This document provides an introduction to nanotechnology and its applications in civil engineering. It discusses how nanotechnology can be used to improve properties of concrete, steel, glass, and other building materials. Specifically, it describes how nano-silica and carbon nanotubes added to concrete can increase its strength and durability. It also explains how copper nanoparticles in steel can enhance fatigue resistance and heat resistance. The document concludes by noting challenges of nanotechnology such as health risks to workers and high production costs.
Nano Technology & Nano Materials
by Ray Fernando, PHD
California Polytechnic State University
Polymers and Coatings Program
Department of Chemistry and Biochemistry
San Luis Obispo, CA
www.polymerscoatings.calpoly.edu
Delivered 22 June 2009 @ SLINTEC
Overview of nanomaterials - Nanoscience and nanotechnologiesNANOYOU
An introduction to nanomaterials.
This chapter is part of the NANOYOU training kit for teachers.
For more resources on nanotechnologies visit: www.nanoyou.eu
sabhapathy19@gmail.com
transparent concrete using optical fibers its emerging techniques which is most helpful in future...
this idea is very much useful to save electrical energy which helpful for our upcoming generations..
to know more about this follow up on
sabhapathy19@gmail.com
Nano Technology & Nano Materials
by Ray Fernando, PHD
California Polytechnic State University
Polymers and Coatings Program
Department of Chemistry and Biochemistry
San Luis Obispo, CA
www.polymerscoatings.calpoly.edu
Delivered 22 June 2009 @ SLINTEC
Overview of nanomaterials - Nanoscience and nanotechnologiesNANOYOU
An introduction to nanomaterials.
This chapter is part of the NANOYOU training kit for teachers.
For more resources on nanotechnologies visit: www.nanoyou.eu
sabhapathy19@gmail.com
transparent concrete using optical fibers its emerging techniques which is most helpful in future...
this idea is very much useful to save electrical energy which helpful for our upcoming generations..
to know more about this follow up on
sabhapathy19@gmail.com
A RESEARCH ON NON COOPERATIVE HYBRID SPECTRUM SENSING TECHNIQUEIAEME Publication
The research designed in this paper is to purpose and implement a Hybrid spectrum sensing technique. As the utilization of wireless devices has been increased, there is a great demand for the radio spectrum .Cognitive Radio is a technology which can sense the spectrum to make the efficient use of resources of spectrum. Sensing of spectrum can be done by using matched filter, energy detection, waveform based detection, cyclostationary feature. Hybrid model is implemented by taking the assumptions for the distance and the SNR value, so it does not require unnecessary time for sensing of every frequency band. Results are formulated on the bases of two parameters probability of false detection and probability of correct detection. The proposed methodology has been implemented in MATLAB and the results obtained are in the form of improvement in Throughput, Energy consumption, Accuracy and improvement in Error.
The proposed model has been found efficient when compared to the other spectrum sensing techniques. It has been proved the effective improvement in throughput is by 9.9135% .Thus the results obtained are excellent and this will definitely help researcher for the future development of Cognitive Radio.
