2. What is corrosion?
• The chemical or electrochemical reaction between a material
and its environment that produces a deterioration of the
material and its properties
3. Due to corrosion !!
• There is no single figure for loss to the nation due to corrosion.
• It can be a minimum of 3.5% of the nation's GDP.
• Losses due to corrosion could be around Rs. 2.0 lakh crores per annum in India
4. Forms of Corrosion
• General
Identified by uniform formation of corrosion products that causes a even
thinning of the substrate steel
• Localized
Caused by different in chemical or physical condition between adjoining
sites
• Bacterial
Caused by formation of bacteria with an affinity for metals on the
surface of the steel
• Galvanic
Cased when two dissimilar metals come in contact
5. Factors Influencing Corrosion
The nature and extent of corrosion depend on the metal and the environment.
The important factors which may influence the corrosion process are
(i) Nature of the metal
(ii) Environment
(iii)Concentration of electrolyte
(iv) Temperature
(v) Electrode potential and
(vi) Hydrogen over voltage
6. Concrete and Mortar
• Concrete and mortar is a mixture of...
•Portland Cement
•Aggregates
•Water
•Admixtures
8. Structure of cement-based materials
• Gel pores in CSH-Cluster
• Capillary pores between the Cluster
Pores
1. Compacting pores (comp)
2. Air pores (entraining)
3. Capillary pores (w/c)
4. Gel pores (Hydration)
9. Carbonation of reinforced concrete
• Brief historical abstract
•1879 Cement cover prevents iron from
oxidizing (rust)
•1908 Realization that the alkaline
ambience prevents this corrosion
• 1916 “Corrosion of highly importance
because of security reasons “
•1919 1.5 cm cover concrete shall be enough
to prevent
12. TYEPS OF CORROSION
• There are basically eight types of corrosion
I. Uniform corrosion
II. Pitting corrosion
III. Trans granular and Intergranular (Intercrystallite ) corrosion
IV. Exfoliation corrosion
V. Stress corrosion
14. Methods of Corrosion Control
• Barrier Protection
Provided by a protective coating that acts as a barrier between corrosive
elements and the metal substrate
• Cathodic Protection
Employs protecting one metal by connecting it to another metal that is more
anodic, according to the galvanic series
• Corrosion Resistant Materials
Materials inherently resistant to corrosion in certain environments
16. Cathodic Protection
• Impressed Current (source of direct current power)
• Galvanic Sacrificial Anode (an active metal placed in contact with the corrosive
environment and are electrically connected to the structure)
• Galvanic Zinc Application
1. Zinc Metallizing (plating)
2. Zinc-rich Paints
3. Hot-dip Galvanizing
17. Corrosion Resistant Materials
• Four Types of Metal That Are Corrosion Resistant or Don’t Rust
1.Stainless steel
2.Aluminum metal
3.Copper, bronze or brass
4.Galvanized steel