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International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-3, Issue-3, Mar- 2017]
https://dx.doi.org/10.24001/ijaems.3.3.19 ISSN: 2454-1311
www.ijaems.com Page | 254
Analysis of fumes emitted during hard facing of
FCAW wires
Mithra S, Venkatakrishnan P G
1
Department of Metallurgical Engineering, Government college of Engineering, Salem, India
Abstract—Flux Cored Arc Welding (FCAW) wires are
widely used for hard facing as they provide high deposition
efficiency, wear resistance and faster speed rates than the
solid wire used in Gas Metal Arc Welding process. Flux
Cored Arc Welding process employs cored electrodes which
contain the fluxing agents, metal powder, deoxidizers and
Ferro alloys which contribute the fume emissions during the
welding operation. The flux ingredients used vary based on
the applications. An open-arc FCAW wire developed for
high temperature wear resistance applications comprise
borides, carbides of iron based alloy system. A high level of
smoke is generated during welding with this wire which
reduces the weld pool visibility. The research work is
carried out to reduce the emission of fumes up to 70-80%
(from present fume emission level) without affecting
composition and wear behaviour of the alloy thereby
making the wire environmental friendly.
Keywords—Carbides of iron based alloy system,
Deoxidizers, Flux Cored Arc Welding, High temperature
wear resistance, Weld pool visibility.
I. INTRODUCTION
The fumes generated during welding mainly come from the
combustion of the volatile materials that is added during
welding. The volatile material that is supplied to the
welding is through flux material added to the welding
process. Not in all welding process flux is added, they are
generally added in the consumable welding process such as
Shielded Metal Arc Welding (SMAW), Gas Metal Arc
Welding (GMAW), Flux Cored Arc Welding (FCAW) and
Submerged Arc Welding (SAW). These processes can be
differentiated based on the way the flux is supplied. In
SMAW flux is added in the form of coated electrode, in
FCAW the flux is added in the form of cored electrodes, in
GMAW, the consumable is in the form of solid wire
whereas in SAW process granulated flux is used. In order to
protect the arc the external shielding medium is provided.
The external shielding medium not only provides stable
operation but also provide shielding from external
atmosphere to prevent contamination of the weld
A study was performed to investigate the factors
contributing to the emission of welding fumes and the main
factors that manipulate the fume formation are welding
current, voltage, shielding gases, mode of metal transfer,
and the chemical composition of the material welded. All
such factors are interrelated and hence they influence one
over the other. The influence of each factor on weld fume
emission was explored to understand the most effective
factors for minimizing the welding fumes.
The initial evaluation focused on determining the flux
ingredients that are more in the fumes through X-RAY
diffraction. The mode of metal transfer occurring during the
process is viewed through high speed camera to find spray
transition current at which reduced smoke level is obtained.
The amount of fume emission is reduced by bringing the
drop spray mode of metal transfer by varying the current
parameter.
II. LITERATURE REVIEW
The welding process is accompanied by emission of fumes.
In order to minimize the fumes emitted during welding a
thorough knowledge regarding the factors that causing the
welding fumes. The factors that contribute for the formation
of the welding fumes are Electrode, Welding speed,
Shielding gas, Welding processes, Welding parameters,
Welding geometry and Base metal. Fume generation during
welding can be reduced by controlling the factors that
contribute the emission of welding fumes. From the study,
it can be stated that influence of all the factors such as
welding current, voltage, shielding gas and chemical
composition on the fume generation, are interrelated.
Moreover fume emission solely depends on these factors.
Therefore it is necessary to choose a suitable combination
of parameter for generating better mode of metal transfer.
III. EXPERIMENTAL WORK
To analyze the fumes a comparative study is made between
two wires namely HPW and 6430 wire. The HPW wire is
highly problematic as it emits enormous amounts of fume
during applications. The properties of the wires are essential
International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-3, Issue-3, Mar- 2017]
https://dx.doi.org/10.24001/ijaems.3.3.19 ISSN: 2454-1311
www.ijaems.com Page | 255
as it is widely employed for high temperature applications.
Therefore it highly affects the weld pool visibility. but in
case of 6430 wire the fumes are not much higher . the
chemical composition of the wires are almost similar except
some components. In order to fine the component which is
emitting the following studies have been made.
