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Coolant / Heat Transfer Solutions for
Refrigeration / Heating / Renewable Energy
      Greenway, long-term innovation
1. Greenway® Innovation
  Why change ?




                          Today: heat transfer mediums are
                          derived from fossil sources:



                             Propylene glycol (MPG) is used in
                          many applications (renewable energy,
                          heating, refrigeration, air conditioning)

                             Ethylene glycol (MEG) is mainly
                          used in industrial refrigeration



                               © climalife - www.climalife.dehon.com I 06/02/2013   P2
1. Greenway® Innovation
  Why change ?


                          MPG must be approved where there is a risk
                          of contact with food products

                          MPG has high viscosity at low temperatures

                          MEG, cheaper but harmful, cannot meet
                          sanitary obligations
                          Because change has already happened!
                          Change of attitude towards the environment
                          Need for solutions for the renewable energy
                          sector
                          Move from a "system“ approach to a
                          “systemic" approach



                                © climalife - www.climalife.dehon.com I 06/02/2013   P3
1. Greenway® Innovation
       The BIO PDO : a new alternative



Production schematic of BIO PDO



        CO2
                                                 Fermentation & Refining



                                         Refine to 99,7% = Cosmetics Industry needs




                               Glucose                       (Bio-derived 1,3-Propanediol)
   Plants

                                             © climalife - www.climalife.dehon.com I 06/02/2013   P4
1. Greenway® Innovation
  The BIO PDO : a new alternative

  Energy and Environmental Comparison

                                      Greenhouse gas (GHG)
                                      Non-renewable energy




                                                                  Non-renewable energy Bio PDO
                                                                    42 % vs Propanediol (synthetic)
                                                                    38 % vs Propylene glycol

            GHG emission Bio PDO
              56% vs Propanediol (synthetic)
              42 % vs Propylene glycol




  Propanediol 1,3   Propanediol 1,3                       Propanediol 1,3   Propanediol 1,3
                                       Propylene glycol                                        Propylene glycol
       Bio             Synthetic                               Bio             Synthetic



                                                                   © climalife - www.climalife.dehon.com I 06/02/2013   P5
1. Greenway® Innovation
  Follow the new way

                       Our commitment :

                           Offer alternative to solutions produced from
                          fossil resources and currently in use:
                                  - Mono Propylene glycol
                                  - Mono Ethylene glycol

                           Create environmental and long-lasting
                          consistency in industrial and commercial
                          installations

                           Bring you energy savings for refrigeration
                          and air-conditioning applications


                                 © climalife - www.climalife.dehon.com I 06/02/2013   P6
1. Greenway® Innovation
 Follow the new way


            • The Greenway® range consists of three heat transfer fluids
              derived entirely from a renewable resource called BIO 1,3-
              Propanediol (glucose syrup)

            • Its production has an environmental benefit in terms of CO2
              emissions and an energy footprint 40% lower than classic MPG

            • Use Inhibitor pack developed by our R&D lab in order to offer
              long term protection to the system and its materials.

            • In case of an accidental leak, the impact on the environment
              while using Greenway will be much lower than with an MEG



                                        © climalife - www.climalife.dehon.com I 06/02/2013   P7
1. Greenway® Innovation
  Stop Borax : Focus on regulation


                                     The European Decree 2005/58/CE from the 15th
                                     September 2008 puts Borax in the category 2
                                     (toxic substances), and applies to all products
                                     containing at least 8.5% Borax.

           With BORAX !              Borax was put on the Substances of Very High Concern
                                     list by the European Chemicals Agency in June 2010

                                                           Borax is toxic!

                                     Presence of Borax in products has to be
                                     mentioned of the related risks on the packaging:
                                     R 60 : May impair fertility
                                     R 61 : Risks of irrevocable damage to the child during pregnancy
                                     S 45 : In case of accident or discomfort see a doctor immediately
                                     S 53 : Avoid explosion, obtain special instructions before use



                                                © climalife - www.climalife.dehon.com I 06/02/2013   P8
1. Greenway® Innovation
 Stop borax : Climalife is committed with innovating solutions


                                  Stopping the production of all of our heat transfer
                                 fluids that contain Borax
            With BORAX
                                  Anticipating regulatory prohibitions and
                                 protecting the end users

                                  Developing a new pack of long-lasting inhibitors,
                                 free of Borax with keeping the same anti
                                 corrosion properties

                                 inhibitor pack compatible with our MEG & MPG
                                 heat transfer fluids "old-formula"

                                  Offering safer products
                                               © climalife - www.climalife.dehon.com I 06/02/2013   P9
1. Greenway® Innovation
         Long-term organic corrosion inhibitors


