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1
Dr.Himanshu Tiwari
Senior Lecturer
Dept. Of Prosthodontics and
Crown & Bridge
Dental Wax Materials
⚫thermoplastic molding material.
⚫solid at room temperature.
2
Definition
�Baseplate wax: sheets, establish initial arch
form in construction of CD.
�Bite wax: record the occlusal surfaces of teeth.
�Boxing wax: sheet wax used as a border of an
impression to provide base of the cast to be
made.
�Inlay wax: applied to dies to form direct or
indirect patterns for the lost-wax tech.
�Sticky wax: adheres to dry clean surfaces.
3
Types of waxes
4
5
⚫ BASE Wax: that is almost always paraffin (not
smooth, not glossy, flake when trimmed)
(1) Hydrocarbon of paraffin or esters
(2) High or low MW
⚫ MODIFIER Waxes: contribute properties such as
increased hardness, stickiness, or brittleness
(1) Hydrocarbon or ester types;
(2) High or low MW
⚫ COLORANT: 1%
⚫ Fillers: some waxes contain it to control
expansion and shrinkage of the wax product.
6
General Composition
Natural (mineral, vegetable, or animal origin and/or
synthetic waxes (more homogeneous & pure)
Natural waxes are complex combinations of organic
compounds of high molecular weight:
⚫ Hydrocarbons,e.g. saturated alkanes, & microcrystalline
wax series, carnauba wax, candelilla wax.
⚫ Esters, e.g.myricylpalmitate.
Some waxes also contain free alcohol and acid.
(Esters are formed from union of higher fatty acids with
higher aliphatic alcohol with elimination of water)
Alcohol+Fatty Acid 🡪Ester+Water 7
Chemical composition
Natural waxes Synthetic waxes Additives
Minerals: Paraffin
Microcrystalline
Barns Dahl
Ozokerite
Ceresin
Montan
Acrawax C
Aerosol,OT
Castorwax
Flexowax C
Epolene N-10
Albacer
Aldo 33
Durawax 1032
Fats
□Stearic acid
□Glyceryltristearate
□Oils
□Turpentine
□Color
Plants :Carnauba
Ouricury
Candelilla
Japan wax
Coca butter
Natural Resins
□Rosin
□Copal
□Dammar
□Sandarac
□Mastin, Shellac
□Kauri
Insect: Beeswax
Animal: Spermaceti
Synthetic Resins
□Elvax
□Polyethylene
Polystyrene
8
⚫Gum dammar: smoothness, resistant to
flaking, toughness. (resin)
⚫Ceresin the hardness and water resistance
of wax. Improves carving properties.
⚫Carnuba the hardness and water resistance,
melting range, gives glossiness, flow at
mouth temp.
⚫Beeswax the stickiness, improves flow
properties at mouth temperature. (esters)
⚫Rosin the brittleness. (resin)
⚫Microcrystalline waxes stress release on
cooling.
9
Common Modifier Waxes
Properties
10
⚫Occurs because of the Multiple wax mixtures
⚫The liquidus line (representing the temperature at
which complete melting has occurred)
⚫The solidus line (below which the composition is
entirely solid)
⚫the solid + liquid range in between is quite broad
(almost 40°C). To allow manipulation
⚫To develop wax flow, the temperature only needs
to be heated to a point within the solid+liquid
range or up to the point of the liquidus line but
not much higher.
⚫Excessive heating would cause decomposition.
11
Melting range
12
Melting range
COMPOSITION
(%)
TEMPERATURE
(C)
Paraff
in
Carnuba
40
30
20
60
50
70
80
90
25 50 75 100
LIQUID
LIQUID + SOLID
SOLID
Melting Onset
(Solidus)
Melting Completion (Liquidus)
13
Density and Melting ranges
Name: Origin: Composition: Melting
(°C)
Density
(20°C)
PARAFFIN Mineral Hydrocarbon mixture 50-57 0.90
CERESIN Mineral Complex hydrocarbons 61-78 0.91-0.92
BEESWAX Animal Ester mixture 62-65 0.95-0.96
CANDELILLA Plant C21 hydrocarbons 68-70 0.95-0.99
CARNAUBA Plant Hydrocarbon, Ester, Fatty
Acid
82-86 0.99-0.999
GUM
DAMMAR
Plant Aromatic resin ca 120 1.040-
1.120
ROSIN Plant Aromatic resin acid 100-150 1.08
Methods:
1. Flame heated instruments
2. warmth of hand??
