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B.SREE KRISHNA
116107013
1
SUPERALLOY
 Superalloy is an alloy that exhibits
excellent mechanical strength and creep
resistance at high temperatures.
 Superalloys are metallic materials for
service at high temperatures ,
particularly in hot zones of gas turbine ,
jet engines etc..
2
Development of Superalloys
 Superalloys develop high temperature
strength through Solid solution
strengthening(SSS)
 SSS is a type of alloying that can be
used to improve the strength of the
metals
 The technique works by adding atoms of
one element (alloying element) to the
crystalline lattice of another element (the
base metal)
3
Properties
 High temperature creep resistance
(1050°C to 1200°C)
 Fatigue life
 Corrosion resistance
 Good surface stability
4
Classification
 Superalloys are often classified into
generations and until today there were five
generations
 The sixth generation is in the form of
project at National Institute of Material
Science in Japan (NIMS)
 First generation superalloys are
characterstic with a relatively huge amount
of chromium in comparision with other
generations
5
 The second and third generation
contains about 3 wt % and 6 wt % of
rhenium respectively
 Rhenium is a very expensive addition
but leads to an improvement in creep
strength and fatigue resistance
6
Composition of some Super
alloys
7
 As an example of fourth generation of
superalloys TMS-138 can be
characterised.
 It was developed in NIMS with the
addition of Mo for increasing the lattice
misfit .
 The excellent creep behaviour at high
temperatures (about 1373K) is attributed
with the recent generation of superalloys
8
9
 The representation of the fifth
generation of the superalloys is for
example TMS-169 alloy developed at
NIMS in collaboration with Ishikawajima-
Harima Heavy insdustries co.,Ltd (IHI) in
japan in 2006
 TMS-169 is an advanced superalloy
containing 5 wt % Ru and 4.6 wt % Cr
10
 TMS 169 with superior high temperature
creep and oxidation resistance by
incorporating further Ru and Cr content
over the composition of fourth
generation alloys
 With Ru additions it will enhance the
phase stability
11
 Super alloys are classified into three
based on the predominant metal present
in the alloy. They are
 Nickel based Super alloy
 Iron based Super alloy
 Cobalt based Super alloy
With Al,W,Ti as additional elements
12
Nickel based Super alloy
 Nickel based Super alloys can be either
Solid solution strengthening or
Precipitation hardening.
 Solid solution strengthened alloys such
as Hastelloy are used only in
applications which require very modest
strength
 Most Ni based alloy contain 10-20% Cr,
up to 8% Al and Ti, 5-10% Co, and small
amounts of B , Zr and C
13
Iron based Super alloy
 Iron based Super alloys are
characterised by high temperature as
well as room temperature strength.
 Apart from this, it will have good
resistance to creep , oxidation, corrosion
and wear
 Oxidation resistance increases with
chromium content
14
Cobalt based Super alloy
 Cobalt based Super alloys have their
origin in the stellite alloys.
 Cobalt alloys have higher melting points
than nickel alloys.This gives them the
ability to absorb stress to a higher
temperature
 Cobalt alloys show superior thermal
fatigue resistance and weldability over
the nickel alloys
15
Applications
 Aircraft gas turbines: disks,
combustion chambers, bolts, casings,
shafts, exhaust systems, cases, blades,
vanes, burner cans, afterburners, thrust
reversers
 Steam turbine power plants: bolts,
blades, stack gas re-heaters
16
 Reciprocating engines: turbochargers,
exhaust valves, hot plugs, valve seat
inserts
 Metal processing: hot-work tools and
dies, casting dies
 Space vehicles: aerodynamically
heated skins, rocket engine parts
17
18
MTT TURBINE SUPERBIKE Y2K
19
Engine of Y2K Superbike
High temperature steel
 During the 1950s, utility boilers
operating above 1000°F at pressures
above 1500 psi were experiencing
premature failures.
 These failures were initially attributed to
an extremely fine grain size occasioned
by a low temperature solution heat
treatment
20
 Reheat treatment at higher temperature
to produce coarse grain structure reduce
the incidence of failure
 Results of a subsequent research found
out that carbon content plays a major
role in this along with final solution heat
treatment and not the grain size.
 A new designation was introduced which
incorporated specific heat treatments
and control of carbon.
21
Importance
 High temperature steels are specially
alloyed steels and are designed for
 High strength
 Impact toughness
 Wear resistance
The main categories of this steels are
 High-speed steels(HSS)
 Hot-work steels
22
High speed steels
 It was first developed in the early 1900s,
and are the most highly alloyed steels
which can maintain their hardness and
strength at elevated operating
temperatures
 There are two basic types of high-speed
steels
 Molybdenum type
 Tungsten type
23
Hot-work steels
 These are designated for use at
elevated temperatures and have high
toughness and high resistance to wear
and cracking.