ROLE OF NANO TECHNOLOGY ON AGRI-GREEN PRODUCT PRODUCTION PROCESS: EMERGING NE...IAEME Publication
Nanotechnology is one of the most important tools in modern agriculture, and in the field of
Agri-Green Technology of product Production .where, Agri-food nanotechnology is anticipated to
become a driving economic force in the near future. Agri-food themes focus on sustainability and
protection of agriculturally produced foods, including crops for human consumption and animal
feeding. Nanotechnology provides new agrochemical agents and new delivery mechanisms to
improve crop productivity, and it promises to reduce pesticide use. Nanotechnology can boost
agricultural production, and its applications include: 1) Nano formulations of agrochemicals for
applying pesticides and fertilizers for crop improvement; 2) the application of
nanosensors/nanobiosensors in crop protection for the identification of diseases and residues of
agrochemicals; 3) nanodevices for the genetic manipulation of plants; 4) plant disease diagnostics;
5) animal health, animal breeding, poultry production; and 6) postharvest management. Precision
farming techniques could be used to further improve crop yields but not damage soil and water,
reduce nitrogen loss due to leaching and emissions, as well as enhance nutrients long-term
incorporation by soil microorganisms. Nanotechnology uses include nanoparticle-mediated gene
or DNA transfer in plants for the development of insect-resistant varieties, food processing and
storage, nanofeed additives, and increased product shelf life. Nanotechnology promises to
Dr. Ramesh Chandra Rath, Puspita Acharya, Anoopa Laly and Bishnu Chanran Rout
http://www.iaeme.com/IJARET/index.asp 35 editor@iaeme.com
accelerate the development of biomass-to-fuels production technologies. Experts feel that the
potential benefits of nanotechnology for agriculture, food, fisheries, and aquaculture need to be
balanced against concerns for the soil, water, and environment and the occupational health of
workers. Raising awareness of nanotechnology in the agri-food sector, including feed and food
ingredients, intelligent packaging and quick-detection systems, is one of the keys to influencing
consumer acceptance. On the basis of only a handful of toxicological studies, concerns have arisen
regarding the safety of Nanomaterials, and researchers and companies will need to prove that
these nanotechnologies do not have more of a negative impact on the environment.
presentation about the what is biogas, diffterent types of biogas plant, traditional vs modern, nisargruna biogas pant and detailed analysis about why to install biogas unit.
How to Start Biogas Production, Biogas – An Intense Opportunity (Landfill Gas...Ajjay Kumar Gupta
Generally, biogas is a renewable fuel. In any country, for cooking or heating purposes biogas can be used as a low-cost fuel. Biogas can be used as a fuel in stationary and mobile engines, to supply motive power, pump water, drive machinery (e.g., threshers, grinders) or generate electricity. It can be used in both spark and compression (diesel) engines. The spark ignition engine is easily modified to run on biogas by using a gas carburetor.
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A TEXT BOOK : Complete and comprehensive inputs in Learning about Biogas and Biogas digestors:We have tried to take the mystery away from biogas.
Biogas is a renewable energy source with many different production pathways and various excellent opportunities to use.
One main advantage of biogas is the waste reduction potential. Biogas production by anaerobic digestion is popular for treating biodegradable waste because valuable fuel can be produced while destroying disease-causing pathogens and reducing the volume of disposed waste products.
Biogas burns more cleanly than coal, and emits less carbon dioxide per unit of energy. The carbon in biogas was recently extracted from the atmosphere by photosynthetic plants. Releasing it back into the atmosphere adds less total atmospheric carbon than burning fossil fuels.
Thus, biogas production kills two birds with one stone: it reduces waste and produces energy. In addition, the residues from the digestation process can be used as high quality fertilizer. This closes the nutrient cycle.
Nano technology in construction materialsMir Ansaf
Uses of nano technology in construction
1.Nano Technology for concrete
2. Nano Technology for Steel
3. Nano Technology for wood
4. Nano Technology for glass
5.Sustainability and environment
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
This powerpoint presentation covers the role of Nanotechnology in Civil Engineering materials, future challenge and direction, impact of nano technology in civil engineering, the merits & demerits of nanotechnology.
Application of Nano Technology in Civil Engineering Construction MaterialsJournal For Research
There are many technologies whose applications are widely used in branch of civil engineering. There are both advantages and disadvantages of such technologies. But by using Nanotechnology the performance of material can be enhanced .Nanotechnology deals with understanding and controlling matter, atoms and molecules in the range of 0.1–100 nm (10-9 m). It creates materials, devices, and systems with new properties and functions. Nanoparticles have more surface area relative to their volume, making them useful in energy storage and for making composite materials. Nano materials are also able to be combined with biological materials, producing new structures that have properties of both types of materials. The role of nanotechnology in the infrastructure systems has the potential to set the civil engineering on a different height and widen the vision of civil engineering.
concrete which has enabled the study of chloride diffusion in concrete (which causes corrosion of reinforcement). Concrete is, after all, a macro-material strongly influenced by its nano-properties and understanding it at this new level is yielding new avenues for improvement of strength, durability and monitoring.
nanotechnology in concrete materials
nano cement
nanotechnology review
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hydraulic cement in caulking tubes
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nano concrete sealer
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NO1 Uk best vashikaran specialist in delhi vashikaran baba near me online vas...Amil Baba Dawood bangali
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Saudi Arabia stands as a titan in the global energy landscape, renowned for its abundant oil and gas resources. It's the largest exporter of petroleum and holds some of the world's most significant reserves. Let's delve into the top 10 oil and gas projects shaping Saudi Arabia's energy future in 2024.
