Dear aspirants,
This presentation includes basic terms of crystallography, a brief note on unit cell and its type With derivation of its properties: APF, Coordination no., No. of atoms per unit cell and also its atomic radius. I also added 7 Crystal System, Bravais Lattice and finally Miller Indices concept.
Hope this presentation is helpful.
Any questions or clarifications are welcomed.
Crystal Material, Non-Crystalline Material, Crystal Structure, Space Lattice, Unit Cell, Crystal Systems, and Bravais Lattices, Simple Cubic Lattice, Body-Centered Cubic Structure, Face centered cubic structure, No of Atoms per Unit Cell, Atomic Radius, Atomic Packing Factor, Coordination Number, Crystal Defects, Point Defects, Line Defects, Planar Defects, Volume Defects.
Dear aspirants,
This presentation includes basic terms of crystallography, a brief note on unit cell and its type With derivation of its properties: APF, Coordination no., No. of atoms per unit cell and also its atomic radius. I also added 7 Crystal System, Bravais Lattice and finally Miller Indices concept.
Hope this presentation is helpful.
Any questions or clarifications are welcomed.
Crystal Material, Non-Crystalline Material, Crystal Structure, Space Lattice, Unit Cell, Crystal Systems, and Bravais Lattices, Simple Cubic Lattice, Body-Centered Cubic Structure, Face centered cubic structure, No of Atoms per Unit Cell, Atomic Radius, Atomic Packing Factor, Coordination Number, Crystal Defects, Point Defects, Line Defects, Planar Defects, Volume Defects.
Water scarcity is the lack of fresh water resources to meet the standard water demand. There are two type of water scarcity. One is physical. The other is economic water scarcity.
Overview of the fundamental roles in Hydropower generation and the components involved in wider Electrical Engineering.
This paper presents the design and construction of hydroelectric dams from the hydrologist’s survey of the valley before construction, all aspects and involved disciplines, fluid dynamics, structural engineering, generation and mains frequency regulation to the very transmission of power through the network in the United Kingdom.
Author: Robbie Edward Sayers
Collaborators and co editors: Charlie Sims and Connor Healey.
(C) 2024 Robbie E. Sayers
Welcome to WIPAC Monthly the magazine brought to you by the LinkedIn Group Water Industry Process Automation & Control.
In this month's edition, along with this month's industry news to celebrate the 13 years since the group was created we have articles including
A case study of the used of Advanced Process Control at the Wastewater Treatment works at Lleida in Spain
A look back on an article on smart wastewater networks in order to see how the industry has measured up in the interim around the adoption of Digital Transformation in the Water Industry.
Final project report on grocery store management system..pdfKamal Acharya
In today’s fast-changing business environment, it’s extremely important to be able to respond to client needs in the most effective and timely manner. If your customers wish to see your business online and have instant access to your products or services.
Online Grocery Store is an e-commerce website, which retails various grocery products. This project allows viewing various products available enables registered users to purchase desired products instantly using Paytm, UPI payment processor (Instant Pay) and also can place order by using Cash on Delivery (Pay Later) option. This project provides an easy access to Administrators and Managers to view orders placed using Pay Later and Instant Pay options.
In order to develop an e-commerce website, a number of Technologies must be studied and understood. These include multi-tiered architecture, server and client-side scripting techniques, implementation technologies, programming language (such as PHP, HTML, CSS, JavaScript) and MySQL relational databases. This is a project with the objective to develop a basic website where a consumer is provided with a shopping cart website and also to know about the technologies used to develop such a website.
This document will discuss each of the underlying technologies to create and implement an e- commerce website.
Saudi Arabia stands as a titan in the global energy landscape, renowned for its abundant oil and gas resources. It's the largest exporter of petroleum and holds some of the world's most significant reserves. Let's delve into the top 10 oil and gas projects shaping Saudi Arabia's energy future in 2024.
Explore the innovative world of trenchless pipe repair with our comprehensive guide, "The Benefits and Techniques of Trenchless Pipe Repair." This document delves into the modern methods of repairing underground pipes without the need for extensive excavation, highlighting the numerous advantages and the latest techniques used in the industry.
Learn about the cost savings, reduced environmental impact, and minimal disruption associated with trenchless technology. Discover detailed explanations of popular techniques such as pipe bursting, cured-in-place pipe (CIPP) lining, and directional drilling. Understand how these methods can be applied to various types of infrastructure, from residential plumbing to large-scale municipal systems.
Ideal for homeowners, contractors, engineers, and anyone interested in modern plumbing solutions, this guide provides valuable insights into why trenchless pipe repair is becoming the preferred choice for pipe rehabilitation. Stay informed about the latest advancements and best practices in the field.
Student information management system project report ii.pdfKamal Acharya
Our project explains about the student management. This project mainly explains the various actions related to student details. This project shows some ease in adding, editing and deleting the student details. It also provides a less time consuming process for viewing, adding, editing and deleting the marks of the students.
2. 1
Crystalline materials...
• atoms pack in periodic, 3D
arrays -metals
-many
ceramics
-some
polymers
Noncrystalline materials...
• atoms have no periodic
packing -complex
structures
-rapid cooling
"Amorphous" =
Noncrystalline
noncrystalline
SiO2
Adapted from Fig. 3.22(b),
Callister 7e.
Materials and
Packing
S
i
crystalline SiO2
Adapted from Fig. 3.22(a),
Callister 7e.
Oxyge
n
• typical
of:
• occurs
for:
3. Lattice - An array of atoms arranged in a 3-D grid like pattern.
Unit cell - The smallest representative structural unit of lattice
that can describe the crystal structure. Repetition of the unit
cell generates the entire crystal.
