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APPLIED MATHEMATICS IN CHEMICAL ENGG
SEMINAR ON :
SUBMITTED BY
MAHASWARI JOGIA
11/9/2017DSCE,CHEM ENGG DEPT
1
11/9/2017 DSCE,CHEMICAL DEPT 2
CONTENTS:
•INTRODUCTION
•FIRST ORDER DIFFERENTIALS
•TYPES OF 1ST ORDER DIFFERENTIALS
•SECOND ORDER DIFFERENTIALS
•TYPES OF 2ND ORDER DIFFERENTIALS
•REFERENCES
INTRODUCTION:
Equations which are composed of an unknown function and its derivatives are called
differential equations.
Differential equations play a fundamental role in engineering because many physical
phenomena are best formulated mathematically in terms of their rate of change.
When a function involves one dependent variable, the equation is called an ordinary
differential equation (ODE).
A partial differential equation (PDE) involves two or more independent variables.
v
m
c
g
dt
dv

v - dependent variable
t - independent variable
11/9/2017 3DSCE,CHEMICAL DEPT
( , )y f x y 
11/9/2017 4DSCE,CHEMICAL DEPT
FIRST ORDER DIFFERENTIAL EQUATION:
FIRST ORDER LINEAR AND NON LINEAR EQUATION:
•A first order equation includes a first derivative as its highest derivative.
- Linear 1st order ODE:
Where P and Q are functions of x.
11/9/2017 5DSCE,CHEMICAL DEPT
TYPES OF LINEAR DIFFERENTIAL
EQUATION:
1. Separable Variable
2. Homogeneous Equation
3. Exact Equation
4. Linear Equation
11/9/2017 6DSCE,CHEMICAL DEPT
•SEPARABLE VARIABLE:
The first-order differential equation:
Is called separable provided that f(x,y) can be written as the product of a function of x and a
function of y.
Suppose we can write this equation as:
 ,
dy
f x y
dx

11/9/2017 7DSCE,CHEMICAL DEPT
)()( yhxg
dx
dy

We then say we have “separated” the variables. By taking h(y) to the LHS, the equation becomes:
Integrating, we get the solution as:
1
( )
( )
dy g x dx
h y

1
( )
( )
dy g x dx c
h y
  
11/9/2017 8DSCE,CHEMICAL DEPT
OR
EXAMPLE 1.
Consider the DE :
Separating the variables, we get
Integrating we get the solution as:
Where C is an arbitrary constant.
y
dx
dy

dxdy
y

1
kxy ||ln
x
cey or
11/9/2017 9DSCE,CHEMICAL DEPT
HOMOGENEOUS EQUATIONS:
Definition: A function f(x, y) is said to be homogeneous of degree n in x, y if
for all t, x, y
Examples
Is a homogenous degree of 2
A first order Differential equation is called homogeneous if are homogeneous functions
of x and y of the same degree.
),(),( yxfttytxf n

22
2),( yxyxyxf 
0),(),(  dyyxNdxyxM
11/9/2017 10DSCE,CHEMICAL DEPT
WORKING RULE TO SOLVE A HDE:
•Put the given equation in the form
•Check M and N are Homogeneous function of the same degree.
•Let y=zx
•Differentiate y = z x to get
•Put this value of dy/dx into (1) and solve the equation for z by separating the variables.
•Replace z by y/x and simplify.
)1(0),(),(  dyyxNdxyxM
dx
dz
xz
dx
dy

11/9/2017 11DSCE,CHEMICAL DEPT
EXACT DIFFERENTIAL EQUATIONS:
A first order differential equation
is called an exact DE if
The solution is given by:
EXAMPLE:
The DE is exact as it is d (x2+ y2) = 0
Hence the solution is: x2+ y2 = c
0),(),(  dyyxNdxyxM
M N
y x
 

 
   cNdyMdx
0xdx ydy 
11/9/2017 12DSCE,CHEMICAL DEPT
•LINEAR EQUATIONS:
A linear first order equation is an equation that can be expressed in the form:
where a1(x), a0(x), and b(x) depend only on the independent variable x, not on y.
We assume that the function a1(x), a0(x), and b(x) are continuous on an interval and that a1(x)  0
on that interval. Then, on dividing by a1(x), we can rewrite equation (1) in the standard form
where P(x), Q(x) are continuous functions on the interval.
1 0( ) ( ) ( ), (1)
dy
a x a x y b x
dx
 
