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Thermo Electron
Materials and Minerals
Tianjin Design Institute, Tianjin
2
Thermo Electron
•Helping our customers to succeed…lasting
partnerships and services
Website: www.thermo.com
Our customer value proposition
•A variety of markets…including life sciences,
process control, optical, and photonics
The markets we serve
•Technology innovation
•Good business people
Our core strengths
•Analyze... detect... measure… control…What our products/
services do
•Industry leader in high tech instruments,
systems and software
Our line of business
3
Thermo Electron Global Presence
U.S.
Russian Federation
Argentina
Australia
Canada
Japan
Mexico
New Zealand
India
Chile
China
Malaysia
Hong Kong
• 11,000 Employees
• Ops in 30 Countries
• $170MM Annual R&D Investment
Europe
Our Products and Services Make the World a Healthier,
Cleaner and Safer Place
4
M&M Commercial Organization
Service
Sales & Service with Manufacturing Plant
Sales & Service
Gloucester/UK Erlangen/Germany
France
Shanghai/China
Washington/USA
Santiago/Chile
Adelaide/Australia
Pune/India
Bahrain
South Africa
Mackay
Brisbane
Sydney
Perth
Indiana/USA
San Paulo/Brazil
West Virginia/USA
Mexico
Poland
San Diego/USA
So. Korea
Taiwan
Sales
Malaysia
Belgium
5
Crusher
Stockpile
Raw Mix Station
Raw Mill
Precalciner Homogenization
Silo
KILN
Clinker
Cooler
Storage Silos
Finish Blending
Cement Mill Storage SiloFuel Feed
Exhaust
Stack
Present
Thermo Cement Discrete Instruments
6
Thermo Electron presence in Cement Industry
7
Emerging Trends…in Global Cement Industry
EMERGING TRENDS IN
CEMENT INDUSTRY
• Cost pressures driving
– Efficient plant equipment designs
– Focus on alternative raw material
and fuel usage
– Process optimization
FACTORS DRIVING HIGHER
CEMENT PRODUCTION
COSTS
• 60-65% variables attributable to
raw materials
– Restrict quarry utilization
– Poor flexibility to vary raw
material feed
– Additional costs towards
additives
– Un-stable kiln operation
Online raw material control
Immense process optimization
opportunities for new as well as
existing plants
Real time Analysis can help in
addressing these issues Effectively
and Efficiently
Prompt Gamma
Neutron Activation Analysis
- PGNAA -
What is it?
Why do we use it?
9
PGNAA, What is it?
• Elemental Analysis Technique
• Bulk Analysis Method
–Penetrating Technology
• Non-Destructive Analysis Tool
10
PGNAA, Why Do We Use it?
• PGNAA Enables Accurate, High Frequency Process
Control
• Highly Automated & Mechanically Simple
• Sampling Systems add Time Delay and Error
• Surface Analysis is often not Representative
• Measures the entire bulk of material as it travels on
the belt
• Analysis independent of size and type of material as
well as conveyor speed ( up to 300mm)
• Can measure moisture
11
XRF vs. PGNAA comparison – complementing
technologies for efficient process control
CrossBeltTM Analyzer
PGNAA Domain
XRF Domain
Stages of Cement Production
1.
Quarry
2.
Pre-blending
3.
Raw Mix
4.
Raw Meal
5.
Kiln Feed
6.
Clinker
Variance
in Raw
Material
Quality
Pre-Blending
Optimization
Raw Mix
Optimization
Process Control possibilities
Quality Assurance only
12
RAMOS Reduces the Standard Deviation
LSF & SM as Independent Variables
0
0.5
1
1.5
2
2.5
3
3.5
4
0.0% 3.0% 6.0% 9.0% 12.0% 15.0%
Heat Increase to Prevent Excess Clinker Free Lime
StandardDeviationofLSF
0
0.05
0.1
0.15
0.2
0.25
0.3
0.35
0.4
StandardDeviationofSM
LSF
SM
13
Blend Quality Measured Quality
The Ability for Different Blending Processes
to Track Chemistry Variations
14
Prompt Gamma Neutron Activation Analysis
(PGNAA) – operating principle
Prompt Gamma Neutron Activation Analysis
(PGNAA) – operating principle
γγγγ
Thermal
Neutron
Thermal
Neutron
NucleusNucleus Excited
Nucleus
Excited
Nucleus
Stable
Nucleus
Stable
Nucleus
Gamma
Ray
Gamma
Ray
15
Gamma Detector Zone
Neutron Source Zone
Conveyor Belt (return side)
Conveyor Belt
(loaded side)
Lower Shield
Assembly
Middle Shield
Assemblies
Upper Shield
Assembly
The advanced CBX Analyzer
16
PARAMETERS ANALYZED IN ONE MINUTEPARAMETERS ANALYZED IN ONE MINUTE
• Direct Measurement
– CaO
– SiO2
– Fe2O3
– Al2O3
– MgO
– K2O
– Na2O
– S
– Cl
– Moisture
• Direct Measurement
– CaO
– SiO2
– Fe2O3
– Al2O3
– MgO
– K2O
– Na2O
– S
– Cl
– Moisture
• Computed
– Silica Ratio
– C3S
– C3A
– LSF
– A/F Ratio
– Liquidity
– Burnability
• Computed
– Silica Ratio
– C3S
– C3A
– LSF
– A/F Ratio
– Liquidity
– Burnability
17
Reference Standard
with Lifting Straps
Scope of Supply
18
On-line Bulk Material Analysis Evolution
1985 Chute Type
Analyzer
1993 CrossBelt
Analyzer
1997 CrossBelt GN
Analyzer
2003 CBXpert
Analyzer
19
OverOverOverOver
Over 250 Installations spanning 40 countries andOver 250 Installations spanning 40 countries andOver 250 Installations spanning 40 countries andOver 250 Installations spanning 40 countries and
6 continents6 continents6 continents6 continents
Installed Base
Thermo Cement
CBX Applications
21
Limestone
CrossBelt Xpert (CBX)
Analyzer
Drucker
Weigh Scale
Electronic
Cabinet
Operator Console
SOFTWARE
Blending
Bed
Plant PLC
Clay / Marl
CBX- Manual Stockpile Control using one or two
type of raw material source
22
Limestone
CrossBelt Xpert (CBX)
Analyzer
Drucker
Weigh Scale
Electronic
Cabinet
Operator Console
SOFTWARE
Blending
Bed
Plant PLC
Clay / Marl
CBX- Manual stockpile control using multiple raw
material sources.
