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The International Journal Of Engineering And Science (IJES)
|| Volume || 5 || Issue || 6 || Pages || PP -40-45 || 2016 ||
ISSN (e): 2319 – 1813 ISSN (p): 2319 – 1805
www.theijes.com The IJES Page 40
Experimental Study on Corrosion of Wire Rope Strands under
Sulfuric Acid Attack
M.Meknassi1
, A. Tijani1, 2
, N.Mouhib1
, M. El Ghorba1
1
Laboratory Of Control And Mechanical Characterization Of Materials And Structures, National Higher School
Of Electricity And Mechanics, Bp 8118 Oasis, Hassan Ii University, Casablanca, Morocco
2
Laboratory Of Physics Of The Atmosphere And Modeling, Fst Mohammedia, Bp 146 - Mohammedia
--------------------------------------------------------ABSTRACT-----------------------------------------------------------
A corrosive medium is typically found in the working environment of a wire rope. The wire rope structure has
certain characteristics such as complex details, high working stress, and extremely difficult control. Thus,
corrosion is the key problem related to the use of wire ropes.
The corrosion behaviors of strands extracted from wire rope of type 19x7 in acid medium was investigated in
this paper. The results obtained from tensile tests on virgin and corroded specimens show a decrease in strength
as function of immersion hours. This progressive decrease of strength allowed us to quantify the damage.
Thereafter, and with the establishment of the Damage-Reliability relationship, three stages of damage are
distinguished and the value of the critical life fraction is identified (βC = 0.62).
Keywords: Wire rope, strand, corrosion, damage, reliability.
-------------------------------------------------------------------------------------------------------------------------------------
Date of Submission: 25 March 2016 Date of Accepted: 17 June 2016
--------------------------------------------------------------------------------------------------------------------------------------
I. INTRODUCTION
Wire ropes combine two very useful properties: high axial strength and flexibility in bending. These properties
convert wire ropes into indispensable load transmission elements for many industrial applications [1]. Wire
ropes are frequently used for load transmission.
The wire ropes are widely used in harbours, on ships and in many industrial fields. The safety of a wire rope is
closely related to the life safety and equipment safety [2]. The quality and wearing degree of ropes significantly
influences safety and reliability of mining hoists, cranes, elevators and air transportation.
Wire rope consists of three parts: wires, strands, and core. In the manufacture of rope, a predetermined number
of wires are laid together to form a strand. Then a specific number of strands are laid together around a core to
form the wire rope (Fig.1). A wire rope is able to carry loads in the longitudinal direction while being flexible in
the lateral direction. Steel wires that have been drawn from steel with high percentage of carbon and a fine
pearlitic microstructure are preferred for wire ropes [3]. Lubricants are added inside the wire rope structure.
Fig.1 Basic components of a typical wire rope
The humid and oxygen-rich working environment of the wire ropes can cause corrosion. Corrosion reduces the
cross section area of steel wire ropes as well as their flexibility and mechanical properties. Data shows that
corrosion may cause the wire rope to lose more than 30% of its strength and even 50% in some cases. Besides,
steel wire ropes become loose after intensive corrosion. This can be explained by the accelerating wear between
steel strands by abrasion after rust has entered the wire rope core. As well, the condition of the oil will also be
damaged when aggressive water enters the core, which weakens the lubrication and increases wear between the
internal strand wires [4].
Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack
www.theijes.com The IJES Page 41
The proposed study consists to make an experimental procedure of corrosion degradation of strands extracted
from wire rope of type 19x7 under sulfuric acid attack, in order to predict the damage by corrosion of strands,
based up on experimental tensile tests, and subsequently determine the critical life fraction βc.
II. MATERIALS
The tested specimens are strands extracted from wire rope of type 19x7 and anti gyratory structure (1x7 + 6x7 +
12x7) 8 mm in diameter, composed of steel light greased, metal core, right cross, preformed, used especially in
tower cranes and suspension bridges (Fig.2).