Traditional mineral-based inhibitors                                          Traditional or mineral
                                                                              inhibitors protect from
                                                                              corrosion by forming a
                       heat transfer fluid                                    protective layer on the
                                                                              wall of the installation,
                                                                              which can reduce heat
                                                                              transfer
                                    Reduced or
 Protective                         disturbed thermal
 layer                              exchange
                         Metal, pipe wall


  Mineral inhibitors make physical deposits on sensitive areas
  The silicates can form gels impacting on heat exchange

                                                        © climalife - www.climalife.dehon.com I 06/02/2013   P10
1. Greenway® Innovation
          Long-term organic corrosion inhibitors

                                         Inhibiting agents as a solution in the heat
Organic-based inhibitors                 transfer fluid

                           Heat tranfer fluid                                           The organic inhibitors
                                                                                        only absorb on the relevant
Molecular film, extremely small thickness that does                                     corroded surfaces forming
not alter heat exchange                                                                 a protective molecular film,
                                                                                        hence the optimized
                                                                                        thermal transfer
                    Attack corrosion
                                   Optimized thermal exchange

                              Metal, pipe wall


The inhibitor does not react chemically and does not degrade over time
The electronic barrier that is created is the size of a molecule

                                                                  © climalife - www.climalife.dehon.com I 06/02/2013   P11
1. Greenway® Innovation
 Long-term organic corrosion inhibitors

                                       Metals
                                                                   Tap water           GREENWAY® RANGE
                               (load loss in mg/tip)
                                     COPPER                             3                          2
                                       WELD                           100                          3
                                       BRASS                           4,5                         2
                                       STEEL                          700                          2
                                    CAST IRON                         775                          2
                                    ALUMINIUM                         120                          3


                                       Metals
                                                                   Tap water          FRIOGEL® NEO RANGE
                                (load loss in mg/tip)
                                     COPPER                             3                          ±2
                                       WELD                           100                          ±4
                                       BRASS                           4,5                         ±2
                                       STEEL                          700                          ±1
                                    CAST IRON                         775                          ±2
                                    ALUMINIUM                         120                          ±8
                       Performance standards defined by the ASTM D3306 norms for cooling liquids
                       Norm references for trial methods : AFNOR NF R 15-602-7 ou ASTM D 1384



                                                                 © climalife - www.climalife.dehon.com I 06/02/2013   P12
2. Greenway® Range
          A complete alternative of dedicated solutions

Base           Product                   Freezing pointPackaging         Applications
                                                      Drum 20 l
                                                                         Used for comercial and industrial refrigerant
                                             -55      Drum 210 l
                                                                         systems
                                                      IBC 1000 kg
                                                      Drum 20 l
                   Greenway® RTU             -30      Drum 210 l
                                                      IBC 1000 kg        Used for traditional heating and refrigeration
                                                      Drum 20 l          systems
                                             -25      Drum 210 l
    BIO
                                                      IBC 1000 kg
propanediol
                                                      Drum 20 l
               Greenway® HEAT PUMP           -25      Drum 210 l         Used for heat pump systems
                                                      IBC 1000 kg
                                                      Drum 20 l
                                             -30
                                                      Drum 210 l
                  Greenway® SOLAR                     Drum 20 l          Used for thermal solar systems
                                             -25      Drum 210 l
                                                      IBC 1000 kg
Ask us about bulks for these dilutions




                                                                    © climalife - www.climalife.dehon.com I 06/02/2013    P13
2. Greenway® Range
    Packaging to suit your needs

Products:                          Packing Available:

Greenway®
Greenway® Heat Pump                20 L and 210 L Drums / IBC 1000kg
Greenway® Solar




                                         © climalife - www.climalife.dehon.com I 06/02/2013   P14
3. Thermal solar application
             Greenway® Solar advantages



Acid concentration; issue of heat transfer fluid degradation
                                                                  Greater thermal stability

                                                                  an exceptionally low degradation,
                                                                  4 times less than MPG at 150 C
                                                                  Energy savings in operation

                                                                  Savings in maintenance costs (no
                                                                  tarring)

                                                                  A reduced bill on installation and on
                              Hours                               operating
   Degradation of glycol solutions diluted at 50% at 150 C




                                                               © climalife - www.climalife.dehon.com I 06/02/2013   P15
3. Thermal solar application
  Greenway® Solar advantages




                               A longer life

                               Maintained efficiency

                               Better control of corrosion

                                Highly reduced risk of extreme
                               deterioration (tarring)

                                Greenway® Solar, the ideal solution for
                               thermal solar applied systems



                                © climalife - www.climalife.dehon.com I 06/02/2013   P16
4. Heat pump application

                           Issues in geothermal application:
                           Possible leak of coolant from the buried
                           sensor network (natural obstructions, tree
                           roots ...)

