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SUPERCONDUCTING MATERIALS
Superconductivity - The phenomenon of losing resistivity wh
en sufficiently cooled to a very low temperature (below a cer
tain critical temperature).
 H. Kammerlingh Onnes – 1911 – Pure Mercury
Resistance (Ω)
4.0 4.1 4.2 4.3 4.4
Temperature (K)
0.15
0.10
0.0
Tc
SUPERCONDUCTORS
• Superconductivity is a pheno
menon in certain materials at extr
emely low temperatures ,charact
erized by exactly zero electrical re
sistance and exclusion of the inter
ior magnetic field (i.e. the Meissn
er effect)
• This phenomenon is nothing bu
t losing the resistivity absolutely
when cooled to sufficient low tem
peratures
Transition Temperature or Critical Temperature (TC)
Temperature at which a normal conductor lose
s its resistivity and becomes a superconductor.
• Very good electrical conductors not supercond
uctors eg. Cu, Ag, Au
TYPES
1. Low TC superconductors
2. High TC superconductors
Occurrence of Superconductivity
Superconducting Elements TC (K)
Sn (Tin) 3.72
Hg (Mercury) 4.15
Pb (Lead) 7.19
Superconducting Compounds
NbTi (Niobium Titanium) 10
Nb3Sn (Niobium Tin) 18.1
Properties of Superconductors
Electrical Resistance
• Zero Electrical Resi
stance
• Critical Temperatur
e
• Quickest test
• 10-5Ωcm
Effect of Magnetic Field
Critical magnetic field (HC) – Mini
mum magnetic field required t
o destroy the superconducting
property at any temperature
H0 – Critical field at 0K
T - Temperature below TC
TC - Transition Temperature
Superconducting
Normal
T (K) TC
H0
HC
Element HC at 0K
(mT)
Nb 198
Pb 80.3
Sn 30.92
0 1C
C
T
H H
T
  
   
   
Stress
• Stress ↑, dimension ↑, TC ↑, HC affected
Frequency
• Frequency ↑, Zero resistance – modified, TC not
affected
Impurities
• Magnetic properties affected
Size
• Size < 10-4cm – superconducting state modified
GENERAL PROPERTIES
No change in crystal structure
No change in elastic & photo-elect
ric properties
No change in volume at TC in the a
bsence of magnetic field
Types of Superconductors
Type I
• Sudden loss of magnetisation
• Exhibit Meissner Effect
• One HC = 0.1 tesla
• No mixed state
• Soft superconductor
• Eg.s – Pb, Sn, Hg
Type II
• Gradual loss of magnetisation
• Does not exhibit complete Meissn
er Effect
• Two HCs – HC1 & HC2 (≈30 tesla)
• Mixed state present
• Hard superconductor
• Eg.s – Nb-Sn, Nb-Ti
-M
HHC
Superconducting
Normal
Superconducting
-M
Normal
Mixed
HC1 HC
HC2
H
APPLICATIONSOF
SUPER CONDUCT
ORS
Applications
• Large distance power transmission (ρ = 0)
• Switching device (easy destruction of supe
rconductivity)
• Sensitive electrical equipment (small V var
iation  large constant current)
• Memory / Storage element (persistent curr
ent)
• Highly efficient small sized electrical gener
ator and transformer
Medical Applications
•NMR – Nuclear Magnetic Resonance – Sca
nning
•Brain wave activity – brain tumour, defectiv
e cells
•Separate damaged cells and healthy cells
•Superconducting solenoids – magneto hydr
odynamic power generation – plasma maint
enance
Transmission of power
Switching devices
Sensitive electrical instruments
Memory (or) storage element in computers
.
Manufacture of electrical generators and tr
ansformers
 Magnetic levitated trains.
Engineering
Magnetic Levitated Train
Principle: Electro-magnetic induction
Introduction:
Magnetic levitation transport is a form of transport
ation that suspends, guides and propels vehicles via
electromagnetic force. This method can be faster tha
n wheeled mass transit systems, potentially reaching
velocities comparable to turboprop and jet aircraft (5
00 to 580 km/h).
Electrodynamic suspension
In Electrodynamic suspension (EDS), both the rail and the train exer
t a magnetic field, and the train is levitated by the repulsive force bet
ween these magnetic fields. The magnetic field in the train is produc
ed by either electromagnets or by an array of permanent magnets.
The repulsive force in the track is created by an induced magnetic fi
eld in wires or other conducting strips in the track.
At slow speeds, the current induced in these coils and the resultant
magnetic flux is not large enough to support the weight of the train.
For this reason the train must have wheels or some other form of la
nding gear to support the train until it reaches a speed that can sust
ain levitation.
Propulsion coils on the guideway are used to exert a force on the m
agnets in the train and make the train move forwards.
Diagrammatic representation
of magnetic levitate train
Advantages
 No need of initial energy in case of magnets
for low speeds
One litre of Liquid nitrogen costs less than on
e litre of mineral water
These trains can attain very high speeds (500
km/h); no wheels or secondary propulsion syste
m needed
 Free of friction as it is “Levitating”.
Superconducting materials

