The posterior triangle of the neck contains important structures such as the external jugular vein and branches of the cervical plexus. It is bounded by the sternocleidomastoid muscle anteriorly and the trapezius muscle posteriorly. The posterior triangle is further divided into the occipital triangle superiorly and the subclavian triangle inferiorly by the omohyoid muscle. Key contents include nerves like the spinal accessory nerve, lymph nodes such as the supraclavicular nodes, and the brachial plexus trunks in the subclavian triangle.