                           Results: Pollution of the ground


                           Greenway® Heat Pump advantages

                             Good thermal transfer

                              Reduced effects on the environment in
                           case of a leak

                             Efficient protection against ice and
                             corrosion
                              © climalife - www.climalife.dehon.com I 06/02/2013   P17
5. Refrigeration application
      Greenway® RTU -55 innovation
                                     Characteristics :

                                                                                    Greenway RTU
                                                               Friogel Néo
                                                                                           - 55
V
i
s        MEG
c
                                     Specific heat                   2,9                   3,31
         MPG                         kJ/Kg.K
o
         Greenway®
s
i
t                                    Density
y                                                                  1085                   1085
                                     Kg/m3

c
p                                    Dynamic
s                                                                  10,28                   5,95
                                     viscosity
                                     Pa.s
         Temperature C
                                     Thermal
                                     conductivity                  0,364                  0,296
                                     W/m.K

                                             © climalife - www.climalife.dehon.com I 06/02/2013   P18
5. Refrigeration application
  Greenway® RTU -55 innovation

                                 The advantages of Greenway® RTU - 55:

                                 Greenway® RTU -55 viscosity index is lower
                                 than MPG’s and allows you to:

                                   Reduce pressure losses
                                    Reduce the size of the pumps and of the
                                 pipe work
                                   Energy savings on operation

                                   Savings on the installation procedure

                                   Installing and operating bills reduced




                                      © climalife - www.climalife.dehon.com I 06/02/2013   P19
5. Refrigeration application
  The General Direction of the Health and Safety Department Approval



                                           The Climalife Greenway® BIO PDO
                                           based heat transfer fluids have the
                                           authorization of the French Health
                                           and Safety Department for the
                                           production of sanitary hot water via a
                                           simple exchange

                                           A ‘food safe’ approval for coolants, as
                                          such, does not exist as Heat Transfer
                                          Fluids are not used as food ingredients,
                                          however:
                                           Some have the approval of the French General
                                          Direction of the Health and Safety Department as per
                                          the opinion given by the AFSSA for use in single
                                          exchangers or other approvals depending on the country




                                            © climalife - www.climalife.dehon.com I 06/02/2013   P20
6. Opportunities


                      Long lasting stability properties

                      An ecological opportunity

                      Interesting characteristics at low temperature

                      Low toxicity (not classified)

                      100% made from a renewable source

                      Systems become more eco-friendly

                       Compatibility with existing materials already
                   in use in these applications




                          © climalife - www.climalife.dehon.com I 06/02/2013   P21
7. Life Cycle Analysis

                             Method used to assess a product’s
                         environmental impact over the course of its
                         life cycle.

                         Results from the study comparing the
                         life cycle of Greenway® -30 C and
                         MPG -30 C:

                            Lower impact than MPG -30 C
                         regarding 5 indicators of a total of 7

                            Almost non existent impact on the
                         deterioration of the ozone cover

                            Bio PDO has less effect on climate
                         change


                         © climalife - www.climalife.dehon.com I 06/02/2013   P22
Developing innovative, sustainable solutions
        for climate control systems

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"Greenway" Heat Transfer Fluid (Bio-Propandiol)