 The alloying elements are generally
tungsten ,molybdenum , chromium and
vanadium
24
Applications
25
Kawasaki H1 – Engine exhaust
26
Valves used in combustion chamber
References
 http://www.msm.cam.ac.uk/phase-
trans/2003/Superalloys/superalloys.html.
 http://www.patentstorm.us/patents/5366
695.html
 Manufacturing process for engineering
materials by Kalpakjian
 Material science and Engg by William
callister
27
28

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High temperature materials & super alloys ppt

  • 2. SUPERALLOY  Superalloy is an alloy that exhibits excellent mechanical strength and creep resistance at high temperatures.  Superalloys are metallic materials for service at high temperatures , particularly in hot zones of gas turbine , jet engines etc.. 2
  • 3. Development of Superalloys  Superalloys develop high temperature strength through Solid solution strengthening(SSS)  SSS is a type of alloying that can be used to improve the strength of the metals  The technique works by adding atoms of one element (alloying element) to the crystalline lattice of another element (the base metal) 3
  • 4. Properties  High temperature creep resistance (1050°C to 1200°C)  Fatigue life  Corrosion resistance  Good surface stability 4
  • 5. Classification  Superalloys are often classified into generations and until today there were five generations  The sixth generation is in the form of project at National Institute of Material Science in Japan (NIMS)  First generation superalloys are characterstic with a relatively huge amount of chromium in comparision with other generations 5
  • 6.  The second and third generation contains about 3 wt % and 6 wt % of rhenium respectively  Rhenium is a very expensive addition but leads to an improvement in creep strength and fatigue resistance 6
  • 7. Composition of some Super alloys 7
  • 8.  As an example of fourth generation of superalloys TMS-138 can be characterised.  It was developed in NIMS with the addition of Mo for increasing the lattice misfit .  The excellent creep behaviour at high temperatures (about 1373K) is attributed with the recent generation of superalloys 8
  • 9. 9
  • 10.  The representation of the fifth generation of the superalloys is for example TMS-169 alloy developed at NIMS in collaboration with Ishikawajima- Harima Heavy insdustries co.,Ltd (IHI) in japan in 2006  TMS-169 is an advanced superalloy containing 5 wt % Ru and 4.6 wt % Cr 10
  • 11.  TMS 169 with superior high temperature creep and oxidation resistance by incorporating further Ru and Cr content over the composition of fourth generation alloys  With Ru additions it will enhance the phase stability 11
  • 12.  Super alloys are classified into three based on the predominant metal present in the alloy. They are  Nickel based Super alloy  Iron based Super alloy  Cobalt based Super alloy With Al,W,Ti as additional elements 12
  • 13. Nickel based Super alloy  Nickel based Super alloys can be either Solid solution strengthening or Precipitation hardening.  Solid solution strengthened alloys such as Hastelloy are used only in applications which require very modest strength  Most Ni based alloy contain 10-20% Cr, up to 8% Al and Ti, 5-10% Co, and small amounts of B , Zr and C 13
  • 14. Iron based Super alloy  Iron based Super alloys are characterised by high temperature as well as room temperature strength.  Apart from this, it will have good resistance to creep , oxidation, corrosion and wear  Oxidation resistance increases with chromium content 14
  • 15. Cobalt based Super alloy  Cobalt based Super alloys have their origin in the stellite alloys.  Cobalt alloys have higher melting points than nickel alloys.This gives them the ability to absorb stress to a higher temperature  Cobalt alloys show superior thermal fatigue resistance and weldability over the nickel alloys 15
  • 16. Applications  Aircraft gas turbines: disks, combustion chambers, bolts, casings, shafts, exhaust systems, cases, blades, vanes, burner cans, afterburners, thrust reversers  Steam turbine power plants: bolts, blades, stack gas re-heaters 16
  • 17.  Reciprocating engines: turbochargers, exhaust valves, hot plugs, valve seat inserts  Metal processing: hot-work tools and dies, casting dies  Space vehicles: aerodynamically heated skins, rocket engine parts 17
  • 19. 19 Engine of Y2K Superbike
  • 20. High temperature steel  During the 1950s, utility boilers operating above 1000°F at pressures above 1500 psi were experiencing premature failures.  These failures were initially attributed to an extremely fine grain size occasioned by a low temperature solution heat treatment 20
  • 21.  Reheat treatment at higher temperature to produce coarse grain structure reduce the incidence of failure  Results of a subsequent research found out that carbon content plays a major role in this along with final solution heat treatment and not the grain size.  A new designation was introduced which incorporated specific heat treatments and control of carbon. 21
  • 22. Importance  High temperature steels are specially alloyed steels and are designed for  High strength  Impact toughness  Wear resistance The main categories of this steels are  High-speed steels(HSS)  Hot-work steels 22
  • 23. High speed steels  It was first developed in the early 1900s, and are the most highly alloyed steels which can maintain their hardness and strength at elevated operating temperatures  There are two basic types of high-speed steels  Molybdenum type  Tungsten type 23
  • 24. Hot-work steels  These are designated for use at elevated temperatures and have high toughness and high resistance to wear and cracking.  The alloying elements are generally tungsten ,molybdenum , chromium and vanadium 24
  • 26. 26 Valves used in combustion chamber
  • 27. References  http://www.msm.cam.ac.uk/phase- trans/2003/Superalloys/superalloys.html.  http://www.patentstorm.us/patents/5366 695.html  Manufacturing process for engineering materials by Kalpakjian  Material science and Engg by William callister 27
  • 28. 28