About
Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
• Remote control: Parallel or serial interface.
• Compatible with MAFI CCR system.
• Compatible with IDM8000 CCR.
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
• Easy in configuration using DIP switches.
Technical Specifications
Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
Key Features
Indigenized remote control interface card suitable for MAFI system CCR equipment. Compatible for IDM8000 CCR. Backplane mounted serial and TCP/Ethernet communication module for CCR remote access. IDM 8000 CCR remote control on serial and TCP protocol.
• Remote control: Parallel or serial interface
• Compatible with MAFI CCR system
• Copatiable with IDM8000 CCR
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
Application
• Remote control: Parallel or serial interface.
• Compatible with MAFI CCR system.
• Compatible with IDM8000 CCR.
• Compatible with Backplane mount serial communication.
• Compatible with commercial and Defence aviation CCR system.
• Remote control system for accessing CCR and allied system over serial or TCP.
• Indigenized local Support/presence in India.
• Easy in configuration using DIP switches.
Hierarchical Digital Twin of a Naval Power SystemKerry Sado
A hierarchical digital twin of a Naval DC power system has been developed and experimentally verified. Similar to other state-of-the-art digital twins, this technology creates a digital replica of the physical system executed in real-time or faster, which can modify hardware controls. However, its advantage stems from distributing computational efforts by utilizing a hierarchical structure composed of lower-level digital twin blocks and a higher-level system digital twin. Each digital twin block is associated with a physical subsystem of the hardware and communicates with a singular system digital twin, which creates a system-level response. By extracting information from each level of the hierarchy, power system controls of the hardware were reconfigured autonomously. This hierarchical digital twin development offers several advantages over other digital twins, particularly in the field of naval power systems. The hierarchical structure allows for greater computational efficiency and scalability while the ability to autonomously reconfigure hardware controls offers increased flexibility and responsiveness. The hierarchical decomposition and models utilized were well aligned with the physical twin, as indicated by the maximum deviations between the developed digital twin hierarchy and the hardware.
Cosmetic shop management system project report.pdfKamal Acharya
Buying new cosmetic products is difficult. It can even be scary for those who have sensitive skin and are prone to skin trouble. The information needed to alleviate this problem is on the back of each product, but it's thought to interpret those ingredient lists unless you have a background in chemistry.
Instead of buying and hoping for the best, we can use data science to help us predict which products may be good fits for us. It includes various function programs to do the above mentioned tasks.
Data file handling has been effectively used in the program.
The automated cosmetic shop management system should deal with the automation of general workflow and administration process of the shop. The main processes of the system focus on customer's request where the system is able to search the most appropriate products and deliver it to the customers. It should help the employees to quickly identify the list of cosmetic product that have reached the minimum quantity and also keep a track of expired date for each cosmetic product. It should help the employees to find the rack number in which the product is placed.It is also Faster and more efficient way.