3. dry heat as wax pot
4. Water bath, but not for inlay wax??
Flow :
⚫ after the highest melting point is reached.
⚫ Temperature α 1/ viscosity
⚫ Flow temperature must be > mouth temp if needed in
solid state
Over heating should be avoided?
the base or modifier waxes can be decomposed.
14
Heating issues
⚫In solids its analogous to creep
⚫In liquids its analogous to viscosity
⚫Waxes are usually non-flowable at room temperature
⚫Temperature α 1/ viscosity
⚫It is critical for inlay wax to have flow less than 1%
15
Flow
⚫ It is low
⚫ Wax should be softened evenly by
⚫ rotation above the flame until it evenly softens or
flows
⚫ Tempered in a water bath alternately with the
flame heating to allow the core to soften before
dripping
⚫ If a soft core of a bulk of wax is to be made, roll the
wax when it is in softened status – (unable to hold
shape by itself)
16
Thermal conductivity
⚫Used with cast metal techniques
⚫Wax patterns need to be burned to the
point where no excess residue may
interfere with metal casting
⚫Heat melt and/or decompose wax by the
process of oxidation which completely
transform it into water vapor and carbon
dioxide so that no residue is left.
17
Lost wax technique
18
Tackiness or stickiness
⚫ Created by the bees wax addition
in the mixture
⚫ Increased if material is warmed
by hand
⚫ Solid waxes become tacky to
other material if heated
⚫ Adhesives may be applied on
casts before wax application
⚫ Wax dipping in bees wax increase
stickiness of refractory casts
⚫ Old wax adheres to new one if
surface is dry
19
Dimensional stability
⚫Wax should be dimensionally stable
once it has solidified (less than 1%).
⚫ Invest the pattern immediately after
removal from the die.
Deformations:
⚫Plastic deformation
⚫ Under force is by ductility.
⚫ Ductility allows it to be carved
or burnished
⚫Residual stress recovery
⚫Elastic Recovery
⚫Residual stress reduction
⚫ Heat material evenly
⚫ Follow manufacturer instructions
⚫ Invest within 30 min of carving
⚫ Whenever wax additions are cooled. The
exterior surface tends to cool first. The molten
interior slowly solidifies and contracts. This
encourages distortion or flow. Add in small
increments, layering
⚫ Store at low temperatures
20
Residual stress
21
Coefficient of thermal
expansion
⚫Very high
⚫ ceramics (1-15 ppm/°C)
⚫ metals (10-30 ppm/°C)
⚫ waxes (30-600 ppm/°C)
⚫ inlay wax (250-300 ppm/°C)
( wax pattern made in the mouth
will shrink appreciably)
⚫Residual thermal stresses may change
dimensions
⚫Paraffin > beeswax >carnuba
Ñ Do not
heat
above
melting
point
during
work
22
Thermal Expansion
250
ppm/°
C
Paraffin
0 25 30 40 45
35 50
0
1.2
1.0
0.8
0.6
0.4
0.2
TEMPERATURE
(C)
EXPANSION
(%)
KERR
HARD
WAX
⚫Wax is hydrophobic
⚫To increase its wetting a surfactant could be sprayed
over wax to increase flow of investment material
23
Surface tension
⚫Coloring is not standardized
⚫Dark colors provide good color contrast for
processing wax
⚫Opaque and Tooth-colored waxes provide good
material for esthetic case presentations and patient
education
24
Color
Applications
25
26
CLASSIFICATION OF DENTAL WAXES
Pattern Waxes
27
Uses
⚫metal castings of
⚫ Inlays
⚫ Attachments
⚫ Crowns
⚫ Pontics
⚫ Partial dentures
⚫ Denture base material
28
Pattern waxes
Forms
sticks pallets, tins
�Blue or green
Consistencies
�Hard, medium, soft, regular
Application
�indirect and direct technique
29
Inlay wax
Removable
Die with
Waxed Inlay
INLAY WAX
Composition
