depending upon load, velocity of sliding and sliding distance, material used in this study can be ranked as
25% carbon filled PTFE > 25% glass filled PTFE > 25% bronze filled PTFE > pure PTFE for their wear
performance.
References
[1] Meigin Shi, F. Miyazawa, S. Tobe, T.A. Stolarski, “The friction and wear properties of PTFE composite- Thermal spray metallic
binary coatings”, Material transactions, Vol. 46, No. 1(2005) pp. 84-87.
[2] S.Basavarajappay and G.Chandramohan, “Wear studies on metal matrix composites: A Taguchi Approach”, J. Mater. Sci. Technol.
21 (2005) pp. 845-850.
[3] Deepak D. Bagale, “Wear analysis of PTFE and its composites under dry conditions using design expert”, ME dissertation, SSBT‟s
COET, Bambhori, Jalgaon, 2011-12.
[4] Jaydeep Khedkar, Ioan Negulescu and Efstathios I. Meletis, “Sliding wear behavior of PTFE composites”, Wear 252 (2002) pp.
361–369.
[5] H. Unal, A. Mimaroglu, U. Kadıoglu, H. Ekiz, “Sliding friction and wear behaviour of polytetrafluroethylene and its composites
under dry conditions”, Materials and Design 25 (2004) pp. 239-245.
[6] V.B.Raka, “Tribological behaviour of PTFE and its composites”, Innovations in Mechanical Engineering (IME‟ 10) (2010) pp.148-
155.
[7] D.S.Bajaj, G.J.Vikhe, Y.R.Kharde, “An investigation of tribological behavior of PTFE+ glass fiber against variable surface
roughness of counter surface”, Indian Journal of Tribology 3 (2008) pp. 47-54.

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Wear Analysis of Polytetrafluoroethylene (PTFE) and it’s Composites under Wet Conditions

  • 1. IOSR Journal of Mechanical and Civil Engineering (IOSR-JMCE) e-ISSN: 2278-1684,p-ISSN: 2320-334X, Volume 8, Issue 2 (Jul. - Aug. 2013), PP 07-18 www.iosrjournals.org www.iosrjournals.org 7 | Page Wear Analysis of Polytetrafluoroethylene (PTFE) and it’s Composites under Wet Conditions Sandip B. Chaudhari1 , Prof. S.P. Shekhawat2 1 P.G. Student, Department of Mechanical Engineering, SSBT’s COET, Bambhori, Maharashtra, India 2 Associate Professor, Department of Mechanical Engineering, SSBT’s COET, Bambhori, Maharashtra, India Abstract : In this paper, the effect of load, Velocity of sliding and sliding distance on friction and wear of materials made of Polytetrafluoroethylele (PTFE) and PTFE composites under wet condition with filler materials such as 25% bronze, 25% glass fiber and 25 % carbon have studied. The experimental work has performed on pin-on-disc friction and wear test rig and analyzed with the help of Design Expert software. The results of experiments are presented in tables and graphs which shows that the addition of bronze, glass and carbon filler to the virgin PTFE decreases wear rate significantly and there is marginal increase in coefficient of friction. The highest wear resistance was found for 25% carbon filled PTFE followed by 25% glass filled PTFE, 25% bronze filled PTFE and virgin PTFE. Through this study, we can develop the best bearing material for the various industrial applications which is available easily at the minimum cost. Keywords: Design of Experiments, Friction, Pin-on-Disc, Polytetrafluoroethylene (PTFE), Wear I. Introduction Tribological behaviour may be evaluated by several qualitative and quantitative parameters. We select friction coefficient and wear as relevant for this study. PTFE based materials are notable for their characteristics such as very low friction coefficient and good resistance to heat and corrosion in different application environments. Unfortunately, pure PTFE is not performing satisfactory in wear resistance and needs to be modified. The use of fillers and additives in PTFE is the most common way to improve its tribological and mechanical properties. The influence of fillers on the tribological behaviour of the composites cannot be predicted and has to be tested experimentally [1]. 1.1 Nature of Problem Unfortunately PTFE has poor thermal conductivity, high coefficient of thermal expansion and relatively not strong. PTFE suffers from poor wear resistance too. Because of this PTFE is suitable only for light loads and at low speeds. Because of the relative softness of PTFE, it is logical to expect that its load-carrying ability and its wear resistance might be improved by the addition of suitable fillers. Accordingly, several fillers were tried by researchers in combination with this plastic, including graphite, molybdenum disulfide, fiber glass, carbon ,bronze, dental silicate, silicon, titanium dioxide, silver, copper, tungsten and molybdenum [2]. 