Unit cells are stacked together endlessly to form the lattice (with
no empty
spaces between cells).
Crystal
Systems
9. 6
Metallic Crystal
Structures
• Tend to be densely packed.
• Reasons for dense packing:
-Typically, only one element is present (as in pure
metal), so all atomic radii are the identical. Alloy
contains another atomic species added to metal, but
the material still remains crystalline
We will examine ....
•Simple Cubic (SC)
•body-centered cubic (BCC)
•face-centered cubic (FCC)
•hexagonal close-packed (HCP).
10. 7
Simple Cubic Structure
(SC)
Crystal structure formed by
periodic
• Rare due to low packing denisty
• Close-packed directions are cube edges.
The coordination
number, CN = the
number of closest
neighbors to which
an atom is bonded
= number of
touching atoms
A simple cubic (SC) unit cell
(Courtesy P.M. Anderson)
Number of atoms per
unit cell, n = 1
8 corner atoms shared
by
eight cells: 8 x 1/8 = 1
11. 8
• APF for a simple cubic structure =
0.52
APF =
a 3
4
3
π
(0.5a)
3
1
atom
s
unit
cell
ato
m
volum
e
unit
cell
volum
e
Atomic Packing Factor
(APF)
APF =
Volume of atoms in unit
cell
Volume of unit cell
a
R=0.5
a
close-packed
directions contains
8 x 1/8 =
1 atom/unit
12. 9
Adapted from Fig.
3.2,
Callister 7e.
Body Centered Cubic Structure
(BCC)
• Atoms touch each other along cube diagonals.
--Note: All atoms are identical; the center atom is
shaded differently only for ease of viewing.
ex: Cr,W, Fe (α), Tantalum, Molybdenum
• Coordination # = 8
2 atoms/unit cell: 1 center + 8 corners x
1/8
A body-centred cubic (BCC) unit
cell (Courtesy P.M.
Anderson)
Crystal structure formed by
periodic
13. Atomic Packing Factor:
BCC
4
3
π ( 3 a/4 )
3
2
unit cell
APF =
ato
m
volum
e
a 3
unit
cell
volume
3
a
a
R
Adapted from
Fig. 3.2(a),
Callister 7e.
atoms
2 a
Close-packed
directions:
length = 4R =
• APF for a body-centered cubic structure = 0.68
3 a
a
14. Face Centered Cubic Structure
(FCC)
•Atoms touch each other along face diagonals.
--Note: All atoms are identical; the face-centered atoms are
shaded
differently only for ease of viewing.
ex: Al, Cu, Au, Pb, Ni,
Pt, Ag
• Coordination # = 12
A face-centred cubic (FCC) unit
cell (Courtesy P.M.
Anderson)
Adapted from Fig. 3.1, Callister 7e.
4 atoms/unit cell: 6 face x 1/2 + 8 corners
x 1/8
15. 12
Atomic Packing Factor:
FCC
• APF for a face-centered cubic structure = 0.74
maximum achievable
APF
4
π
( 2 a/4
3
)
3
4
atom
s
unit cell
APF =
atom
volum
e
a 3
unit
cell
volume
Close-packed
directions: length
= 4R =
2
a
Unit cell
contains: 6 x
1/2 + 8 x 1/8
= 4
atoms/unit cell
a
2
a
Adapted
from Fig.
3.1(a),
Callister 7e.
16. Hexagonal Close-Packed Crysta
Structure
• HCP is one more common structure of metallic crystals
• Six atoms form regular hexagon, surrounding one atom in c
Another plane is situated halfway up unit cell (c-axis),
additional atoms situated at interstices of hexagonal (close-p
planes
• Cd, Mg, Zn, Ti have this crystal structure
17. Hexagonal Close-Packed Crystal
Structure
• Unit cell has two lattice parameters a and c. Ideal ratio c/a = 1.633
• The coordination number, CN = 12 (same as in FCC)
• Number of atoms per unit cell, n = 6.
• 3 mid-plane atoms shared by no other cells: 3 x 1 = 3
• 12 hexagonal corner atoms shared by 6 cells: 12 x 1/6 = 2
• 2 top/bottom plane center atoms shared by 2 cells: 2 x 1/2 = 1
• Atomic packing factor, APF = 0.74 (same as in FCC)
• All atoms are equivalent
18. Principles of Atomic
Packing
Structures based on the square net
Simple cubic
Body centred cubic
Structures based on the close-packed net
Face centred cubic
Hexagonal close-packed
22. 17
A
sites
• FCC Unit
Cell
FCC Stacking
Sequence
B
B
B. site
s
C. site
s
• ABCABC... Stacking Sequence
• 2D Projection
B
C
C
B
C
B
A
B
C
23.
24. • Coordination # =
12
• APF = 0.74
Adapted from Fig.
3.3(a),
Callister 7e.
Hexagonal Close-Packed
Structure (HCP)
6 atoms/unit
cell
ex: Cd, Mg,Ti,
Zn
•c/a =
1.633
c
a
A
sites
Bottom
layer
B sites Middle layer
• ABAB... Stacking Sequence
• 3D Projection • 2D Projection
A sites Top layer
25.
26. VOIDS
Tetrahedral Octahedral OV
TV
Interstitial sites [Voids] in
crystals
❑ The size and distribution of voids in materials plays a role in determining aspects of
material behaviour
❑ Tetrahedral: 4 atoms surround the hole
❑ Octahedral: 6 atoms surround the hole
❑ Cubic : 8 atoms surround the hole