Paraffin + Carnuba + Ceresin
+Beeswax + Colorants
Properties
- low thermal dimensional change
- flow temp higher than mouth
- must have clean excess residue
30
31
Application
⮚Used for metal framework
⮚complete and partial dentures
Forms
Sheets and preformed shapes
Properties
⮚low thermal dimensional change
⮚must have clean excess residue
32
Casting waxes
33
34
Form
sheets
Types I, II & III
Application
�wax registration of ridge form
�Carved into tissue forms and Support teeth
�Bite registration
Properties
�melting range higher than mouth temperature
�Customised to climate
35
Base Plate wax
Processing wax
36
Uses
⚫For edentulous impressions
⚫ Corrects undercuts
⚫Closes bubbles
Properties
⚫flow at mouth temperature
⚫E.g. Bite wax, mizzy
37
Impression wax
Wax Bite Registration
Uses
⚫To articulate models
correctly
Forms
⚫horse shoe shape
⚫May be supported by
metal foil for stability
38
Forms
1 inch sheets
Uses
used to form base of the cast pouring
May be used to modify borders of trays
Properties
Tacky at room temp
39
Boxing wax
Transfer to
impression
40
Forms
Ropes manipulated at room temp
Applications
Add to the tray
� customize for pt mouth
� Comfort from sharp edges
� Control imp material in mouth
�Cover ortho bands and wires
� to register the bite
�Block out undercuts
41
Utility wax
Forms
Pencil shape
orange or yellow
Properties
hard and brittle – can reorient if
broken
Adhere temporarily the metal,
gypsum, resin – for fabrication or
repair
42
Sticky wax
43
Thank you

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29Dec.pptx

  • 1. 1 Dr.Himanshu Tiwari Senior Lecturer Dept. Of Prosthodontics and Crown & Bridge Dental Wax Materials
  • 2. ⚫thermoplastic molding material. ⚫solid at room temperature. 2 Definition
  • 3. �Baseplate wax: sheets, establish initial arch form in construction of CD. �Bite wax: record the occlusal surfaces of teeth. �Boxing wax: sheet wax used as a border of an impression to provide base of the cast to be made. �Inlay wax: applied to dies to form direct or indirect patterns for the lost-wax tech. �Sticky wax: adheres to dry clean surfaces. 3 Types of waxes
  • 4. 4
  • 5. 5
  • 6. ⚫ BASE Wax: that is almost always paraffin (not smooth, not glossy, flake when trimmed) (1) Hydrocarbon of paraffin or esters (2) High or low MW ⚫ MODIFIER Waxes: contribute properties such as increased hardness, stickiness, or brittleness (1) Hydrocarbon or ester types; (2) High or low MW ⚫ COLORANT: 1% ⚫ Fillers: some waxes contain it to control expansion and shrinkage of the wax product. 6 General Composition
  • 7. Natural (mineral, vegetable, or animal origin and/or synthetic waxes (more homogeneous & pure) Natural waxes are complex combinations of organic compounds of high molecular weight: ⚫ Hydrocarbons,e.g. saturated alkanes, & microcrystalline wax series, carnauba wax, candelilla wax. ⚫ Esters, e.g.myricylpalmitate. Some waxes also contain free alcohol and acid. (Esters are formed from union of higher fatty acids with higher aliphatic alcohol with elimination of water) Alcohol+Fatty Acid 🡪Ester+Water 7 Chemical composition
  • 8. Natural waxes Synthetic waxes Additives Minerals: Paraffin Microcrystalline Barns Dahl Ozokerite Ceresin Montan Acrawax C Aerosol,OT Castorwax Flexowax C Epolene N-10 Albacer Aldo 33 Durawax 1032 Fats □Stearic acid □Glyceryltristearate □Oils □Turpentine □Color Plants :Carnauba Ouricury Candelilla Japan wax Coca butter Natural Resins □Rosin □Copal □Dammar □Sandarac □Mastin, Shellac □Kauri Insect: Beeswax Animal: Spermaceti Synthetic Resins □Elvax □Polyethylene Polystyrene 8