1.2 Previous Work Deepak Bagle [3] has studied the tribological behavior of polytetrafluoroethylene and its composites with filler materials as carbon and bronze under dry conditions. He found that addition of filler materials such as bronze and carbon to PTFE causes an increase in hardness and wear resistance, while the coefficient of friction is slightly increased. From the results the highest wear resistance was found for PTFE with carbon filler followed by PTFE with bronze filler and pure PTFE. Jaydeep Khedkar et al [4] studied the tribological behaviour of polytetrafluoroethylene (PTFE) and PTFE composites with filler materials such as carbon, graphite, glass fibers, MoS2 and poly-p-phenyleneterephthalamide (PPDT) fibers. The present filler additions found to increase hardness and wear resistance in all composites studied. The highest wear resistance was found for composites containing (i) 18% carbon + 7% graphite, (ii) 20% glass fibers + 5% MoS2 and (iii) 10% PPDT fibers. It was proposed by Lancaster [5] that addition of high aspect ratio filler materials (carbon fibers, glass fibers) to PTFE can improve its wear resistance due to preferential load supporting action by these fibers. There have also been some reports on the use of particulate filler materials like MoS2 and graphite to modify the tribological properties of PTFE.V.B. Raka [6], has study and analyze the effect of applied load, sliding velocity and sliding time on friction and wear behaviour of Polytetrafluoroethylene (PTFE) and its two composites viz. 25% carbon filled PTFE and 60% bronze filled PTFE, is experimentally examined and analytically analyzed. Taguchi‟s approach and L9 orthogonal array is used for design of experiment. Depending on pressure, sliding velocity and sliding time, material used in this study can be ranked as 60BFT>25CFT>PTFE for their friction
  • 2. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 8 | Page performance and 25CFT >60BFT >PTFE for their wear performance. Adding fillers to pure PTFE matrix reduces wear rate for both the composite used in the study. D.S. Bajaj et al [7], have studied the tribological properties of PTFE can be improved by adding some filler materials such as glass fibers, carbon, bronze, graphite. Friction and wear are very important surface phenomenon. This paper describes the dependency of wear and friction on surface roughness, sliding velocity and contact pressure for PTFE and its composites using a Pin- On-Disc tribometer. The parameters studied include wear rate and coefficient friction under varying load and for different surface roughness. 1.3 Purpose of Present Study The present study will be aimed at developing a new bearing material, which is known as super bush bearing material, which consists of carbon filled PTFE, glass fiber filled PTFE and bronze filled PTFE which is cost effective and superior in properties to the conventional bronze bearing materials. Fruitful research in this area could lead to development of superior and less expensive bearing materials. The new carbon filled PTFE, glass filled PTFE and bronze filled PTFE will be developed during the present investigation and the properties of these materials will be evaluated. Following are the main objectives of the study. a. To find the effect of carbon filler, bronze filler and glass fiber filler in PTFE on wear rate. b. To study the wear behaviour of the selected materials and the effect of various parameters like load, sliding velocity and sliding distance on wear rate. II. Experimental Tools, Techniques and Methodology 2.1 Design of Experiment It is methodology based on statistics and other discipline for arriving at an efficient and effective planning of experiments with a view to obtain valid conclusion from the analysis of experimental data. Design of experiments determines the pattern of observations to be made with a minimum of experimental efforts. To be specific Design of experiments (DOE) offers a systematic approach to study the effects of multiple variables / factors on products / process performance by providing a structural set of analysis in a design matrix. More specifically, the use of orthogonal Arrays (OA) for DOE provides an efficient and effective method for determining the most significant factors and interactions in a given design problem [3]. 