3.1 CHEMICAL COMPOSITION OF FCAW WIRES
The comparison of chemical composition of the two wires
are made in the following tables
Table.3.1: chemical composition of 6430 wire
S.no Name of the material in
power form
Quantity
(weight %)
1 Boron carbide 1-3
2 Hydrocarbon ferro
chromium
80-90
3 Graphite 3-6
4 Ferro niobium 2-4
5 Silicon carbide 1-3
6 Ferro silicon zirconium 1-3
7 Sodium fluoride 0.2-2
Table.3.2: Chemical composition of HPW wire
S.NO Name of the material (in
powder form)
Quantity (in
weight %)
1 Ferro-Molybdenum 10-14
2 Ferro-Niobium 10-15
3 Tungsten carbide 5-10
4 Boron carbide 7-12
5 Ferro-chromium 8-12
6 Manganese 1-5
7 Chromium 20-30
8 Ferro-Titanium 1-4
9 Ferro silicon manganese 1-3
10 Ferro silicon zirconium 1-3
11 Chromium Nitride 4-6
12 Fluorspar 0.2-2
13 Sodium fluoride 0.2-2
Table.3.3: Comparison of two wires
HPW WIRE 6430 WIRE
Hardness HRc 65 Hardness HRc 60
High temperature wear
application
Ambient temperature
applications
High fume level and
poor weld pool visibility
Common as in other
welding process
WELD BEAD OF 6430 WIRE
Fig.1: Weld bead of 6430 wire
WELD BEAD OF HPW WIRE
Fig.2: Weld bead ofHPWwire
3.2 VARIATION OF WELD BEAD SIZE WITH
CURRENT
The bead size generally increases with the increase in the
current. The spatter is enormous in case of HPW wire and
over a particular range of current the spatter is found to
decrease and the fume is also reduced over that range
International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-3, Issue-3, Mar- 2017]
https://dx.doi.org/10.24001/ijaems.3.3.19 ISSN: 2454-1311
www.ijaems.com Page | 256
Fig.3: Variation of weld bead size with current
3.3 METALLOGRAPHIC EXAMINATION
The weld beads are sectioned and examined
metallographically. The samples are emery polished first
and then with cloth polishing. The etchant used is pikral
and the etching time is 10 to 15 seconds. The micrographs
obtained from 6430 and HPW flux cored wires are shown
in the figure 4 and 5
MICROSTRUCTURE OF HPW WIRE
a) Base Metal
b) Heat affected Zone
c) Weld metal
Fig.4: Microstructures of 6430 wire
MICROSTRUCTURE OF HPW WIRE
a) Weld Metal
b)Heat affected Zone
50X
50X
50X
50X
50X
International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-3, Issue-3, Mar- 2017]
https://dx.doi.org/10.24001/ijaems.3.3.19 ISSN: 2454-1311
www.ijaems.com Page | 257
c)Base metal
Fig.5: Microstructures of HPW wire
From the micrographs it can be inferred that base metal is mild
steels and weld bead gives superior martensitic microstructure
and HAZ is superior in case of HPW wire than the 6430 wire .the
proximity to cracks are limited in case of HPW wire. Hence
HPW wire has superior properties when compared with 6430
wire
3.4 X RAY DIFFRACTION
The fumes of HPW wire and 6430 wire are collected using
vacuum pump and are examined for X RAY diffraction. The X-
ray diffraction is done in D8 BRUKER axswith copper k alpha
radiation.
HPW FLUX VS FUMES
Fig.6: X ray graph of HPW flux and fumes
HPW FLUX
Fig.7: X ray graph of HPW flux
HPW FUMES
Fig.8: X ray graph of HPW fume
6430 FLUX VS FUMES
Fig.9: X ray graph of HPW fume
International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-3, Issue-3, Mar- 2017]
https://dx.doi.org/10.24001/ijaems.3.3.19 ISSN: 2454-1311
www.ijaems.com Page | 258
6430 FLUX
Fig.10: X ray graph of 6430 flux
6430 FUMES
Fig.11: X ray graph of 6430 fume
From the graph it has been found that the most emitting
component in HPW wire is Fe2O3 which is not emitted in
the 6430 wire. So the reason behind the fumes in HPW wire
is Fe2O3. The chemistry behind the fume emission has to be
analyzed.
