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Terpenes and Terpenoids
Presented by :
Jitu Kumar Agarwal
What are Terpenes?
Terpenes are strong smelling natural
compounds which are produced by a
variety of plants specially conifers.
Occurence
• They originate from Terpentine , which flows
on cutting or curving the bark and new wood
of several pine tree species.
General Definition of Terpene
• Any naturally occuring compounds built up of
isporene subunits are called terpenes.
Isoprene
Terpenoids
Substiuted
Terpenes
are called
as
terpenoids.
Isoprene Rule And Special Isoprene
Rule
• These rules states that:
• The molecules of all terpenes are constituted
of two or more isoprene units.
• In Natural terpenoids isoprene units were
linked head to tail arrangement, head being
the branched end.
Head to tail arrangement
Classification
of Terpenes
• Hemiterpenes consist of a single isoprene
unit.
• Monoterpenes consist of two isoprene units
• Sesquiterpenes consist of three isoprene
units
• Diterpenes are composed of four isoprene
units
• Sesterterpenes, terpenes have five
isoprene units
• Triterpenes consist of six isoprene units.
• Sesquarterpenes are composed of seven
isoprene units.
• Tetraterpenes contain eight isoprene units.
• Polyterpenes consist of long chains of many
isoprene units.
Terpenes may be
classified according
to the number of
isoprene units
present in the
molecule.
General Properties
• Colorless except a few
• Pleasantly smelling
• Highly refractive solids or liquids
• Insoluble in water, volatile in steam.
• Optically active, some are reacimic
• Lighter than water
• Boiling point 150-180°C
Citral
Occurs in 70 to 80 % in Lemon Grass oil. It is also
found in oil of Orange, oil of lemon and in
Citronella oil.
Isomers of Citral
Both give same chemical
reactions
Difference is found on the rate of
cyclisation of their corresponding alcohols
Alpha Terpeniol
The End

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TERPENES AND TERPENOIDS EXPLAINED

  • 1. Terpenes and Terpenoids Presented by : Jitu Kumar Agarwal
  • 2. What are Terpenes? Terpenes are strong smelling natural compounds which are produced by a variety of plants specially conifers.
  • 3. Occurence • They originate from Terpentine , which flows on cutting or curving the bark and new wood of several pine tree species.
  • 4. General Definition of Terpene • Any naturally occuring compounds built up of isporene subunits are called terpenes. Isoprene
  • 6. Isoprene Rule And Special Isoprene Rule • These rules states that: • The molecules of all terpenes are constituted of two or more isoprene units. • In Natural terpenoids isoprene units were linked head to tail arrangement, head being the branched end.
  • 7. Head to tail arrangement
  • 8. Classification of Terpenes • Hemiterpenes consist of a single isoprene unit. • Monoterpenes consist of two isoprene units • Sesquiterpenes consist of three isoprene units • Diterpenes are composed of four isoprene units • Sesterterpenes, terpenes have five isoprene units • Triterpenes consist of six isoprene units. • Sesquarterpenes are composed of seven isoprene units. • Tetraterpenes contain eight isoprene units. • Polyterpenes consist of long chains of many isoprene units. Terpenes may be classified according to the number of isoprene units present in the molecule.
  • 9. General Properties • Colorless except a few • Pleasantly smelling • Highly refractive solids or liquids • Insoluble in water, volatile in steam. • Optically active, some are reacimic • Lighter than water • Boiling point 150-180°C
  • 10. Citral Occurs in 70 to 80 % in Lemon Grass oil. It is also found in oil of Orange, oil of lemon and in Citronella oil.
  • 11. Isomers of Citral Both give same chemical reactions Difference is found on the rate of cyclisation of their corresponding alcohols