  • 1. Coolant / Heat Transfer Solutions for Refrigeration / Heating / Renewable Energy Greenway, long-term innovation
  • 2. 1. Greenway® Innovation Why change ? Today: heat transfer mediums are derived from fossil sources: Propylene glycol (MPG) is used in many applications (renewable energy, heating, refrigeration, air conditioning) Ethylene glycol (MEG) is mainly used in industrial refrigeration © climalife - www.climalife.dehon.com I 06/02/2013 P2
  • 3. 1. Greenway® Innovation Why change ? MPG must be approved where there is a risk of contact with food products MPG has high viscosity at low temperatures MEG, cheaper but harmful, cannot meet sanitary obligations Because change has already happened! Change of attitude towards the environment Need for solutions for the renewable energy sector Move from a "system“ approach to a “systemic" approach © climalife - www.climalife.dehon.com I 06/02/2013 P3
  • 4. 1. Greenway® Innovation The BIO PDO : a new alternative Production schematic of BIO PDO CO2 Fermentation & Refining Refine to 99,7% = Cosmetics Industry needs Glucose (Bio-derived 1,3-Propanediol) Plants © climalife - www.climalife.dehon.com I 06/02/2013 P4
  • 5. 1. Greenway® Innovation The BIO PDO : a new alternative Energy and Environmental Comparison Greenhouse gas (GHG) Non-renewable energy Non-renewable energy Bio PDO 42 % vs Propanediol (synthetic) 38 % vs Propylene glycol GHG emission Bio PDO 56% vs Propanediol (synthetic) 42 % vs Propylene glycol Propanediol 1,3 Propanediol 1,3 Propanediol 1,3 Propanediol 1,3 Propylene glycol Propylene glycol Bio Synthetic Bio Synthetic © climalife - www.climalife.dehon.com I 06/02/2013 P5
  • 6. 1. Greenway® Innovation Follow the new way Our commitment : Offer alternative to solutions produced from fossil resources and currently in use: - Mono Propylene glycol - Mono Ethylene glycol Create environmental and long-lasting consistency in industrial and commercial installations Bring you energy savings for refrigeration and air-conditioning applications © climalife - www.climalife.dehon.com I 06/02/2013 P6
  • 7. 1. Greenway® Innovation Follow the new way • The Greenway® range consists of three heat transfer fluids derived entirely from a renewable resource called BIO 1,3- Propanediol (glucose syrup) • Its production has an environmental benefit in terms of CO2 emissions and an energy footprint 40% lower than classic MPG • Use Inhibitor pack developed by our R&D lab in order to offer long term protection to the system and its materials. • In case of an accidental leak, the impact on the environment while using Greenway will be much lower than with an MEG © climalife - www.climalife.dehon.com I 06/02/2013 P7
  • 8. 1. Greenway® Innovation Stop Borax : Focus on regulation The European Decree 2005/58/CE from the 15th September 2008 puts Borax in the category 2 (toxic substances), and applies to all products containing at least 8.5% Borax. With BORAX ! Borax was put on the Substances of Very High Concern list by the European Chemicals Agency in June 2010 Borax is toxic! Presence of Borax in products has to be mentioned of the related risks on the packaging: R 60 : May impair fertility R 61 : Risks of irrevocable damage to the child during pregnancy S 45 : In case of accident or discomfort see a doctor immediately S 53 : Avoid explosion, obtain special instructions before use © climalife - www.climalife.dehon.com I 06/02/2013 P8
  • 9. 1. Greenway® Innovation Stop borax : Climalife is committed with innovating solutions Stopping the production of all of our heat transfer fluids that contain Borax With BORAX Anticipating regulatory prohibitions and protecting the end users Developing a new pack of long-lasting inhibitors, free of Borax with keeping the same anti corrosion properties inhibitor pack compatible with our MEG & MPG heat transfer fluids "old-formula" Offering safer products © climalife - www.climalife.dehon.com I 06/02/2013 P9
  • 10. 1. Greenway® Innovation Long-term organic corrosion inhibitors Traditional mineral-based inhibitors Traditional or mineral inhibitors protect from corrosion by forming a heat transfer fluid protective layer on the wall of the installation, which can reduce heat transfer Reduced or Protective disturbed thermal layer exchange Metal, pipe wall Mineral inhibitors make physical deposits on sensitive areas The silicates can form gels impacting on heat exchange © climalife - www.climalife.dehon.com I 06/02/2013 P10
  • 11. 1. Greenway® Innovation Long-term organic corrosion inhibitors Inhibiting agents as a solution in the heat Organic-based inhibitors transfer fluid Heat tranfer fluid The organic inhibitors only absorb on the relevant Molecular film, extremely small thickness that does corroded surfaces forming not alter heat exchange a protective molecular film, hence the optimized thermal transfer Attack corrosion Optimized thermal exchange Metal, pipe wall The inhibitor does not react chemically and does not degrade over time The electronic barrier that is created is the size of a molecule © climalife - www.climalife.dehon.com I 06/02/2013 P11