They are composed of two layers of strands wired in opposite directions, which avoids the rotation of the
suspended load when the lift height is important and that the burden is not guided. Their use requires a certain
amount of caution at rest and during operation. This construction, robust nature, is widely used for common
applications and especially for lifting heights reduced.
Fig. 2 Cross section of a 19*7 ―antigiratoire‖ wire rope
The characteristics of this cable are shown in Table 1, the Ultimate Load is 41,14KN (Table 1).
Table 1 Mechanical properties of the material
Cable diameter (mm) 8mm
Design 19*7 (1 * 7 + 6 * 7 + 12 *7)
Construction du toron 6/1
Young modulus of the wire (MPa) 200 Gpa
Surface quality of the wires Galvanized steel
Twisting direction Right
Type de l’âme RHR
Mass per unit length (kg/m) 0,272 kg/m
Lubrification A2/W-3
Minimum breaking strength 41,14KN
Poisson’s ratio ν = 0,3
The studied strands are composed of 7 individual wires; a core wire and six peripheral wires disposed helically
around the core wire.
The minimum length of the specimens is equal to the length of the test 200 mm plus the necessary for the
mooring. Therefore, a length of 300 mm is anticipated as the length of the test for the strands. The measurements
tolerance in the length is ± a millimeter for all samples [5]. Dimensions of the strand are shown in Fig.3.
Fig. 3 Dimensions of the studied strand
The chemical composition is obtained by spectrometric analysis using an advanced spark spectrometers for
precise analysis of metals (Fig.4).
Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack
www.theijes.com The IJES Page 42
Fig. 4 Advanced spark spectrometers
The apparatus used for mechanical characterization tests is a traction machine "Zwick Roell" of a 10 KN load
cell (Fig.5).
Fig.5 Zwick Roell testing machine (10 KN)
III. METHODS
The strands were cut at a length of 300 mm. The areas of 100 mm length were defined in the middle of the
specimen (Fig.6), and then they were immersed in 30% H2SO4 solution at room temperature (Fig.7) [6].
Fig.6 strand prepared for immersion
Fig. 7 Schema of accelerated corrosion testing
IV. RESULTS AND DISCUSSION
IV.1 Chemical characterization
The chemical composition of the steel wire is given in Tables 2.
Table 2: The Chemical composition of the material
Composition C Si Mn S P
Percentage 1,478 2,04 3 0,144 0,091
IV.2 Static tensile test on virgin and corroded strands
The curves of the applied force in function of the elongation of the virgin and corroded strands are given in
Fig.8.
The mechanical tensile tests show only a little decline in the breaking force after 8 hours of immersion; this
Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack
www.theijes.com The IJES Page 43
decline increases with the time of immersion.
Fig.8 Comparison of tensile curves of corroded strands
The values of residual ultimate strength reported in Table 3
Immersion time (H) 0 8 16 24 32
Residual ultimate force (N) 2558 2400 2122 1666 1272
IV.3 Calculation of static damage
The model of static damage (D) aims to determine the loss of force whose variations are mainly due to damage.
Then we quantify the damage by the variable D expressed as [7]:
Fu
Fa
Fu
Fur
D



1
1
(2)
Where Fu is the value of the maximum ultimate strength, Fur is the value of the ultimate strength and Fa is the
force just before the break.
During the course of the test, we are following the phenomenon of damage from the virgin to the degraded state
of the specimen by measuring the ultimate residual force in function of the life fraction β.
In our case, β is given by the following equation:
t f
t i
 (3)
Where β is the life fraction, ti is the initial time of corrosion; tf is the time of strands in the final state.
The variation of the static damage according to the life fraction is illustrated by the curve with the following
conditions (Fig.9):
β = 0→ Fur = Fu → D = 0
β = 1 → Fur = Fa → D = 1
Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack
www.theijes.com The IJES Page 44
Fig.9 Static damage due to corrosion of strands according to the life fraction
The increase of the damage means the loss in resistance of static tensile strength; this loss evolves as the time
becomes more important.
