Glycogen is an important stored form of glucose that is used as an energy source during intense exercise. When glycogen stores are depleted through exercise, athletic performance decreases. The document discusses how adjusting carbohydrate intake before, during, and after exercise can help athletes increase and maintain glycogen levels, improving endurance and performance. Specifically, it recommends that athletes consume high carbohydrate meals before exercise to replenish liver and muscle glycogen, and that they consume carbohydrates during long exercises to avoid depletion. After exercise, consuming carbohydrates helps to optimize glycogen synthesis and replenish stores.