2.2 Introduction to Design Expert Design-Expert, version 8 software (DX8) is a powerful and easy-to-use program for design of experiments (DOE). With it you can quickly set-up an experiment, analyze your data, and graphically display the results. This intuitive software is a must for anyone wanting to improve a process or a product. Design- Expert software offers an impressive array of design options and provides the flexibility to handle categorical factors and combine them with mixture and/or process variables. After building your design, generate a run sheet with your experiments laid out for you in randomized run order. DX8 offers features for ease of use, functionality and power that you won't find in general statistical packages. Add, delete or duplicate runs in any design with the handy design editor. Rotatable 3-D colour plots make response visualization easy [3]. 2.3 Taguchi Method Taguchi has envisaged a new method of conducting the design of experiments which are based on well defined guidelines. This method uses a special set of arrays called orthogonal array. These standard arrays stipulate the way of conducting the minimal number of experiments which could give the full information of all the factors that affect the performance parameter. The crux of the orthogonal arrays method lies in choosing the level combinations of the input design variables for each experiment. The technique of laying out the conditions of experiments involving multiple factors was first proposed by the Englishman, Sir R. A. Fisher. The method is popularly known as the factorial design of experiments. A full factorial design will identify all possible combinations for a given set of factors. Since most industrial experiments usually involve a significant number of factors, a full factorial design results in a large number of experiments. To reduce the number of experiments to a practical level, only a small set from all the possibilities is selected. The method of selecting a limited number of experiments which produces the most information is known as a partial fraction experiment. Although this method is well known, there are no general guidelines for its application or the analysis of the results obtained by performing the experiments. Taguchi constructed a special set of general design guidelines for factorial experiments that cover many applications. 2.4 Statistical Regression Analysis Statistical regression analysis is the study of the relationship between two or more variables, used to establish the empirical equation relating input-output parameters, by utilizing least square method. Moreover, it
  • 3. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 9 | Page is the most commonly used statistical modelling technique developed based on experimental data. The following steps are to be considered for carrying out statistical regression analysis of a process. 1. Identifying the important process control variables and finding their upper and lower limits. 2. Developing the design matrix (Statistical design of experiments). 3. Conducting the experiments as per the design matrix and recording the response parameters. 4. Developing the models and calculating the regression coefficients. 5. Checking the adequacy of the models. 6. Testing the significance of coefficients and arriving at the final models. 7. Presenting the direct and interaction effects of the process. 8. Analysis of Results. 2.5 Analysis of Variance (ANOVA) The adequacy of the models is tested using the analysis of variance (ANOVA) technique. It is a statistical tool for testing null hypothesis for designed experimentation, where a number of different variables are being studied simultaneously. ANOVA is used to quickly analyze the variances present in the experiment with the help of fisher test (F test). The results of F test indicate whether there are differences in the means due to varying the test conditions. If the estimates are similar, the changes of the subgroup averages being detectably different are small. If the estimates are significantly different, then the subgroup averages may be significantly different. If the F value calculated based on the data is greater than the F theoretical value based on F distribution, then the null hypothesis is rejected and the means are considered to be statistically significant. Usually analysis of variance computation would be done using a statistical software package. In the present work more number of variables are involved therefore, analysis of variance is carried out using the standard “Design Expert 8” statistical software. 