IV.4 Relationship Damage –Reliability
When a system is in operation under static solicitations, its physical properties undergo a progressive
degradation, so we often need to reduce the probability of sudden failure.
The reliability theory permits to evaluate the probability of failure and considers the uncertainties associated
with different variables.
Reliability varies inversely to the damage [8]. Intuitively, there must be a relationship between these two
parameters. This allows us to write:
1)()(   DR (4)
Fig.10 Superposition of static curves Damage –Reliability
The Increasing damage is necessarily accompanied by the decrease of the reliability (Fig. 10). At the beginning,
we have the damage initiation area (stage I), then specimens start to lose their internal resistance, it is the
progressive damage zone (stage II) which requires maintenance. Starting from 80% of the damage (20%
reliability) the specimens under tension are in the brutal damage zone.
The advantage of determining the relationship between the damage and the reliability is that it allows, in
particular, to know the values of life fractions when the damage becomes progressive and critical which
corresponds in this case to βc = 0.62.
V. CONCLUSION
In this study, an experimental protocol was developed to study the effects of corrosion on the mechanical
properties of strands extracted from steel wire rope of type 19x7 with anti gyratory structure. Tensile tests are
Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack
www.theijes.com The IJES Page 45
performed on virgin and on corroded strands after 8h, 16h, 24h and 32h of immersion. The acid medium change
the strands mechanical characterization and the tensile mechanical test showed a decrease in tensile strength after
only 8 hours of immersion. The establishment of the relationship Damage-Reliability allowed identifying the
three stages of damage due to corrosion: Stage I that corresponds to the initiation of an elastic damage, Stage II
that corresponds to progressive damage and Stage III that represents the brutal damage. At the same time, the
value of critical life fraction is determined (βC = 0.62) which permits us to predict the instant of critical damage
and thus to intervene at the appropriate moment.
REFERENCES
[1]. Argatov II, Gomez X, Tato W, Urchegui MA,Wear evolution in a stranded rope under cyclic bending: Implications to fatigue life
estimation,Wear, 2011;271:2857–67.
[2]. K. Feyrer, Wire Ropes—Tension ,Endurance, Reliability: Springer-Verlag,Ger- many,2007.H.H.
[3]. Jianxin CJC, Wei GWG. Study and development on detecting device of wire rope localized fault. In: Proceedings of the 4th
World Congress on Intelligent Control and Automation Cat No02EX527, 2002. p. 1
[4]. W. Songquan, Z .Dekun, W. Dagang, Z. Zefeng, Electrochemical corrosion behavior of steel wires in a coalmine with a
corrosive, Mining Science and Technology (China), 21 (2011) 71e76.
[5]. A. Meksem, Probabilistic approach and experimental characterization of the behavior of wire rope hoist, Ph.D. Thesis,
ENSEM, University Hassan 2, Ain Chock, Casablanca, 2010.
[6]. M.Meknassi, N.Mouhib, A.Tijani, M. El Ghorba, Experimental study of wires extracted from steel wire rope and exposed to
sulfuric acid, IPASJ International Journal of Mechanical Engineering (IIJME), Volume 3, Issue 4, April 2015, ISSN 2321-
6441.
[7]. N.Mouhib, H.Ouaomar, M.Lahlou, A.Ennaji, M. El Ghorba, Tensile test of a strand with 2 broken wires artificially damaged
and life prediction,The International Journal Of Engineering And Science (IJES), Vol.4, Issue .4 ,Pages ,PP.11-16, 2015 .ISSN
(e): 2319 – 1813 ISSN (p): 2319 – 1805.
[8]. A. Chouairi, M. El Ghorba, A. Benali, A. Hachim K. El Had and M. Boudlal, Maintenance scheduling and reliability estimation
of structural lifting cables using the theory of accelerated tests Approach based on reliability block diagrams, International
Journal of Innovation in Science and Mathematics (IJISM), Vol.2, Issue.1, January 2014, ISSN: 2347-9051, Pages: 4-10,
United Kingdom.

