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The Group 14 flip
Why share questions?
• There are many excellent open
educational resources on the
internet.
• These include many videos of
more-or-less traditional university
lecturing.
• These questions have been
provided on a CC-BY basis to
facilitate peer instruction.
Why is the diamond structure found in
multiple group 14 element allotropes
but multiply bonded structures are
exclusive to carbon?
A. Lone pair repulsion
disfavours multiple bonds
and larger atoms disfavour
pi bonding
B. Lone pair repulsion
disfavours multiple bonds
and the diamond structure
results from four equivalent
covalent bonds
C. The inert pair effect means
that two electrons do not
engage in bonding and the
diamond structure results
from two equivalent covalent
bonds
D. Larger atoms disfavour pi
bonding and the diamond
structure results from four
equivalent covalent bonds
Lone
pairrepulsion
disfa...
Lone
pairrepulsion
disfa...
Theinertpaireffectm
ea..
Largeratom
sdisfavourp...
4
3
4
3
Which has the lowest boiling
point?
A. α-quartz
B. silicon
C. silicon
tetrachloride
D. blue asbestos
What sort of gloves do you use to
handle organotin compounds?
A. None
B. Disposable
nitrile
C. Double-dip
natural rubber
(Marigolds)
D. Woollen NoneDisposable
nitrile
Double-dip
naturalrubbe...
W
oollen
0 000
Why does the stability of MCl4
decrease as you go down group 14?
A. 3rd ionisation
energy increases
B. 3rd ionisation
energy decreases
C. Increased size of
p orbitals
D. Decreased size of
p orbitals 3rd
ionisation
energyinc...
3rd
ionisation
energyde...
Increased
size
ofp
orbitals
Decreased
sizeofp
orbitals
0% 0%0%0%

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Group 14 flip diamond structure multiple bonds

  • 2. Why share questions? • There are many excellent open educational resources on the internet. • These include many videos of more-or-less traditional university lecturing. • These questions have been provided on a CC-BY basis to facilitate peer instruction.
  • 3. Why is the diamond structure found in multiple group 14 element allotropes but multiply bonded structures are exclusive to carbon? A. Lone pair repulsion disfavours multiple bonds and larger atoms disfavour pi bonding B. Lone pair repulsion disfavours multiple bonds and the diamond structure results from four equivalent covalent bonds C. The inert pair effect means that two electrons do not engage in bonding and the diamond structure results from two equivalent covalent bonds D. Larger atoms disfavour pi bonding and the diamond structure results from four equivalent covalent bonds Lone pairrepulsion disfa... Lone pairrepulsion disfa... Theinertpaireffectm ea.. Largeratom sdisfavourp... 4 3 4 3
  • 4. Which has the lowest boiling point? A. α-quartz B. silicon C. silicon tetrachloride D. blue asbestos
  • 5. What sort of gloves do you use to handle organotin compounds? A. None B. Disposable nitrile C. Double-dip natural rubber (Marigolds) D. Woollen NoneDisposable nitrile Double-dip naturalrubbe... W oollen 0 000
  • 6. Why does the stability of MCl4 decrease as you go down group 14? A. 3rd ionisation energy increases B. 3rd ionisation energy decreases C. Increased size of p orbitals D. Decreased size of p orbitals 3rd ionisation energyinc... 3rd ionisation energyde... Increased size ofp orbitals Decreased sizeofp orbitals 0% 0%0%0%