2.6 Methodology In this study the wear rate of each material i.e. plain PTFE, 25% carbon filled PTFE, 25% bronze filled PTFE and 25% glass filled PTFE have been calculated under the wet conditions (Lubricated condition). So, we need the Pin-on-Disc apparatus for the experimental work which must provide the lubrication facility. For the present work following methodology has been followed. 1. It starts with the specimen preparation according to the “Pin-on-Disc Friction and Wear Testing Machine” specifications. The sample specimens has been prepared by performing necessary turning and facing operations on the respective rods. 2. After specimen preparation perform the wear test on each of the specimen for varying conditions of load, sliding distance and sliding velocity. 3. Then calculating the wear rate of each material. For the present work we are using “Pin-on-Disc Friction and Wear Testing Machine” manufactured by Magnum Engineers which gives the direct values of wear, coefficient of friction and frictional force so, there is no need to calculate the wear and coefficient of friction manually. 4. Then experimental results are analyzed with the “Design Expert 8 Software”. Analysis involves the regression analysis of all four materials which can be done in “Design Expert 8 Software”. Analysis of experimental data using the design expert software generates the equation of wear for each material. This equation contains the variables as load, velocity of sliding and sliding distance. By putting the values of all variables in the given equation we can calculate the wear of all materials. Then we will compare the values of experimental wear with the values of wear which are obtained by solving the equation of wear. Then perform the confirmation test. Confirmation tests are done to check the accuracy of the model by selecting the random values of all involved variables. III. Laboratory Work 3.1 Experimental Set up The Pin on Disc Friction & Wear Testing Machine designed and developed by MAGNUM ENGINEERS is primarily intended for determining the tribological characteristics of wide range of materials under conditions of various normal loads, sliding speeds & temperatures (optional). A stationary pin mounted on a pin holder is brought into contact against a rotating disc at a specified speed as the pin is sliding, resulting frictional force acting between the pin and disc are measured by arresting the deflecting pin holder against a load cell. Both normal load and speed can be set as desired. Results such as wear rate, frictional force and coefficient of friction etc. are displayed digitally on the computer screen.
  • 4. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 10 | Page 3.2 Specifications of Friction & Wear Test Rig 1. Normal Load Range : 0 – 200 N 2. Frictional Force Range : 0 - 200N with a resolution of 1N with tare facility 3. Wear Measurement range : +/-2mm with tare facility RESULTS 4. Disc Speed : 100 to 3000 rpm 5. Preset Timer Range : up to 99:59:59 6. Wear Disc Track Diameter :10 mm- 140 mm 7. Specimen Diameter : 3 mm to 12 mm 8. Specimen Length : 25mm -30 mm Figure 1: Experimental Set Up 3.3 Specimen Preparation The standard rod of virgin PTFE and its composite with fillers such as 25% bronze, 25% glass fiber and 25% carbon are available in the market. The sample specimen has been prepared by performing necessary turning and facing operations on the respective rods. Each specimen has the following dimension: 1. Diameter of Specimen : 8 mm 2. Length of Specimen : 25 mm Figure 2: Test Specimens Gap for Oil Collection
  • 5. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 11 | Page 3.4 Procedure 1. Insert the test specimen into the pin holder. 2. Put the desired load on load span. 3. Switch on the control panel and set the desired speed and time. 4. Switch on the computer which is connected to the control panel and open the program Wear & Friction monitor by double clicking the icon. 5. Then enter the desired parameters such as specimen diameter, speed, time, load etc. in the program. 6. Now click on “START TEST” icon of program and press the button “CYCLE START” simultaneously. So the test will start after pressing the button. 