23
CrossBelt Xpert (CBX)
Analyzer
Drucker
Weigh Scale
Electronic
Cabinet
Operator Console
SOFTWARE
Blending
Bed
Limestone
Clay / Marl
CBX- Auto Stockpile Control for multiple raw
material sources.
Plant PLC
Apron feeders
24
Combination of Manual and Auto Stockpile Control to
optimize stockpile building using variety of raw materials
Clay like Materials
Intermediate Clay Mix Pile
Weigh Scale
CrossBelt Analyzer
Electronics
Control software
DEMANDS/
ADVISORIES
Wireless Station
Pre-blending Stockpile
Control
SM & IM Wireless Terminal
in Loader
LIMESTONE
From quarry
25
CBX- Raw Mix – Typical
Crushe
r
Stockpile
Plant PLC
CrossBelt Xpert (CBX)
Analyzer
Electronic
Cabinet
Operator Console
SOFTWARE
Vertical Roller
Mill
Raw Mill Hoppers
26
CBX – Multiple Hoppers and Raw Mills
10 Raw Mill hoppers – 3 of the hoppers are used to feed limestone, additional 3
hoppers are used to feed Catalyst fine a chemical waste, 1 for iron ore, 1 for
shale, 1 for silica and the last hopper to feed slag
Ball Mill 1
200TPH
Ball Mill 2
200 TPH
CrossBelt
Analyzer
Electronic Cabinet
Operator ConsolePlant PLC
Client supplied
Feeder Control
signals
Flap Gate enabling flow
to alternative mills. This
senses the level of
material in each hopper
to alternate the flow
600 mm two speed belt conveyor is used to feed two ball mills of capacity 200
TPH each, when feeding single mill the belt runs at a lower speed and
switches to higher speed when feeding two mills.
Small surge bin of
1 Ton capacity
equipped with
sensors and
airlock
Small surge bin of
1 Ton capacity
equipped with
sensors and
airlock
27
CBX – Multiple hoppers and variety of mills
6 Raw Mill hopers – 2 of the hoppers are used to feed limestone, 2 more are
used for clay feed, 1 hopper is used for iron ore and the last one feeds
mineralizer
Ball Mill 1
90TPH
Vertical Roller
Mill 2
240 TPH
CrossBelt
Analyzer
Electronic Cabinet
Operator ConsolePlant PLC
Client supplied
Feeder Control
signals
A surge hopper
equipped with reversible
belt to enable feeding
the two mills. This
reversible belt operates
in rapid succession
dispensing more
material in the VRM and
less in Ball Mill
1000 mm two speed belt conveyor is used to feed one VRM of 240 TPH
and one ball mill of capacity 90 TPH each, when feeding one mill the belt
runs at a lower speed. The ball mill is used only when you need to
increase the capacity
Each mill is
equipped with
very small
capacity bins to
enable material
flow into the mills
Please note Holcim Cerro Blanco runs Vertical Roller Mill most of the times, and the
ball mill is only used when there is a need to increase capacity
28
CBX – Unique Application Designed to Reduce and Optimize
Capital Expenditure – Tianshan Yunfu Cement
High Grade
Limestone
Crusher
Plant PLC
CrossBelt Xpert (CBX)
Analyzer
Electronic
Cabinet
Operator Console
SOFTWARE
Vertical Roller
Mill
Raw Mill Hoppers
STOCKPILE IS ELIMINATED
$ 2M- 3M SAVINGS
Low Grade
Limestone
Crusher
29
29
85
90
95
100
105
110
115
1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 49 51
Stockpile No
LSF
Pre CBX installation Post CBX installation
Raw Mill Target, 98
Stockpile Target, 96
Dynamic
Performance
Test
Stockpile LSF before and after installation of CBX
30
WHY High Frequency Control ??
LSF Target
CONVENTIONAL CONTROL
HIGH
FREQUENCY
CONTROL
TIME
LSF
31
RAMOS Reduces the Standard Deviation
LSF & SM as Independent Variables
0
0.5
1
1.5
2
2.5
3
3.5
4
0.0% 3.0% 6.0% 9.0% 12.0% 15.0%
Heat Increase to Prevent Excess Clinker Free Lime
StandardDeviationofLSF
0
0.05
0.1
0.15
0.2
0.25
0.3
0.35
0.4
StandardDeviationofSM
LSF
SM
32
Benefits of High Frequency Raw Mix
Proportioning
• Assured raw meal homogeneity consistently
• Stable kiln operation
• Reduction in fuel cost
• Reduction in clinker grinding cost
• Extended brick life
• Higher production
• Improved end product quality
33
Raw mix control : User feed back
Cement Plant Country Improvements Realized
Apasco Norte Mexico Refractory life exceeded two years.
Cementi Rossi Italy Fuel costs reduced 5.6%.
Colacem Italy Able to run entire plant with one person on night shift.
Discontinued active homogenization in homo silos.
Compagnie des Belgium Reduced kiln feed variability by a factor of 3.
Ciments Belges Discontinued active homogenization in homo silos.
Lafarge Cormeilles France Reduced kiln feed variability by 60%.
Sococim Senegal Reduced fuel costs by 4%.
Blue Circle Southern Australia Kiln feed LSF S.D. reduced from 3 to <1
Lafarge Mannersdorf Austria Kiln feed homogeneity achieved without blending in silos
Luilihe China Improved productivity by 10%, 70% quality improvement
34
CBX
35
To have the maximum variability in
analyser width a modular shielding
block design with two sizes has
been developed
CBXpert Design Features - Shielding
Flexible analyzer width
432 mm
584 mm
36
CBXpert Design Features - Shielding
Flexible analyzer width The two block sizes allow the
configuration of different analyser
width
CBX1 Belt width 600-1000 mm
1 600mmCBX1
CBX2 Belt width 1200 mm
1 752 mmCBX2
CBX3 Belt width 1400 – 1600 mm
2 032 mmCBX3
CBX4 Belt width 1800 – 2000 mm
2 337 mmCBX4
CBX5 Belt width 2100 – 2200 mm
2 616 mm
CBX5
37
CBXpert Shielding Integration
Then the bottom shielding blocks
are placed on the bottom frame
supports
38
CBXpert Belt Integration
Distance between belt and return
belt is 710 mm. If distance is less a
roller can be attached to the frame
structure to guide the return belt
below the analyser
39
CBXpert Shielding Integration
The middle section of the analyzer
has to be custom tailored to the
existing belt.
