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Dr. Tianyu LIU
Prof. Yat Li Laboratory
Department of Chemistry and Biochemistry
University of California, Santa Cruz
Dec. 2nd, 2019
EN07.01.07
Zipping Up Ni-Fe Hydroxide-
Coated Hematite Nanowires
Outline
p Background & Motivation
p Hematite Photoanode
Ø Structure Design
Ø Characterizations
p Photoelectrochemical Performances
p Summary
Outline
p Background & Motivation
p Hematite Photoanode
Ø Structure Design
Ø Characterizations
p Photoelectrochemical Performances
p Summary
Photoelectrochemical Cells
Electrode/Catalyst Interface
Outline
p Background & Motivation
p Hematite Photoanode
Ø Structure Design
Ø Characterizations
p Photoelectrochemical Performances
p Summary
The Design
Ni-Fe Hydroxide
Hematite
OER Catalyst
Photoanode
Sodium Citrate
“Zipper”
ACS Energy Lett. 2019, 4, 1983-1990
The Design
ACS Energy Lett. 2019, 4, 1983-1990
Synthesis
ACS Energy Lett. 2019, 4, 1983-1990
Morphology
p Hematite nanowire arrays
p Conformal, void-free NiFe(OH)x
coating
ACS Energy Lett. 2019, 4, 1983-1990
Elemental Distribution
ACS Energy Lett. 2019, 4, 1983-1990
Fe Ni
X-Ray Photoelectron Spectroscopy
ACS Energy Lett. 2019, 4, 1983-1990
p Blue shifts of Ni 2p and Fe 2p peaks – sodium citrate coordinates hematite and NiFe(OH)x
Outline
p Background & Motivation
p Hematite Photoanode
Ø Structure Design
Ø Characterizations
p Photoelectrochemical Performances
p Summary
OER Turn-On Potential
ACS Energy Lett. 2019, 4, 1983-1990
first-order
derivative
0.53V vs. RHE
p Linear scan voltammograms
Adv. Funct. Mater. 2010, 20, 1099-1107
Charge Transfer Efficiency
!"#$%&'(# =
*+,-
*+,-.-/,/
Photo-current without hole scavengers
Photo-current with hole scavengers
[min. recombination]
ACS Energy Lett. 2019, 4, 1983-1990
* Added 0.5 M H2O2 (hole scavenger)
Stability Performance
ACS Energy Lett. 2019, 4, 1983-1990
p Constant-potential stability p H2 and O2 evolution
1.23V vs. RHE Pt counter electrode
Outline
p Background & Motivation
p Hematite Photoanode
Ø Structure Design
Ø Characterizations
p Photoelectrochemical Performances
p Summary
Summary
Zipped-Up Interface
Acknowledgements
Dr. Mingyang Li
Sun Yat-sen University, China
Prof. Yexiang TongProf. Yat Li
Dr. Yi Yang (UCSC), Weitao Qiu (SYU), and Dr. Chaolun Liang (SYU)
Co-authors
Funding
• Merced nAnomaterials Center for Energy and Sensing (MACES), NNX15AQ01
• National Key Research and Development Program of China, 2016YFA0202604
• Natural Science Foundation of China (21773315)
• The Fundamental Research Funds for the Central Universities (2015KCXTD029)
• Guangdong Provincial Key Platform and Major Scientific Research Projects for Colleges and
Universities (2018A030310300)
Credit: Joel M. Serrano, Virginia Tech
Bird-Eating Cyclic Voltammogram
Electrochemistry is fun!

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Zipping Up Ni-Fe Hydroxide-Coated Hematite Nanowires

  • 1. Dr. Tianyu LIU Prof. Yat Li Laboratory Department of Chemistry and Biochemistry University of California, Santa Cruz Dec. 2nd, 2019 EN07.01.07 Zipping Up Ni-Fe Hydroxide- Coated Hematite Nanowires
  • 2. Outline p Background & Motivation p Hematite Photoanode Ø Structure Design Ø Characterizations p Photoelectrochemical Performances p Summary
  • 3. Outline p Background & Motivation p Hematite Photoanode Ø Structure Design Ø Characterizations p Photoelectrochemical Performances p Summary
  • 6. Outline p Background & Motivation p Hematite Photoanode Ø Structure Design Ø Characterizations p Photoelectrochemical Performances p Summary
  • 7. The Design Ni-Fe Hydroxide Hematite OER Catalyst Photoanode Sodium Citrate “Zipper” ACS Energy Lett. 2019, 4, 1983-1990
  • 8. The Design ACS Energy Lett. 2019, 4, 1983-1990
  • 9. Synthesis ACS Energy Lett. 2019, 4, 1983-1990
  • 10. Morphology p Hematite nanowire arrays p Conformal, void-free NiFe(OH)x coating ACS Energy Lett. 2019, 4, 1983-1990
  • 11. Elemental Distribution ACS Energy Lett. 2019, 4, 1983-1990 Fe Ni
  • 12. X-Ray Photoelectron Spectroscopy ACS Energy Lett. 2019, 4, 1983-1990 p Blue shifts of Ni 2p and Fe 2p peaks – sodium citrate coordinates hematite and NiFe(OH)x
  • 13. Outline p Background & Motivation p Hematite Photoanode Ø Structure Design Ø Characterizations p Photoelectrochemical Performances p Summary
  • 14. OER Turn-On Potential ACS Energy Lett. 2019, 4, 1983-1990 first-order derivative 0.53V vs. RHE p Linear scan voltammograms Adv. Funct. Mater. 2010, 20, 1099-1107
  • 15. Charge Transfer Efficiency !"#$%&'(# = *+,- *+,-.-/,/ Photo-current without hole scavengers Photo-current with hole scavengers [min. recombination] ACS Energy Lett. 2019, 4, 1983-1990 * Added 0.5 M H2O2 (hole scavenger)
  • 16. Stability Performance ACS Energy Lett. 2019, 4, 1983-1990 p Constant-potential stability p H2 and O2 evolution 1.23V vs. RHE Pt counter electrode
  • 17. Outline p Background & Motivation p Hematite Photoanode Ø Structure Design Ø Characterizations p Photoelectrochemical Performances p Summary
  • 19. Acknowledgements Dr. Mingyang Li Sun Yat-sen University, China Prof. Yexiang TongProf. Yat Li Dr. Yi Yang (UCSC), Weitao Qiu (SYU), and Dr. Chaolun Liang (SYU) Co-authors Funding • Merced nAnomaterials Center for Energy and Sensing (MACES), NNX15AQ01 • National Key Research and Development Program of China, 2016YFA0202604 • Natural Science Foundation of China (21773315) • The Fundamental Research Funds for the Central Universities (2015KCXTD029) • Guangdong Provincial Key Platform and Major Scientific Research Projects for Colleges and Universities (2018A030310300)
  • 20. Credit: Joel M. Serrano, Virginia Tech Bird-Eating Cyclic Voltammogram Electrochemistry is fun!