7. As we are taking the tests in wet condition so switch on lubricant motor if continuous lubrication is required otherwise drop lubrication can be done. Here we are using drop lubrication and dropping the two drops of lubricant on the disc after every one minute. 8. Test will automatically stopped once preset time is over and the results are directly saved in computer. There is no need to take the readings manually. Above procedure can be used for various conditions of load, speed and time and for all test specimens. Table 1: Assigning Codes for Four PTFE Materials Material Chemical Composition in Wt.% I Plain PTFE II 25% Bronze filled PTFE III 25% Glass fiber filled PTFE IV 25% Carbon filled PTFE 3.5 Result Data The Pin on Disc Friction & Wear Testing Machine designed and developed by MAGNUM ENGINEERS shows results digitally. So, wear rate (microns), frictional force (N), and coefficient of friction can be directly read and there is no need to calculate them manually which greatly saves the time. Table 2: Result Data of Material ‘I’ & ‘II’ Sr. No. Load in Weight Span (kg) Disc Speed (N)in (rpm) Sliding Distance (L) in (km) Velocity of Sliding* (Vr) in (m/s) Time* (T) in (min) Wear Rate (I) of „Material I‟ in (microns) Coefficient of Friction of „Material I‟ ( µ ) Wear Rate (I) of „Material II‟ in (microns) Coefficient of Friction of „Material II‟ ( µ ) 1 1 500 1.5 2.62 9.55 19.556 0.1701 14.222 0.1779 2 1 700 3.0 3.66 14.04 24.222 0.1724 17.222 0.1764 3 1 900 4.5 4.71 16.32 25.111 0.1715 18.444 0.1753 4 2 500 3.0 2.62 19.09 33.222 0.1690 23.00 0.1708 5 2 700 4.5 3.66 20.49 34.44 0.1679 25.33 0.1724 6 2 900 1.5 4.71 5.30 19.55 0.1624 15.55 0.1692 7 3 500 4.5 2.62 29.02 54.22 0.1561 41.77 0.1599 8 3 700 1.5 3.66 7.23 22.22 0.1544 16.00 0.1582 9 3 900 3.0 4.71 11.01 23.22 0.1554 18.00 0.1601 Table 3: Result Data of Material ‘III’ & ‘IV’ Sr. No. Load in Weight Span (kg) Disc Speed (N)in (rpm) Sliding Distance (L) in (km) Velocity of Sliding* (Vr) in (m/s) Time* (T) in (min) Wear Rate (I) of „Material III‟ in (microns) Coefficient of Friction of „Material III‟ ( µ ) Wear Rate (I) of „Material IV‟ in (microns) Coefficient of Friction of „Material IV‟ ( µ ) 1 1 500 1.5 2.62 9.55 13.556 0.1830 12.222 0.1894 2 1 700 3.0 3.66 14.04 16.555 0.1841 13.00 0.1897 3 1 900 4.5 4.71 16.32 17.555 0.1802 13.333 0.1860 4 2 500 3.0 2.62 19.09 22.22 0.1754 15.00 0.1797 5 2 700 4.5 3.66 20.49 23.33 0.1790 15.55 0.1798 6 2 900 1.5 4.71 5.30 15.00 0.1706 12.22 0.1766 7 3 500 4.5 2.62 29.02 36.11 0.1670 20.66 0.1692 8 3 700 1.5 3.66 7.23 16.33 0.1637 12.55 0.1687 9 3 900 3.0 4.71 11.01 16.55 0.1639 13.22 0.1696 *Velocity of sliding & Time is find out from sample calculation and early included in table 2& table 3.
  • 6. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 12 | Page 3.6 Sample Calculations For material no. 1 & reading no. (1), We have, N=500 rpm, L=1.5 Km, d=100 mm Velocity of sliding Vr =  × d × N m/s 60  Vr =  × 100×10-3 × 500 m/s 60  Vr = 2.6179 m/s  Vr = 2.62 m/s Sliding distance L = Vr x T ……..m  Time T = L Sec Vr  T = 1500 2.62  T = 572.5190 Sec  T = 9.55 min In this way we can find out velocity of sliding and time for all materials and for all readings which are summarized in table 2 & table 3. Table 4: Cumulative Wear Data of All Materials Sr. No Material Total Wear Rate (I) in (Microns) Average Coefficient of Friction 1 Plain PTFE 255.761 0.1644 2 PTFE + 25% Bronze 189.538 0.1689 3 PTFE + 25% Glass Fiber 177.206 0.1741 4 PTFE + 25% Carbon 127.755 0.1787 IV. Data Analysis & Interpretation 4.1 Regression Analysis of Material ‘I’ Linear regression analyses have been carried out based on the data collected as per design of experiments, which are discussed below Table 5: Model Fit Summary of Material ‘I’ Source Sum of Squares Df Mean Square F-value P-value Prob >F Mean vs Total 7888.23 1 7888.23 Linear vs Mean 881.08 3 293.68 16.76 0.0025 2FI vs Linear 104.94 3 34.98 600.69 0.0001 Suggested Quadratic vs 2FI 0.17 2 0.087 <0.0001 Aliased Cubic vs Quadratic 0.000 0 0.000 Aliased Residual 0.000 1 0.000 Total 8874.42 10 887.44 Select the highest order polynomial where the additional terms are significant and the model is not aliased. Table 6: Model Summary Statistics of Material ‘I’ Source Std. Dev. R-squared Adjusted R-squared Predicted R-Squared PRESS Linear 4.19 0.8934 0.8401 0.5731 421.03 2FI 0.24 0.9998 0.9995 0.9936 6.28 Suggested Quadratic 0.000 1.0000 1.0000 + Aliased Cubic + Aliased Focus on the model maximizing the "Adjusted R-Squared" and the "Predicted R-Squared".