Idler angle
• Idler angle between 35°and 45°
Side idler width
• Side idler width
Following parameters have to be
configured:
• Material height
Material height
• Centre idler width
Center idler width
40
Tunnel height defined
by max. material height
Idler angle
Center idler width
CBXpert Shielding Integration
Side blocks get configured to
customer belt specification
Side idler width
41
CBXpert Shielding Integration
Side blocks are installed on the
bottom shielding blocks
42
CBXpert Shielding Integration
For the top shielding the same
shielding blocks are used as at the
bottom. Side blocks have no load
from the top and can be moved to
fine adjust to belt position
43
CBXpert Shielding Integration
Source block has 4 sources
positions. Initial source loading
depends on application.
Stockpile 38 µg 252Cf
Raw-Mix 66 µg 252Cf
44
CBXpert Shielding Integration
Detector block contains the new
horizontally positioned heated
detectors.
Detectors are individually
positioned for optimum detection
efficiency
45
CBXpert Shielding Integration
Access to source and detector is
always from one side. Customer
can define position prior to order
46
CBXpert Shielding Integration
Custom tailored liners are installed
to protect the tunnel area
47
CBXpert Shielding Integration
All shielding parts get bolted to the
frame and fixed in position
48
CBXpert Shielding Integration
The analyser shielding is in
position. For hot environments it is
recommended to install a sun shield
over the analyser
49
Example CBX Installation: Dragon Products
No Building or Sun-
Shade
10-Block Modular
Design
No Platform
No Bend Pulleys for
Belt Return
Single Sided
Maintenance Access
No A/C Requirement
35○ Trough Angle
Proprietary Modular
Reference Standards
50
Installation Photo
51
CBXpert Electrical connection
The electronics enclosure can be
positioned up to 100 m from the
analyser and does not require any
air-conditioning
52
CBXpert Electrical connection
Connection to the control room can
be done by RS422 or optical cable.
The RS422 connection is limited to
a distance of 2000 m.
53
Plant Interface
• OPC – Ole for Process Control
• ODBC – Open Data Base Connectivity
• Serial Protocol
54
• No Overhead hoist required
• Easily handled by one person
Maximum 22Kg
• Easily stored
Best of both the worlds (Baggies and Modular
Reference standards)
Non-symmetrical Loading is Duplicated
in Factory Testing
55
CBX
56
Static guarantees – typical for stockpile
STATIC REPEATABILITY
The system is guaranteed to perform equal to or better than the following static repeatability specifications. Values are stated on a dry basis (LOI included).
0.04%0.07%SO3
0.08%0.13%Na2O
0.02%0.04%K2O
0.20%0.30%MgO
0.20%0.27%CaO
0.02%0.04%Fe2O3
0.11%0.17%Al2O3
0.10 %0.15%SiO2
Expected Repeatability
One Standard Deviation (1)
Guarantee
One Standard Deviation (1)Oxide
57
Static guarantees –typical for stockpile
•STATIC ACCURACY
•The system is guaranteed to perform equal to or better than the following static accuracy specifications in stockpile monitoring applications.
•The values are stated on a dry basis (LOI included).
•Standard Range
•0.09 %•0.17 %•3% (0%-3%)•SO3
•0.20 %•0.30 %•3% (0%-3%)•Na2O
•0.10 %•0.15 %•3% (0%-3%)•K2O
•0.38%•0.50 %•6% (0%-6%)•MgO
•0.35 %•0.40 %•35% (18%-53%)•CaO
•0.06 %•0.10 %•10% (0%-10%)•Fe2O3
•0.26 %•0.35 %•10% (0%-10%)•Al2O3
•0.35 %•0.40 %•20% (4%-24%)•SiO2
•Expected Maximum
RMSD (2)
•Guaranteed Maximum
RMSD (2)•Range (1)•Oxide
• (1) Range of material composition in reference standards.
• Guarantees are a function of the range, a larger range will dictate a larger guarantee. Conversely, a
• smaller range will dictate a smaller guarantee
(2) Root Mean Squared Deviation, one-hour period
58
Typical repeatability guarantees – raw mix
0.090.170.050.460.350.220.050.19115
0.090.170.050.470.350.220.050.20110
0.100.180.060.480.360.230.060.20105
0.100.180.060.490.370.230.060.21100
0.100.180.060.510.380.240.060.2195
0.100.190.060.520.390.250.060.2290
0.110.190.060.540.400.250.060.2285
0.110.200.060.550.410.260.060.2380
0.110.210.060.570.430.270.060.2475
0.120.210.070.590.440.280.070.2570
0.120.220.070.610.460.290.070.2665
0.130.230.070.640.480.300.070.2760
0.130.240.080.670.500.320.080.2855
SO3Na2OK2OMgOCaOAl2O3Fe2O3SiO2Kg/m
Guaranteed Ten-minute Repeatability by Oxide(1)Belt
Loading
59
Typical Accuracy guarantees – raw mix
0.20%0% - 1%SO3
0.20%0% - 1%Na2O
0.10%0% - 1%K2O
0.25%0% - 2%MgO
0.30%39.5% - 45.5%CaO
0.07%0.5% - 3.5%Fe2O3
0.28%2% - 4%Al2O3
0.30%12% - 15%SiO2
RMSDRange (1)Oxide
Guaranteed Maximum RMSD (2)
60
Dynamic performance -typical
Guarantee
Based on the test procedure and conditions specified below, Thermo Electron guarantees that the one-hour standard deviation
of the difference between will not exceed the values in the following table.
