This document discusses modeling the optical and energy performance of tungsten-oxide-based electrochromic windows, including their intermediate states of tint. It finds that even small amounts of tint significantly reduce solar heat gain through absorption. It compares the performance of electrochromic windows to low-emissivity windows. The document considers different configurations, such as placements of electrochromic layers and additional low-emissivity coatings. It models transmittance and reflectance using optical data and software to evaluate performance.
Design and Simulation of Dye Sensitized Solar Cell as a Cost-Effective Alt...Scientific Review SR
The continuous research in the area of renewable energy technology to substitute the unsustainable nature of fossil
fuel in terms of it future availability and negative environmental impact created by fossil fuel has ensure the explore
of solar energy as a good alternative. Dye sensitized solar cells (DSSCs) serve to be a good alternative means of
producing photovoltaic solar cell. This work reports the working principle and construction process of dye-sensitized
solar cell. A synthesized dye (Ruthenium oxide) and an iodide electrolyte were used for better performance based on
already researched work. Also, this work reports the evaluation process with results recorded by the produced solar
cell within 6:00am (GMT) and 6:00pm (GMT) for selected days. The results from the evaluation process show a
better performance of a dye-sensitized solar cell in low and normal sunny day. The solar cell has a good performance
at 12:00noon with a 0.5V output.
A Dye-sensitized solar cell is third generation low cost solar cell compared to silicon solar cell, has received widespread attention in recent years. Several researches are going on to improve their energy-conversion efficiency as the solar energy is one of the renewable energy based on modern technologies, which are suitable for the sustainability.
This document analyzes the absorption properties and I-V characterization of a dye sensitized solar cell using a natural Ruthenium dye extracted from fruits. Anees Ur Rehman et al. fabricated a DSSC using Ruthenium dye extracted from fruits as a sensitizer on a titanium dioxide layer. They measured the cell's short circuit current, open circuit voltage, fill factor, and efficiency, finding values of 11.52 mA/cm2, 0.70V, 0.61, and 4.47% respectively under 110 mW/cm2 illumination. The dye was found to absorb visible light well and support electron transfer at the semiconductor interface, demonstrating the potential of natural dyes as lower-
This document analyzes the effect of increasing the work function of the anode material on the performance of organic light-emitting diodes (OLEDs). Two OLEDs are designed and simulated using different anode materials: indium tin oxide (ITO) and zinc oxide (ZnO). The results show that using ZnO, which has a higher work function than ITO, increases the anode current, luminance power, and recombination rate in the organic layer. Increasing the anode work function improves device performance by increasing the built-in potential and thus charge injection and recombination in the OLED.
Nano conductive adhesives for nano-electronics interconnectionnguyentruong22
1. Electrically conductive adhesives (ECAs) are becoming more important for electronics packaging as alternatives to tin/lead solders due to their environmental friendliness and ability to enable fine-pitch interconnects.
2. Incorporating nano-sized conductive fillers into ECAs can enhance their electrical properties and enable ultra-fine pitch capabilities by reducing the percolation threshold and improving conductivity.
3. Recent research has focused on developing nanoconductive adhesives containing nanofillers like nanoparticles, nanowires, and carbon nanotubes to achieve the properties required for applications like flexible electronics and transparent electrodes.
Done By: Arwa_Black7
School Name: Arwa Bint Abdul Motaleb Secondary Independent School for Girls
Dye-Sensitized Solar Cell (DSSC) Module:
The students study the concept of using dyes to plant dyes to capture the solar energy to convert it into electrical energy simulating the natural process “photosynthesis”. They use the workshop-gained knowledge in DSSC to invent new products.
Our project idea is about using of basil pigment in lighting tents in the desert using Dye-sensitized solar cell.
This document discusses polyfluorene materials and their applications in organic light-emitting diodes (OLEDs) and plastic solar cells. It provides background on fluorene and its structure. The author synthesized two fluorene-based monomers that could be copolymerized to form materials for devices, but limitations prevented full characterization and testing. Polyfluorenes are widely used in OLEDs and solar cells due to properties like color tunability and high efficiency at low voltages. The document also reviews OLED architecture and advantages over LCDs, as well as principles of plastic solar cells.
Bathochromic shift in photo-absorption spectra of organic dye sensitizers thr...Narges Mohamadi
This document discusses the rational design of new organic dye sensitizers for dye-sensitized solar cells using computational methods. It begins by noting the increasing global energy demand and limitations of current energy sources. It then provides background on dye-sensitized solar cells and their advantages over traditional silicon solar cells. The objectives are to design dyes with broader absorption spectra extending into the near-infrared, reduced HOMO-LUMO gaps, and suitability for solar cells. Several dye structures are computationally modified and evaluated using density functional theory and time-dependent DFT to obtain optical and electronic properties. Promising new dyes with red-shifted absorption are identified.
Design and Simulation of Dye Sensitized Solar Cell as a Cost-Effective Alt...Scientific Review SR
The continuous research in the area of renewable energy technology to substitute the unsustainable nature of fossil
fuel in terms of it future availability and negative environmental impact created by fossil fuel has ensure the explore
of solar energy as a good alternative. Dye sensitized solar cells (DSSCs) serve to be a good alternative means of
producing photovoltaic solar cell. This work reports the working principle and construction process of dye-sensitized
solar cell. A synthesized dye (Ruthenium oxide) and an iodide electrolyte were used for better performance based on
already researched work. Also, this work reports the evaluation process with results recorded by the produced solar
cell within 6:00am (GMT) and 6:00pm (GMT) for selected days. The results from the evaluation process show a
better performance of a dye-sensitized solar cell in low and normal sunny day. The solar cell has a good performance
at 12:00noon with a 0.5V output.
A Dye-sensitized solar cell is third generation low cost solar cell compared to silicon solar cell, has received widespread attention in recent years. Several researches are going on to improve their energy-conversion efficiency as the solar energy is one of the renewable energy based on modern technologies, which are suitable for the sustainability.
This document analyzes the absorption properties and I-V characterization of a dye sensitized solar cell using a natural Ruthenium dye extracted from fruits. Anees Ur Rehman et al. fabricated a DSSC using Ruthenium dye extracted from fruits as a sensitizer on a titanium dioxide layer. They measured the cell's short circuit current, open circuit voltage, fill factor, and efficiency, finding values of 11.52 mA/cm2, 0.70V, 0.61, and 4.47% respectively under 110 mW/cm2 illumination. The dye was found to absorb visible light well and support electron transfer at the semiconductor interface, demonstrating the potential of natural dyes as lower-
This document analyzes the effect of increasing the work function of the anode material on the performance of organic light-emitting diodes (OLEDs). Two OLEDs are designed and simulated using different anode materials: indium tin oxide (ITO) and zinc oxide (ZnO). The results show that using ZnO, which has a higher work function than ITO, increases the anode current, luminance power, and recombination rate in the organic layer. Increasing the anode work function improves device performance by increasing the built-in potential and thus charge injection and recombination in the OLED.
Nano conductive adhesives for nano-electronics interconnectionnguyentruong22
1. Electrically conductive adhesives (ECAs) are becoming more important for electronics packaging as alternatives to tin/lead solders due to their environmental friendliness and ability to enable fine-pitch interconnects.
2. Incorporating nano-sized conductive fillers into ECAs can enhance their electrical properties and enable ultra-fine pitch capabilities by reducing the percolation threshold and improving conductivity.
3. Recent research has focused on developing nanoconductive adhesives containing nanofillers like nanoparticles, nanowires, and carbon nanotubes to achieve the properties required for applications like flexible electronics and transparent electrodes.
Done By: Arwa_Black7
School Name: Arwa Bint Abdul Motaleb Secondary Independent School for Girls
Dye-Sensitized Solar Cell (DSSC) Module:
The students study the concept of using dyes to plant dyes to capture the solar energy to convert it into electrical energy simulating the natural process “photosynthesis”. They use the workshop-gained knowledge in DSSC to invent new products.