( ) ( ) (2)
dy
P x y Q x
dx
 
11/9/2017 13DSCE,CHEMICAL DEPT
RULES TO SOLVE A LINEAR DE:
1. Write the equation in the standard form
2. Calculate the IF (x) by the formula
3. Multiply the equation by (x).
4. Integrate the last equation.
( ) ( )
dy
P x y Q x
dx
 
 ( ) exp ( )x P x dx  
11/9/2017 14DSCE,CHEMICAL DEPT
SECOND ORDER LINEAR AND NON LINEAR
DIFFERENTIAL EQUATIONS
A second order differential equation is an equation involving the unknown function y, its
derivatives y' and y” and the variable x:
We will only consider explicit differential equations of the form,
Homogeneous Equations: If g(t) = 0, then the equation above becomes
y″ + p(t) y′ + q(t) y = 0.
It is called a homogeneous equation. Otherwise, the equation is nonhomogeneous (or
inhomogeneous).
0),,,(  yyyxF
),,( yyxfy 
11/9/2017 15DSCE,CHEMICAL DEPT
SECOND ORDER LINEAR HOMOGENEOUS
DIFFERENTIAL EQUATIONS WITH
CONSTANT COEFFICIENTS
For the most part, we will only learn how to solve second order linear equation with constant
coefficients (that is, when p(t) and q(t) are constants). Since a homogeneous equation is easier to
solve compares to its non homogeneous counterpart, we start with second order linear
homogeneous equations that contain constant coefficients only:
a y″ + b y′ + c y = 0.
Where a, b, and c are constants, a ≠ 0.
11/9/2017 16DSCE,CHEMICAL DEPT
THE CHARACTERISTIC POLYNOMIAL
a y″ + b y′ + c y = 0, a ≠ 0. (1)
This polynomial, a r2 + b r + c, is called the characteristic polynomial of the differential equation
(1). The equation a r2 + b r + c = 0 is called the characteristic equation of (1). Each and every
root, sometimes called a characteristic root, r, of the characteristic polynomial gives rise to a
solution y = e rt of (1).
We will take a more detailed look of the 3 possible cases of the solutions thusly found:
1. (When b2 − 4 ac > 0) There are two distinct real roots r1, r2.
2. (When b2 − 4 ac < 0) There are two complex conjugate roots r = λ ± μi.
3. (When b2 − 4 ac = 0) There is one repeated real root r.
11/9/2017 17DSCE,CHEMICAL DEPT
CASE 1: TWO DISTINCT REAL ROOTS
When b2 − 4 ac > 0, the characteristic polynomial have two distinct real roots r1, r2. They give
two distinct solutions and OR
Therefore, a general solution of (*) is
11/9/2017 18DSCE,CHEMICAL DEPT
Example: y″ + 5 y′ + 4 y = 0
The characteristic equation is r2 + 5 r + 4 = (r + 1)(r + 4) = 0, the roots of the polynomial are r =
−1 and −4. The general solution is then
y = C1 e−t + C2 e−4t.
Suppose there are initial conditions y(0) = 1, y′(0) = −7. A unique particular solution can be found
by solving for C1 and C2 using the initial conditions.
First we need to calculate y′ = −C1 e −t − 4C2 e −4t, then apply the initial values:
1 = y(0) = C1 e 0 + C2 e 0 = C1 + C2
−7 = y′(0) = −C1 e 0 − 4C2 e 0 = −C1 − 4C2
The solution is C1 = −1, and C2 = 2 → y = −e −t + 2 e −4t.
11/9/2017 19DSCE,CHEMICAL DEPT
CASE 2 :TWO COMPLEX CONJUGATE ROOTS
When b2 − 4 ac < 0, the characteristic polynomial has two complex roots, which are conjugates,
r1 = λ + μi and r2 = λ − μi (λ, μ are real numbers,μ > 0). As before they give two linearly
independent solutions
Consequently the linear combination will be a general solution. At this juncture
you might have this question: “but aren’t r1 and r2 complex numbers; what would become of the
exponential function with a complex number exponent?” The answer to that question is given by
the Euler’s formula.
11/9/2017 20DSCE,CHEMICAL DEPT
Hence, when r is a complex number λ + μi, the exponential function e rt becomes
CASE 3 ONE REPEATED REAL ROOT
When b2 − 4 ac = 0, the characteristic polynomial has a single repeated real
root, This causes a problem, because unlike the previous two cases the roots of characteristic
polynomial presently only give us one distinct solution y1 = e rt. It is not enough to give us a
general solution. We would need to come up with a second solution, linearly independent with y1,
on our own. How do we find a second solution?
11/9/2017 21DSCE,CHEMICAL DEPT
By the Abel’s Theorem, the fact C ≠ 0 guarantees that y1 and y2 are going to be linearly
independent. Now, we have two expressions for the Wronskian of the same pair of solutions. The
two expressions must be equal:
11/9/2017 22DSCE,CHEMICAL DEPT
This is a first order linear differential equation with y2 as the unknown. Put it into its standard
form and solve by the integrating factor method.
11/9/2017 23DSCE,CHEMICAL DEPT
Any such a function would be a second, linearly independent solution of the differential equation.
We just need one instance of such a function. The only condition for the coefficients in the above
expression is C ≠ 0. Pick, say, C = 1, and C1 = 0 would work nicely.
Therefore, the general solution in the case of a repeated real root r is
11/9/2017 24DSCE,CHEMICAL DEPT
11/9/2017 25DSCE,CHEMICAL DEPT
11/9/2017 DSCE,CHEMICAL DEPT 26
REFERENCES
•advanced engineering mathematics by erwin kreyszig
•engineering mathematics iv by dr. k.s.c
•lecture notes on mathematical methods bymihir sen and joseph m. powers,department of
aerospace and mechanical engineering, university of notre dame
notre dame, indiana 46556-5637,usa
•first and second order linear differential equations,dr. radhakant padhi, asst.
professor,dept. of aerospace engineering,indian institute of science – bangalore
•linear differential equation by nofal umair
11/9/2017 DSCE,CHEMICAL DEPT 27

