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Thin film Deposition Of Nano Colloidal Prepared By
Laser Ablation On ITO Substrate For
Optoelectronics Applications
‫قواعد‬ ‫على‬ ‫بالليزر‬ ‫محضر‬ ‫نانوي‬ ‫محلول‬ ‫من‬ ‫رقيقه‬ ‫اغشيه‬ ‫ترسيب‬
‫كهروبصريه‬ ‫تطبيقات‬ ‫في‬ ‫واستخدامها‬ ‫االنديوم‬ ‫القصدير‬ ‫اوكسيد‬
by
Ghufran Sattar Jaber
Supervised by
Assist. Prof. Dr. Abdulrahman K. Ali
Assist. Prof. Dr. Mukhlis M. Ismail
Aim of Work
• Fabrication of Dye Sensitized Solar Cell
• Enhance the efficiency by adding gold
nanoparticles
Generations of Solar Cell
• The first a semiconductor PN junction solar
cell such as silicon.
• The second TF-solar cell depend on thin
layers of different semiconductor materials like
amorphous silicon(organic Solar cell).
• The third is based on devices that may exceed
Schockley-Queisser limit like multi-junction
(tandem) solar cell and DSSC.
hν
Electrolyte regeneration
Working Principle of DSSC
Practical
Side
Experimental Work
PLAL
Fabrication Steps of The DSSC
Results
and
Discussions
Size Distributions of AuNPs
0
2
4
6
8
10
12
14
16
18
20
22
10 20 30 40 50 60 70 80 90 100 110
Number
Nanoparticle Diameter (nm)
AuNPs
TiO2-surface
X-Ray Diffractions
Energy Band Gab for DSSC
0
0.5
1
1.5
2
2.5
3
3.5
350 450 550 650 750 850
Abs
λ(nm)
AuNPs
dye only
dye+AuNPs
Sensitized Dye Enhancement
0
0.2
0.4
0.6
0.8
1
1.2
1.4
350 380 410 440 470 500 530 560 590 620
Abs
λ(nm)
only dye
Au.NPs+ dye
Spectroscopy of DSSC
0
2
4
6
8
10
12
14
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
Jsc
(mA/cm2)
V(Volt)
DSSC with AuNPs
DSSC without AuNPs
Electrical Measurement for
Our Lab TiO2-past
0
2
4
6
8
10
12
14
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
J
SC
(mA/cm
2
)
V(Volt)
DSSC with AuNPs
DSSC without AuNPs
Electrical Measurement for
Dyesol TiO2- past
Cell type 𝑉𝑜𝑐
(Volt)
J𝑠𝑐
(𝑚𝐴/m2)
Fill
Factor
Efficiency Enhanced
efficiency
Gcell without
AuNPs(Dyesol)
0.59 5.25 0.359 1.75 60%
GCell with
AuNPs(Dyesol)
0.63 9.25 0.504 2.8
GCell without
AuNPs (our lab)
0.67 4.75 0.359 1.07 87%
Gcell with
AuNPs(our lab)
0.65 12.5 0.258 2.009
0
10
20
30
40
50
60
70
80
90
100
300 500 700 900 1100
IPCE%
λ(nm)
IPCE with AuNPs
IPCE without
AUNPs
IPCE-Measurements
The Responsivity
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
100 300 500 700 900 1100 1300
R(µA/cm)
λ(nm)
DSSC without AuNPs
DSSC with AuNPs
Final –Assembly of DSSC
DSSC-Advantages
Face And Back-Measurements
0
1
2
3
4
5
6
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
J
SC
(mA/cm2)
V(Volt)
DSSC back
DSSC face
DSSC with 2-Faces
Cell type 𝑉𝑜𝑐
(Volt)
J𝑠𝑐
(𝑚𝐴/cm2)
Fill Factor Efficiency
GCell with AuNPs
(face of the cell)
0.65 5.357143 0.3 1.09
GCell with AuNPs
(back of the cell)
0.62 5.714286 0.25 1
Conclusion
• Adding AuNPs to N719-dye having high
absorption peak about twice peak of N719-dye
due the high SPR of gold nanoparticles which
lead to increase the total absorption.
• DSSC have various applications and effective
in aviation and space.
Future work
• Another method can be used to prepare TiO2 such
as electrophortic-deposition.
• Using gel-electrolyte to get good sealing regard a
main problem in DSSC fabrication.
• Using another noble metal(like silver
nanoparticles) with different particle size to
enhance the efficiency of DSSC, also another
preparation method can be used to get difference
nano-shapes such as chemical method.
THANKYOU
forLISTENING

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