  • 9. ⚫Gum dammar: smoothness, resistant to flaking, toughness. (resin) ⚫Ceresin the hardness and water resistance of wax. Improves carving properties. ⚫Carnuba the hardness and water resistance, melting range, gives glossiness, flow at mouth temp. ⚫Beeswax the stickiness, improves flow properties at mouth temperature. (esters) ⚫Rosin the brittleness. (resin) ⚫Microcrystalline waxes stress release on cooling. 9 Common Modifier Waxes
  • 11. ⚫Occurs because of the Multiple wax mixtures ⚫The liquidus line (representing the temperature at which complete melting has occurred) ⚫The solidus line (below which the composition is entirely solid) ⚫the solid + liquid range in between is quite broad (almost 40°C). To allow manipulation ⚫To develop wax flow, the temperature only needs to be heated to a point within the solid+liquid range or up to the point of the liquidus line but not much higher. ⚫Excessive heating would cause decomposition. 11 Melting range
  • 12. 12 Melting range COMPOSITION (%) TEMPERATURE (C) Paraff in Carnuba 40 30 20 60 50 70 80 90 25 50 75 100 LIQUID LIQUID + SOLID SOLID Melting Onset (Solidus) Melting Completion (Liquidus)
  • 13. 13 Density and Melting ranges Name: Origin: Composition: Melting (°C) Density (20°C) PARAFFIN Mineral Hydrocarbon mixture 50-57 0.90 CERESIN Mineral Complex hydrocarbons 61-78 0.91-0.92 BEESWAX Animal Ester mixture 62-65 0.95-0.96 CANDELILLA Plant C21 hydrocarbons 68-70 0.95-0.99 CARNAUBA Plant Hydrocarbon, Ester, Fatty Acid 82-86 0.99-0.999 GUM DAMMAR Plant Aromatic resin ca 120 1.040- 1.120 ROSIN Plant Aromatic resin acid 100-150 1.08
  • 14. Methods: 1. Flame heated instruments 2. warmth of hand?? 3. dry heat as wax pot 4. Water bath, but not for inlay wax?? Flow : ⚫ after the highest melting point is reached. ⚫ Temperature α 1/ viscosity ⚫ Flow temperature must be > mouth temp if needed in solid state Over heating should be avoided? the base or modifier waxes can be decomposed. 14 Heating issues
  • 15. ⚫In solids its analogous to creep ⚫In liquids its analogous to viscosity ⚫Waxes are usually non-flowable at room temperature ⚫Temperature α 1/ viscosity ⚫It is critical for inlay wax to have flow less than 1% 15 Flow
  • 16. ⚫ It is low ⚫ Wax should be softened evenly by ⚫ rotation above the flame until it evenly softens or flows ⚫ Tempered in a water bath alternately with the flame heating to allow the core to soften before dripping ⚫ If a soft core of a bulk of wax is to be made, roll the wax when it is in softened status – (unable to hold shape by itself) 16 Thermal conductivity
  • 17. ⚫Used with cast metal techniques ⚫Wax patterns need to be burned to the point where no excess residue may interfere with metal casting ⚫Heat melt and/or decompose wax by the process of oxidation which completely transform it into water vapor and carbon dioxide so that no residue is left. 17 Lost wax technique
  • 18. 18 Tackiness or stickiness ⚫ Created by the bees wax addition in the mixture ⚫ Increased if material is warmed by hand ⚫ Solid waxes become tacky to other material if heated ⚫ Adhesives may be applied on casts before wax application ⚫ Wax dipping in bees wax increase stickiness of refractory casts ⚫ Old wax adheres to new one if surface is dry
