The document provides steps to calculate the number of moles of liquid water needed to freeze and remove 100 kJ of heat. It first converts the heat given in kJ to joules. Using the heat of fusion value of 334 J/g, it calculates the grams of ice formed, and then the number of moles of water needed using the molar mass of water. The calculation determines that 16.6 moles of liquid water are needed to freeze and remove 100 kJ of heat.