  • 12. 1. Greenway® Innovation Long-term organic corrosion inhibitors Metals Tap water GREENWAY® RANGE (load loss in mg/tip) COPPER 3 2 WELD 100 3 BRASS 4,5 2 STEEL 700 2 CAST IRON 775 2 ALUMINIUM 120 3 Metals Tap water FRIOGEL® NEO RANGE (load loss in mg/tip) COPPER 3 ±2 WELD 100 ±4 BRASS 4,5 ±2 STEEL 700 ±1 CAST IRON 775 ±2 ALUMINIUM 120 ±8 Performance standards defined by the ASTM D3306 norms for cooling liquids Norm references for trial methods : AFNOR NF R 15-602-7 ou ASTM D 1384 © climalife - www.climalife.dehon.com I 06/02/2013 P12
  • 13. 2. Greenway® Range A complete alternative of dedicated solutions Base Product Freezing pointPackaging Applications Drum 20 l Used for comercial and industrial refrigerant -55 Drum 210 l systems IBC 1000 kg Drum 20 l Greenway® RTU -30 Drum 210 l IBC 1000 kg Used for traditional heating and refrigeration Drum 20 l systems -25 Drum 210 l BIO IBC 1000 kg propanediol Drum 20 l Greenway® HEAT PUMP -25 Drum 210 l Used for heat pump systems IBC 1000 kg Drum 20 l -30 Drum 210 l Greenway® SOLAR Drum 20 l Used for thermal solar systems -25 Drum 210 l IBC 1000 kg Ask us about bulks for these dilutions © climalife - www.climalife.dehon.com I 06/02/2013 P13
  • 14. 2. Greenway® Range Packaging to suit your needs Products: Packing Available: Greenway® Greenway® Heat Pump 20 L and 210 L Drums / IBC 1000kg Greenway® Solar © climalife - www.climalife.dehon.com I 06/02/2013 P14
  • 15. 3. Thermal solar application Greenway® Solar advantages Acid concentration; issue of heat transfer fluid degradation Greater thermal stability an exceptionally low degradation, 4 times less than MPG at 150 C Energy savings in operation Savings in maintenance costs (no tarring) A reduced bill on installation and on Hours operating Degradation of glycol solutions diluted at 50% at 150 C © climalife - www.climalife.dehon.com I 06/02/2013 P15
  • 16. 3. Thermal solar application Greenway® Solar advantages A longer life Maintained efficiency Better control of corrosion Highly reduced risk of extreme deterioration (tarring) Greenway® Solar, the ideal solution for thermal solar applied systems © climalife - www.climalife.dehon.com I 06/02/2013 P16
  • 17. 4. Heat pump application Issues in geothermal application: Possible leak of coolant from the buried sensor network (natural obstructions, tree roots ...) Results: Pollution of the ground Greenway® Heat Pump advantages Good thermal transfer Reduced effects on the environment in case of a leak Efficient protection against ice and corrosion © climalife - www.climalife.dehon.com I 06/02/2013 P17
  • 18. 5. Refrigeration application Greenway® RTU -55 innovation Characteristics : Greenway RTU Friogel Néo - 55 V i s MEG c Specific heat 2,9 3,31 MPG kJ/Kg.K o Greenway® s i t Density y 1085 1085 Kg/m3 c p Dynamic s 10,28 5,95 viscosity Pa.s Temperature C Thermal conductivity 0,364 0,296 W/m.K © climalife - www.climalife.dehon.com I 06/02/2013 P18
  • 19. 5. Refrigeration application Greenway® RTU -55 innovation The advantages of Greenway® RTU - 55: Greenway® RTU -55 viscosity index is lower than MPG’s and allows you to: Reduce pressure losses Reduce the size of the pumps and of the pipe work Energy savings on operation Savings on the installation procedure Installing and operating bills reduced © climalife - www.climalife.dehon.com I 06/02/2013 P19
  • 20. 5. Refrigeration application The General Direction of the Health and Safety Department Approval The Climalife Greenway® BIO PDO based heat transfer fluids have the authorization of the French Health and Safety Department for the production of sanitary hot water via a simple exchange A ‘food safe’ approval for coolants, as such, does not exist as Heat Transfer Fluids are not used as food ingredients, however: Some have the approval of the French General Direction of the Health and Safety Department as per the opinion given by the AFSSA for use in single exchangers or other approvals depending on the country © climalife - www.climalife.dehon.com I 06/02/2013 P20
  • 21. 6. Opportunities Long lasting stability properties An ecological opportunity Interesting characteristics at low temperature Low toxicity (not classified) 100% made from a renewable source Systems become more eco-friendly Compatibility with existing materials already in use in these applications © climalife - www.climalife.dehon.com I 06/02/2013 P21
  • 22. 7. Life Cycle Analysis Method used to assess a product’s environmental impact over the course of its life cycle. Results from the study comparing the life cycle of Greenway® -30 C and MPG -30 C: Lower impact than MPG -30 C regarding 5 indicators of a total of 7 Almost non existent impact on the deterioration of the ozone cover Bio PDO has less effect on climate change © climalife - www.climalife.dehon.com I 06/02/2013 P22
  • 23. Developing innovative, sustainable solutions for climate control systems