Polarisation of group ii nitrates

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[object Object],[object Object],[object Object],Polarisation of electron cloud of an anion by a cation

[object Object],[object Object],[object Object],Decomposition of Group II nitrates occurs M 2+ N - O O O M 2+ O 2- + NO 2 Heat Bond is weakened due to polarisation of electron cloud by cation Polarisation of electron cloud of nitrate ion by a Group II cation. + -

In summary, Down the group, Charge density of cation decreases Polarising power of cation decreases Distortion of electron cloud of anion decreases Weakening of bonds within anion to a lesser extent Decomposition temperature increases Size of cation increases ,[object Object],Ease of thermal decomposition decreases Thermal stability increases

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