Our project idea is about using of basil pigment in lighting tents in the desert using Dye-sensitized solar cell.
This document discusses polyfluorene materials and their applications in organic light-emitting diodes (OLEDs) and plastic solar cells. It provides background on fluorene and its structure. The author synthesized two fluorene-based monomers that could be copolymerized to form materials for devices, but limitations prevented full characterization and testing. Polyfluorenes are widely used in OLEDs and solar cells due to properties like color tunability and high efficiency at low voltages. The document also reviews OLED architecture and advantages over LCDs, as well as principles of plastic solar cells.
Bathochromic shift in photo-absorption spectra of organic dye sensitizers thr...Narges Mohamadi
This document discusses the rational design of new organic dye sensitizers for dye-sensitized solar cells using computational methods. It begins by noting the increasing global energy demand and limitations of current energy sources. It then provides background on dye-sensitized solar cells and their advantages over traditional silicon solar cells. The objectives are to design dyes with broader absorption spectra extending into the near-infrared, reduced HOMO-LUMO gaps, and suitability for solar cells. Several dye structures are computationally modified and evaluated using density functional theory and time-dependent DFT to obtain optical and electronic properties. Promising new dyes with red-shifted absorption are identified.
This document provides an overview of dye sensitized solar cells (DSSC). It discusses the principle and working of DSSCs, including the key components - a photosensitive dye, nanostructured semiconductor (typically TiO2), redox electrolyte, and two electrodes. Upon light absorption, electrons are injected from the dye into the semiconductor. The electrolyte regenerates the oxidized dye and transports electrons between the electrodes. The document outlines the preparation, applications, and commercial potential of DSSCs, noting their advantages over silicon solar cells.
Composites combine multiple materials to create new materials with improved properties. Nanocomposites embed nanoscale particles in a matrix material. Epoxy resins are commonly used as the matrix for nanocomposites due to their versatility. Incorporating nanoscale fillers like graphene and carbon nanotubes into epoxy matrices can enhance the material's thermal and electrical conductivity compared to using microscale or no fillers. The type and concentration of filler, as well as the fabrication method, influence the degree of enhancement in the epoxy composite's properties.
This document summarizes the fabrication and characterization of an AgAl/Si solar cell. AgAl alloys were used for electrical connections due to properties that affect electrical conductivity. A boron layer was diffused into an n-type silicon wafer to create a p-n heterojunction. XRD analysis showed boron inclusion in the silicon. The heterojunction had a direct optical bandgap of 3.1 eV. The solar cell demonstrated a conversion efficiency of 10.54% with a short circuit current of 2.042 mA, open circuit voltage of 0.592 V, and fill factor of 0.682.
This document summarizes a research paper on dye sensitized solar cells (DSSCs). It provides background on the development of DSSCs since 1991 and their advantages over traditional silicon solar cells in terms of lower cost and simpler preparation. However, liquid electrolytes used in early DSSCs limited long-term performance. Recent research has focused on improving electrolytes, particularly developing quasi-solid state electrolytes, to enhance photoelectric performance and stability for practical applications of DSSCs. The document reviews progress on quasi-solid state electrolytes and their advantages over liquid electrolytes for DSSCs.
Some Aspects of Stress Distribution and Effect of Voids Having Different Gase...IOSR Journals
1) The document analyzes the stress distribution and effect of voids with different gases in MV power cables through finite element modeling. It studies the electric field and temperature distribution within cable insulation containing voids.
2) Cylindrical voids are found to have higher electric stress than spherical or elliptical voids. Among gases, oxygen consumption during partial discharge causes greater temperature rise and faster breakdown than nitrogen.
3) The analysis examines factors like void shape, position, and size that influence stress distribution and partial discharge inception voltage. Nearer and larger voids have lower inception voltages. Oxygen consumption leads to uniform erosion and higher temperatures, making its effect greater than other gases.
This document summarizes a study on the photoelectrochemical properties of nanocrystalline indium selenide (In2Se3) thin films deposited via a chemical bath deposition method. The In2Se3 films exhibited n-type conductivity. Current-voltage measurements in the dark showed non-symmetrical rectifying behavior with a junction ideality factor of 3.85, suggesting the influence of series resistance and structural imperfections. Capacitance-voltage measurements determined a flat band potential of -0.530V versus saturated calomel electrode. Barrier height measurements from reverse saturation current at different temperatures yielded a barrier height. Under 30 mW/cm2 illumination, the cell demonstrated an open circuit voltage of 153mV
A dye sensitized solar cell (DSSC) functions by using light absorbing dye molecules to convert sunlight into electricity through photovoltaic processes. When light is absorbed by the dye, electrons are injected into the conduction band of a nanostructured titanium dioxide layer. The electrons then travel through an external circuit, generating electricity, and are collected by a counter electrode. The oxidized dye is regenerated by electron donation from an electrolyte, allowing the process to repeat continuously. DSSCs have the advantages of being relatively inexpensive, flexible in design, and using natural dyes, making them a promising solar technology.
This document discusses using density functional theory to model the initial steps of dimethyl ether (DME) dissociation on platinum and nickel catalyst surfaces for DME fuel cells. The researchers calculated the adsorption energies of DME on different surface sites of platinum and nickel crystals. Their results showed that DME adsorbed most strongly to the nickel fcc(111) surface, indicating it may be the most promising catalyst material. Future work will calculate additional energies to determine the most effective catalyst structure and aid experimental research.
Done by Group: Golden
School: Al Wakra Independent School for Girls
Dye-Sensitized Solar Cells (DSSC) Module: The students study the concept of using dyes to plant dyes to capture the solar energy to convert it into electrical energy simulating the natural process “photosynthesis”. They use the workshop-gained knowledge in DSSC to invent new products.
The project consists of two parts, one of them is improving DSSC (They used different dyes) and the other part is an idea about application on the traffic lights.
This is an effective method of solving energy crisis in a low cost method other than photo-voltaic cell. This DSSC are more efficient and economic than traditional solar cells
The document summarizes a study that used a scanning Kelvin probe to characterize the surface modification of indium tin oxide (ITO) substrates with photopatternable silane adlayers. A photoreactive silane molecule containing an o-nitrobenzyl group was used to form self-assembled monolayers on ITO. UV light through a photomask was used to selectively remove regions of the silane layer, and changes in surface potential were detected using contact potential difference measurements from the scanning Kelvin probe. Additional characterization techniques including X-ray photoelectron spectroscopy and contact angle measurements were also used to analyze the modified surfaces.
Dye Sensitized Solar Cells- PhD Stage 3 SeminarNarges Mohamadi
This document discusses computational modeling of organic dye sensitizers for application in solar cells. It outlines the research question of how rational in silico design can be used to develop new organic dyes to increase photocurrent density by decreasing the optical band gap and extending light absorption into the near-infrared region. The document describes computational methods used, including density functional theory and time-dependent density functional theory to optimize dye structures, calculate frontier molecular orbital energies, and simulate UV-Vis absorption spectra. Selected results are presented on modifications made to an existing dye sensitizer to lower the band gap and shift absorption spectra bathochromically into the near-infrared. The overall outcome was successful design of new dyes with improved light absorption properties for potential
This document summarizes a presentation on dye sensitized solar cells (DSSC) given by Ashok Kumar Jangid. It describes the basic components and structure of a DSSC, which includes a titanium dioxide semiconductor, sensitizing dye, iodide redox mediator, platinum counter electrode, and glass support. The document explains that light absorption by the dye generates electron injection into the semiconductor to produce a current. Common dyes used include N3, N719, and various ruthenium-based dyes. Potential applications of DSSCs include use in buildings, agriculture, and domestic settings due to their low cost and environmental friendliness.
