4. Material Safety Data
Sheets
A material safety data
sheet (MSDS) is a
document that contain
information on the
potential health effect
of exposure to
chemicals, or other
potentially dangerous
substances, and on safe
working procedures when
handling chemical
products.
5. HISTORY
• The earlier written
material has been
found in the tombs of
the Egyptians, either
on the walls of their
tombs or on papyrus
record.
6. Material Safety Data Sheets
• Include specific identity and
common name
• Must provide information about:
• Physical and chemical characteristics.
• Health effects
• Exposure limits
• Carcinogenicity(cancer causing)
• Identifications( name, address,
telephone NO. of the organization e.t.c)
7. Who Prepare and Provides MSDS?
• Manufacturers and importers of
dangerous goods and hazardous
substances must:
• Prepare an MSDS for each of
their products.
Provide the current MSDS to
employers or occupiers of
premises where the product is
used or stored.
Review and revise each MSDS as
often as necessary and at least
every 5 years to make sure that
the information is accurate and up
to date.
8. TYPES OF HAZARDS:
• when you read an MSDS, you should keep in mind that
there are three main types of hazards:
• Health Hazard: For example, skin contact with strong
acids will cause burns.
• Fire Hazard: For example, propane burns very easily and
may explode.
• Reactivity Hazards: For example mixing ammonia and
household bleach will result in the release of harmful gas
10. oxidizer
• An oxidizer is the type of chemical
which a fuel requires to burn.
• Chemical capable of evolving oxygen
at room temperature.
• It does not burn but is a powerful
explosive when mixed with
combustible materials.
19. First Aid Measures:
EYE CONTACT:
• check for and remove any contact Lenses.
• Immediately flash eyes with plenty of
water for 15 min.
• Get Medical attention immediately.
20. SKIN CONTACT:
• Immediately flash skin with the plenty
of water for at least 15 min while
removing contaminated clothing and
shoes.
• Cover the irritated skin with emollient.
• Get medical attention immediately.
21. INHALATION:
• Remove to fresh air
• If not breathing give artificial breathing
Warning- it may be hazardous to person
providing the aide.
• If breathing is difficult , gives breathing.
• Get medical attention immediately.
22. Need of MSDS and How to prepare:
• In 1993, the American National Standard for Hazardous
Industrial chemical – Material Safety Data Sheets –
preparation ,ANSI Z400.1 was developed to address the
need for a MSDS format that was comprehensive,
understandable and consistent.
• ANSI Z400.1-1993 introduced the standardized 16-
section MSDS.
• Revision were made to the standard in 1998 and 2005. The
2005 revision improve readability , minimize redundancies
and reorder the MSDS section.
23. Sections of MSDS:
• Section 1: Chemical product and company
identification.
• Section 2: Composition/ information on
ingredients.
• Section 3: Hazard .identification potential
Health Effects.
• Section 4: First Aid Measures.
• Section 5: Fire Fighting Measures.
• Section 6: Accidental Release Measures.
• Section 7 : Handling and storage.
24. • Section 8: Exposure Controls/ personal
protection.
• Section 9: Physical and chemical Properties.
• Section 10: Stability and Reactivity
• Section 11: Toxicological Information
• Section 12: Ecological Information
• Section 13: Disposal Consideration
• Section 14: Transport Information
• Section 15: Regulation Information
• Section 16 : Other Information