Hybrid optimization of pumped hydro system and solar- Engr. Abdul-Azeez.pdffxintegritypublishin
Advancements in technology unveil a myriad of electrical and electronic breakthroughs geared towards efficiently harnessing limited resources to meet human energy demands. The optimization of hybrid solar PV panels and pumped hydro energy supply systems plays a pivotal role in utilizing natural resources effectively. This initiative not only benefits humanity but also fosters environmental sustainability. The study investigated the design optimization of these hybrid systems, focusing on understanding solar radiation patterns, identifying geographical influences on solar radiation, formulating a mathematical model for system optimization, and determining the optimal configuration of PV panels and pumped hydro storage. Through a comparative analysis approach and eight weeks of data collection, the study addressed key research questions related to solar radiation patterns and optimal system design. The findings highlighted regions with heightened solar radiation levels, showcasing substantial potential for power generation and emphasizing the system's efficiency. Optimizing system design significantly boosted power generation, promoted renewable energy utilization, and enhanced energy storage capacity. The study underscored the benefits of optimizing hybrid solar PV panels and pumped hydro energy supply systems for sustainable energy usage. Optimizing the design of solar PV panels and pumped hydro energy supply systems as examined across diverse climatic conditions in a developing country, not only enhances power generation but also improves the integration of renewable energy sources and boosts energy storage capacities, particularly beneficial for less economically prosperous regions. Additionally, the study provides valuable insights for advancing energy research in economically viable areas. Recommendations included conducting site-specific assessments, utilizing advanced modeling tools, implementing regular maintenance protocols, and enhancing communication among system components.
Immunizing Image Classifiers Against Localized Adversary Attacksgerogepatton
This paper addresses the vulnerability of deep learning models, particularly convolutional neural networks
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introduce a novel volumization algorithm, which transforms 2D images into 3D volumetric representations.
When combined with 3D convolution and deep curriculum learning optimization (CLO), itsignificantly improves
the immunity of models against localized universal attacks by up to 40%. We evaluate our proposed approach
using contemporary CNN architectures and the modified Canadian Institute for Advanced Research (CIFAR-10
and CIFAR-100) and ImageNet Large Scale Visual Recognition Challenge (ILSVRC12) datasets, showcasing
accuracy improvements over previous techniques. The results indicate that the combination of the volumetric
input and curriculum learning holds significant promise for mitigating adversarial attacks without necessitating
adversary training.
Welcome to WIPAC Monthly the magazine brought to you by the LinkedIn Group Water Industry Process Automation & Control.
In this month's edition, along with this month's industry news to celebrate the 13 years since the group was created we have articles including
A case study of the used of Advanced Process Control at the Wastewater Treatment works at Lleida in Spain
A look back on an article on smart wastewater networks in order to see how the industry has measured up in the interim around the adoption of Digital Transformation in the Water Industry.
2. PRESENTATION BY,
JERRY PAUL VARGHESE
REG.NO:11021149
SNGIST 2
GUIDED BY:
SHINE JOB
SENIOR TUTOR
DEPT. OF CIVIL ENGINEERING
SNGIST
3. Introduction
Introduction to nano materials
Applications in civil engineering
• Concrete
• Steel
• High strength bolts
• Nanotech in glass
• Fire and heat protection
Nanotechnology in other disciplines
Introductions to some new technology using nanotehnology
Conclusion
References
3
4. Nanotechnology deals with understanding, controlling and
manipulating the matter at the level of individual atoms and
molecules at the range of 0.1-100nm.
“Nanotechnology is an enabling technology that allows us
to develop materials with improved or totally new
properties”
A nanometer is a billionth of a meter.
At the length scale of the nanometer ,10-9m,the
properties of the material actually become affected.
NANOTECHNOLOGY IN CIVIL ENGINEERING 4
5. Nano particle: particle with at
least one dimension<100nm.
Quantum dots if they are small
enough (< 10nm) such that
jumps in energy levels occur .
(fig.1)
Nano composite: Produced by
adding nano particle to a bulk
material to improve the bulk
materials properties. (fig.2)
5
1.
• Nano particles
2.
• Nano composites
3.
• Carbon Nano
tubes (CNT)
4.
• Titanium
oxide(TiO2)
NANOTECHNOLOGY IN CIVIL ENGINEERING
6. 6
Fig.1 Fig.2
NANOTECHNOLOGY IN CIVIL ENGINEERING
Nano composite
8. White pigment.
Can oxidize organic materials , so added to paints,
cements, windows, tiles, or other products for
sterilizing, deodorizing and anti-fouling properties.
In outdoor building, materials can substantially
reduce concentrations of airborne pollutants.
Additionally, as TiO2 is exposed to UV light, it
becomes increasingly hydrophilic, thus it can be used
in windows.