Dye-sensitized solar cells (DSSCs), also known as Gratzel cells, work by using a photo-sensitized dye to generate electricity from sunlight. DSSCs were invented in 1991 as a low-cost alternative to traditional silicon solar cells. In a DSSC, light absorption in a dye triggers electrons to inject into a semiconductor, usually titanium dioxide, where they are collected on an electrode. The electrons then travel through an external circuit to the counter electrode, producing electricity. The circuit is completed by an electrolyte that transports ions back to the dye to regenerate it. DSSCs have the potential for lower manufacturing costs than silicon cells and can be produced using solution-based processes on many different
This document presents information on dye-sensitized solar cells (DSSCs). It discusses that DSSCs are a type of thin-film solar cell composed of a semiconductor, dye, electrolyte, and counter electrode. DSSCs work by using a dye to absorb sunlight and inject electrons into a semiconductor, like titanium dioxide. The electrons then flow through an external circuit to the counter electrode, while the dye is regenerated by the electrolyte. Though DSSCs have lower efficiency than other thin film cells, they have a better price to performance ratio and do not require pure silicon. The maximum reported conversion efficiency of DSSCs is around 11-15%.
International Journal of Engineering Research and Development (IJERD)IJERD Editor
The document discusses a study that assessed the performance of window films in reducing solar heat gain in buildings in Kurdistan, Iraq. A test wooden cabinet was constructed and measurements were taken over 9 hours both with and without a window film installed. Results showed that the window film reduced maximum indoor temperatures by 10°C and blocked 50-97% of solar radiation depending on weather conditions. Calculations estimated that applying the window film reduced the solar heat gain of the cabinet by 477.15 Watts, with the largest reduction due to decreased light transmission through the windows. The study demonstrates that window films can effectively support environmental protection by lowering energy use for cooling in hot climates like Kurdistan.
Nowadays the concept of Net ZEB is well-known
and widespread in the scientific community. The European
Union has set ambitious targets for 2020 and even more
ambitious for 2050. In order to reduce the domestic GHG
emissions by 80-95%, compared to 1990 levels- till 2050, the
building sector has to do its part and to pass through a deep
restructure. Therefore, it is grown the interest in design and
technical solutions for achieving a zero or nearly zero energy
building. This paper investigate several construction technologies
and system of energy production that can be adopted to build an
“enhanced saving” (parsimonious) building, which can strive for
the objective of NetZEB. Moreover the economic analysis of the
feasibility of the NZEB target has been developed.
This document discusses using earthen pots and solar paneling on rooftops and walls to improve the energy efficiency of building envelopes. Installing earthen pots in the roof creates an insulating air cavity that reduces heat transfer, lowering cooling costs by 22-25%. Solar paneling on windows and outer walls further increases energy efficiency. While initial setup costs may be high, these modifications save on energy usage over the long term and pay for themselves within 15 years. Building envelope design aims to balance construction costs with required performance, and using earthen pots and transparent luminescent solar concentrators can significantly reduce heat loads and electricity costs in India.
The document summarizes the steps taken to optimize the façade of a mid-rise commercial building in Delhi to reduce its energy consumption. It describes analyzing the building's initial energy use, orientation, window-to-wall ratio, shading devices, fenestration, and wall and roof assemblies. Simulations showed that optimizing these elements could reduce the building's annual energy consumption by up to 47% and decrease its cooling load by 25%.
Pdlc film energy saving reports uniteglassUniteglass
In this study, the building energy reduction and daylight performance improvement effects of
remodeling old buildings using PDLC films were analyzed. The analysis results showed that both
remodeling methods using PDLC films were effective in terms of heating and cooling energy reduction
and daylight performance improvement.
Solar energy concentration techniques in flat plate collectorIAEME Publication
The document summarizes research on improving the efficiency of flat plate solar collectors through various concentration techniques. It discusses the limitations of conventional flat plate collectors and reviews studies that have incorporated things like twisted wire coils inside tubes, double glazing, selective coatings including nanoparticles, and optical lenses to increase absorption. Experimental results showed efficiency increases ranging from 5% to 15% compared to standard flat plate collectors without these enhancements. The review concludes that ongoing developments aim to make flat plate collectors more compact and effective through improved materials and designs.
This document provides an overview of dye sensitized solar cells (DSSC). It discusses the principle and working of DSSCs, including the key components - a photosensitive dye, nanostructured semiconductor (typically TiO2), redox electrolyte, and two electrodes. Upon light absorption, electrons are injected from the dye into the semiconductor. The electrolyte regenerates the oxidized dye and transports electrons between the electrodes. The document outlines the preparation, applications, and commercial potential of DSSCs, noting their advantages over silicon solar cells.
Composites combine multiple materials to create new materials with improved properties. Nanocomposites embed nanoscale particles in a matrix material. Epoxy resins are commonly used as the matrix for nanocomposites due to their versatility. Incorporating nanoscale fillers like graphene and carbon nanotubes into epoxy matrices can enhance the material's thermal and electrical conductivity compared to using microscale or no fillers. The type and concentration of filler, as well as the fabrication method, influence the degree of enhancement in the epoxy composite's properties.
This document summarizes the fabrication and characterization of an AgAl/Si solar cell. AgAl alloys were used for electrical connections due to properties that affect electrical conductivity. A boron layer was diffused into an n-type silicon wafer to create a p-n heterojunction. XRD analysis showed boron inclusion in the silicon. The heterojunction had a direct optical bandgap of 3.1 eV. The solar cell demonstrated a conversion efficiency of 10.54% with a short circuit current of 2.042 mA, open circuit voltage of 0.592 V, and fill factor of 0.682.
This document summarizes a research paper on dye sensitized solar cells (DSSCs). It provides background on the development of DSSCs since 1991 and their advantages over traditional silicon solar cells in terms of lower cost and simpler preparation. However, liquid electrolytes used in early DSSCs limited long-term performance. Recent research has focused on improving electrolytes, particularly developing quasi-solid state electrolytes, to enhance photoelectric performance and stability for practical applications of DSSCs. The document reviews progress on quasi-solid state electrolytes and their advantages over liquid electrolytes for DSSCs.
Some Aspects of Stress Distribution and Effect of Voids Having Different Gase...IOSR Journals
1) The document analyzes the stress distribution and effect of voids with different gases in MV power cables through finite element modeling. It studies the electric field and temperature distribution within cable insulation containing voids.
2) Cylindrical voids are found to have higher electric stress than spherical or elliptical voids. Among gases, oxygen consumption during partial discharge causes greater temperature rise and faster breakdown than nitrogen.
3) The analysis examines factors like void shape, position, and size that influence stress distribution and partial discharge inception voltage. Nearer and larger voids have lower inception voltages. Oxygen consumption leads to uniform erosion and higher temperatures, making its effect greater than other gases.
This document summarizes a study on the photoelectrochemical properties of nanocrystalline indium selenide (In2Se3) thin films deposited via a chemical bath deposition method. The In2Se3 films exhibited n-type conductivity. Current-voltage measurements in the dark showed non-symmetrical rectifying behavior with a junction ideality factor of 3.85, suggesting the influence of series resistance and structural imperfections. Capacitance-voltage measurements determined a flat band potential of -0.530V versus saturated calomel electrode. Barrier height measurements from reverse saturation current at different temperatures yielded a barrier height. Under 30 mW/cm2 illumination, the cell demonstrated an open circuit voltage of 153mV
A dye sensitized solar cell (DSSC) functions by using light absorbing dye molecules to convert sunlight into electricity through photovoltaic processes. When light is absorbed by the dye, electrons are injected into the conduction band of a nanostructured titanium dioxide layer. The electrons then travel through an external circuit, generating electricity, and are collected by a counter electrode. The oxidized dye is regenerated by electron donation from an electrolyte, allowing the process to repeat continuously. DSSCs have the advantages of being relatively inexpensive, flexible in design, and using natural dyes, making them a promising solar technology.