IV. CONCLUSION
From the various analyses the problematic wire HPW is
superior in its properties. But its fume emission is the only
problem that restricts the usage of such wire. So its fume
emission should be reduced through optimizing the current
parameter but not with changing the chemical composition
of the flux as it plays a major role in their properties.
REFERENCES
[1] Carpenter K.R., Monaghan B.J. and Norrish J.(2009),
‘Influence of Shielding Gas on Fume Formation Rate
For Gas Metal Arc Welding of Plain Carbon Steels’,
ASM international, p 436-442
[2] Den Ouden G, Hermans M.J.M. (2009), “Welding
technology”, Delft University of technology.
[3] Eagar T.W and Kim Y.S (1993), ‘Metal transfer in
pulsed current GMAW’, Welding Journal Vol. 72
No.6 PP. 279-287
[4] Geoffrey Slater (2004), ‘Weld Fume Plume
Dispersion’, University of Wollongong, theses 384.
[5] Haidar J and Lowke J J (1997), ‘Effect of CO2
shielding gas on metal droplet formation in arc
welding’, IEEE Trans. Plasma Sc. Vol.25 No.5, P931-
936
[6] Heile R. F., and Hill D.C (1975), ‘Particulate fume
generation in arc welding processes’, Weld. J., 54,
201s–210s
[7] Hermans M.J.M, Den Ouden G (1999), ‘Process
behavior and stability in short circuit gas metal arc
welding’, Weld J 78(4):137–141
[8] Ian Richarclson, John Norrish and Marcel Hermans
(1989) ‘The mechanism and significance of drop spray
transfer in GMAW’, International Institute of
Welding, IIW-1893-06.
[9] Ines Pires, Luisa Quintino, Victor Amaral (2010),
Tobias Rosado, ‘Reduction of Fume And Gas
Emissions Using Innovative Gas Metal Arc Welding
Variants’, International journal for advanced
manufacturing technology, 50:557-567.
[10] John Norrish (2006), ‘Advanced welding processes,
Technologies and process control’, Institute of Physics
Publishing.
[11] Lancaster J F (1986), ‘The physics of welding’, 2nd
Edition, Pergamon Press, ISBN 0-08-034076-8, p246.
[12] LevchenkoO.G(1998), ‘Methods of reducing the
generation of the welding fumes’, Welding
international 1998 12(9) 747-752.

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Analysis of fumes emitted during hard facing of FCAW wires

  • 1. International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-3, Issue-3, Mar- 2017] https://dx.doi.org/10.24001/ijaems.3.3.19 ISSN: 2454-1311 www.ijaems.com Page | 254 Analysis of fumes emitted during hard facing of FCAW wires Mithra S, Venkatakrishnan P G 1 Department of Metallurgical Engineering, Government college of Engineering, Salem, India Abstract—Flux Cored Arc Welding (FCAW) wires are widely used for hard facing as they provide high deposition efficiency, wear resistance and faster speed rates than the solid wire used in Gas Metal Arc Welding process. Flux Cored Arc Welding process employs cored electrodes which contain the fluxing agents, metal powder, deoxidizers and Ferro alloys which contribute the fume emissions during the welding operation. The flux ingredients used vary based on the applications. An open-arc FCAW wire developed for high temperature wear resistance applications comprise borides, carbides of iron based alloy system. A high level of smoke is generated during welding with this wire which reduces the weld pool visibility. The research work is carried out to reduce the emission of fumes up to 70-80% (from present fume emission level) without affecting composition and wear behaviour of the alloy thereby making the wire environmental friendly. Keywords—Carbides of iron based alloy system, Deoxidizers, Flux Cored Arc Welding, High temperature wear resistance, Weld pool visibility. I. INTRODUCTION The fumes generated during welding mainly come from the combustion of the volatile materials that is added during welding. The volatile material that is supplied to the welding is through flux material added to the welding process. Not in all welding process flux is added, they are generally added in the consumable welding process such as Shielded Metal Arc Welding (SMAW), Gas Metal Arc Welding (GMAW), Flux Cored Arc Welding (FCAW) and Submerged Arc Welding (SAW). These processes can be differentiated based on the way the flux is supplied. In SMAW flux is added in the form of coated electrode, in FCAW the flux is added in the form of cored electrodes, in