NANOTECHNOLOGY IN CIVIL ENGINEERING 8
10. Cylindrical with
nanometer diameter.
Several millimeters in
length .
Have 5 times the
young’s modulus and
8 times (theoretically
100 times)the strength
of steel whilst being
1/6th the density.
Thermal conduction is
also very high among
the tube axis.
NANOTECHNOLOGY IN CIVIL ENGINEERING 10
12. CONSTRUCTION
Inevitably be a beneficiary
Already is in the fields of concrete, steel and
Glass, and many more.
Concrete is stronger ,more durable and more
easily placed:
Steel is made tougher:
Glass is self-cleaning.
Paints are made more insulating and water
repelling.
NANOTECHNOLOGY IN CIVIL ENGINEERING 12
14. Concrete-mixture of cement,
sand(fine aggregate) and
water.
As concrete is most usable.
Require to improve.
Mechanical behavior of
concrete materials depends
on phenomena that occur on
a micro and nanoscale.
NANOTECHNOLOGY IN CIVIL ENGINEERING 14
15. Nanotechnology can
modify: the molecular
structure of concrete
material to improve the
materials properties.
Nano-concrete: “a concrete
made with Portland cement
particles that are less than
500 nano-meters as the
cementing agent”.
15
Bulk properties
Mechanical performance.
Volume stability
Durability
Sustainability of concrete
NANOTECHNOLOGY IN CIVIL ENGINEERING
16. NANO-SILICA: Particle packing in concrete improved
by using nano-silica which leads to the densification of
the micro and nano structure resulting in improved
mechanical properties
Nano- silica adding to cement based materials can:
Refine pore structure
Strength enhancement
Reducing cal-leaching
Increasing durability
Accelerating hydration
NANOTECHNOLOGY IN CIVIL ENGINEERING 16
17. Average size of Portland cement particle
is about 50 microns.
In thinner products for faster setting time,
micro cement with maximum particle size
of about 5 microns is being used.
Hydration tests indicated that the nano-cement
had a more rapid hydration rate
17
18. Can be used as an excellent reflective coating.
Hydrophilic and therefore gives self cleaning
properties to surfaces to which it is applied.
Rain water is attracted to the surface and
forms sheets .
The resulting concrete ,already used in
projects around the world has a white color
that retains its whiteness very effectively
unlike the stained building of the material’s
pioneering past.
18
19. The addition of small amounts (1%wt)of CNT’s
can improve the mechanical properties of
samples consisting of the main Portland cement
phase and water.
Oxidized multi-walled nano tubes (MWNT’s)
show the best improvements both in
compressive strength(+25N/mm2) and flexural
strength(+8N/mm2)compared to the samples
without the reinforcement.
A number of investigations have been carried
out for developing smart concrete using carbon
fibers.
19
21. Fatigue leads to the structural failure of steel
subject to cyclic loading, such as in bridge or
towers.
Stress risers are responsible for initiating cracks
from which fatigue failure results and research has
shown that the addition of copper nanoparticle
reduces the surface unevenness of steel which then
limits the number of stress risers.
Advancements in this technology lead to increased
safety, less need for monitoring and more efficient
materials use in construction prone to fatigue
issues.
21
22. Above 75 deg.Fa,regular steel starts to lose its
structural integrity ,and at 1100 F, steel loses
50% of its strength.
With nano scale copper particles ,this formula
could maintain structural integrity at
temperatures up to 1000 F.
The new steel allows ultra-high strength to be
combined with good formability, corrosion
resistance and a good surface finish.
22
23. Cementite phase of steel to a Nano-size has
produced stronger cables.
A stronger cable material reduces cost,
period of constructon ,especially in
suspension bridges.
Sustainability is also enhanced by the use
of higher cable strength as this leads to a
more efficient use of materials.
23
24. The capacity of high strength bolts is realized
generally through quenching and tempering
The microstructures consists of tempered
martensite.
Vanadium and molybdenum nanoparticles
delays the problems associated with high
strength bolts and also improving the steel’s
micro- structure
24
25. Sandvik nanoflex
1. Produced by Sandvik Materials Technology
MMFX2 steel
1. Produced by MMFX steel corp.
25
26. TiO2 is used in nanoparticle form to coat glazing
since it has sterilizing and anti-fouling
properties.