This document discusses using density functional theory to model the initial steps of dimethyl ether (DME) dissociation on platinum and nickel catalyst surfaces for DME fuel cells. The researchers calculated the adsorption energies of DME on different surface sites of platinum and nickel crystals. Their results showed that DME adsorbed most strongly to the nickel fcc(111) surface, indicating it may be the most promising catalyst material. Future work will calculate additional energies to determine the most effective catalyst structure and aid experimental research.
Done by Group: Golden
School: Al Wakra Independent School for Girls
Dye-Sensitized Solar Cells (DSSC) Module: The students study the concept of using dyes to plant dyes to capture the solar energy to convert it into electrical energy simulating the natural process “photosynthesis”. They use the workshop-gained knowledge in DSSC to invent new products.
The project consists of two parts, one of them is improving DSSC (They used different dyes) and the other part is an idea about application on the traffic lights.
This is an effective method of solving energy crisis in a low cost method other than photo-voltaic cell. This DSSC are more efficient and economic than traditional solar cells
The document summarizes a study that used a scanning Kelvin probe to characterize the surface modification of indium tin oxide (ITO) substrates with photopatternable silane adlayers. A photoreactive silane molecule containing an o-nitrobenzyl group was used to form self-assembled monolayers on ITO. UV light through a photomask was used to selectively remove regions of the silane layer, and changes in surface potential were detected using contact potential difference measurements from the scanning Kelvin probe. Additional characterization techniques including X-ray photoelectron spectroscopy and contact angle measurements were also used to analyze the modified surfaces.
Dye Sensitized Solar Cells- PhD Stage 3 SeminarNarges Mohamadi
This document discusses computational modeling of organic dye sensitizers for application in solar cells. It outlines the research question of how rational in silico design can be used to develop new organic dyes to increase photocurrent density by decreasing the optical band gap and extending light absorption into the near-infrared region. The document describes computational methods used, including density functional theory and time-dependent density functional theory to optimize dye structures, calculate frontier molecular orbital energies, and simulate UV-Vis absorption spectra. Selected results are presented on modifications made to an existing dye sensitizer to lower the band gap and shift absorption spectra bathochromically into the near-infrared. The overall outcome was successful design of new dyes with improved light absorption properties for potential
This document summarizes a presentation on dye sensitized solar cells (DSSC) given by Ashok Kumar Jangid. It describes the basic components and structure of a DSSC, which includes a titanium dioxide semiconductor, sensitizing dye, iodide redox mediator, platinum counter electrode, and glass support. The document explains that light absorption by the dye generates electron injection into the semiconductor to produce a current. Common dyes used include N3, N719, and various ruthenium-based dyes. Potential applications of DSSCs include use in buildings, agriculture, and domestic settings due to their low cost and environmental friendliness.
Dye-sensitized solar cells (DSSCs), also known as Gratzel cells, work by using a photo-sensitized dye to generate electricity from sunlight. DSSCs were invented in 1991 as a low-cost alternative to traditional silicon solar cells. In a DSSC, light absorption in a dye triggers electrons to inject into a semiconductor, usually titanium dioxide, where they are collected on an electrode. The electrons then travel through an external circuit to the counter electrode, producing electricity. The circuit is completed by an electrolyte that transports ions back to the dye to regenerate it. DSSCs have the potential for lower manufacturing costs than silicon cells and can be produced using solution-based processes on many different
This document presents information on dye-sensitized solar cells (DSSCs). It discusses that DSSCs are a type of thin-film solar cell composed of a semiconductor, dye, electrolyte, and counter electrode. DSSCs work by using a dye to absorb sunlight and inject electrons into a semiconductor, like titanium dioxide. The electrons then flow through an external circuit to the counter electrode, while the dye is regenerated by the electrolyte. Though DSSCs have lower efficiency than other thin film cells, they have a better price to performance ratio and do not require pure silicon. The maximum reported conversion efficiency of DSSCs is around 11-15%.
International Journal of Engineering Research and Development (IJERD)IJERD Editor
The document discusses a study that assessed the performance of window films in reducing solar heat gain in buildings in Kurdistan, Iraq. A test wooden cabinet was constructed and measurements were taken over 9 hours both with and without a window film installed. Results showed that the window film reduced maximum indoor temperatures by 10°C and blocked 50-97% of solar radiation depending on weather conditions. Calculations estimated that applying the window film reduced the solar heat gain of the cabinet by 477.15 Watts, with the largest reduction due to decreased light transmission through the windows. The study demonstrates that window films can effectively support environmental protection by lowering energy use for cooling in hot climates like Kurdistan.
Nowadays the concept of Net ZEB is well-known
and widespread in the scientific community. The European
Union has set ambitious targets for 2020 and even more
ambitious for 2050. In order to reduce the domestic GHG
emissions by 80-95%, compared to 1990 levels- till 2050, the
building sector has to do its part and to pass through a deep
restructure. Therefore, it is grown the interest in design and
technical solutions for achieving a zero or nearly zero energy
building. This paper investigate several construction technologies
and system of energy production that can be adopted to build an
“enhanced saving” (parsimonious) building, which can strive for
the objective of NetZEB. Moreover the economic analysis of the
feasibility of the NZEB target has been developed.
This document discusses using earthen pots and solar paneling on rooftops and walls to improve the energy efficiency of building envelopes. Installing earthen pots in the roof creates an insulating air cavity that reduces heat transfer, lowering cooling costs by 22-25%. Solar paneling on windows and outer walls further increases energy efficiency. While initial setup costs may be high, these modifications save on energy usage over the long term and pay for themselves within 15 years. Building envelope design aims to balance construction costs with required performance, and using earthen pots and transparent luminescent solar concentrators can significantly reduce heat loads and electricity costs in India.
The document summarizes the steps taken to optimize the façade of a mid-rise commercial building in Delhi to reduce its energy consumption. It describes analyzing the building's initial energy use, orientation, window-to-wall ratio, shading devices, fenestration, and wall and roof assemblies. Simulations showed that optimizing these elements could reduce the building's annual energy consumption by up to 47% and decrease its cooling load by 25%.
Pdlc film energy saving reports uniteglassUniteglass
In this study, the building energy reduction and daylight performance improvement effects of
remodeling old buildings using PDLC films were analyzed. The analysis results showed that both
remodeling methods using PDLC films were effective in terms of heating and cooling energy reduction
and daylight performance improvement.
Solar energy concentration techniques in flat plate collectorIAEME Publication
The document summarizes research on improving the efficiency of flat plate solar collectors through various concentration techniques. It discusses the limitations of conventional flat plate collectors and reviews studies that have incorporated things like twisted wire coils inside tubes, double glazing, selective coatings including nanoparticles, and optical lenses to increase absorption. Experimental results showed efficiency increases ranging from 5% to 15% compared to standard flat plate collectors without these enhancements. The review concludes that ongoing developments aim to make flat plate collectors more compact and effective through improved materials and designs.
Solar energy concentration techniques in flat plate collectorIAEME Publication
The document summarizes research on improving the efficiency of flat plate solar collectors through various concentration techniques. It discusses the limitations of conventional flat plate collectors and reviews studies that have incorporated things like twisted wire coils inside tubes, double glazing, selective coatings including nanoparticles, and optical lenses to increase absorption. Experimental results showed efficiency increases ranging from 5% to 15% compared to standard flat plate collectors without these enhancements. The review concludes that ongoing developments aim to make flat plate collectors more compact and effective through improved materials and designs.
This document summarizes a student group's progress defense presentation on their research developing nano-structured transparent contacts for dye sensitized solar cells. The group reports on their goals of analyzing photon absorption characteristics and enhancing efficiency. Their experimental design involves modeling amorphous silicon layers in a solar cell. Simulation results so far are presented. The group's timeline shows further analysis planned through the end of the year, culminating in a final defense. References cited research on TiO2 anodes, organic sensitizers, and carbon nanotube photoanodes to enhance dye sensitized solar cell efficiency.
The document discusses several methods to reduce operational energy in buildings, including:
1. Using energy efficient building envelopes with high insulation to control air, water, and heat flow. This includes roofs, walls, foundations, and thermal barriers.