GMAW, the consumable is in the form of solid wire whereas in SAW process granulated flux is used. In order to protect the arc the external shielding medium is provided. The external shielding medium not only provides stable operation but also provide shielding from external atmosphere to prevent contamination of the weld A study was performed to investigate the factors contributing to the emission of welding fumes and the main factors that manipulate the fume formation are welding current, voltage, shielding gases, mode of metal transfer, and the chemical composition of the material welded. All such factors are interrelated and hence they influence one over the other. The influence of each factor on weld fume emission was explored to understand the most effective factors for minimizing the welding fumes. The initial evaluation focused on determining the flux ingredients that are more in the fumes through X-RAY diffraction. The mode of metal transfer occurring during the process is viewed through high speed camera to find spray transition current at which reduced smoke level is obtained. The amount of fume emission is reduced by bringing the drop spray mode of metal transfer by varying the current parameter. II. LITERATURE REVIEW The welding process is accompanied by emission of fumes. In order to minimize the fumes emitted during welding a thorough knowledge regarding the factors that causing the welding fumes. The factors that contribute for the formation of the welding fumes are Electrode, Welding speed, Shielding gas, Welding processes, Welding parameters, Welding geometry and Base metal. Fume generation during welding can be reduced by controlling the factors that contribute the emission of welding fumes. From the study, it can be stated that influence of all the factors such as welding current, voltage, shielding gas and chemical composition on the fume generation, are interrelated. Moreover fume emission solely depends on these factors. Therefore it is necessary to choose a suitable combination of parameter for generating better mode of metal transfer. III. EXPERIMENTAL WORK To analyze the fumes a comparative study is made between two wires namely HPW and 6430 wire. The HPW wire is highly problematic as it emits enormous amounts of fume during applications. The properties of the wires are essential
  • 2. International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-3, Issue-3, Mar- 2017] https://dx.doi.org/10.24001/ijaems.3.3.19 ISSN: 2454-1311 www.ijaems.com Page | 255 as it is widely employed for high temperature applications. Therefore it highly affects the weld pool visibility. but in case of 6430 wire the fumes are not much higher . the chemical composition of the wires are almost similar except some components. In order to fine the component which is emitting the following studies have been made. 3.1 CHEMICAL COMPOSITION OF FCAW WIRES The comparison of chemical composition of the two wires are made in the following tables Table.3.1: chemical composition of 6430 wire S.no Name of the material in power form Quantity (weight %) 1 Boron carbide 1-3 2 Hydrocarbon ferro chromium 80-90 3 Graphite 3-6 4 Ferro niobium 2-4 5 Silicon carbide 1-3 6 Ferro silicon zirconium 1-3 7 Sodium fluoride 0.2-2 Table.3.2: Chemical composition of HPW wire S.NO Name of the material (in powder form) Quantity (in weight %) 1 Ferro-Molybdenum 10-14 2 Ferro-Niobium 10-15 3 Tungsten carbide 5-10 4 Boron carbide 7-12 5 Ferro-chromium 8-12 6 Manganese 1-5 7 Chromium 20-30 8 Ferro-Titanium 1-4 9 Ferro silicon manganese 1-3 10 Ferro silicon zirconium 1-3 11 Chromium Nitride 4-6 12 Fluorspar 0.2-2 13 Sodium fluoride 0.2-2 Table.3.3: Comparison of two wires HPW WIRE 6430 WIRE Hardness HRc 65 Hardness HRc 60 High temperature wear application Ambient temperature applications High fume level and poor weld pool visibility Common as in other welding process WELD BEAD OF 6430 WIRE Fig.1: Weld bead of 6430 wire WELD BEAD OF HPW WIRE Fig.2: Weld bead ofHPWwire 3.2 VARIATION OF WELD BEAD SIZE WITH CURRENT The bead size generally increases with the increase in the current. The spatter is enormous in case of HPW wire and over a particular range of current the spatter is found to decrease and the fume is also reduced over that range