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Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack

  • 1. The International Journal Of Engineering And Science (IJES) || Volume || 5 || Issue || 6 || Pages || PP -40-45 || 2016 || ISSN (e): 2319 – 1813 ISSN (p): 2319 – 1805 www.theijes.com The IJES Page 40 Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack M.Meknassi1 , A. Tijani1, 2 , N.Mouhib1 , M. El Ghorba1 1 Laboratory Of Control And Mechanical Characterization Of Materials And Structures, National Higher School Of Electricity And Mechanics, Bp 8118 Oasis, Hassan Ii University, Casablanca, Morocco 2 Laboratory Of Physics Of The Atmosphere And Modeling, Fst Mohammedia, Bp 146 - Mohammedia --------------------------------------------------------ABSTRACT----------------------------------------------------------- A corrosive medium is typically found in the working environment of a wire rope. The wire rope structure has certain characteristics such as complex details, high working stress, and extremely difficult control. Thus, corrosion is the key problem related to the use of wire ropes. The corrosion behaviors of strands extracted from wire rope of type 19x7 in acid medium was investigated in this paper. The results obtained from tensile tests on virgin and corroded specimens show a decrease in strength as function of immersion hours. This progressive decrease of strength allowed us to quantify the damage. Thereafter, and with the establishment of the Damage-Reliability relationship, three stages of damage are distinguished and the value of the critical life fraction is identified (βC = 0.62). Keywords: Wire rope, strand, corrosion, damage, reliability. ------------------------------------------------------------------------------------------------------------------------------------- Date of Submission: 25 March 2016 Date of Accepted: 17 June 2016 -------------------------------------------------------------------------------------------------------------------------------------- I. INTRODUCTION Wire ropes combine two very useful properties: high axial strength and flexibility in bending. These properties convert wire ropes into indispensable load transmission elements for many industrial applications [1]. Wire ropes are frequently used for load transmission. The wire ropes are widely used in harbours, on ships and in many industrial fields. The safety of a wire rope is closely related to the life safety and equipment safety [2]. The quality and wearing degree of ropes significantly influences safety and reliability of mining hoists, cranes, elevators and air transportation. Wire rope consists of three parts: wires, strands, and core. In the manufacture of rope, a predetermined number of wires are laid together to form a strand. Then a specific number of strands are laid together around a core to form the wire rope (Fig.1). A wire rope is able to carry loads in the longitudinal direction while being flexible in the lateral direction. Steel wires that have been drawn from steel with high percentage of carbon and a fine pearlitic microstructure are preferred for wire ropes [3]. Lubricants are added inside the wire rope structure. Fig.1 Basic components of a typical wire rope The humid and oxygen-rich working environment of the wire ropes can cause corrosion. Corrosion reduces the cross section area of steel wire ropes as well as their flexibility and mechanical properties. Data shows that corrosion may cause the wire rope to lose more than 30% of its strength and even 50% in some cases. Besides, steel wire ropes become loose after intensive corrosion. This can be explained by the accelerating wear between steel strands by abrasion after rust has entered the wire rope core. As well, the condition of the oil will also be damaged when aggressive water enters the core, which weakens the lubrication and increases wear between the internal strand wires [4].