2. Considering the solar heat gain coefficient and U-values of facade materials like windows to reduce unwanted solar heat gain and heat loss.
3. Implementing efficient lighting technologies, energy efficient appliances, renewable energy sources, and energy monitoring systems to reduce overall energy usage.
This research investigates the vitality advantages and future capability of using Electrochromic Glazing (ECG) System in sustainable courtyards in residential buildings inside the climatic states of the Amman city at the concept stage.This research considers the applied methodology to improve sustainability of courtyard, considering solar irradiation and buildings energy needs for cooling and heating.The Revit “energy modeling software” programming is utilized to evaluate the energy efficiency, chiefly the decreases in lighting,”heating, ventilating, and air conditioning” (HVAC), for various states and contrast that to the regular glassThe study findings show that adding ECG system to courtyard reduces the energy consumption, therefore the building saves 25 % of the energy in clear state, and when the system is tinted, it saves 57,5% of the energy, this applies to the summer season. While in the case of winter, the ECG system is efficient in energy consumption with heating, the building saves 80% of energy consumption, which reduces the cost. The study concludes that the number of years needed to recover the price of ECG system is 7.8 years which means that the courtyard is a sustainable solution in residential design according to Revit Program and Enterprise Green Communities (EGC) standard
(1) Solar irradiance is the power per unit area received from the sun and is measured in watts per square meter. It affects the efficiency of solar collectors.
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Model of optical and perfomance of tungsten based electrocromic windows including their intermediate states, lim Isidorsson et al, 2012
1. Modeling of optical and energy performance of tungsten-oxide-based
electrochromic windows including their intermediate states
Sunnie H.N. Lim a
, Jan Isidorsson b
, Lizhong Sun b
, B. Leo Kwak b
, Andre´ Anders a,n
a
Lawrence Berkeley National Laboratory, Berkeley, CA, USA
b
Applied Materials Inc., Santa Clara, CA, USA
a r t i c l e i n f o
Article history:
Received 5 March 2012
Received in revised form
31 August 2012
Accepted 7 September 2012
Available online 16 October 2012
Keywords:
Electrochromic windows
Smart windows
Energy simulation
Energy efficient window modeling
a b s t r a c t
Tungsten-oxide-based electrochromic (EC) windows are currently the most robust and matured
dynamic windows where the transmittance of visual light and near-infrared radiation can be controlled
by a small applied voltage. In its standard application, the window is commonly either in its clear or
colored state. In this contribution, we study the optical and energy performance of such window in the
fully bleached and fully colored state as well as when it is kept in intermediate states. Different
configurations in terms of placement of the EC layer stack and possible additional low-emissivity
(low-E) coating within the insulated glass unit are considered. Using optical data and software tools we
find that even a small coloration has a significant effect on the energy performance because the solar
heat gain coefficient is readily reduced by the absorption of the EC layer stack. We compare the
performance of the EC windows to commercially available solar-control (spectrally selective) low-E
windows.
& 2012 Elsevier B.V. All rights reserved.
1. Introduction
The 2010 United Nations Environment Programme Annual
Report stated that buildings consume more than one-third of the
global energy [1]. Over the past decades, increasing attention has
been given to the reduction of energy consumption in residential
and commercial buildings. Windows are a critical component of the
building envelope which can greatly improve energy efficiency of
buildings. Windows should provide usable daylight and comfort to
occupants. This implies that means are implemented which deal
with discomforting glare while optimizing the use of daylight for
lighting purposes. This could be done, for example, by shutters,
blinds, or the later–discussed chromogenic window solutions. A
window is expected to provide visual contact to the outside, which
affects the type of window and shading device selected. For best
thermal insulation, heat transfer through the window should be
minimized, or better yet, controlled depending on environmental,
occupational and other conditions. Reducing heat transfer is gen-
erally advantageous in both summer and winter conditions. One
needs to reduce the solar heat entering the building under cooling
conditions in summer. In winter, heat loss to the outside needs to
be reduced. Those heat transfers involve very different parts of the
electromagnetic spectrum, and require detailed consideration of the
visible wavelength (380–780 nm), solar infrared (780–2500 nm),
and near-room-temperature infrared (3–50 mm) radiations.
The two main measures of energy performance for windows
are the U-factor and the Solar Heat Gain Coefficient (SHGC).
The U-factor can be a measure of the heat transfer for either the
complete window, including glass and framing components, or for
the center-of-glass. It expresses the energy transfer per time, area
and temperature difference between the inside and outside of a
building, hence the unit W/(m2
K). The U-factor describes the
thermal insulating property of the window and is inversely propor-
tional to the R-value, a common measure of thermal insulation in
buildings. The U-value does not consider direct sunlight. This is
accomplished by the SHGC, which is defined as the fraction of solar
radiation (incl. the re-radiated portion of the absorbed solar
radiation) which is transmitted through the window into the
building [2]. Therefore all window properties, including gas fill
and emittances of the glazing surfaces, will affect the SHGC. Besides
energy performance in terms of U-value and SHGC, transmittance in
the visible part of the solar spectrum is important to daylight
illumination, reducing the need for artificial lighting, and to provide
the above-mentioned visual contact to the outside world.
Since the late 1970s, the glass coating industry has invested
huge efforts in improving the energy performance of windows [3],
leading to insulated glass units (IGU) having at least two glass
panes. Usually one of the glass panes has a heat-reflecting coating,
also known as low-emissivity or ‘‘low-E’’ coating. Indeed, low-E
windows have become the standard for energy efficient window
Contents lists available at SciVerse ScienceDirect
journal homepage: www.elsevier.com/locate/solmat
Solar Energy Materials & Solar Cells
0927-0248/$ - see front matter & 2012 Elsevier B.V. All rights reserved.
http://dx.doi.org/10.1016/j.solmat.2012.09.010
n
Corresponding author.
E-mail address: aanders@lbl.gov (A. Anders).
Solar Energy Materials & Solar Cells 108 (2013) 129–135
2. technology, where the reduced emissivity is based on the pre-
sence of a transparent conducting layer. There is a direct relation-
ship which shows that decreasing the sheet resistance of the
coating decreases the emissivity of the surface [3]. Low emissivity
can be achieved by coating glass with transparent conducting
oxides such as SnO:F (a.k.a. FTO) or In2O3:SnO2 (a.k.a. ITO), for
example. However, a superior low-E coating is achieved by
sandwiching an ultrathin layer of metal, typically silver, between
two or more transparent, antireflecting thin film layers. Layer
systems with two or even three silver layers have been designed
and are widely used to not only block the near-room-temperature
infrared radiation but also a good portion of the solar infrared,
leading to products known as spectrally selective low-E, ‘‘double-
silver’’, ‘‘triple-silver’’, or low-solar-gain low-E [4,5].
Low-E is a mature, ‘‘static’’ window technology that does not
adapt to changing environmental conditions like the time of the
day, weather conditions, or seasonal changes. Recently, dynamic,
switchable windows emerged in the market [6]. The most devel-
oped and tested technology is based on electrochromic (EC)
material systems. They have the ability to change transmittance
and reflectance when a low voltage (typically 1.5–3 V) is applied
across the transparent electrodes of the layer system (Fig. 1),
thereby affecting its optical and energy performance.
To-date, the most durable and thus commercially viable EC
material is tungsten oxide which can be switched by the inter-
calation of small ions such as hydrogen (protons), lithium or
sodium ions, where lithium is preferred for performance and
stability reasons [6,7]. One can control the transmittance of the
visible and infrared radiation flowing in and out of the building by
adjusting the small voltage applied across the multilayer system.
The electrochromic properties of tungsten oxides have been
extensively studied [6,8,9]. Practically all of the studies have been
limited to the fully bleached and fully colored states. Very little
has been reported on the intermediate states and in particular on
the correlation between the intercalated ion density in the
switching layers and their optical and thermal properties, which
may be attributed to the difficulty of experimental studies.
