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Isotopes
atoms of a given element that
differ in the number of neutrons
…and consequently in mass.
Working with Atomic Notation
A
zX
Atomic Number
Chemical Symbol
Atomic Mass
(of Isotope)
Example #1
12
6C
Atomic Number
Chemical Symbol
Atomic Mass
(of Isotope)
Example #2
13
6C
Atomic Number
Chemical Symbol
Atomic Mass
(of Isotope)
Example #3
14
6C
Atomic Number
Chemical Symbol
Atomic Mass
(of Isotope)
Some isotopes of carbon
12
6C 13
6C 14
6C
10
Ne
Neon
20.1797
3
Li
Lithium
6.941
47
Ag
Silver
107.8682
11
Na
Sodium
22.98977
Various ways of identifying
Isotopes
• Using atomic notation,
Example: 12
6 C or simply 12 C
•Using the mass notation.
Example: Carbon-12 or C-12
(read “carbon twelve” or “C twelve”)
Some Isotopes of Carbon
mass
notation
atomic
notation
# of p+ # of e- # of no
C-11 11C 6 6
C-12 12C 6 6
C-13 13C 6 6
C-14 14C 6 6
Another example of isotopes
1
1H 2
1H 3
1H
or
H-1 H-2 H-3
The Isotopes of Hydrogen
mass
notation
atomic
notation
# of p+ # of e- # of no
Hydrogen-1 1H 1 1
Hydrogen-2 2H 1 1
Hydrogen-3 3H 1 1
p+ =
no =
e- =
p+ =
no =
e- =
p+ =
no =
e- =
Figure #1 Figure #2 Figure #3
Isotopes
atoms of a given element that
differ in the number of neutrons
…and consequently in mass.
Why are masses on the periodic
table usually expressed as decimal
numbers?
• masses on the table are weighted
averages of all known isotopes of
the element of interest
Keep in mind:
It is not possible to determine how many
different isotopes exist by looking at the
periodic table.
It is not possible to determine the
frequency of various nuclides by looking
at the periodic table.
The following does not occur in nature!
1
1H occurrence 33.3%
2
1H occurrence 33.3%
3
1H occurrence 33.3%
The following does occur in nature!
1
1H occurrence 99.98%
2
1H occurrence 0.0156%
3
1H occurrence 0.0044%
another way of looking at it:
1
1H occurrence 9,998
2
1H occurrence 1.56
3
1H occurrence 0.44
Imagine having 10,000 H atoms
That means the weighted average is:
1
1H 1 x 0.9998 = 0.9998
2
1H 2 x 0.00156 = 0.00312
3
1H 3 x 0.00004 = 0.00012
Weighted Average (0.9998 + 0.00312 + 0.00012)  1.01
Zn has 5 naturally occurring isotopes
64
30Zn occurrence
66
30Zn occurrence
67
30Zn occurrence
68
30Zn occurrence
70
30Zn occurrence
Zn has 5 naturally occurring isotopes
64
30Zn occurrence 49 %
66
30Zn occurrence ~28 %
67
30Zn occurrence ~4 %
68
30Zn occurrence ~18 %
70
30Zn occurrence ~1 %
Zn has 5 naturally occurring isotopes
64
30Zn 49 %
66
30Zn ~28 %
67
30Zn ~4 %
68
30Zn ~18 %
70
30Zn ~1 %
65.39
(parenthesis) on the
Periodic Table indicate the
most stable isotope
stable means “longest living”
Parenthesis also suggest the element of
interest is radioactive.
Review problem #1
Represent the following using atomic notation.
92
U
Uranium
238.0289
Review problem #2
Represent the following using mass notation.
10
Ne
Neon
20.1797
Review problem #3
If the atom described below had 2 naturally occurring
isotopes, which of the 2 would have a greater
frequency of occurrence? Express your answer in
atomic and mass notation.
3
Li
Lithium
6.941
Review problem #4
How many total subatomic particles are in the following
“neutral” atoms of Fe-55 and Fe-57?