0.1(2)0.18(2)IM
0.10.15SM
1.5 – 2.02.5LSF
Expected
One standard
deviation(1)
Guarantee
One standard
deviation(1)
Quality
Parameter
(1)Values are stated on a dry basis (Loss On Ignition included)
(2)IM must be below 2.5
61
QUESTIONS
Thank you for your time
Base Cement and PREBOS Plus Software for
CBX Analyser
63
Control Software
• Controls the CBX analyser
• Handles Oxide Calibration
• Calculates Oxides and user
defined control parameters
64
PREBOS Plus Software
• Keeps track of the mound (stockpile) by monitoring the
cumulative chemistry of the stockpile and maintaining the
history data for control purposes
• Monitors the composition of the mound and based on several
parameters mentioned below provides advisories to the plant
operator to change the proportions of raw material sources to
achieve the target and desired chemistry:
– The target and desired chemistry
– The cost of various raw material
– The priority of usage
– The actual chemistry of the stockpile
65
System Configuration
Based on the Application,
Stockpile Control or Raw
Mix Control, the additional
control software can be
selected
In Base Cement mode
the software allows the
Mound tracking
The minimum kg/m that
is allowed for the
analysis can be
adjusted. For MVIA the
minimum is 18 kg/m
Display of digits can be
selected and for data
analysis purposes the
display of negative
Oxide vales can be
enabled
66
Standard Configuration
All major control parameters
are pre-defined
Equations can be customised to
comply with local requirements
67
Customised Configuration
Customised equation can be
defined to comply with
specific customer control
parameters
68
Oxide Display Configuration
Standard Oxide analysis
and feed information can
be selected for later real
time display and data
logging
69
Oxide Display Configuration
And all control
parameters can be
selected for later real
time display and data
logging as well
70
Oxide Display Configuration
Displayed information can
be easily modified
71
Alarm Configuration
For each control
parameter alarm levels
can be defined
separately
as well as the type of
message or the output
to the DCS system
Low and high limits can
be defined
72
Alarm Configuration
For each control
parameter alarm levels
can be defined
separately
For each alarm the
alarm level can be
configured to enable the
operator to judge the
alarm correctly
73
User Configuration
Software configuration
and control level
access are easily
added or removed
For each operator a
permission profile can
be defined and access
is controlled by
password
74
Analysis Page
The analysis page
summarises the
current analysis
the rolling analysisthe cumulative
analysisand a pre-defined
analysis interval
Date and time
information for
each summary are
given at the
bottom of the page
75
Analysis Status
A complete status
on all analysis and
control parameters
is calculated
76
Hardware Status
A complete status
on all analyser
hardware
components is
available
This includes
detector
monitoring
Electronic
components
Temperature and
communication
Material flow
information
And statistical
analytical
information
77
Statistical Oxide Data-Base
Over a pre-defined
interval all oxides
and selected
control parameters
are logged
For each pre-
defined oxide or
control parameter
Statistics are
calculated at the
bottom of the page
78
Trend Display
Trend lines are
given for all pre-
defined oxides and
control parameters
Current time and
date as well as
current and rolling
analysis values
are indicated
79
Graph Display
Graphs with different
information can be
combined into one
and be scaled
80
Alarm Summary Page
All alarms are
logged by date
and time
And alarm
condition and
description is
given
81
Tag Data Pool- Base Cement
82
Mound Trend Display- PREBOS Plus
Basic information
and settings of
current mound
Analysis data of
current mound
Trend data of
control parameters
of current mound
83
Mound History- PREBOS Plus
Basic information,
settings and
analysis data of
current mountList of mounds that
can be recalled
Analysis data of
finished mound
Basic information
of finished mound
Result of planned
modification is
displayed in the
last column
Different mound
analysis can be
added to calculate
further modifications
84
Main Control Screen - PREBOS Plus
Flexibility to
configure the raw
material sources
Actual consumption of
each raw material source
depicted in %
The demand signal suggesting
the correct value to attain the
target chemistry on completion of
the stockpile
Flexibility to
configure dirrent
products
Flexibility to
configure different
sources of raw
material
Trends of the selected
parameters depicting
the mound data,
rolling, target and
demand
85
Other Features
• Software can control several stock-piles
sequentially
• All logged data can be exported in
ASCII format
• All oxide vales and calculated control
parameters can be linked into the DCS
system from the control PC
• DCS link can be via Ethernet or PLC
communication card
86
What is Important for Process Control?
1. Repeatability / Precision
2. Uniformity of Analysis
3. Robustness of Analysis
4. Accuracy
1. Robustness of Analysis
2. Uniformity of Analysis
3. Repeatability / Precision
4. Accuracy
Raw MixRaw Mix StockpileStockpile
87
Level 1 PSA “Self Service”
Inclusions
ACCESS & RESPONSE
RADIATION SERVICES (excluding RSO Training)
PREDICTIVE & PREVENTATIVE MAINTENANCE
RECOVERY & ASSISTANCE (Remote Support Only)
Remote Technical Support
Remote Software Support (Assistance)
SURVEILLANCE & OPTIMIZATION
System Repeatability and Linearity
Dynamic Calibration and Accuracy (Verification / Adjustment)
OPERATIONS TRAINING
Exclusions
RECOVERY & ASSISTANCE
On-Site Labor
Travel & Living Expenses
SURVEILLANCE & OPTIMIZATION
Plant Performance Verification
PARTS
SYSTEM LIFE EXTENSION
88
Level 2a PSA
Inclusions
ACCESS & RESPONSE
RADIATION SERVICES (excluding RSO Training)
PREDICTIVE & PREVENTATIVE MAINTENANCE
RECOVERY & ASSISTANCE
SURVEILLANCE & OPTIMIZATION
System Repeatability and Linearity
Dynamic Calibration and Accuracy (Verification / Adjustment)
PARTS
Replacement of Failed Parts
Preemptive Replacement Parts
OPERATIONS TRAINING
On-Site Operator Training
Exclusions
SURVEILLANCE & OPTIMIZATION OPERATIONS TRAINING
Plant Performance Verification Operations & Maintenance Training
PARTS SYSTEM LIFE EXTENSION
Consumable Parts
On-Site Spare Parts
89
Level 2 PSA “3 Year”
Inclusions
ACCESS & RESPONSE