An alternative approach to assess the optical and energy
performance of EC windows is to adopt modeling tools, such as
that demonstrated in recent publications by Nilsson and Roos
[10], and Jonsson and Roos [11]. Nilsson et al. used WinSel, a
window energy simulation tool developed at Uppsala University
[12] to demonstrate how optical and thermal properties of
windows (including coatings) can be used to evaluate the energy
performance in a specific building under specific climate condi-
tions. Also using WinSel, Jonsson studied different window glaz-
ing combinations with and without electrochromic coatings in
their clear and tinted states [11].
In this paper, we demonstrate a similar methodology for
modeling and assessing the optical and thermal performance of
tungsten-oxide-based electrochromic windows including the
intermediate states. Intermediate states are important as future
EC windows are likely to offer not only fully bleached or fully
tinted states as consumers may prefer partially tinted states for
comfort reasons. We will discuss the coloration response for
different thicknesses of the counter electrode (i.e. for different
lithium ion reservoirs). We will compare optical properties and
energy performance of EC windows in specific intermediate states
with those of commercially available solar-control low-E win-
dows. Finally, we will explore the energy performance of a hybrid
window that is comprised of an EC-IGU and an additional low-E
coating. Our modeling is designed to better utilize the advantages
and potential offered by EC window technology.
2. Simulation
2.1. Approach
The simulation was performed in two stages. In the first stage,
we used TFCalc 3.5.14 [13] to obtain the transmittance and
reflectance from the front and back surfaces of glass coated with
the layer system of interest as a function of wavelength. This was
done by defining the multilayer thin film structure of an electro-
chromic device and using the refractive indices of the constituent
layers. As shown in Fig. 1, the structure consisted of a glass pane
with an indium tin oxide (ITO) bottom electrode (thickness
200 nm), a LiNiO2 counter electrode (150 nm), a lithium phos-
phorus oxynitride (LiPON) ion conductor (1500 nm), the WO3
electrochromic layer (483 nm) and finally an ITO top electrode
(200 nm). LiPON is a solid electrolyte commonly used in thin film
batteries and related technologies [14,15]. The justification for the
thicknesses of the WO3 and LiNiO2 will be given in Section 2.2. In
TFCalc, the illuminating source is the standard solar spectrum
irradiance air mass 1.5 [16], and the incidence of light was normal
to the surface of the glass.
The refractive indices of seven intermediate states for WO3 and
LiNiO2 were taken from the publications by von Rottkay and Rubin
[17,18], and the refractive indices of ITO from the Lawrence Berkeley
National Lab website [19]. Since the refractive indices of LiPON were
not available in the form of published data, a film of LiPON was
deposited using RF sputtering at 13.56 MHz using a Li3PO4 target
(99.99%) in nitrogen atmosphere. We measured the n&k components
of the refractive index using a Woolam M2000 ellipsometer. For
reasons of practicality we used the optical data determined for
normal incidence light although it is understood that the angle of
incidence of solar radiation changes with time of day and season.
In the second stage of simulation, the transmittances and reflec-
tances of the seven intermediate states were used as input data for
the Optics 5 and Window 6.3.26 [20] software packages. From Optics
5 we obtained the CIE color coordinates describing the window tint in
transmission as seen from the inside. In Window 6.3.26, a dual-pane
electrochromic insulated glass unit (IGU) was modeled in terms of U-
value and SHGC. The IGU is assumed to consist of an electrochromic
coated glass pane and a 3 mm thick second glass pane separated by
Fig. 1. Schematic of the electrochromic setup used in TFCalc and Window 6.3.26
simulations.
S.H.N. Lim et al. / Solar Energy Materials & Solar Cells 108 (2013) 129–135130
3. a 12.7 mm argon-filled gap as shown in Fig. 1. The EC coating stack
was placed on surface 2 (by convention, surfaces are counted from
the outside). Effects of the frame are neglected, i.e., we considered
only the center-of-glass properties. Standard environmental condi-
tions were used for the SHGC calculations as defined in standard
NFRC 100-2010, which sets the inside temperature to 24 1C and the
outside air temperature to 32 1C, with a wind speed of 2.8 m/s. The
emissivity of the ITO layer was assumed to be 0.15, which is
reasonable based on literature data [21,22].
2.2. Charge and film thickness matching of the electrochromic layers
In this work we made the following assumptions:
1 In the fully bleached state, all mobile lithium ions are in the
LiNiO2 layer. When the window is fully tinted, all Li ions are in
the WO3 layer. Lithium in the LiPON is assumed to be constant
and does not contribute to the switching state.
2 The total amount of mobile lithium will stay constant during the
switching process. That is, mobile lithium ions will not undergo
an irreversible chemical change or otherwise become immobile.
3 The window is large and the frame is well-insulating, thus the
frame does not play an important role for the energy analysis.
Therefore the simulation of thermal properties can be limited
to the center-of-glass U-factor.
The switching state is determined by the localization of lithium
within the layer stack. Changes of the mobile lithium ions localiza-
tion within the stack can be expressed as volumetric charge density
changes of lithium. The charge densities can be related to the film
thicknesses of WO3 and LiNiO2 because the extinction coefficient for
a given injected charge does not depend on thickness or mass
density of the host layer but just on the injected lithium charge [17].
For LiNiO2 the volumetric charge density of lithium in its fully
clear state is 219 mC/(cm2
mm) [18]. At a fixed thickness of
150 nm, we can calculate the lithium areal charge density to be
32.85 mC/cm2
. From the two assumptions above, we require that
the same amount of charge to be present in WO3 when the
system is in its fully tinted state. Knowing that the volumetric
charge density for a fully tinted WO3 is 68 mC/(cm2
mm) [18], we
calculate the appropriate thickness of WO3 to be 483 nm.
We have selected our intermediate states to be the same as the
measured intermediate states for LiNiO2 given in [18]. The matching
refractive indices n&k of WO3 are then interpolated from the data in
[17] to ensure that the charge density of the WO3 and LiNiO2 layers
preserves the total lithium ion content. Table 1 shows a summary of
the lithium charge matching of the intermediate states of the two
host layers. As mentioned before, the lithium concentration in the
LiPON ion conductor remains constant during the switching process
and therefore does not need to be further considered.
3. Results
3.1. Transmittance and solar heat gain coefficient
Fig. 2 shows a plot of the solar transmittance as a function of
wavelength of the intermediate states. In its fully clear state
(0 mC/cm2
in WO3), the average transmittance in the visible
region is approximately 64%. The average visible transmittance
is defined between 380 nm and 780 nm, and it is weighted to the
photopic response of the human eye [23]. It is important to note
that the transmittance decreases substantially with the first
injection of lithium ions. For example, with a lithium ion density
of only 6.75 mC/cm2
in WO3, the maximum transmittance is
already reduced to 25% in the visible region. Further intercalation
of lithium into the WO3 layer results in further but less dramatic
decrease of the transmittance. The noticeable fringes, which are
very discernible in the infrared, arise from interference caused by
reflection at the multiple interfaces within the thin film stack.
Fig. 3 shows a plot of the SHGC and the solar and visible
transmittances as a function of lithium concentration in the WO3
layer (bottom axis) and in the LiNiO2 layer (top axis).
An important feature is that the changes in the transmittance and
SHGC with the intercalation of lithium ions are nonlinear. Inter-
calating the electrochromic WO3 layer with 6.75 mC/cm2
of lithium
ions resulted in more than 50% decrease in the SHGC. However,
only a relatively small change in the SHGC is seen when the Li
concentration is further increased from 20.0 mC/cm2
to 32.9 mC/
cm2
. We include both visible (Tvis) and solar (Tsol) transmittance to
Fig. 2. A plot of the visible transmittance as a function of wavelength for the
intermediate states.
Table 1
A summary of the Li charge density matching of the intermediate states of the electrochromic and counter electrode layers.