  • 2. Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack www.theijes.com The IJES Page 41 The proposed study consists to make an experimental procedure of corrosion degradation of strands extracted from wire rope of type 19x7 under sulfuric acid attack, in order to predict the damage by corrosion of strands, based up on experimental tensile tests, and subsequently determine the critical life fraction βc. II. MATERIALS The tested specimens are strands extracted from wire rope of type 19x7 and anti gyratory structure (1x7 + 6x7 + 12x7) 8 mm in diameter, composed of steel light greased, metal core, right cross, preformed, used especially in tower cranes and suspension bridges (Fig.2). They are composed of two layers of strands wired in opposite directions, which avoids the rotation of the suspended load when the lift height is important and that the burden is not guided. Their use requires a certain amount of caution at rest and during operation. This construction, robust nature, is widely used for common applications and especially for lifting heights reduced. Fig. 2 Cross section of a 19*7 ―antigiratoire‖ wire rope The characteristics of this cable are shown in Table 1, the Ultimate Load is 41,14KN (Table 1). Table 1 Mechanical properties of the material Cable diameter (mm) 8mm Design 19*7 (1 * 7 + 6 * 7 + 12 *7) Construction du toron 6/1 Young modulus of the wire (MPa) 200 Gpa Surface quality of the wires Galvanized steel Twisting direction Right Type de l’âme RHR Mass per unit length (kg/m) 0,272 kg/m Lubrification A2/W-3 Minimum breaking strength 41,14KN Poisson’s ratio ν = 0,3 The studied strands are composed of 7 individual wires; a core wire and six peripheral wires disposed helically around the core wire. The minimum length of the specimens is equal to the length of the test 200 mm plus the necessary for the mooring. Therefore, a length of 300 mm is anticipated as the length of the test for the strands. The measurements tolerance in the length is ± a millimeter for all samples [5]. Dimensions of the strand are shown in Fig.3. Fig. 3 Dimensions of the studied strand The chemical composition is obtained by spectrometric analysis using an advanced spark spectrometers for precise analysis of metals (Fig.4).
  • 3. Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack www.theijes.com The IJES Page 42 Fig. 4 Advanced spark spectrometers The apparatus used for mechanical characterization tests is a traction machine "Zwick Roell" of a 10 KN load cell (Fig.5). Fig.5 Zwick Roell testing machine (10 KN) III. METHODS The strands were cut at a length of 300 mm. The areas of 100 mm length were defined in the middle of the specimen (Fig.6), and then they were immersed in 30% H2SO4 solution at room temperature (Fig.7) [6]. Fig.6 strand prepared for immersion Fig. 7 Schema of accelerated corrosion testing IV. RESULTS AND DISCUSSION IV.1 Chemical characterization The chemical composition of the steel wire is given in Tables 2. Table 2: The Chemical composition of the material Composition C Si Mn S P Percentage 1,478 2,04 3 0,144 0,091 IV.2 Static tensile test on virgin and corroded strands The curves of the applied force in function of the elongation of the virgin and corroded strands are given in Fig.8. The mechanical tensile tests show only a little decline in the breaking force after 8 hours of immersion; this
  • 4. Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack www.theijes.com The IJES Page 43 decline increases with the time of immersion. Fig.8 Comparison of tensile curves of corroded strands The values of residual ultimate strength reported in Table 3 Immersion time (H) 0 8 16 24 32 Residual ultimate force (N) 2558 2400 2122 1666 1272 IV.3 Calculation of static damage The model of static damage (D) aims to determine the loss of force whose variations are mainly due to damage. Then we quantify the damage by the variable D expressed as [7]: Fu Fa Fu Fur D    1 1 (2) Where Fu is the value of the maximum ultimate strength, Fur is the value of the ultimate strength and Fa is the force just before the break. During the course of the test, we are following the phenomenon of damage from the virgin to the degraded state of the specimen by measuring the ultimate residual force in function of the life fraction β. In our case, β is given by the following equation: t f t i  (3) Where β is the life fraction, ti is the initial time of corrosion; tf is the time of strands in the final state. The variation of the static damage according to the life fraction is illustrated by the curve with the following conditions (Fig.9): β = 0→ Fur = Fu → D = 0 β = 1 → Fur = Fa → D = 1
