2. SUPERALLOY
Superalloy is an alloy that exhibits
excellent mechanical strength and creep
resistance at high temperatures.
Superalloys are metallic materials for
service at high temperatures ,
particularly in hot zones of gas turbine ,
jet engines etc..
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3. Development of Superalloys
Superalloys develop high temperature
strength through Solid solution
strengthening(SSS)
SSS is a type of alloying that can be
used to improve the strength of the
metals
The technique works by adding atoms of
one element (alloying element) to the
crystalline lattice of another element (the
base metal)
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4. Properties
High temperature creep resistance
(1050°C to 1200°C)
Fatigue life
Corrosion resistance
Good surface stability
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5. Classification
Superalloys are often classified into
generations and until today there were five
generations
The sixth generation is in the form of
project at National Institute of Material
Science in Japan (NIMS)
First generation superalloys are
characterstic with a relatively huge amount
of chromium in comparision with other
generations
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6. The second and third generation
contains about 3 wt % and 6 wt % of
rhenium respectively
Rhenium is a very expensive addition
but leads to an improvement in creep
strength and fatigue resistance
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8. As an example of fourth generation of
superalloys TMS-138 can be
characterised.
It was developed in NIMS with the
addition of Mo for increasing the lattice
misfit .
The excellent creep behaviour at high
temperatures (about 1373K) is attributed
with the recent generation of superalloys
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10. The representation of the fifth
generation of the superalloys is for
example TMS-169 alloy developed at
NIMS in collaboration with Ishikawajima-
Harima Heavy insdustries co.,Ltd (IHI) in
japan in 2006
TMS-169 is an advanced superalloy
containing 5 wt % Ru and 4.6 wt % Cr
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11. TMS 169 with superior high temperature
creep and oxidation resistance by
incorporating further Ru and Cr content
over the composition of fourth
generation alloys
With Ru additions it will enhance the
phase stability
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12. Super alloys are classified into three
based on the predominant metal present
in the alloy. They are
Nickel based Super alloy
Iron based Super alloy
Cobalt based Super alloy
With Al,W,Ti as additional elements
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13. Nickel based Super alloy
Nickel based Super alloys can be either
Solid solution strengthening or
Precipitation hardening.
Solid solution strengthened alloys such
as Hastelloy are used only in
applications which require very modest
strength
Most Ni based alloy contain 10-20% Cr,
up to 8% Al and Ti, 5-10% Co, and small
amounts of B , Zr and C
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14. Iron based Super alloy
Iron based Super alloys are
characterised by high temperature as
well as room temperature strength.
Apart from this, it will have good
resistance to creep , oxidation, corrosion
and wear
Oxidation resistance increases with
chromium content
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15. Cobalt based Super alloy
Cobalt based Super alloys have their
origin in the stellite alloys.
Cobalt alloys have higher melting points
than nickel alloys.This gives them the
ability to absorb stress to a higher
temperature
Cobalt alloys show superior thermal
fatigue resistance and weldability over
the nickel alloys
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20. High temperature steel
During the 1950s, utility boilers
operating above 1000°F at pressures
above 1500 psi were experiencing
premature failures.
These failures were initially attributed to
an extremely fine grain size occasioned
by a low temperature solution heat
treatment
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21. Reheat treatment at higher temperature
to produce coarse grain structure reduce
the incidence of failure
Results of a subsequent research found
out that carbon content plays a major
role in this along with final solution heat
treatment and not the grain size.
A new designation was introduced which
incorporated specific heat treatments
and control of carbon.
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22. Importance
High temperature steels are specially
alloyed steels and are designed for
High strength
Impact toughness
Wear resistance
The main categories of this steels are
High-speed steels(HSS)
Hot-work steels
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23. High speed steels
It was first developed in the early 1900s,
and are the most highly alloyed steels
which can maintain their hardness and
strength at elevated operating
temperatures
There are two basic types of high-speed
steels
Molybdenum type
Tungsten type
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24. Hot-work steels
These are designated for use at
elevated temperatures and have high
toughness and high resistance to wear
and cracking.
The alloying elements are generally
tungsten ,molybdenum , chromium and
vanadium
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