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Superconducting materials

  • 1. SUPERCONDUCTING MATERIALS Superconductivity - The phenomenon of losing resistivity wh en sufficiently cooled to a very low temperature (below a cer tain critical temperature).  H. Kammerlingh Onnes – 1911 – Pure Mercury Resistance (Ω) 4.0 4.1 4.2 4.3 4.4 Temperature (K) 0.15 0.10 0.0 Tc
  • 2. SUPERCONDUCTORS • Superconductivity is a pheno menon in certain materials at extr emely low temperatures ,charact erized by exactly zero electrical re sistance and exclusion of the inter ior magnetic field (i.e. the Meissn er effect) • This phenomenon is nothing bu t losing the resistivity absolutely when cooled to sufficient low tem peratures
  • 3. Transition Temperature or Critical Temperature (TC) Temperature at which a normal conductor lose s its resistivity and becomes a superconductor. • Very good electrical conductors not supercond uctors eg. Cu, Ag, Au TYPES 1. Low TC superconductors 2. High TC superconductors
  • 4. Occurrence of Superconductivity Superconducting Elements TC (K) Sn (Tin) 3.72 Hg (Mercury) 4.15 Pb (Lead) 7.19 Superconducting Compounds NbTi (Niobium Titanium) 10 Nb3Sn (Niobium Tin) 18.1
  • 5. Properties of Superconductors Electrical Resistance • Zero Electrical Resi stance • Critical Temperatur e • Quickest test • 10-5Ωcm
  • 6. Effect of Magnetic Field Critical magnetic field (HC) – Mini mum magnetic field required t o destroy the superconducting property at any temperature H0 – Critical field at 0K T - Temperature below TC TC - Transition Temperature Superconducting Normal T (K) TC H0 HC Element HC at 0K (mT) Nb 198 Pb 80.3 Sn 30.92 0 1C C T H H T           
  • 7. Stress • Stress ↑, dimension ↑, TC ↑, HC affected Frequency • Frequency ↑, Zero resistance – modified, TC not affected Impurities • Magnetic properties affected Size • Size < 10-4cm – superconducting state modified
  • 8. GENERAL PROPERTIES No change in crystal structure No change in elastic & photo-elect ric properties No change in volume at TC in the a bsence of magnetic field
  • 9. Types of Superconductors Type I • Sudden loss of magnetisation • Exhibit Meissner Effect • One HC = 0.1 tesla • No mixed state • Soft superconductor • Eg.s – Pb, Sn, Hg Type II • Gradual loss of magnetisation • Does not exhibit complete Meissn er Effect • Two HCs – HC1 & HC2 (≈30 tesla) • Mixed state present • Hard superconductor • Eg.s – Nb-Sn, Nb-Ti -M HHC Superconducting Normal Superconducting -M Normal Mixed HC1 HC HC2 H
  • 11. Applications • Large distance power transmission (ρ = 0) • Switching device (easy destruction of supe rconductivity) • Sensitive electrical equipment (small V var iation  large constant current) • Memory / Storage element (persistent curr ent) • Highly efficient small sized electrical gener ator and transformer
  • 12. Medical Applications •NMR – Nuclear Magnetic Resonance – Sca nning •Brain wave activity – brain tumour, defectiv e cells •Separate damaged cells and healthy cells •Superconducting solenoids – magneto hydr odynamic power generation – plasma maint enance
  • 13. Transmission of power Switching devices Sensitive electrical instruments Memory (or) storage element in computers . Manufacture of electrical generators and tr ansformers  Magnetic levitated trains. Engineering
  • 14. Magnetic Levitated Train Principle: Electro-magnetic induction Introduction: Magnetic levitation transport is a form of transport ation that suspends, guides and propels vehicles via electromagnetic force. This method can be faster tha n wheeled mass transit systems, potentially reaching velocities comparable to turboprop and jet aircraft (5 00 to 580 km/h).
  • 15. Electrodynamic suspension In Electrodynamic suspension (EDS), both the rail and the train exer t a magnetic field, and the train is levitated by the repulsive force bet ween these magnetic fields. The magnetic field in the train is produc ed by either electromagnets or by an array of permanent magnets. The repulsive force in the track is created by an induced magnetic fi eld in wires or other conducting strips in the track. At slow speeds, the current induced in these coils and the resultant magnetic flux is not large enough to support the weight of the train. For this reason the train must have wheels or some other form of la nding gear to support the train until it reaches a speed that can sust ain levitation. Propulsion coils on the guideway are used to exert a force on the m agnets in the train and make the train move forwards.
  • 17. Advantages  No need of initial energy in case of magnets for low speeds One litre of Liquid nitrogen costs less than on e litre of mineral water These trains can attain very high speeds (500 km/h); no wheels or secondary propulsion syste m needed  Free of friction as it is “Levitating”.