State LiNiO2 WO3
Li volumetric charge
density
Li areal charge density for
150 nm thick film
Li volumetric
charge density
Li areal charge density for
483 nm thick film
(mC/(cm2
mm)) (mC/cm2
) (mC/(cm2
mm)) (mC/cm2
)
Clear 219 32.9 0 0
174 26.1 14 6.75
120 18 31 14.85
85.2 12.8 42 20.07
64.6 9.7 48 23.16
52.2 7.8 52 25.02
Dark 0 0 68 32.85
S.H.N. Lim et al. / Solar Energy Materials & Solar Cells 108 (2013) 129–135 131
4. account for both the visual appearance and the energy performance
of the EC window. The standard solar spectra air-mass 1.5 was used
to determine the solar transmittance in the wavelength range from
300 nm to 2500 nm [23]. Both Tvis and Tsol display the same
nonlinear decrease as the amount of lithium increases in the
WO3 layer.
3.2. Coloration
Coordinates corresponding to the color space chromaticity
diagram for both transmission and reflection for the intermediate
states can be obtained from Optics 5 simulations. The color at
various tinted states is an important factor in how EC windows are
accepted by consumers. The appearance of the window from the
outside is dictated by the color in reflection while the color of
transmitted light is important to occupants inside the building. In
Fig. 4(a) we indicate how the coloration changes in both reflection
(R) and transmission (T) as the window darkens. In the clear state,
the color is relatively neutral. It shifts towards blue as the window
is tinted, which is typical for tungsten-oxide-based EC systems.
We explored the idea of maintaining a more neutral coloration
in the tinted state by increasing the thickness of the LiNiO2 layer.
The amount of mobile lithium is kept constant at 32.84 mC/cm2
,
which was the value previously considered for fully charged WO3
of thickness of 483 nm. When a thicker LiNiO2 is selected, it is still
charged to its maximum volumetric charge of Qfull ¼219 mC/
(cm2
mm) in its clear state but the lithium is not fully unloaded
in its tinted state. A color shift toward a more neutral appearance
is therefore obtained at the expense of reduction in the maximum
transmittance in the clear state. Using the data again for partially
lithiated nickel oxide [18] we can determine the layer thickness
necessary to maintain the same amount of lithium in LiNiO2 using
a simple proportional ratio:
sthick ¼ sfull
Qf ull
Qf ullÀQext
ð1Þ
where Qext is the lithium charge that has been extracted from a fully
charged LiNiO2 to obtain the volumetric charge density of the
partially charged LiNiO2 of interest. The result is shown in Table 2.
Fig. 4(b) shows the change in coloration when the thickness of
LiNiO2 is increased while a constant thickness of WO3 is main-
tained. The coloration in both reflection and transmission tends be
Fig. 3. A plot of the SHGC and both the solar and visible transmittance as a
function of the Li concentration in the WO3 layer (bottom axis) and the LiNiO2
layer (top axis). The solid lines are for visual aid purpose.
Fig. 4. (a) The change in the coloration of the electrochromic window tints in both
transmission (T) and reflection (R). In its clear state, the window remains color-
neutral. It shifts towards blue as it darkens. (b) Adjusting the thickness of the
LiNiO2, the blue coloration in the tinted state can be shifted to a more neutral
color. (For interpretation of the references to color in this figure legend, the reader
is referred to the web version of this article.)
Table 2
Variation of the thickness in LiNiO2 to ensure that an areal lithium charge
density of 32.84 mC/cm2
is maintained.
LiNiO2
Li volumetric charge
density (mC/(cm2
mm))
Thickness to accommodate
the charge (nm)
220 150
167 197
154 213
134 245
100 332
45 730
S.H.N. Lim et al. / Solar Energy Materials & Solar Cells 108 (2013) 129–135132
5. more neutral with thicker LiNiO2, i.e. away from the previously
observed blue shift. However, we stress that this advantage is
obtained at the expense of a reduction of the maximum transmit-
tance in the clear state.
3.3. Comparison with conventional low-E coatings
We compare the results of the simulated electrochromic
window with two examples of spectrally selective silver-based
low-E windows which are readily commercially available.
The first example is the LoE2
272 manufactured by Cardinal Glass
Industries, and the second ClimaGuard 63/31 LE from Guardian.
Both these windows use 3 mm glass and the coating is on surface
#2. The emissivities for the two example windows are 0.042 (LoE2
272 ) and 0.026 (ClimaGuard 63/31 LE). Further specifications for
these windows can be found in the database ‘‘Library of Glass’’
found in the LBNL Window software [20]. In each case, the low-E
coating was placed on surface #2 of the IGU since this has the
greatest energy benefit. The simulation parameters such as
environmental conditions were kept the same to ensure that a
comparison is valid. The results are shown in Table 3. The silver-
based low-E window #1 has the highest transmittance and both
low-E windows show a lower U-value compared to the EC
windows. The low-E windows have a lower SHGC when compared
to the clear state of the EC window. However, as the EC window
darkens, its SHGC decreases and can become lower than the
SHGCs of the low-E windows. In Table 3, we also show the light-
to-solar gain ratio (LSG). The higher the ratio, the greater the
spectral selectivity, a characteristic desired for glazing systems in
hot climate conditions. For the EC system, the LSG ratio is high in
its clear state, and drops rapidly as the windows darkens. Both
low-E systems show a high LSG ratio indicating that they are well
suited for hot climate locations.
3.4. Considerations for an EC/low-E hybrid window
The EC layer stack intrinsically has low-E properties due to the
conducting transparent oxide electrode on top of the layer stack.
However, one may consider the benefits of having an additional,
silver-based low-E coating on surface #3 of the IGU. We call this an
EC/low-E hybrid window. We thus should compare an EC window
(with its intrinsic low-E property), with a traditional silver-based
low-E window, and an EC/low-E hybrid window. In the simulation,
the Cardinal Glass — LoE2
272 was used as the low-E window.
The results from the previous section show that there are
advantages of having traditional silver-based low-E windows due
to the achievable very low U-value. However, when the EC window
is darkened, it can achieve a very low SHGC, which is advantageous
under sunny conditions.
To evaluate the potential benefit of an additional low-E coating on
surface 3, one needs to define environmental conditions of interest.
For this, we have used the NFRC 100-2010 environmental conditions
as specified in the software, and the temperature of the glass surfaces
based on the defined indoor and outdoor temperatures for summer
and winter seasons. The two surfaces of each glass pane have
practically the same temperature due to the relatively high heat
conductivity of glass, i.e., it is sufficient to only show the temperature
of one surface for each pane. In Fig. 5, the temperatures of the two
glass panes for the EC/low-E hybrid window are depicted with
squares (&, ’). This is compared with the temperatures of the glass
panes to the conventional EC windows depicted with circles (J, K),
with the EC layer stack placed on surface #2.
In Fig. 5(a), when the EC coating is on surface #2 and the low-E
coating is on surface #3, the temperature of the outer pane
increases when the EC layer stack darkens and increasingly
Fig. 5. (a) The temperature of the inner (&) and outer (’) glass pane for a hybrid
window where the EC is on surface #2 and low-E on surface #3. This is compared
to a conventional EC windows where the EC layer is placed on surface #2 (J, K),
(b) The temperature of the inner (&) and outer (’) glass pane for a hybrid
window with low-E on surface #2 and EC on surface #3. This is compared to a
conventional EC window where the EC layer is placed on surface #2 (J, K).
Table 3
Comparison of the optical and energy performances of the electrochromic window
at various states and two commercially available silver-based low-E windows. EC
refers to electrochromic and the value inside the parentheses refers to the Li
volumetric charge density in WO3.