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formulation of first order linear and nonlinear 2nd order differential equation

  • 1. APPLIED MATHEMATICS IN CHEMICAL ENGG SEMINAR ON : SUBMITTED BY MAHASWARI JOGIA 11/9/2017DSCE,CHEM ENGG DEPT 1
  • 2. 11/9/2017 DSCE,CHEMICAL DEPT 2 CONTENTS: •INTRODUCTION •FIRST ORDER DIFFERENTIALS •TYPES OF 1ST ORDER DIFFERENTIALS •SECOND ORDER DIFFERENTIALS •TYPES OF 2ND ORDER DIFFERENTIALS •REFERENCES
  • 3. INTRODUCTION: Equations which are composed of an unknown function and its derivatives are called differential equations. Differential equations play a fundamental role in engineering because many physical phenomena are best formulated mathematically in terms of their rate of change. When a function involves one dependent variable, the equation is called an ordinary differential equation (ODE). A partial differential equation (PDE) involves two or more independent variables. v m c g dt dv  v - dependent variable t - independent variable 11/9/2017 3DSCE,CHEMICAL DEPT
  • 4. ( , )y f x y  11/9/2017 4DSCE,CHEMICAL DEPT
  • 5. FIRST ORDER DIFFERENTIAL EQUATION: FIRST ORDER LINEAR AND NON LINEAR EQUATION: •A first order equation includes a first derivative as its highest derivative. - Linear 1st order ODE: Where P and Q are functions of x. 11/9/2017 5DSCE,CHEMICAL DEPT
  • 6. TYPES OF LINEAR DIFFERENTIAL EQUATION: 1. Separable Variable 2. Homogeneous Equation 3. Exact Equation 4. Linear Equation 11/9/2017 6DSCE,CHEMICAL DEPT
  • 7. •SEPARABLE VARIABLE: The first-order differential equation: Is called separable provided that f(x,y) can be written as the product of a function of x and a function of y. Suppose we can write this equation as:  , dy f x y dx  11/9/2017 7DSCE,CHEMICAL DEPT
  • 8. )()( yhxg dx dy  We then say we have “separated” the variables. By taking h(y) to the LHS, the equation becomes: Integrating, we get the solution as: 1 ( ) ( ) dy g x dx h y  1 ( ) ( ) dy g x dx c h y    11/9/2017 8DSCE,CHEMICAL DEPT
  • 9. OR EXAMPLE 1. Consider the DE : Separating the variables, we get Integrating we get the solution as: Where C is an arbitrary constant. y dx dy  dxdy y  1 kxy ||ln x cey or 11/9/2017 9DSCE,CHEMICAL DEPT
  • 10. HOMOGENEOUS EQUATIONS: Definition: A function f(x, y) is said to be homogeneous of degree n in x, y if for all t, x, y Examples Is a homogenous degree of 2 A first order Differential equation is called homogeneous if are homogeneous functions of x and y of the same degree. ),(),( yxfttytxf n  22 2),( yxyxyxf  0),(),(  dyyxNdxyxM 11/9/2017 10DSCE,CHEMICAL DEPT
  • 11. WORKING RULE TO SOLVE A HDE: •Put the given equation in the form •Check M and N are Homogeneous function of the same degree. •Let y=zx •Differentiate y = z x to get •Put this value of dy/dx into (1) and solve the equation for z by separating the variables. •Replace z by y/x and simplify. )1(0),(),(  dyyxNdxyxM dx dz xz dx dy  11/9/2017 11DSCE,CHEMICAL DEPT