RADIATION SERVICES (excluding RSO Training)
PREDICTIVE & PREVENTATIVE MAINTENANCE
RECOVERY & ASSISTANCE
SURVEILLANCE & OPTIMIZATION
System Repeatability and Linearity
Dynamic Calibration and Accuracy (Verification / Adjustment)
PARTS
Replacement of Failed Parts
Preemptive Replacement Parts
Consumable Parts
OPERATIONS TRAINING
On-Site Operator Training
Operations & Maintenance Training
Exclusions
SURVEILLANCE & OPTIMIZATION PARTS
Plant Performance Verification On-Site Spare Parts
SYSTEM LIFE EXTENSION
90
68 Installations with TOP 10 Cement Producers68 Installations with TOP 10 Cement Producers68 Installations with TOP 10 Cement Producers68 Installations with TOP 10 Cement Producers
Holcim
Lafarge
Cemex
Heidelberger
Italcementi
Cimpor
Grasim Industries
Onoda Chichibu
Buzzi Unicem
SECIL
Installed Base
Thermo Cement

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cb omni flex analizador en linea

  • 1. Thermo Electron Materials and Minerals Tianjin Design Institute, Tianjin
  • 2. 2 Thermo Electron •Helping our customers to succeed…lasting partnerships and services Website: www.thermo.com Our customer value proposition •A variety of markets…including life sciences, process control, optical, and photonics The markets we serve •Technology innovation •Good business people Our core strengths •Analyze... detect... measure… control…What our products/ services do •Industry leader in high tech instruments, systems and software Our line of business
  • 3. 3 Thermo Electron Global Presence U.S. Russian Federation Argentina Australia Canada Japan Mexico New Zealand India Chile China Malaysia Hong Kong • 11,000 Employees • Ops in 30 Countries • $170MM Annual R&D Investment Europe Our Products and Services Make the World a Healthier, Cleaner and Safer Place
  • 4. 4 M&M Commercial Organization Service Sales & Service with Manufacturing Plant Sales & Service Gloucester/UK Erlangen/Germany France Shanghai/China Washington/USA Santiago/Chile Adelaide/Australia Pune/India Bahrain South Africa Mackay Brisbane Sydney Perth Indiana/USA San Paulo/Brazil West Virginia/USA Mexico Poland San Diego/USA So. Korea Taiwan Sales Malaysia Belgium
  • 5. 5 Crusher Stockpile Raw Mix Station Raw Mill Precalciner Homogenization Silo KILN Clinker Cooler Storage Silos Finish Blending Cement Mill Storage SiloFuel Feed Exhaust Stack Present Thermo Cement Discrete Instruments
  • 6. 6 Thermo Electron presence in Cement Industry
  • 7. 7 Emerging Trends…in Global Cement Industry EMERGING TRENDS IN CEMENT INDUSTRY • Cost pressures driving – Efficient plant equipment designs – Focus on alternative raw material and fuel usage – Process optimization FACTORS DRIVING HIGHER CEMENT PRODUCTION COSTS • 60-65% variables attributable to raw materials – Restrict quarry utilization – Poor flexibility to vary raw material feed – Additional costs towards additives – Un-stable kiln operation Online raw material control Immense process optimization opportunities for new as well as existing plants Real time Analysis can help in addressing these issues Effectively and Efficiently
  • 8. Prompt Gamma Neutron Activation Analysis - PGNAA - What is it? Why do we use it?
  • 9. 9 PGNAA, What is it? • Elemental Analysis Technique • Bulk Analysis Method –Penetrating Technology • Non-Destructive Analysis Tool
  • 10. 10 PGNAA, Why Do We Use it? • PGNAA Enables Accurate, High Frequency Process Control • Highly Automated & Mechanically Simple • Sampling Systems add Time Delay and Error • Surface Analysis is often not Representative • Measures the entire bulk of material as it travels on the belt • Analysis independent of size and type of material as well as conveyor speed ( up to 300mm) • Can measure moisture
  • 11. 11 XRF vs. PGNAA comparison – complementing technologies for efficient process control CrossBeltTM Analyzer PGNAA Domain XRF Domain Stages of Cement Production 1. Quarry 2. Pre-blending 3. Raw Mix 4. Raw Meal 5. Kiln Feed 6. Clinker Variance in Raw Material Quality Pre-Blending Optimization Raw Mix Optimization Process Control possibilities Quality Assurance only
  • 12. 12 RAMOS Reduces the Standard Deviation LSF & SM as Independent Variables 0 0.5 1 1.5 2 2.5 3 3.5 4 0.0% 3.0% 6.0% 9.0% 12.0% 15.0% Heat Increase to Prevent Excess Clinker Free Lime StandardDeviationofLSF 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 StandardDeviationofSM LSF SM
  • 13. 13 Blend Quality Measured Quality The Ability for Different Blending Processes to Track Chemistry Variations
  • 14. 14 Prompt Gamma Neutron Activation Analysis (PGNAA) – operating principle Prompt Gamma Neutron Activation Analysis (PGNAA) – operating principle γγγγ Thermal Neutron Thermal Neutron NucleusNucleus Excited Nucleus Excited Nucleus Stable Nucleus Stable Nucleus Gamma Ray Gamma Ray
  • 15. 15 Gamma Detector Zone Neutron Source Zone Conveyor Belt (return side) Conveyor Belt (loaded side) Lower Shield Assembly Middle Shield Assemblies Upper Shield Assembly The advanced CBX Analyzer
  • 16. 16 PARAMETERS ANALYZED IN ONE MINUTEPARAMETERS ANALYZED IN ONE MINUTE • Direct Measurement – CaO – SiO2 – Fe2O3 – Al2O3 – MgO – K2O – Na2O – S – Cl – Moisture • Direct Measurement – CaO – SiO2 – Fe2O3 – Al2O3 – MgO – K2O – Na2O – S – Cl – Moisture • Computed – Silica Ratio – C3S – C3A – LSF – A/F Ratio – Liquidity – Burnability • Computed – Silica Ratio – C3S – C3A – LSF – A/F Ratio – Liquidity – Burnability
  • 17. 17 Reference Standard with Lifting Straps Scope of Supply
  • 18. 18 On-line Bulk Material Analysis Evolution 1985 Chute Type Analyzer 1993 CrossBelt Analyzer 1997 CrossBelt GN Analyzer 2003 CBXpert Analyzer
  • 19. 19 OverOverOverOver Over 250 Installations spanning 40 countries andOver 250 Installations spanning 40 countries andOver 250 Installations spanning 40 countries andOver 250 Installations spanning 40 countries and 6 continents6 continents6 continents6 continents Installed Base Thermo Cement
  • 21. 21 Limestone CrossBelt Xpert (CBX) Analyzer Drucker Weigh Scale Electronic Cabinet Operator Console SOFTWARE Blending Bed Plant PLC Clay / Marl CBX- Manual Stockpile Control using one or two type of raw material source
  • 22. 22 Limestone CrossBelt Xpert (CBX) Analyzer Drucker Weigh Scale Electronic Cabinet Operator Console SOFTWARE Blending Bed Plant PLC Clay / Marl CBX- Manual stockpile control using multiple raw material sources.