  • 7. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 13 | Page From table 5 & 6 it is clear that for predicting the wear behaviour of material, the 2FI approach is better compared to the Quadratic, Cubic approach hence 2FI approach is used for regression analysis of the model as approach 1. 4.2 Linear Regression Analysis using 2FI Model To establish the correlation between the wear parameters velocity of sliding, load and sliding distance, multiple linear regression models is obtained using statistical software “DESIGN EXPERT 8”. The terms that are statistically significant are included in the model. The regression coefficient of the model is 0.9991. Table 7: Effect List of Parameters of Material ‘I’ Term Intercept Effect Sum of Squares % Contribution A-load 4.17 159.82 16.84 B-velocity -4.53 264.48 27.86 C-sliding distance 6.26 469.03 49.42 AB -4.97 32.31 3.41 AC 3.97 18.63 1.96 BC -1.91 4.75 0.51 ABC Aliased Lack Of Fit 0.17 0.087 The last column in table 7 shows the percentage contribution of each factor on the total variation indicating their degree of influence on the result. One can observe from the above table that the sliding distance (49.42%) has great influence on the wear; followed by velocity of sliding (27.86%). However, the interaction between the velocity of sliding and sliding distance (0.51%) has negligible influence on the wear. Table 8: ANOVA for Selected Factorial Model of Material ‘I’ Source Sum of Squares Df Mean Square F-value P-value Prob > F Model 986.02 6 164.34 2822.03 <0.0001 A-load 45.82 1 45.82 786.83 <0.0001 B-speed 58.19 1 58.19 999.2 <0.0001 C-sliding distance 103.3 1 103.30 1773.88 <0.0001 AB 32.31 1 32.31 554.76 0.0002 AC 18.63 1 18.63 319.95 0.0004 BC 4.75 1 4.75 81.62 0.0029 Residual 0.17 3 0.058 Cor Total 986.19 9 This analysis was carried out for a level of significance of 5% i.e the level of confidance 95%. The Model F-value of 2822.03 implies the model is significant. There is only a 0.01% chance that a "Model F- Value" this large could occur due to noise. Values of "Prob > F" less than 0.0500 indicate model terms are significant. In this case A, B, C, AB, BC, AC are significant model terms. Values greater than 0.1000 indicate the model terms are not significant. Final equation in terms of actual factors is Wear (Microns) = -8.89488 + 13.64941×Load + 8.82208×Velocity of Sliding + 3.33472×SD - 4.75357×Load×Velocity of Sliding + 2.64801×Load×SD - 1.21555×Velocity of Sliding×SD …………. (1) Substituting values of the variables for the above equation, the sliding wear of the material “I” can be calculated. The positive value of the coefficient suggests that the sliding wear of material increases with their associated variables. Whereas the negative value of the coefficient suggest that the sliding wear of the material will decreases with the increase in associated variables. Same procedure can be used for the regression analysis of material „II‟, material „III‟ & material „IV‟. Therefore, for material „II‟, material „III‟ & material „IV‟ final equation in terms of actual factors are Wear (Microns)= -8.23498 + 11.23300×Load + 8.84215×Velocity of Sliding - 1.73256×SD – 4.63657×Load×Velocity of Sliding + 3.22306×Load×SD - 0.52162×Velocity of Sliding×SD …………. (2)
