The atom is a fundamental unit of matter, comprising a central nucleus of protons and neutrons, surrounded by negatively charged electrons bound by electromagnetic force. The Bohr model describes electrons orbiting the nucleus in defined paths, helping to introduce the concept of atomic structure, despite being considered an obsolete theory. Atomic orbitals represent the probabilistic locations of electrons and are defined by quantum numbers, with different categories such as s, p, d, and f orbitals indicating varying angular momentum.