Isotopes.ppt

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Isotopes.ppt

  • 1. Isotopes atoms of a given element that differ in the number of neutrons …and consequently in mass.
  • 2. Working with Atomic Notation A zX Atomic Number Chemical Symbol Atomic Mass (of Isotope)
  • 3. Example #1 12 6C Atomic Number Chemical Symbol Atomic Mass (of Isotope)
  • 4. Example #2 13 6C Atomic Number Chemical Symbol Atomic Mass (of Isotope)
  • 5. Example #3 14 6C Atomic Number Chemical Symbol Atomic Mass (of Isotope)
  • 6. Some isotopes of carbon 12 6C 13 6C 14 6C
  • 8. Various ways of identifying Isotopes • Using atomic notation, Example: 12 6 C or simply 12 C •Using the mass notation. Example: Carbon-12 or C-12 (read “carbon twelve” or “C twelve”)
  • 9. Some Isotopes of Carbon mass notation atomic notation # of p+ # of e- # of no C-11 11C 6 6 C-12 12C 6 6 C-13 13C 6 6 C-14 14C 6 6
  • 10. Another example of isotopes 1 1H 2 1H 3 1H or H-1 H-2 H-3
  • 11. The Isotopes of Hydrogen mass notation atomic notation # of p+ # of e- # of no Hydrogen-1 1H 1 1 Hydrogen-2 2H 1 1 Hydrogen-3 3H 1 1
  • 12. p+ = no = e- = p+ = no = e- = p+ = no = e- = Figure #1 Figure #2 Figure #3
  • 13. Isotopes atoms of a given element that differ in the number of neutrons …and consequently in mass.
  • 14. Why are masses on the periodic table usually expressed as decimal numbers? • masses on the table are weighted averages of all known isotopes of the element of interest
  • 15. Keep in mind: It is not possible to determine how many different isotopes exist by looking at the periodic table. It is not possible to determine the frequency of various nuclides by looking at the periodic table.
  • 16. The following does not occur in nature! 1 1H occurrence 33.3% 2 1H occurrence 33.3% 3 1H occurrence 33.3%
  • 17. The following does occur in nature! 1 1H occurrence 99.98% 2 1H occurrence 0.0156% 3 1H occurrence 0.0044%
  • 18. another way of looking at it: 1 1H occurrence 9,998 2 1H occurrence 1.56 3 1H occurrence 0.44 Imagine having 10,000 H atoms
  • 19. That means the weighted average is: 1 1H 1 x 0.9998 = 0.9998 2 1H 2 x 0.00156 = 0.00312 3 1H 3 x 0.00004 = 0.00012 Weighted Average (0.9998 + 0.00312 + 0.00012)  1.01
  • 20. Zn has 5 naturally occurring isotopes 64 30Zn occurrence 66 30Zn occurrence 67 30Zn occurrence 68 30Zn occurrence 70 30Zn occurrence
  • 21. Zn has 5 naturally occurring isotopes 64 30Zn occurrence 49 % 66 30Zn occurrence ~28 % 67 30Zn occurrence ~4 % 68 30Zn occurrence ~18 % 70 30Zn occurrence ~1 %
  • 22. Zn has 5 naturally occurring isotopes 64 30Zn 49 % 66 30Zn ~28 % 67 30Zn ~4 % 68 30Zn ~18 % 70 30Zn ~1 % 65.39
  • 23. (parenthesis) on the Periodic Table indicate the most stable isotope stable means “longest living” Parenthesis also suggest the element of interest is radioactive.
  • 24. Review problem #1 Represent the following using atomic notation. 92 U Uranium 238.0289
  • 25. Review problem #2 Represent the following using mass notation. 10 Ne Neon 20.1797
  • 26. Review problem #3 If the atom described below had 2 naturally occurring isotopes, which of the 2 would have a greater frequency of occurrence? Express your answer in atomic and mass notation. 3 Li Lithium 6.941
  • 27. Review problem #4 How many total subatomic particles are in the following “neutral” atoms of Fe-55 and Fe-57?