  • 12. EXACT DIFFERENTIAL EQUATIONS: A first order differential equation is called an exact DE if The solution is given by: EXAMPLE: The DE is exact as it is d (x2+ y2) = 0 Hence the solution is: x2+ y2 = c 0),(),(  dyyxNdxyxM M N y x         cNdyMdx 0xdx ydy  11/9/2017 12DSCE,CHEMICAL DEPT
  • 13. •LINEAR EQUATIONS: A linear first order equation is an equation that can be expressed in the form: where a1(x), a0(x), and b(x) depend only on the independent variable x, not on y. We assume that the function a1(x), a0(x), and b(x) are continuous on an interval and that a1(x)  0 on that interval. Then, on dividing by a1(x), we can rewrite equation (1) in the standard form where P(x), Q(x) are continuous functions on the interval. 1 0( ) ( ) ( ), (1) dy a x a x y b x dx   ( ) ( ) (2) dy P x y Q x dx   11/9/2017 13DSCE,CHEMICAL DEPT
  • 14. RULES TO SOLVE A LINEAR DE: 1. Write the equation in the standard form 2. Calculate the IF (x) by the formula 3. Multiply the equation by (x). 4. Integrate the last equation. ( ) ( ) dy P x y Q x dx    ( ) exp ( )x P x dx   11/9/2017 14DSCE,CHEMICAL DEPT
  • 15. SECOND ORDER LINEAR AND NON LINEAR DIFFERENTIAL EQUATIONS A second order differential equation is an equation involving the unknown function y, its derivatives y' and y” and the variable x: We will only consider explicit differential equations of the form, Homogeneous Equations: If g(t) = 0, then the equation above becomes y″ + p(t) y′ + q(t) y = 0. It is called a homogeneous equation. Otherwise, the equation is nonhomogeneous (or inhomogeneous). 0),,,(  yyyxF ),,( yyxfy  11/9/2017 15DSCE,CHEMICAL DEPT
  • 16. SECOND ORDER LINEAR HOMOGENEOUS DIFFERENTIAL EQUATIONS WITH CONSTANT COEFFICIENTS For the most part, we will only learn how to solve second order linear equation with constant coefficients (that is, when p(t) and q(t) are constants). Since a homogeneous equation is easier to solve compares to its non homogeneous counterpart, we start with second order linear homogeneous equations that contain constant coefficients only: a y″ + b y′ + c y = 0. Where a, b, and c are constants, a ≠ 0. 11/9/2017 16DSCE,CHEMICAL DEPT
  • 17. THE CHARACTERISTIC POLYNOMIAL a y″ + b y′ + c y = 0, a ≠ 0. (1) This polynomial, a r2 + b r + c, is called the characteristic polynomial of the differential equation (1). The equation a r2 + b r + c = 0 is called the characteristic equation of (1). Each and every root, sometimes called a characteristic root, r, of the characteristic polynomial gives rise to a solution y = e rt of (1). We will take a more detailed look of the 3 possible cases of the solutions thusly found: 1. (When b2 − 4 ac > 0) There are two distinct real roots r1, r2. 2. (When b2 − 4 ac < 0) There are two complex conjugate roots r = λ ± μi. 3. (When b2 − 4 ac = 0) There is one repeated real root r. 11/9/2017 17DSCE,CHEMICAL DEPT
  • 18. CASE 1: TWO DISTINCT REAL ROOTS When b2 − 4 ac > 0, the characteristic polynomial have two distinct real roots r1, r2. They give two distinct solutions and OR Therefore, a general solution of (*) is 11/9/2017 18DSCE,CHEMICAL DEPT
