2. Martensitic stainless steel
High hardenable steels ductile in nature ductility
is subjected to the maximum hardness w.r.t
tempering
Cr=15-25%
Hardness of the stainless steel depend on carbon
content
Quenching rate is depend on martensite phase
formed
Development of martensite phase is assisted with
increase in corrosion
3. series alloys
400 series alloys, including 410, 420 and 440 are
martensitic stainless steel alloys.
4. MARTENSITE
Martensite refers to a very hard form of steel
by diffusion less transformation.
It includes a class of hard minerals occurring as
lath- or plate-shaped crystal grains.
needle-shaped
5. Formation of martensite
Martensite is formed in carbon steels by the rapid
cooling (quenching) of austenite at such a high
rate that carbon atoms do not have time to diffuse
out of the crystal structure in large enough
quantities to form cementite (Fe3C)
As a result, the face centered cubic austenite
transforms to a highly strained body centered
cubic form of ferrite that is supersaturated with
carbon.
6. Hardness
The highest hardness of a pearlitic steel is
400 Brinell whereas martensite can achieve
700 Brinell
7. Condition to form martensite
The martensitic reaction begins during cooling
when the austenite reaches the martensite start
temperature (Ms) and the parent austenite
becomes mechanically unstable. As the sample is
quenched, an increasingly large percentage of
the austenite transforms to martensite until the
lower transformation temperature Mf is reached,
at which time the transformation is completed
8.
9. Retained austenite
For a eutectoid steel, between 6 and 10% of
austenite, called retained austenite, will remain.
The percentage of retained austenite increases
from insignificant for less than 0.6% C to 13%
retained austenite at 0.95% C and 30–47% for a
1.4% carbon steels
11. Properties
Martensitic alloys contain lower amounts of
chromium (between 12-14%) and are less
corrosion resistant than austenitic and ferritic
alloys. Their properties include:
Extreme strength and toughness
Can be work-hardened
High machinability and workability to tight
tolerances
Smooth surface finish
12. APPLICATIONS
A sample of the products that are manufactured using
stainless steel includes:
Pots, pans, flatware and utensils
Kitchen and restaurant equipment
Sinks and drains
Fittings, clamps and connectors for sanitary and
processing applications
Tanks, tubing, piping for sanitary, foodservice
chemical and petrochemical processing
Automotive components
Enclosures, housings and cabinets
Springs