Window Tvis
(%)
Tsol
(%)
SHGC U-factor
(W/
m2
K)
LSG
(Tvis/
SHGC)
EC (0) 64 36 0.43 1.62 1.49
EC (14) 25 12.7 0.20 1.62 1.25
EC (31) 8 4.5 0.12 1.62 0.67
EC (42) 5 2.3 0.10 1.62 0.50
EC (48) 3 1.3 0.09 1.62 0.33
EC (52) 2 1 0.09 1.62 0.22
EC (68) 1 0.5 0.08 1.62 0.13
Cardinal Glass Industries — LoE2
272 72 37.7 0.41 1.39 1.76
Guardian — ClimaGuard 63/31 LE 63 28.3 0.31 1.35 2.03
S.H.N. Lim et al. / Solar Energy Materials & Solar Cells 108 (2013) 129–135 133
6. absorbs solar radiation. The temperature on surface #1 in the
hybrid window (&) is comparable to the case of a traditional EC
window with the EC stack on surface #2 (J). The temperature of
surface #3 is approximately 32 1C independent of the tinting state
for the case of the hybrid window (’). The traditional EC
configuration assumes a surface #3 temperature of approximately
34 1C (K), which is slightly higher than the comparable tempera-
ture for the hybrid EC/low-E window.
For the sake of comparison, and not necessarily for practical
use, we include the case when the order of the low-E and EC
layers in a hybrid EC/low-E window is reversed, i.e. when the low-
E and EC coatings are applied on surfaces #2 and #3, respectively.
Fig. 5(b) shows the temperatures of surfaces #1 and #3 in this
configuration. The temperature of surface #3 is increasing with
the tint of the EC layer due to absorption of solar radiation. In its
darkest state, the temperature of the inner pane of the IGU is
substantially higher than the temperature of surface #1 (outer
pane). This case is usually not desirable since it would lead to
much increased cooling loads in warm climates.
4. Discussion
The visible transmittance for a low-E coating is generally higher
than the transmittance of an electrochromic window in its clear
state. In low-E windows, ultrathin silver is used, since silver exhibits
the lowest absorption of visible light of all metals while having very
good conductivity, hence low emissivity. The reflection in the visible,
usually associated with metals, is suppressed by the use of anti-
reflecting layers. The EC layer stack, in contrast, is comprised of
relatively thick, slightly absorbing oxide and oxynitride layers. The
total layer stack in our example is quite thick, leading to relatively
low transmittance even in the clear state. The total thickness of the
device can be reduced substantially, as 1% transmission in the dark
state may be lower than needed. A few percent higher transmittance
in the dark state would allow for a thinner device, and hence also
higher transmittance in the clear state without compromising the
SHGC. For commercial building applications, a lower limit of visual
transmittance of about 60% in the clear state is considered accep-
table, although some enhancements are possible by implementing
antireflection coatings to EC windows [24]. Attention is often given
to the lower bound of transmittance since it determines the lower
limit of the SHGC and the suppression of glare, which, when
insufficiently addressed, requires the presence of curtains, blinds
or other kinds of shading devices. In intermediate states, as they
may be desired by consumers, glare is suppressed but building
occupants may still desire to use additional shading options.
The results show that even a slight coloration of the EC
window reduces the SHGC compared to the two commercial
low-E windows. Such reduction can be quite desirable from an
energy performance point of view.
The U-factor includes heat transfer by conduction, convection,
and thermal radiation (but excludes solar radiation, as mentioned
in Section 1 and is defined as
U ¼
QA
DT
ð2Þ
where QA is the thermal energy transfer per unit area and time,
and DT is the difference in temperature between the outside and
inside. The software Window 6.3.26 deals with radiated heat
transfer using the Stefan–Boltzmann law for the case of a grey
body radiation:
QA ¼ esT4
ð3Þ
where e is the emissivity, s is the Stefan–Boltzmann constant
(5.67 Â 10À8
W mÀ2
KÀ4
) and T is the absolute temperature in
Kelvin. This equation is used for each surface with its own
temperature and emissivity. Since the emissivity of a silver-
based coating is smaller than the emissivity of a transparent
conducting oxide, it is clear that the intrinsic low-E property of a
traditional EC stack is unaffected by the switching and will not be
as good as the silver-based low-E coating. The simulation shows
that the additional benefit of a silver-based low-E coating on
surface 3 affects the temperature of the inner glass pane only
marginally, and therefore the cost for such additional low-E
coating may not be economically justified.
The idea of adding a low-E coating to a conventional EC
window was recently discussed by Jonsson and Roos [11] who
investigated the energy balance using EC window with different
types of low-E coatings (silver based, transparent conducting
oxide, and solar selective). Here we extend the study of the
hybrid system and consider the differences in the energy perfor-
mance when we reverse the order of the two coatings that are
applied. Due to the absorbing nature of EC in its tinted state, there
is a great difference in performance as to on which surfaces the
low-E and EC stack should be placed.
Fig. 5(a) shows that when placing the EC on surface #2, a
significant amount of heat is absorbed on the outer pane causing
the increase in its temperature while the inner pane remains
relatively cool. This configuration allows the low-E coating on
surface #3 to reflect the absorbed heat (coming from the EC when
tinted). The situation is very different when the low-E coating is
placed on surface #2 and the EC is on surface #3 (Fig. 5b). In this
configuration, although the temperature of the outer glass pane is
substantially lower compared to the previous configuration, the
inner pane is excessively heated in its tinted state as the EC
absorbs solar radiation. In the summer when the building is
typically cooled, this extra heat load would require addition
cooling, i.e. such window would have a very negative effect on
energy efficiency.
Fig. 6 shows the SHGC of a single EC on surface #2 and both
configurations of the hybrid window as a function of the Li
concentration in WO3. Clearly, in the EC/low-E hybrid system,
with the EC is on surface #3 and low-E on #2, the SHGC is higher
and actually makes cooling requirement much worse compared
to the single EC placed on surface #2. There is a small beneficial
reduction of the SHGC when using a hybrid window (EC on
surface #2; low-E on surface #3). The slight decrease in the SHGC
may not be worthwhile the cost of the additional layer. In the
Fig. 6. A comparison of the SHGC for an IGU with an EC layer stack on surface #2
(’), and the two hybrid window configurations of Fig. 5(a) (m) and (b) (K).
S.H.N. Lim et al. / Solar Energy Materials & Solar Cells 108 (2013) 129–135134
7. unusual case where the low-E is placed on surface #2 and the EC
layer system is on surface #3, the SHGC is much higher, which is
under most circumstances undesirable.
5. Conclusions
In this contribution, we used published optical data and
software tools to assess the optical and energy performances of
the intermediate states of a tungsten-oxide based electrochromic
window. The results show that even with a small amount of
coloration by lithium intercalation in WO3, there is a substantial
change in the energy performance due to a significant decrease in
the SHGC. We also investigated the possibility of a hybrid window
by placing EC and low-E coatings on different surfaces. Our result
shows that there is little additional benefit for a configuration
where the EC layer stack on surface #2 is complemented with a
low-E coating on surface #3. Reversing the order of EC and low-E
coatings implies raising the SHGC to undesirably high levels.
Disclaimer
This report was prepared as an account of work sponsored by
an agency of the United States Government. Neither the United
States Government nor any agency thereof, nor any of their
employees, makes any warranty, express or implied, or assumes
any legal liability or responsibility for the accuracy, completeness,
or usefulness of any information, apparatus, product, or process
disclosed, or represents that its use would not infringe privately
owned rights. Reference herein to any specific commercial pro-
duct, process, or service by trade name, trademark, manufacturer,
or otherwise does not necessarily constitute or imply its endorse-
ment, recommendation, or favoring by the United States Govern-
ment or any agency thereof. The views and opinions of authors
expressed herein do not necessarily state or reflect those of the
United States Government or any agency thereof.
Acknowledgments
We thank Steve Selkowitz, Christian Kohler, and Rueben
Mendelsberg (all LBNL) for insightful discussions. This work was
supported by the Assistant Secretary for Energy Efficiency and
Renewable Energy, Office of Building Technology, of the US
Department of Energy under Contract no. DE-AC02-05CH11231,
and by the American Reconstruction and Reinvestment Act, under
Contract DE-EE0003838.
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