  • 8. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 14 | Page Wear (Microns) = -7.63966 + 10.17766×Load + 6.87640×Velocity of Sliding + 1.54834×SD - 3.45471×Load×Velocity of Sliding + 1.81235×Load×SD - 0.76617×Velocity of Sliding×SD ……………. (3) Wear (Microns) = +5.56007 + 3.27859×Load + 2.50113×Velocity of Sliding - 0.10254×SD – 1.34578×Load×Velocity of Sliding + 0.90871×Load×SD - 0.21560×Velocity of Sliding×SD ……………. (4) 4.3 Confirmation Test To test the accuracy of the model the confirmation tests were performed by selecting the set of parameters as shown in table 9. The wear value for materials calculated from the mathematical model developed by 2FI Approach were compared with values obtained experimentally as shown in table 10. Table 9: Parameters used in the Confirmation Test Table 10: Confirmation Test of all Selected Materials Material Velocity of Sliding (Vr) in (m/s) Load in (Kg) Sliding Distance in (Km) Actual Wear (Microns) Predicted Wear (Microns) Deviation % I 1.5 2 2 30.111 30.991 -2.923 2.8 3.5 2.5 40.886 39.995 2.184 II 1.5 2 2 21.666 21.446 1.011 2.8 3.5 2.5 30.956 30.619 1.088 III 1.5 2 2 17.85 17.258 3.310 2.8 3.5 2.5 31.985 31.373 1.913 IV 1.5 2 2 14.321 14.614 -2.049 2.8 3.5 2.5 16.756 17.035 -1.666 From the analysis of above table 10, we can observe that the calculated error varies from 1% to 3.31 %. Therefore the multiple regression equation derived above correlate the evaluation of wear in the polymer with the degree of approximation. V. Results & Discussions 5.1 Interaction Effect of Parameters on Wear of Material ‘I’ Figure 3 shows interaction effect of load and velocity of sliding on wear at maximum sliding distance 4500 m. Figure 4 shows interaction effect of load and sliding distance on wear at maximum velocity 4.71m/s. Figure 5 shows interaction effect of velocity of sliding and sliding distance on wear at maximum load 3 kg. Figure 3: Graph of Interaction of Load and Velocity of Sliding with Wear at SD=4500 m Figure 4: Graph of Interaction of Load and Sliding Distance with Wear at Vr =4.71 m/s Material Test Velocity of Sliding (Vr) in (m/s) Load in (kg) Sliding Distance (L) in (km) I 1 1.5 2 2 2 2.8 3.5 2.5 II 3 1.5 2 2 4 2.8 3.5 2.5 III 5 1.5 2 2 6 2.8 3.5 2.5 IV 7 1.5 2 2 8 2.8 3.5 2.5
  • 9. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 15 | Page Figure 5: Graph of Interaction of Velocity of Sliding and SD with Wear at Load=3 Kg 5.2 Interaction Effect of Parameters on Wear of Material ‘II’ Figure 6 shows interaction effect of load and velocity of sliding on wear at maximum sliding distance 4500 m. Figure 7 shows interaction effect of load and sliding distance on wear at maximum velocity 4.71m/s. Figure 8 shows interaction effect of velocity of sliding and sliding distance on wear at maximum load 3 kg. Figure 6: Graph of Interaction of Load and Velocity of Sliding with wear at SD=4500 m Figure 7: Graph of Interaction of Load and Sliding distance with Wear at Vr =4.71 m/s Figure 8: Graph of Interaction of Velocity and SD. with Wear at Load=3 Kg 5.3 Interaction Effect of Parameters on Wear of Material ‘III’ Figure 9 shows interaction effect of load and velocity of sliding on wear at maximum sliding distance 4500 m. Figure 10 shows interaction effect of load and sliding distance on wear at maximum velocity 4.71m/s. Figure 11 shows interaction effect of velocity of sliding and sliding distance on wear at maximum load 3 kg.