  • 19. Example: y″ + 5 y′ + 4 y = 0 The characteristic equation is r2 + 5 r + 4 = (r + 1)(r + 4) = 0, the roots of the polynomial are r = −1 and −4. The general solution is then y = C1 e−t + C2 e−4t. Suppose there are initial conditions y(0) = 1, y′(0) = −7. A unique particular solution can be found by solving for C1 and C2 using the initial conditions. First we need to calculate y′ = −C1 e −t − 4C2 e −4t, then apply the initial values: 1 = y(0) = C1 e 0 + C2 e 0 = C1 + C2 −7 = y′(0) = −C1 e 0 − 4C2 e 0 = −C1 − 4C2 The solution is C1 = −1, and C2 = 2 → y = −e −t + 2 e −4t. 11/9/2017 19DSCE,CHEMICAL DEPT
  • 20. CASE 2 :TWO COMPLEX CONJUGATE ROOTS When b2 − 4 ac < 0, the characteristic polynomial has two complex roots, which are conjugates, r1 = λ + μi and r2 = λ − μi (λ, μ are real numbers,μ > 0). As before they give two linearly independent solutions Consequently the linear combination will be a general solution. At this juncture you might have this question: “but aren’t r1 and r2 complex numbers; what would become of the exponential function with a complex number exponent?” The answer to that question is given by the Euler’s formula. 11/9/2017 20DSCE,CHEMICAL DEPT
  • 21. Hence, when r is a complex number λ + μi, the exponential function e rt becomes CASE 3 ONE REPEATED REAL ROOT When b2 − 4 ac = 0, the characteristic polynomial has a single repeated real root, This causes a problem, because unlike the previous two cases the roots of characteristic polynomial presently only give us one distinct solution y1 = e rt. It is not enough to give us a general solution. We would need to come up with a second solution, linearly independent with y1, on our own. How do we find a second solution? 11/9/2017 21DSCE,CHEMICAL DEPT
  • 22. By the Abel’s Theorem, the fact C ≠ 0 guarantees that y1 and y2 are going to be linearly independent. Now, we have two expressions for the Wronskian of the same pair of solutions. The two expressions must be equal: 11/9/2017 22DSCE,CHEMICAL DEPT
  • 23. This is a first order linear differential equation with y2 as the unknown. Put it into its standard form and solve by the integrating factor method. 11/9/2017 23DSCE,CHEMICAL DEPT
  • 24. Any such a function would be a second, linearly independent solution of the differential equation. We just need one instance of such a function. The only condition for the coefficients in the above expression is C ≠ 0. Pick, say, C = 1, and C1 = 0 would work nicely. Therefore, the general solution in the case of a repeated real root r is 11/9/2017 24DSCE,CHEMICAL DEPT
  • 26. 11/9/2017 DSCE,CHEMICAL DEPT 26 REFERENCES •advanced engineering mathematics by erwin kreyszig •engineering mathematics iv by dr. k.s.c •lecture notes on mathematical methods bymihir sen and joseph m. powers,department of aerospace and mechanical engineering, university of notre dame notre dame, indiana 46556-5637,usa •first and second order linear differential equations,dr. radhakant padhi, asst. professor,dept. of aerospace engineering,indian institute of science – bangalore •linear differential equation by nofal umair