Catalyzing reactions-breakdown organic
pollutants, volatile organic compounds and
bacterial membranes.
It is hydrophilic and this attraction to water
forms sheets out of rain drops which then wash
off the dirt particles broken down in the previous
process.
Glass incorporation this self cleaning technology
is available on the market today.
26
27. SELF CLEANING GLASSES.
Major problems facing :Light and heat
entering through glazing-rain drops-organic
pollutants-volatile organic compounds and
bacterial membranes.
27
28. Fire-protective glass
• Achieved by using a clear instumescent layer
sandwiched between glass panels (an
interlayer) formed of fumed silica(SIO2)
Nanoparticle which turns into a rigid and
opaque fire shield when heated.
28
29. For heat protection: thin film coatings
developed which are spectrally sensitive
surface applications for window glass and
filter out unwanted I.R frequencies of light
.(passive solution)
As an active solution, thermo chromatic
technologies are being studied which react to
temperature and provide insulation to give
protection from heating whilst maintaining
adequate lighting.
29
31. Wood is also comprised of nanotubes or nano
fibrils -lignocelluloses are twice as strong as
steel .
Lignocelluloses surfaces at the nanoscale
could open new opportunities for such things
as self-sterilizing surfaces, internal self-repair,
and electronic lignocelluloses devices.
31
32. Currently,however,research in these Areas
appears limited.
Researchers have developed highly water
repellent coating based on the actions of
lotus leaf as a result of the incorporation of
silica and alumina nanoparticles and
hydrophobic polymers .
32
33. Applied to paints -insulating properties-produced
by the addition of nano-sized cells -
giving very limited paths for thermal conduction
(R values are double for insulating foam),are
currently available.
This type of paint is used ,for corrosion
protection under insulation since it Is
hydrophobic and repels water from the metal
pipe and can also protect metal from sat water
attack.
33
34. POLLUTION AMOUNT
POLLU-TANT
CARBON –
MONO-XIDE
HYDR-OCARBON
S
NITR-OGEN
OXIDES
PARTIC-ULATE
MATTER
POLLU-TION
PER DAY
421.84 184.37 110.45 12.77
The absorption of carbon
monoxide -using cuprous salt
adsorption of hydrocarbons-using
a complex nano
material.i.e., carbon monolithic
aero gels.
Sol-gel process.
Adsorption capacity
measurements show that
modified hydrophobic carbon
aero gels are excellent
adsorbents for different toxic
organic compounds from water.
34
35. FLEXIBLE DISPLAY
DIRT NON-STICKY WALL
OIL REPELENT METAL
WATER RESISATANT SURFACE
35
37. Because of their small particle size, nano
particles have the potential to negatively
affect the respiratory and digestive tracks
and the skin or eye surface thus exposes
workers to hazards.
▪
Small production volumes and high cost
remain the main barriers to the use of
nanotechnology .
37
38. Nano-science and nanotechnology help seed
construction related nano-technological
development.
Nanotechnology has its biggest impact on
the field of civil engineering.
38
39. [1] Mann, S. (2006). “Nanotechnology and Construction,”
Nanoforum Report. www.nanoforum.org, May 30,
2008.
[2] Balaguru, P. N., “Nanotechnology and Concrete:
Background, Opportunities and Challenges.” Proceedings
of the International Conference – Application of Technology
in Concrete Design, Scotland, UK, p.113-122,
2005.
[3] ARI News (2005). “Nanotechnology in Construction – One
of the Top Ten Answers to World’s Biggest
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www.aggregateresearch.com/article.asp?id=6279, June 1,
2007.
39
Grt priv
For semi on the topic
NANO ON ce concentratin to its apps
As I ws colectng th infrmations…I found its numerous in count ,bt due to the lited time for prsnttion I would like to give a strong base of knowledge abt nanotech applications in ce .in this presentation I have included
Martn- carbonn steel with rapid coolin..crystls formed.austenite