  • 5. Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack www.theijes.com The IJES Page 44 Fig.9 Static damage due to corrosion of strands according to the life fraction The increase of the damage means the loss in resistance of static tensile strength; this loss evolves as the time becomes more important. IV.4 Relationship Damage –Reliability When a system is in operation under static solicitations, its physical properties undergo a progressive degradation, so we often need to reduce the probability of sudden failure. The reliability theory permits to evaluate the probability of failure and considers the uncertainties associated with different variables. Reliability varies inversely to the damage [8]. Intuitively, there must be a relationship between these two parameters. This allows us to write: 1)()(   DR (4) Fig.10 Superposition of static curves Damage –Reliability The Increasing damage is necessarily accompanied by the decrease of the reliability (Fig. 10). At the beginning, we have the damage initiation area (stage I), then specimens start to lose their internal resistance, it is the progressive damage zone (stage II) which requires maintenance. Starting from 80% of the damage (20% reliability) the specimens under tension are in the brutal damage zone. The advantage of determining the relationship between the damage and the reliability is that it allows, in particular, to know the values of life fractions when the damage becomes progressive and critical which corresponds in this case to βc = 0.62. V. CONCLUSION In this study, an experimental protocol was developed to study the effects of corrosion on the mechanical properties of strands extracted from steel wire rope of type 19x7 with anti gyratory structure. Tensile tests are
  • 6. Experimental Study on Corrosion of Wire Rope Strands under Sulfuric Acid Attack www.theijes.com The IJES Page 45 performed on virgin and on corroded strands after 8h, 16h, 24h and 32h of immersion. The acid medium change the strands mechanical characterization and the tensile mechanical test showed a decrease in tensile strength after only 8 hours of immersion. The establishment of the relationship Damage-Reliability allowed identifying the three stages of damage due to corrosion: Stage I that corresponds to the initiation of an elastic damage, Stage II that corresponds to progressive damage and Stage III that represents the brutal damage. At the same time, the value of critical life fraction is determined (βC = 0.62) which permits us to predict the instant of critical damage and thus to intervene at the appropriate moment. REFERENCES [1]. Argatov II, Gomez X, Tato W, Urchegui MA,Wear evolution in a stranded rope under cyclic bending: Implications to fatigue life estimation,Wear, 2011;271:2857–67. [2]. K. Feyrer, Wire Ropes—Tension ,Endurance, Reliability: Springer-Verlag,Ger- many,2007.H.H. [3]. Jianxin CJC, Wei GWG. Study and development on detecting device of wire rope localized fault. In: Proceedings of the 4th World Congress on Intelligent Control and Automation Cat No02EX527, 2002. p. 1 [4]. W. Songquan, Z .Dekun, W. Dagang, Z. Zefeng, Electrochemical corrosion behavior of steel wires in a coalmine with a corrosive, Mining Science and Technology (China), 21 (2011) 71e76. [5]. A. Meksem, Probabilistic approach and experimental characterization of the behavior of wire rope hoist, Ph.D. Thesis, ENSEM, University Hassan 2, Ain Chock, Casablanca, 2010. [6]. M.Meknassi, N.Mouhib, A.Tijani, M. El Ghorba, Experimental study of wires extracted from steel wire rope and exposed to sulfuric acid, IPASJ International Journal of Mechanical Engineering (IIJME), Volume 3, Issue 4, April 2015, ISSN 2321- 6441. [7]. N.Mouhib, H.Ouaomar, M.Lahlou, A.Ennaji, M. El Ghorba, Tensile test of a strand with 2 broken wires artificially damaged and life prediction,The International Journal Of Engineering And Science (IJES), Vol.4, Issue .4 ,Pages ,PP.11-16, 2015 .ISSN (e): 2319 – 1813 ISSN (p): 2319 – 1805. [8]. A. Chouairi, M. El Ghorba, A. Benali, A. Hachim K. El Had and M. Boudlal, Maintenance scheduling and reliability estimation of structural lifting cables using the theory of accelerated tests Approach based on reliability block diagrams, International Journal of Innovation in Science and Mathematics (IJISM), Vol.2, Issue.1, January 2014, ISSN: 2347-9051, Pages: 4-10, United Kingdom.