  • 23. 23 CrossBelt Xpert (CBX) Analyzer Drucker Weigh Scale Electronic Cabinet Operator Console SOFTWARE Blending Bed Limestone Clay / Marl CBX- Auto Stockpile Control for multiple raw material sources. Plant PLC Apron feeders
  • 24. 24 Combination of Manual and Auto Stockpile Control to optimize stockpile building using variety of raw materials Clay like Materials Intermediate Clay Mix Pile Weigh Scale CrossBelt Analyzer Electronics Control software DEMANDS/ ADVISORIES Wireless Station Pre-blending Stockpile Control SM & IM Wireless Terminal in Loader LIMESTONE From quarry
  • 25. 25 CBX- Raw Mix – Typical Crushe r Stockpile Plant PLC CrossBelt Xpert (CBX) Analyzer Electronic Cabinet Operator Console SOFTWARE Vertical Roller Mill Raw Mill Hoppers
  • 26. 26 CBX – Multiple Hoppers and Raw Mills 10 Raw Mill hoppers – 3 of the hoppers are used to feed limestone, additional 3 hoppers are used to feed Catalyst fine a chemical waste, 1 for iron ore, 1 for shale, 1 for silica and the last hopper to feed slag Ball Mill 1 200TPH Ball Mill 2 200 TPH CrossBelt Analyzer Electronic Cabinet Operator ConsolePlant PLC Client supplied Feeder Control signals Flap Gate enabling flow to alternative mills. This senses the level of material in each hopper to alternate the flow 600 mm two speed belt conveyor is used to feed two ball mills of capacity 200 TPH each, when feeding single mill the belt runs at a lower speed and switches to higher speed when feeding two mills. Small surge bin of 1 Ton capacity equipped with sensors and airlock Small surge bin of 1 Ton capacity equipped with sensors and airlock
  • 27. 27 CBX – Multiple hoppers and variety of mills 6 Raw Mill hopers – 2 of the hoppers are used to feed limestone, 2 more are used for clay feed, 1 hopper is used for iron ore and the last one feeds mineralizer Ball Mill 1 90TPH Vertical Roller Mill 2 240 TPH CrossBelt Analyzer Electronic Cabinet Operator ConsolePlant PLC Client supplied Feeder Control signals A surge hopper equipped with reversible belt to enable feeding the two mills. This reversible belt operates in rapid succession dispensing more material in the VRM and less in Ball Mill 1000 mm two speed belt conveyor is used to feed one VRM of 240 TPH and one ball mill of capacity 90 TPH each, when feeding one mill the belt runs at a lower speed. The ball mill is used only when you need to increase the capacity Each mill is equipped with very small capacity bins to enable material flow into the mills Please note Holcim Cerro Blanco runs Vertical Roller Mill most of the times, and the ball mill is only used when there is a need to increase capacity
  • 28. 28 CBX – Unique Application Designed to Reduce and Optimize Capital Expenditure – Tianshan Yunfu Cement High Grade Limestone Crusher Plant PLC CrossBelt Xpert (CBX) Analyzer Electronic Cabinet Operator Console SOFTWARE Vertical Roller Mill Raw Mill Hoppers STOCKPILE IS ELIMINATED $ 2M- 3M SAVINGS Low Grade Limestone Crusher
  • 29. 29 29 85 90 95 100 105 110 115 1 3 5 7 9 11 13 15 17 19 21 23 25 27 29 31 33 35 37 39 41 43 45 47 49 51 Stockpile No LSF Pre CBX installation Post CBX installation Raw Mill Target, 98 Stockpile Target, 96 Dynamic Performance Test Stockpile LSF before and after installation of CBX
  • 30. 30 WHY High Frequency Control ?? LSF Target CONVENTIONAL CONTROL HIGH FREQUENCY CONTROL TIME LSF
  • 31. 31 RAMOS Reduces the Standard Deviation LSF & SM as Independent Variables 0 0.5 1 1.5 2 2.5 3 3.5 4 0.0% 3.0% 6.0% 9.0% 12.0% 15.0% Heat Increase to Prevent Excess Clinker Free Lime StandardDeviationofLSF 0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 StandardDeviationofSM LSF SM
  • 32. 32 Benefits of High Frequency Raw Mix Proportioning • Assured raw meal homogeneity consistently • Stable kiln operation • Reduction in fuel cost • Reduction in clinker grinding cost • Extended brick life • Higher production • Improved end product quality
  • 33. 33 Raw mix control : User feed back Cement Plant Country Improvements Realized Apasco Norte Mexico Refractory life exceeded two years. Cementi Rossi Italy Fuel costs reduced 5.6%. Colacem Italy Able to run entire plant with one person on night shift. Discontinued active homogenization in homo silos. Compagnie des Belgium Reduced kiln feed variability by a factor of 3. Ciments Belges Discontinued active homogenization in homo silos. Lafarge Cormeilles France Reduced kiln feed variability by 60%. Sococim Senegal Reduced fuel costs by 4%. Blue Circle Southern Australia Kiln feed LSF S.D. reduced from 3 to <1 Lafarge Mannersdorf Austria Kiln feed homogeneity achieved without blending in silos Luilihe China Improved productivity by 10%, 70% quality improvement
  • 35. 35 To have the maximum variability in analyser width a modular shielding block design with two sizes has been developed CBXpert Design Features - Shielding Flexible analyzer width 432 mm 584 mm
  • 36. 36 CBXpert Design Features - Shielding Flexible analyzer width The two block sizes allow the configuration of different analyser width CBX1 Belt width 600-1000 mm 1 600mmCBX1 CBX2 Belt width 1200 mm 1 752 mmCBX2 CBX3 Belt width 1400 – 1600 mm 2 032 mmCBX3 CBX4 Belt width 1800 – 2000 mm 2 337 mmCBX4 CBX5 Belt width 2100 – 2200 mm 2 616 mm CBX5
  • 37. 37 CBXpert Shielding Integration Then the bottom shielding blocks are placed on the bottom frame supports
  • 38. 38 CBXpert Belt Integration Distance between belt and return belt is 710 mm. If distance is less a roller can be attached to the frame structure to guide the return belt below the analyser
  • 39. 39 CBXpert Shielding Integration The middle section of the analyzer has to be custom tailored to the existing belt. Idler angle • Idler angle between 35°and 45° Side idler width • Side idler width Following parameters have to be configured: • Material height Material height • Centre idler width Center idler width
  • 40. 40 Tunnel height defined by max. material height Idler angle Center idler width CBXpert Shielding Integration Side blocks get configured to customer belt specification Side idler width
