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General Chemistry: Chapter 1Slide 1 of 25
PHILIP DUTTON
UNIVERSITY OF WINDSOR
DEPARTMENT OF CHEMISTRY AND
BIOCHEMISTRY
TENTH EDITION
GENERAL CHEMISTRY
Principles and Modern Applications
PETRUCCI HERRING MADURA BISSONNETTE
Copyright © 2011 Pearson Canada Inc.
Matter: Its Properties
and Measurement 1
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 2 of 25
Matter: Its Properties
and Measurement
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 3 of 25
1-1 The Scientific Method
Louis Pasteur (1822-1895)
developer of germ theory
pasteurization
rabies vaccination
Called the greatest physician of
all time by some.
He was a chemist by training
and profession.
FIGURE 1-1
The Scientific Method Illustrated
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 4 of 25
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 5 of 25
1-2 Properties of Matter
tter: Occupies space, has mass and inertia
mposition: Parts or components
ex. H2O, 11.19% H and 88.81% O
perties: Distinguishing features
physical and chemical properties
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 6 of 25
1-3 Classification of Matter
Matter is made of atoms.
114 elements.
About 90% available from natural sources
Compounds are comprised of two or more elements.
Molecules are the smallest units of compounds.
FIGURE 1-4
A classification scheme for matter
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 7 of 25
Separating Mixtures: a physical process
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 8 of 25
FIGURE 1-5
A chemical change: decomposition of ammonium dichromate
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 9 of 25
FIGURE 1-6
Macroscopic and microscopic views of matter
Figure 1-7
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 10 of 25
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 11 of 25
1-4 The Measurement of Matter
Copyright © 2011 Pearson Canada Inc.Slide 12 of 25
General Chemistry: Chapter 1
Mass
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 13 of 25
Mass is the quantity of
matter in an object.
Weight is the force of
gravity on an object
W ∝m W = g × m
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 14 of 25
Temperature
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 15 of 25
Volume
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 16 of 25
SI and non-SI Units Compared
1 kg 1 lb
1 in 1 cm
1 US qt
0.936 L
1 L
1 Imperial qt
1.136 L
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 17 of 25
SI Units
Length meter, m
Mass Kilogram, kg
Time second, s
Temperature Kelvin, K
Quantity Mole, 6.022×1023
mol-1
Derived Units
Force Newton, kg m s-2
Pressure Pascal, kg m-1
s-2
Energy Joule, kg m2
s-2
Non-SI Units
Length Angstrom, Å, 10-8
cm
Volume Liter, L, 10-3
m3
Energy Calorie, cal, 4.184 J
Pressure
1 Atm = 1.064 × 102
kPa
1 Atm = 760 mm Hg
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 18 of 25
1-5 Density and Percent Composition
δ= m/V
m=Vδ V=m/δ
g/mL
Mass and volume are extensive properties
Density is an intensive property
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 19 of 25
Density in Conversion Pathways
What is the mass of a cube of osmium that is 1.25
inches on each side?
Have volume, need density = 22.59g/cm3
Measuring Volume of an Irregular Object
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 20 of 25
FIGURE 1-10
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 21 of 25
1-6 Uncertainties in Scientific Measurements
Systematic errors.
Thermometer constantly 2°C too low.
Random errors
Limitation in reading a scale.
Precision
Reproducibility of a measurement.
Accuracy
How close to the real value.
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 22 of 25
Precision
Reproducibility ∼ 0.1 g ∼ 0.0001 g
Precision low high
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 23 of 25
1-7 Significant Figures
Determining the number of significant figures in a quantity
Figure 1-11
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 24 of 25
Significant Figures
The calculators show the effect of the change in a low precision
number (N) in a calculation 14.79 × 12.11 × N
N = 5.04 5.05 5.06
Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 25 of 25
End of Chapter Questions
Instructors may provide lists of questions that
reinforce topics they feel are particularly pertinent in
the chapter. If no list is given students should attempt
questions from each section of the chapter.
Build from the easier questions where the topic is
identified, to the more difficult integrative examples
where the approach to the question must be identified.

