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3.Avoid the use and formation of toxic materials.
This principle aims to develop new methodoloigies which will make
use of environment friendly starting materials and also avoid the
formation hazardous or toxic by-products.
4.Design and use of non-toxic chemicals or having
minimum toxicity
Chemicals used for various activities should be non-toxic
but should have the efficacy to function. Many chemical
industries use toxic substances as starting material or
sometimes the starting materials are derived from toxic
substances.
For ex.
5.Minimum use of auxiliary substances
This principle aims to use green solvents such as water, super critical
co2 in place of volatile halogenated organic solvents like
Dichloromethane , chloroform for chemical synthesis.
Some times solvent free synthesis is preferred e.g. Claisen
rearrangement can be earned out in solid phase.
o-Allyl phenol
Allyl phenyl
ether
6.Minimum energy consumption
 To save energy synthetic procedures need to be
modified. By reducing the temperature and pressure to
ambient conditions a large amount of energy can be
saved.
 Biocatalysts such as enzymes are catalysts which can
work at ambient temperature.
7.Use of Renewable sources
 The continuous use of non-renewable source have
depleted them beyond repairs and the future generation
will be deprived of these. This principle promotes the use
of raw materials from renewable sources, wherever
possible.
8.Minimisation of steps
9.Use of catalytic reagents
Catalytic reagents are much effective than
stoichiometric reagents in chemical synthesis.
Use of catalytic reagent reduces the energy required
for a reaction to proceed thereby saving energy. It
also reduces burden on the environment.
 Benzene is starting material for
Adipic acid. Benzene is highly Carciongenic,
being a voc, it pollutes air.
10.Degradation of waste
 At the end of reaction the products
that will be released in the
environment or discarded as wastes
should degrade or break down
rapidly into harmless products i.e.
after they should not remain in the
environment.
Ex. Polymers which degrade
Photochemically can be used as
starting materials for some products.
11.Monitoring the generation of
hazaradous substance
This has following advantages
 100% atom efficiency can be achieved.
 Catalysed reactions are faster and therefore energy is
saved.
 Better yields of products are obtained.
 Maximum selectively can be achieved.
 Maximum utilization of starting materials and
minimum generation of waste. Example of such
reactions showing 100% atom economy.
Major uses of green chemistry
Energy
Global change
Resource depletion
Food supply
Toxics in the environment
conclusion
Green chemistry not a solution to all
ENVIRONMENTAL problems but the most
fundamental approach to prevent POLLUTION
Use of safer substances
 Processes and substances used in chemical industries
should ne selected in s such a way that they can
minimise the occurrence of the chemical accidents,
explosions, fires and hazardous emissions.
 If the chemical process uses gaseous substance,
posssiblity of accidents, including explosion is
relatively higher compared to when using; non volatile
liquids or solids.
 green chemistry with 12 principle
 green chemistry with 12 principle

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green chemistry with 12 principle

  • 1.
  • 2.
  • 3.
  • 4.
  • 5. 3.Avoid the use and formation of toxic materials. This principle aims to develop new methodoloigies which will make use of environment friendly starting materials and also avoid the formation hazardous or toxic by-products.
  • 6. 4.Design and use of non-toxic chemicals or having minimum toxicity Chemicals used for various activities should be non-toxic but should have the efficacy to function. Many chemical industries use toxic substances as starting material or sometimes the starting materials are derived from toxic substances. For ex.
  • 7. 5.Minimum use of auxiliary substances This principle aims to use green solvents such as water, super critical co2 in place of volatile halogenated organic solvents like Dichloromethane , chloroform for chemical synthesis. Some times solvent free synthesis is preferred e.g. Claisen rearrangement can be earned out in solid phase. o-Allyl phenol Allyl phenyl ether
  • 8. 6.Minimum energy consumption  To save energy synthetic procedures need to be modified. By reducing the temperature and pressure to ambient conditions a large amount of energy can be saved.  Biocatalysts such as enzymes are catalysts which can work at ambient temperature.
  • 9. 7.Use of Renewable sources  The continuous use of non-renewable source have depleted them beyond repairs and the future generation will be deprived of these. This principle promotes the use of raw materials from renewable sources, wherever possible.
  • 11. 9.Use of catalytic reagents Catalytic reagents are much effective than stoichiometric reagents in chemical synthesis. Use of catalytic reagent reduces the energy required for a reaction to proceed thereby saving energy. It also reduces burden on the environment.
  • 12.  Benzene is starting material for Adipic acid. Benzene is highly Carciongenic, being a voc, it pollutes air.
  • 13. 10.Degradation of waste  At the end of reaction the products that will be released in the environment or discarded as wastes should degrade or break down rapidly into harmless products i.e. after they should not remain in the environment. Ex. Polymers which degrade Photochemically can be used as starting materials for some products.
  • 14. 11.Monitoring the generation of hazaradous substance
  • 15.
  • 16. This has following advantages  100% atom efficiency can be achieved.  Catalysed reactions are faster and therefore energy is saved.  Better yields of products are obtained.  Maximum selectively can be achieved.  Maximum utilization of starting materials and minimum generation of waste. Example of such reactions showing 100% atom economy.
  • 17.
  • 18. Major uses of green chemistry Energy Global change Resource depletion Food supply Toxics in the environment
  • 19.
  • 20.
  • 21.
  • 22. conclusion Green chemistry not a solution to all ENVIRONMENTAL problems but the most fundamental approach to prevent POLLUTION
  • 23. Use of safer substances  Processes and substances used in chemical industries should ne selected in s such a way that they can minimise the occurrence of the chemical accidents, explosions, fires and hazardous emissions.  If the chemical process uses gaseous substance, posssiblity of accidents, including explosion is relatively higher compared to when using; non volatile liquids or solids.