  • 3. International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-3, Issue-3, Mar- 2017] https://dx.doi.org/10.24001/ijaems.3.3.19 ISSN: 2454-1311 www.ijaems.com Page | 256 Fig.3: Variation of weld bead size with current 3.3 METALLOGRAPHIC EXAMINATION The weld beads are sectioned and examined metallographically. The samples are emery polished first and then with cloth polishing. The etchant used is pikral and the etching time is 10 to 15 seconds. The micrographs obtained from 6430 and HPW flux cored wires are shown in the figure 4 and 5 MICROSTRUCTURE OF HPW WIRE a) Base Metal b) Heat affected Zone c) Weld metal Fig.4: Microstructures of 6430 wire MICROSTRUCTURE OF HPW WIRE a) Weld Metal b)Heat affected Zone 50X 50X 50X 50X 50X
  • 4. International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-3, Issue-3, Mar- 2017] https://dx.doi.org/10.24001/ijaems.3.3.19 ISSN: 2454-1311 www.ijaems.com Page | 257 c)Base metal Fig.5: Microstructures of HPW wire From the micrographs it can be inferred that base metal is mild steels and weld bead gives superior martensitic microstructure and HAZ is superior in case of HPW wire than the 6430 wire .the proximity to cracks are limited in case of HPW wire. Hence HPW wire has superior properties when compared with 6430 wire 3.4 X RAY DIFFRACTION The fumes of HPW wire and 6430 wire are collected using vacuum pump and are examined for X RAY diffraction. The X- ray diffraction is done in D8 BRUKER axswith copper k alpha radiation. HPW FLUX VS FUMES Fig.6: X ray graph of HPW flux and fumes HPW FLUX Fig.7: X ray graph of HPW flux HPW FUMES Fig.8: X ray graph of HPW fume 6430 FLUX VS FUMES Fig.9: X ray graph of HPW fume
  • 5. International Journal of Advanced Engineering, Management and Science (IJAEMS) [Vol-3, Issue-3, Mar- 2017] https://dx.doi.org/10.24001/ijaems.3.3.19 ISSN: 2454-1311 www.ijaems.com Page | 258 6430 FLUX Fig.10: X ray graph of 6430 flux 6430 FUMES Fig.11: X ray graph of 6430 fume From the graph it has been found that the most emitting component in HPW wire is Fe2O3 which is not emitted in the 6430 wire. So the reason behind the fumes in HPW wire is Fe2O3. The chemistry behind the fume emission has to be analyzed. IV. CONCLUSION From the various analyses the problematic wire HPW is superior in its properties. But its fume emission is the only problem that restricts the usage of such wire. So its fume emission should be reduced through optimizing the current parameter but not with changing the chemical composition of the flux as it plays a major role in their properties. REFERENCES [1] Carpenter K.R., Monaghan B.J. and Norrish J.(2009), ‘Influence of Shielding Gas on Fume Formation Rate For Gas Metal Arc Welding of Plain Carbon Steels’, ASM international, p 436-442 [2] Den Ouden G, Hermans M.J.M. (2009), “Welding technology”, Delft University of technology. [3] Eagar T.W and Kim Y.S (1993), ‘Metal transfer in pulsed current GMAW’, Welding Journal Vol. 72 No.6 PP. 279-287 [4] Geoffrey Slater (2004), ‘Weld Fume Plume Dispersion’, University of Wollongong, theses 384. [5] Haidar J and Lowke J J (1997), ‘Effect of CO2 shielding gas on metal droplet formation in arc welding’, IEEE Trans. Plasma Sc. Vol.25 No.5, P931- 936 [6] Heile R. F., and Hill D.C (1975), ‘Particulate fume generation in arc welding processes’, Weld. J., 54, 201s–210s [7] Hermans M.J.M, Den Ouden G (1999), ‘Process behavior and stability in short circuit gas metal arc welding’, Weld J 78(4):137–141 [8] Ian Richarclson, John Norrish and Marcel Hermans (1989) ‘The mechanism and significance of drop spray transfer in GMAW’, International Institute of Welding, IIW-1893-06. [9] Ines Pires, Luisa Quintino, Victor Amaral (2010), Tobias Rosado, ‘Reduction of Fume And Gas Emissions Using Innovative Gas Metal Arc Welding Variants’, International journal for advanced manufacturing technology, 50:557-567. [10] John Norrish (2006), ‘Advanced welding processes, Technologies and process control’, Institute of Physics Publishing. [11] Lancaster J F (1986), ‘The physics of welding’, 2nd Edition, Pergamon Press, ISBN 0-08-034076-8, p246. [12] LevchenkoO.G(1998), ‘Methods of reducing the generation of the welding fumes’, Welding international 1998 12(9) 747-752.