5. Alkali
a)Dilute alkali- used in hydrolysis of esters ,amides,fats etc.
Saponification-Hydrolysis of fats and oils by NaOH
b) Concentrated alkali- Excess alkali at high pressure and concentration can cause hydrolysis
at primary and secondary C-Cl linkages.
C6H5-Cl+NaOH C6H5-OH +NaOH C6H5-ONa+H2O
C)Alkali fusion- Concentration of alkali very high: Product formed will be in the form of
sodium salt and acidification is needed for obtaining the desired product.
Used in the preparation of phenols and sulphonic acids.
Enzymatic Hydrolysis- important in biological systems
Molasses invertase glucose+ fructose zymase ethyl alcohol