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Ch01lecture 150104195146-conversion-gate01

  • 1. General Chemistry: Chapter 1Slide 1 of 25 PHILIP DUTTON UNIVERSITY OF WINDSOR DEPARTMENT OF CHEMISTRY AND BIOCHEMISTRY TENTH EDITION GENERAL CHEMISTRY Principles and Modern Applications PETRUCCI HERRING MADURA BISSONNETTE Copyright © 2011 Pearson Canada Inc. Matter: Its Properties and Measurement 1
  • 2. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 2 of 25 Matter: Its Properties and Measurement
  • 3. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 3 of 25 1-1 The Scientific Method Louis Pasteur (1822-1895) developer of germ theory pasteurization rabies vaccination Called the greatest physician of all time by some. He was a chemist by training and profession.
  • 4. FIGURE 1-1 The Scientific Method Illustrated Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 4 of 25
  • 5. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 5 of 25 1-2 Properties of Matter tter: Occupies space, has mass and inertia mposition: Parts or components ex. H2O, 11.19% H and 88.81% O perties: Distinguishing features physical and chemical properties
  • 6. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 6 of 25 1-3 Classification of Matter Matter is made of atoms. 114 elements. About 90% available from natural sources Compounds are comprised of two or more elements. Molecules are the smallest units of compounds.
  • 7. FIGURE 1-4 A classification scheme for matter Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 7 of 25
  • 8. Separating Mixtures: a physical process Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 8 of 25 FIGURE 1-5
  • 9. A chemical change: decomposition of ammonium dichromate Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 9 of 25 FIGURE 1-6
  • 10. Macroscopic and microscopic views of matter Figure 1-7 Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 10 of 25
  • 11. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 11 of 25 1-4 The Measurement of Matter
  • 12. Copyright © 2011 Pearson Canada Inc.Slide 12 of 25 General Chemistry: Chapter 1
  • 13. Mass Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 13 of 25 Mass is the quantity of matter in an object. Weight is the force of gravity on an object W ∝m W = g × m
  • 14. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 14 of 25 Temperature
  • 15. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 15 of 25 Volume
  • 16. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 16 of 25 SI and non-SI Units Compared 1 kg 1 lb 1 in 1 cm 1 US qt 0.936 L 1 L 1 Imperial qt 1.136 L
  • 17. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 17 of 25 SI Units Length meter, m Mass Kilogram, kg Time second, s Temperature Kelvin, K Quantity Mole, 6.022×1023 mol-1 Derived Units Force Newton, kg m s-2 Pressure Pascal, kg m-1 s-2 Energy Joule, kg m2 s-2 Non-SI Units Length Angstrom, Å, 10-8 cm Volume Liter, L, 10-3 m3 Energy Calorie, cal, 4.184 J Pressure 1 Atm = 1.064 × 102 kPa 1 Atm = 760 mm Hg
  • 18. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 18 of 25 1-5 Density and Percent Composition δ= m/V m=Vδ V=m/δ g/mL Mass and volume are extensive properties Density is an intensive property
  • 19. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 19 of 25 Density in Conversion Pathways What is the mass of a cube of osmium that is 1.25 inches on each side? Have volume, need density = 22.59g/cm3
  • 20. Measuring Volume of an Irregular Object Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 20 of 25 FIGURE 1-10
  • 21. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 21 of 25 1-6 Uncertainties in Scientific Measurements Systematic errors. Thermometer constantly 2°C too low. Random errors Limitation in reading a scale. Precision Reproducibility of a measurement. Accuracy How close to the real value.
  • 22. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 22 of 25 Precision Reproducibility ∼ 0.1 g ∼ 0.0001 g Precision low high
  • 23. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 23 of 25 1-7 Significant Figures Determining the number of significant figures in a quantity Figure 1-11
  • 24. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 24 of 25 Significant Figures The calculators show the effect of the change in a low precision number (N) in a calculation 14.79 × 12.11 × N N = 5.04 5.05 5.06
  • 25. Copyright © 2011 Pearson Canada Inc.General Chemistry: Chapter 1Slide 25 of 25 End of Chapter Questions Instructors may provide lists of questions that reinforce topics they feel are particularly pertinent in the chapter. If no list is given students should attempt questions from each section of the chapter. Build from the easier questions where the topic is identified, to the more difficult integrative examples where the approach to the question must be identified.