  • 10. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 16 | Page Figure 9: Graph of Interaction of Load and Velocity of Sliding with Wear at SD=4500 m Figure 10: Graph of Interaction of Load and Sliding distance with Wear at Vr =4.71 m/s Figure 11: Graph of Interaction of Velocity and SD with Wear at Load=3 Kg 5.4 Interaction Effect of Parameters on Wear of Material ‘IV’ Figure 12 shows interaction effect of load and velocity of sliding on wear at maximum sliding distance 4500 m. Figure 13 shows interaction effect of load and sliding distance on wear at maximum velocity 4.71m/s. Figure 14 shows interaction effect of velocity of sliding and sliding distance on wear at maximum load 3 kg. Figure 12: Graph of Interaction of Load and Velocity of Sliding with Wear at SD=4500 m Figure 13: Graph of Interaction of Load and Sliding distance with Wear at Vr =4.71 m/s
  • 11. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 17 | Page Figure 14: Graph of Interaction of Velocity and SD with Wear at Load=3 Kg 5.5 Comparative Study of Materials One can observe from the Figure 15-17 that as load increases wear of all material goes on increasing and sliding distance has great influence on the wear for of all the tested materials. For all the test materials as velocity of sliding increases wear of all material goes on decreasing. It is observed that the wear of material “IV” is less than material “III”, material “II” and pure PTFE i.e. material “I” has higher wear rate. Figure 15: Wear v/s Load Figure 16: Wear v/s Velocity of Sliding
  • 12. Wear Analysis of Polytetrafluoroethylene (PTFE) & it’s Composites under Wet Conditions www.iosrjournals.org 18 | Page Figure 17: Wear v/s Sliding Distance VI. Conclusions The following conclusions can be drawn from the study:  Addition of filler materials such as bronze, glass and carbon to PTFE causes an increase in hardness and wear resistance, while the coefficient of friction is slightly increased.  Wear of pure PTFE is decreased about 26% by adding 25% bronze, 31% by adding 25% glass and 50% by adding 25% carbon.  It is observed that the addition of carbon filler to plain PTFE improves wear resistance significantly as compared to glass and bronze filler.  Depending upon load, velocity of sliding and sliding distance, material used in this study can be ranked as 25% carbon filled PTFE > 25% glass filled PTFE > 25% bronze filled PTFE > pure PTFE for their wear performance. References [1] Meigin Shi, F. Miyazawa, S. Tobe, T.A. Stolarski, “The friction and wear properties of PTFE composite- Thermal spray metallic binary coatings”, Material transactions, Vol. 46, No. 1(2005) pp. 84-87. [2] S.Basavarajappay and G.Chandramohan, “Wear studies on metal matrix composites: A Taguchi Approach”, J. Mater. Sci. Technol. 21 (2005) pp. 845-850. [3] Deepak D. Bagale, “Wear analysis of PTFE and its composites under dry conditions using design expert”, ME dissertation, SSBT‟s COET, Bambhori, Jalgaon, 2011-12. [4] Jaydeep Khedkar, Ioan Negulescu and Efstathios I. Meletis, “Sliding wear behavior of PTFE composites”, Wear 252 (2002) pp. 361–369. [5] H. Unal, A. Mimaroglu, U. Kadıoglu, H. Ekiz, “Sliding friction and wear behaviour of polytetrafluroethylene and its composites under dry conditions”, Materials and Design 25 (2004) pp. 239-245. [6] V.B.Raka, “Tribological behaviour of PTFE and its composites”, Innovations in Mechanical Engineering (IME‟ 10) (2010) pp.148- 155. [7] D.S.Bajaj, G.J.Vikhe, Y.R.Kharde, “An investigation of tribological behavior of PTFE+ glass fiber against variable surface roughness of counter surface”, Indian Journal of Tribology 3 (2008) pp. 47-54.