  • 41. 41 CBXpert Shielding Integration Side blocks are installed on the bottom shielding blocks
  • 42. 42 CBXpert Shielding Integration For the top shielding the same shielding blocks are used as at the bottom. Side blocks have no load from the top and can be moved to fine adjust to belt position
  • 43. 43 CBXpert Shielding Integration Source block has 4 sources positions. Initial source loading depends on application. Stockpile 38 µg 252Cf Raw-Mix 66 µg 252Cf
  • 44. 44 CBXpert Shielding Integration Detector block contains the new horizontally positioned heated detectors. Detectors are individually positioned for optimum detection efficiency
  • 45. 45 CBXpert Shielding Integration Access to source and detector is always from one side. Customer can define position prior to order
  • 46. 46 CBXpert Shielding Integration Custom tailored liners are installed to protect the tunnel area
  • 47. 47 CBXpert Shielding Integration All shielding parts get bolted to the frame and fixed in position
  • 48. 48 CBXpert Shielding Integration The analyser shielding is in position. For hot environments it is recommended to install a sun shield over the analyser
  • 49. 49 Example CBX Installation: Dragon Products No Building or Sun- Shade 10-Block Modular Design No Platform No Bend Pulleys for Belt Return Single Sided Maintenance Access No A/C Requirement 35○ Trough Angle Proprietary Modular Reference Standards
  • 51. 51 CBXpert Electrical connection The electronics enclosure can be positioned up to 100 m from the analyser and does not require any air-conditioning
  • 52. 52 CBXpert Electrical connection Connection to the control room can be done by RS422 or optical cable. The RS422 connection is limited to a distance of 2000 m.
  • 53. 53 Plant Interface • OPC – Ole for Process Control • ODBC – Open Data Base Connectivity • Serial Protocol
  • 54. 54 • No Overhead hoist required • Easily handled by one person Maximum 22Kg • Easily stored Best of both the worlds (Baggies and Modular Reference standards) Non-symmetrical Loading is Duplicated in Factory Testing
  • 56. 56 Static guarantees – typical for stockpile STATIC REPEATABILITY The system is guaranteed to perform equal to or better than the following static repeatability specifications. Values are stated on a dry basis (LOI included). 0.04%0.07%SO3 0.08%0.13%Na2O 0.02%0.04%K2O 0.20%0.30%MgO 0.20%0.27%CaO 0.02%0.04%Fe2O3 0.11%0.17%Al2O3 0.10 %0.15%SiO2 Expected Repeatability One Standard Deviation (1) Guarantee One Standard Deviation (1)Oxide
  • 57. 57 Static guarantees –typical for stockpile •STATIC ACCURACY •The system is guaranteed to perform equal to or better than the following static accuracy specifications in stockpile monitoring applications. •The values are stated on a dry basis (LOI included). •Standard Range •0.09 %•0.17 %•3% (0%-3%)•SO3 •0.20 %•0.30 %•3% (0%-3%)•Na2O •0.10 %•0.15 %•3% (0%-3%)•K2O •0.38%•0.50 %•6% (0%-6%)•MgO •0.35 %•0.40 %•35% (18%-53%)•CaO •0.06 %•0.10 %•10% (0%-10%)•Fe2O3 •0.26 %•0.35 %•10% (0%-10%)•Al2O3 •0.35 %•0.40 %•20% (4%-24%)•SiO2 •Expected Maximum RMSD (2) •Guaranteed Maximum RMSD (2)•Range (1)•Oxide • (1) Range of material composition in reference standards. • Guarantees are a function of the range, a larger range will dictate a larger guarantee. Conversely, a • smaller range will dictate a smaller guarantee (2) Root Mean Squared Deviation, one-hour period
  • 58. 58 Typical repeatability guarantees – raw mix 0.090.170.050.460.350.220.050.19115 0.090.170.050.470.350.220.050.20110 0.100.180.060.480.360.230.060.20105 0.100.180.060.490.370.230.060.21100 0.100.180.060.510.380.240.060.2195 0.100.190.060.520.390.250.060.2290 0.110.190.060.540.400.250.060.2285 0.110.200.060.550.410.260.060.2380 0.110.210.060.570.430.270.060.2475 0.120.210.070.590.440.280.070.2570 0.120.220.070.610.460.290.070.2665 0.130.230.070.640.480.300.070.2760 0.130.240.080.670.500.320.080.2855 SO3Na2OK2OMgOCaOAl2O3Fe2O3SiO2Kg/m Guaranteed Ten-minute Repeatability by Oxide(1)Belt Loading
  • 59. 59 Typical Accuracy guarantees – raw mix 0.20%0% - 1%SO3 0.20%0% - 1%Na2O 0.10%0% - 1%K2O 0.25%0% - 2%MgO 0.30%39.5% - 45.5%CaO 0.07%0.5% - 3.5%Fe2O3 0.28%2% - 4%Al2O3 0.30%12% - 15%SiO2 RMSDRange (1)Oxide Guaranteed Maximum RMSD (2)
  • 60. 60 Dynamic performance -typical Guarantee Based on the test procedure and conditions specified below, Thermo Electron guarantees that the one-hour standard deviation of the difference between will not exceed the values in the following table. 0.1(2)0.18(2)IM 0.10.15SM 1.5 – 2.02.5LSF Expected One standard deviation(1) Guarantee One standard deviation(1) Quality Parameter (1)Values are stated on a dry basis (Loss On Ignition included) (2)IM must be below 2.5
  • 62. Base Cement and PREBOS Plus Software for CBX Analyser
  • 63. 63 Control Software • Controls the CBX analyser • Handles Oxide Calibration • Calculates Oxides and user defined control parameters
  • 64. 64 PREBOS Plus Software • Keeps track of the mound (stockpile) by monitoring the cumulative chemistry of the stockpile and maintaining the history data for control purposes • Monitors the composition of the mound and based on several parameters mentioned below provides advisories to the plant operator to change the proportions of raw material sources to achieve the target and desired chemistry: – The target and desired chemistry – The cost of various raw material – The priority of usage – The actual chemistry of the stockpile
  • 65. 65 System Configuration Based on the Application, Stockpile Control or Raw Mix Control, the additional control software can be selected In Base Cement mode the software allows the Mound tracking The minimum kg/m that is allowed for the analysis can be adjusted. For MVIA the minimum is 18 kg/m Display of digits can be selected and for data analysis purposes the display of negative Oxide vales can be enabled