  • 19. 19 Dimensional stability ⚫Wax should be dimensionally stable once it has solidified (less than 1%). ⚫ Invest the pattern immediately after removal from the die. Deformations: ⚫Plastic deformation ⚫ Under force is by ductility. ⚫ Ductility allows it to be carved or burnished ⚫Residual stress recovery ⚫Elastic Recovery
  • 20. ⚫Residual stress reduction ⚫ Heat material evenly ⚫ Follow manufacturer instructions ⚫ Invest within 30 min of carving ⚫ Whenever wax additions are cooled. The exterior surface tends to cool first. The molten interior slowly solidifies and contracts. This encourages distortion or flow. Add in small increments, layering ⚫ Store at low temperatures 20 Residual stress
  • 21. 21 Coefficient of thermal expansion ⚫Very high ⚫ ceramics (1-15 ppm/°C) ⚫ metals (10-30 ppm/°C) ⚫ waxes (30-600 ppm/°C) ⚫ inlay wax (250-300 ppm/°C) ( wax pattern made in the mouth will shrink appreciably) ⚫Residual thermal stresses may change dimensions ⚫Paraffin > beeswax >carnuba Ñ Do not heat above melting point during work
  • 22. 22 Thermal Expansion 250 ppm/° C Paraffin 0 25 30 40 45 35 50 0 1.2 1.0 0.8 0.6 0.4 0.2 TEMPERATURE (C) EXPANSION (%) KERR HARD WAX
  • 23. ⚫Wax is hydrophobic ⚫To increase its wetting a surfactant could be sprayed over wax to increase flow of investment material 23 Surface tension
  • 24. ⚫Coloring is not standardized ⚫Dark colors provide good color contrast for processing wax ⚫Opaque and Tooth-colored waxes provide good material for esthetic case presentations and patient education 24 Color
  • 28. Uses ⚫metal castings of ⚫ Inlays ⚫ Attachments ⚫ Crowns ⚫ Pontics ⚫ Partial dentures ⚫ Denture base material 28 Pattern waxes
  • 29. Forms sticks pallets, tins �Blue or green Consistencies �Hard, medium, soft, regular Application �indirect and direct technique 29 Inlay wax Removable Die with Waxed Inlay
  • 30. INLAY WAX Composition Paraffin + Carnuba + Ceresin +Beeswax + Colorants Properties - low thermal dimensional change - flow temp higher than mouth - must have clean excess residue 30
  • 31. 31
  • 32. Application ⮚Used for metal framework ⮚complete and partial dentures Forms Sheets and preformed shapes Properties ⮚low thermal dimensional change ⮚must have clean excess residue 32 Casting waxes
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  • 34. 34
  • 35. Form sheets Types I, II & III Application �wax registration of ridge form �Carved into tissue forms and Support teeth �Bite registration Properties �melting range higher than mouth temperature �Customised to climate 35 Base Plate wax
  • 37. Uses ⚫For edentulous impressions ⚫ Corrects undercuts ⚫Closes bubbles Properties ⚫flow at mouth temperature ⚫E.g. Bite wax, mizzy 37 Impression wax
  • 38. Wax Bite Registration Uses ⚫To articulate models correctly Forms ⚫horse shoe shape ⚫May be supported by metal foil for stability 38
  • 39. Forms 1 inch sheets Uses used to form base of the cast pouring May be used to modify borders of trays Properties Tacky at room temp 39 Boxing wax Transfer to impression
  • 40. 40
  • 41. Forms Ropes manipulated at room temp Applications Add to the tray � customize for pt mouth � Comfort from sharp edges � Control imp material in mouth �Cover ortho bands and wires � to register the bite �Block out undercuts 41 Utility wax
  • 42. Forms Pencil shape orange or yellow Properties hard and brittle – can reorient if broken Adhere temporarily the metal, gypsum, resin – for fabrication or repair 42 Sticky wax