  • 66. 66 Standard Configuration All major control parameters are pre-defined Equations can be customised to comply with local requirements
  • 67. 67 Customised Configuration Customised equation can be defined to comply with specific customer control parameters
  • 68. 68 Oxide Display Configuration Standard Oxide analysis and feed information can be selected for later real time display and data logging
  • 69. 69 Oxide Display Configuration And all control parameters can be selected for later real time display and data logging as well
  • 70. 70 Oxide Display Configuration Displayed information can be easily modified
  • 71. 71 Alarm Configuration For each control parameter alarm levels can be defined separately as well as the type of message or the output to the DCS system Low and high limits can be defined
  • 72. 72 Alarm Configuration For each control parameter alarm levels can be defined separately For each alarm the alarm level can be configured to enable the operator to judge the alarm correctly
  • 73. 73 User Configuration Software configuration and control level access are easily added or removed For each operator a permission profile can be defined and access is controlled by password
  • 74. 74 Analysis Page The analysis page summarises the current analysis the rolling analysisthe cumulative analysisand a pre-defined analysis interval Date and time information for each summary are given at the bottom of the page
  • 75. 75 Analysis Status A complete status on all analysis and control parameters is calculated
  • 76. 76 Hardware Status A complete status on all analyser hardware components is available This includes detector monitoring Electronic components Temperature and communication Material flow information And statistical analytical information
  • 77. 77 Statistical Oxide Data-Base Over a pre-defined interval all oxides and selected control parameters are logged For each pre- defined oxide or control parameter Statistics are calculated at the bottom of the page
  • 78. 78 Trend Display Trend lines are given for all pre- defined oxides and control parameters Current time and date as well as current and rolling analysis values are indicated
  • 79. 79 Graph Display Graphs with different information can be combined into one and be scaled
  • 80. 80 Alarm Summary Page All alarms are logged by date and time And alarm condition and description is given
  • 81. 81 Tag Data Pool- Base Cement
  • 82. 82 Mound Trend Display- PREBOS Plus Basic information and settings of current mound Analysis data of current mound Trend data of control parameters of current mound
  • 83. 83 Mound History- PREBOS Plus Basic information, settings and analysis data of current mountList of mounds that can be recalled Analysis data of finished mound Basic information of finished mound Result of planned modification is displayed in the last column Different mound analysis can be added to calculate further modifications
  • 84. 84 Main Control Screen - PREBOS Plus Flexibility to configure the raw material sources Actual consumption of each raw material source depicted in % The demand signal suggesting the correct value to attain the target chemistry on completion of the stockpile Flexibility to configure dirrent products Flexibility to configure different sources of raw material Trends of the selected parameters depicting the mound data, rolling, target and demand
  • 85. 85 Other Features • Software can control several stock-piles sequentially • All logged data can be exported in ASCII format • All oxide vales and calculated control parameters can be linked into the DCS system from the control PC • DCS link can be via Ethernet or PLC communication card
  • 86. 86 What is Important for Process Control? 1. Repeatability / Precision 2. Uniformity of Analysis 3. Robustness of Analysis 4. Accuracy 1. Robustness of Analysis 2. Uniformity of Analysis 3. Repeatability / Precision 4. Accuracy Raw MixRaw Mix StockpileStockpile
  • 87. 87 Level 1 PSA “Self Service” Inclusions ACCESS & RESPONSE RADIATION SERVICES (excluding RSO Training) PREDICTIVE & PREVENTATIVE MAINTENANCE RECOVERY & ASSISTANCE (Remote Support Only) Remote Technical Support Remote Software Support (Assistance) SURVEILLANCE & OPTIMIZATION System Repeatability and Linearity Dynamic Calibration and Accuracy (Verification / Adjustment) OPERATIONS TRAINING Exclusions RECOVERY & ASSISTANCE On-Site Labor Travel & Living Expenses SURVEILLANCE & OPTIMIZATION Plant Performance Verification PARTS SYSTEM LIFE EXTENSION
  • 88. 88 Level 2a PSA Inclusions ACCESS & RESPONSE RADIATION SERVICES (excluding RSO Training) PREDICTIVE & PREVENTATIVE MAINTENANCE RECOVERY & ASSISTANCE SURVEILLANCE & OPTIMIZATION System Repeatability and Linearity Dynamic Calibration and Accuracy (Verification / Adjustment) PARTS Replacement of Failed Parts Preemptive Replacement Parts OPERATIONS TRAINING On-Site Operator Training Exclusions SURVEILLANCE & OPTIMIZATION OPERATIONS TRAINING Plant Performance Verification Operations & Maintenance Training PARTS SYSTEM LIFE EXTENSION Consumable Parts On-Site Spare Parts
  • 89. 89 Level 2 PSA “3 Year” Inclusions ACCESS & RESPONSE RADIATION SERVICES (excluding RSO Training) PREDICTIVE & PREVENTATIVE MAINTENANCE RECOVERY & ASSISTANCE SURVEILLANCE & OPTIMIZATION System Repeatability and Linearity Dynamic Calibration and Accuracy (Verification / Adjustment) PARTS Replacement of Failed Parts Preemptive Replacement Parts Consumable Parts OPERATIONS TRAINING On-Site Operator Training Operations & Maintenance Training Exclusions SURVEILLANCE & OPTIMIZATION PARTS Plant Performance Verification On-Site Spare Parts SYSTEM LIFE EXTENSION
  • 90. 90 68 Installations with TOP 10 Cement Producers68 Installations with TOP 10 Cement Producers68 Installations with TOP 10 Cement Producers68 Installations with TOP 10 Cement Producers Holcim Lafarge Cemex Heidelberger Italcementi Cimpor Grasim Industries Onoda Chichibu Buzzi Unicem SECIL Installed Base Thermo Cement